Explain how it’s possible to have a heterogeneous mixture and still have only one pure substance

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how is it possible to have a hetero mixture that is usually not unform, actually be uniform 

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Hetrogenecity or Homogeneity in this case has much relation with its physical form.

e.g. A mixture of crystals of Sodium chloride (Salt) and amorphous powder of Sodium chloride (Salt) can be said a heterogeneous mixture of a single pure compound.i.e Sodium chloride

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