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In monocots flower parts are in multiples of three while in dicots flower parts are in multiples of four or five. If you count the number of petals, stamens, or other floral parts, you will find that monocot flowers tend to have a number of parts that is divisible by three, usually three or six. Dicot flowers on the other hand, tend to have parts in multiples of four or five (four, five, ten, etc.). This character is not always reliable, however, and is not easy to use in some flowers with reduced or numerous parts.
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