Unit III BASIC JOB HAZARD ANALYSIS FORM
Directions: List the steps involved in performing the process, and identify the potential hazards
associated with each step.
Steps to Perform the Work
Process
Hazards/Potential Hazards
1.
2.
3.
4.
5.
6.
Prepare a two-page homework assignment summarizing your health hazard analysis and answer these
questions from the Basic Job Hazard Analysis form.
1. What are the health hazards associated with the operation?
2. What are the primary exposure routes associated with each health hazard?
3. Are there any potential acute or chronic health effects for any of the health hazards you
identified?
4. Are there any special hazards associated with any of the health hazards?
You may use the Safety Data Sheets provided, information from the OSHA or NIOSH web sites, or any
academic references from the Internet to answer the questions.
SAFETY DATA SHEET
Revision date 25-Apr-2015
Version 2
Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Code
ALS5N0035
Product Name
EARTH VEIN
Other means of identification
No information available
Recommended use of the chemical and restrictions on use
Paint, Coatings
Details of the supplier of the safety data sheet
See section 16 for more
information
The Valspar Corporation
PO Box 1461
Minneapolis, MN 55440
E-mail address
msds@valspar.com
Emergency telephone number
United States of America 1-888-345-5732
American Samoa, Guam, Northern Mariana Islands, Puerto Rico, U.S. Virgin Islands 1-800-255-3924
Section 2: HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label elements
HAZARD STATEMENTS
Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Product Code ALS5N0035
Page 1 / 8
AGHS - USA OSHA SDS
PREVENTION
Do not handle until all safety precautions have been read and understood.
RESPONSE
Get medical advice/attention if you feel unwell.
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention.
Skin
Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.
Inhalation
IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
Ingestion
Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
STORAGE
Store in a closed container.
DISPOSAL
Dispose of contents/containers in accordance with local regulations.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC)
Not applicable. May form combustible dust concentrations in air.
OTHER HAZARDS
Not applicable.
UNKNOWN ACUTE TOXICITY
0% of the mixture consists of ingredient(s) of unknown toxicity.
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
Carbon black
Titanium dioxide
CAS No
1333-86-4
13463-67-7
weight-%
1-3
0.1 - 0.3
*The exact percentage (concentration) of composition has been withheld as a trade secret.
Section 4: FIRST AID MEASURES
First Aid Measures
General advice
Get medical advice/attention if you feel unwell.
Eye contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention.
Skin Contact
Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.
Inhalation
IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
Ingestion
Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Most important symptoms and effects, both acute and delayed
Symptoms
No information available.
Indication of any immediate medical attention and special treatment needed
Product Code ALS5N0035
Page 2 / 8
AGHS - USA OSHA SDS
Treat symptomatically.
Note to physicians
Section 5: FIRE FIGHTING MEASURES
Suitable extinguishing media
Water spray (fog). Carbon dioxide (CO2). Alcohol resistant foam.
Not to be used for safety reasons:
Inert gas under high pressure (e.g. CO2), water jet
Specific hazards arising from the chemical
Burning produces heavy smoke. Fire may produce irritating and/or toxic gases. In the event of fire and/or explosion do not breathe
fumes.
Special protective equipment for fire-fighters
Wear self-contained breathing apparatus and protective suit. Cool containers with flooding quantities of water until well after fire is
out. Do not allow run-off from fire-fighting to enter drains or water courses.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Remove all sources of ignition. Do not breathe dust.
For emergency responders
Use personal protection recommended in Section 8.
Environmental precautions
Do not allow into any sewer, on the ground or into any body of water. If the product contaminates lakes, rivers or sewage, inform
appropriate authorities in accordance with local regulations.
Methods and material for containment and cleaning up
Methods for containment
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Dispose of waste product or used containers according to local regulations. Do not use a dry brush as dust clouds or static can be
created. Contain and collect spillage with an electrically protected vacuum cleaner or by wet-brushing and place in container for
disposal according to local regulations (see section 13).
Section 7: HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Precautions should be taken to prevent the formation of dusts in concentrations above flammable, explosive or occupational
exposure limits. Operators should wear anti-static footwear and clothing and floors should be of the conducting type. Use personal
protection recommended in Section 8. Comply with the health and safety at work laws. Prevent product from entering drains.
General Hygiene Considerations
Take off all contaminated clothing and wash it before reuse. Wash hands thoroughly after handling.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Keep/store only in original container. Store in accordance with local regulations. Keep unauthorized personnel away. Containers
that have been opened must be carefully resealed and kept upright to prevent leakage.
Incompatible materials
Alcohols. Amines.
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Product Code ALS5N0035
Page 3 / 8
AGHS - USA OSHA SDS
Control parameters
Exposure Limits
If S* appears in the OEL table, it indicates this chemical contains a skin notation.
Chemical Name
Carbon black
1333-86-4
ACGIH TLV
TWA: 3 mg/m3 inhalable fraction
OSHA PEL
TWA: 3.5 mg/m3
Titanium dioxide
13463-67-7
TWA: 10 mg/m3
TWA: 15 mg/m3 total dust
NIOSH IDLH
IDLH: 1750 mg/m3
TWA: 3.5 mg/m3
TWA: 0.1 mg/m3 Carbon black in
presence of Polycyclic aromatic
hydrocarbons PAH
IDLH: 5000 mg/m3
Appropriate engineering controls
Engineering Controls
Ensure adequate ventilation, especially in confined areas. Provide local exhaust ventilation. In case of insufficient ventilation, wear
suitable respiratory equipment. Do not breathe dust.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin and body protection
Wear suitable protective clothing. Care should be taken in the selection of protective clothing to ensure that inflammation and
irritation of the skin at neck and wrists through contact with the powder are avoided.
Hand Protection
There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of
chemicals. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on
breakthrough time for specific gloves. The instructions and information provided by the glove manufacturer on use, storage,
maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the
glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance
or effectiveness of the glove may be reduced by physical / chemical damage and poor maintenance.
Respiratory protection
In case of inadequate ventilation wear respiratory protection.
Thermal Protection
No information available
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state
Appearance
Odor
Color
Odor Threshold
pH value
Melting point/freezing point
Boiling point / boiling range
flash point
evaporation rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit:
Lower flammability limit:
Vapor Pressure
vapor density
Density (lbs per US gallon)
powder
No information available
Odorless
brown
No information available
No information available
No information available
No information available °C / °F
510 °C / 950 °F
No information available
No information available
No information available
No information available
No information available
No information available
10.28
Product Code ALS5N0035
Page 4 / 8
AGHS - USA OSHA SDS
specific gravity
Solubility(ies)
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
1.23
No information available
No information available
No information available
No information available
No information available
No information available
Other information
Section 10: STABILITY AND REACTIVITY
Reactivity
No information available.
Chemical stability
Stable under normal conditions.
Possibility of Hazardous Reactions None under normal processing.
Hazardous polymerization
None under normal processing.
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
Alcohols. Amines.
Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). Aldehydes.
Section 11: TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Eye contact
Not applicable
Skin Contact
Not applicable
Ingestion
Not applicable
Inhalation
Not applicable
Numerical measures of toxicity - Component Information
Chemical Name
Carbon black
1333-86-4
Titanium dioxide
13463-67-7
Oral LD50
-
Dermal LD50
-
Inhalation LC50
-
> 10000 mg/kg ( Rat )
-
-
Numerical measures of toxicity - Product Information
UNKNOWN ACUTE TOXICITY
0% of the mixture consists of ingredient(s) of unknown toxicity.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity
According to IARC, Volume 93, no significant exposure to primary particles of titanium dioxide is thought to occur from use in paints
since the pigment is bound to other materials. According to IARC, Volume 93, no significant exposure to primary particles of carbon
black is thought to occur from use in paints since the pigment is bound to other materials.
ACGIH
NTP
OSHA
Chemical Name
IARC
A3
X
Carbon black
Group 2B
1333-86-4
Product Code ALS5N0035
Page 5 / 8
AGHS - USA OSHA SDS
Titanium dioxide
13463-67-7
X
Group 2B
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen.
IARC (International Agency for Research on Cancer)
Group 2B - Possibly Carcinogenic to Humans.
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present.
Not applicable
Skin corrosion/irritation
Serious eye damage/eye irritation Not applicable
Not applicable
Skin sensitization
Not applicable
Respiratory sensitization
Not applicable
Germ cell mutagenicity
Not applicable
Carcinogenicity
Not applicable
Reproductive Toxicity
Specific target organ toxicity (single Not applicable
exposure)
Not applicable
Specific target organ toxicity
(repeated exposure)
Not applicable
Aspiration hazard
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity
Environmental precautions
Prevent product from entering drains.
Persistence and degradability
No information available
Bioaccumulation
No information available
Mobility
No information available
No information available
Other adverse effects
Section 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging
Improper disposal or reuse of this container may be dangerous and illegal. Empty
containers must be scrapped or reconditioned.
Section 14: TRANSPORT INFORMATION
14.1 UN/ID no
14.2 Proper shipping name
DOT
IMDG
IATA
Not regulated
Not regulated
Not regulated
14.3 Hazard Class
14.4 Packing Group
14.5 Environmental hazard Not applicable
14.6 Special Provisions
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No information available
Section 15: REGULATORY INFORMATION
International Inventories
Product Code ALS5N0035
Page 6 / 8
AGHS - USA OSHA SDS
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL - Canadian Domestic Substances List
US Federal Regulations
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
No
No
No
No
No
US State Regulations
Rule 66 status of product
Not photochemically reactive.
U.S. EPA Label information
EPA Pesticide registration number Not applicable
U.S. State Right-to-Know Regulations
Chemical Name
Proprietary Non-Hazardous Ingredient - Proprietary CAS
.
.
Proprietary Non-Hazardous Ingredient - Proprietary CAS
.
Proprietary Inert
.
Carbon black
1333-86-4
Iron oxide (Fe2O3)
1309-37-1
.
.
Section 16: OTHER INFORMATION
HMIS
Health hazards
Flammability
Physical hazards
Personal Protection
0
1
0
X
Supplier Address
Valspar Coatings
10300 Claude Freeman Dr.
Charlotte, NC 28262
704-548-2820
Valspar Powder Coatings
13129 Harland Dr. NE
Covington, GA 30014
770-784-4140
Prepared By
Product Stewardship
Revision date
Revision Note
25-Apr-2015
No information available
Product Code ALS5N0035
Page 7 / 8
AGHS - USA OSHA SDS
All components are listed or exempt
from listing
Not all components are listed or
exempt from listing
Disclaimer
The information on this Safety Data Sheet (SDS) is based on the present state of our knowledge, current national
legislation and guidelines. As the specific conditions of use of the product are outside the supplier's knowledge and
control the user is responsible for ensuring that the requirements of relevant legislation are complied with. This SDS
should not be construed as any guarantee of the technical performance or suitability for particular applications. UNLESS
SUPPLIER AGREES OTHERWISE IN WRITING, SUPPLIER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND
DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. SUPPLIER WILL NOT BE LIABLE FOR ANY SPECIAL,
INCIDENTAL OR CONSEQUENTIAL DAMAGES.
End of Safety Data Sheet
Product Code ALS5N0035
Page 8 / 8
AGHS - USA OSHA SDS
SAFETY DATA SHEET
Klean Strip Paint Thinner
Page: 1
Printed: 11/17/2015
Revision: 11/16/2015
Supersedes Revision: 06/01/2015
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name:
Company Name:
Klean Strip Paint Thinner
W. M. Barr
2105 Channel Avenue
Memphis, TN 38113
Web site address:
www.wmbarr.com
Emergency Contact:
Information:
3E 24 Hour Emergency Contact
W.M. Barr Customer Service
Phone Number:
(901)775-0100
(800)451-8346
(800)398-3892
Intended Use:
Paint, stain, and varnish thinning.
Product Code:
CKPT94402, GKPT94002B, DKPT94403CA, EKPT94401, GKPT94002, GKPT94002P,
GKPT94002T, GKPT94400, GPT1KS, PA12779, QKPT94003, QKPT94203, QPT1KS,
GKPTDP, EKPT94404
Additional Information
This product is regulated by the United States Consumer Product Safety Commission
and is subject to certain labeling requirements under the Federal Hazardous Substances
Act. These requirements differ from the classification criteria and hazard information
required for safety data sheets (SDS). The product label also includes other important
information, including directions for use, and should always be read in its entirety prior to
using the product.
2. HAZARDS IDENTIFICATION
Flammable Liquids, Category 3
Acute Toxicity: Inhalation, Category 4
Skin Corrosion/Irritation, Category 2
Serious Eye Damage/Eye Irritation, Category 2B
Germ Cell Mutagenicity, Category 1B
Toxic To Reproduction, Category 2
Specific Target Organ Toxicity (single exposure), Category 3
Specific Target Organ Toxicity (repeated exposure), Category 2
Aspiration Toxicity, Category 1
GHS Signal Word:
GHS Hazard Phrases:
Danger
H226: Flammable liquid and vapor.
H304: May be fatal if swallowed and enters airways.
H315: Causes skin irritation.
H320: Causes eye irritation.
H332: Harmful if inhaled.
H336: May cause drowsiness or dizziness.
H340: May cause genetic defects.
H361: Suspected of damaging fertility or the unborn child.
H373: May cause damage to Central Nervous System (CNS) through prolonged or
repeated exposure.
GHS Precaution Phrases:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/lighting equipment.
P242: Use only non-sparking tools.
Licensed to W.M. Barr and Company
GHS format
SAFETY DATA SHEET
Klean Strip Paint Thinner
Page: 2
Printed: 11/17/2015
Revision: 11/16/2015
Supersedes Revision: 06/01/2015
P243: Take precautionary measures against static discharge.
P260: Do not breathe gas/mist/vapors/spray.
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P281: Use personal protective equipment as required.
P235: Keep cool.
GHS Response Phrases:
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated
clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical attention/advice.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical attention/advice if you feel unwell.
P321: Specific treatment see label.
P331: Do NOT induce vomiting.
P332+313: If skin irritation occurs, get medical advice/attention.
P337+313: If eye irritation persists, get medical advice/attention.
P362: Take off contaminated clothing and wash before re-use.
P370+378: In case of fire, use dry chemical powder to extinguish.
GHS Storage and Disposal
Phrases:
P403+233: Store container tightly closed in well-ventilated place.
P405: Store locked up.
P501: Dispose of contents/container according to local, state and federal regulations.
Hazard Rating System:
*
HEALTH
FLAMMABILITY
PHYSICAL
PPE
1
2
0
Flammability
Instability
2
Health
1
0
HMIS:
OSHA Regulatory Status:
Special Hazard
NFPA:
This material is classified as hazardous under OSHA regulations.
Potential Health Effects
(Acute and Chronic):
Inhalation Acute Exposure Effects:
May cause dizziness; headache; watering of eyes; eye irritation; weakness; nausea;
muscle twitches, and depression of central nervous system. Severe overexposure may
cause convulsions; unconsciousness; and death. Intentional misuse of this product by
deliberately concentrating and inhaling can be harmful or fatal.
Skin Contact Acute Exposure Effects:
May cause irritation; numbness in the fingers and arms; drying of skin; and dermatitis.
May cause increased severity of symptoms listed under inhalation.
Eye Contact Acute Exposure Effects:
This material is an eye irritant. May cause irritation; burns; conjunctivitis of eyes; and
corneal ulcerations of the eye. Vapors may irritate eyes.
Ingestion Acute Exposure Effects:
Harmful or fatal if swallowed. May cause nausea; weakness; muscle twitches;
gastrointestinal irritation; and diarrhea. Severe overexposure may cause convulsions;
unconsciousness; and death.
Licensed to W.M. Barr and Company
GHS format
SAFETY DATA SHEET
Klean Strip Paint Thinner
Page: 3
Printed: 11/17/2015
Revision: 11/16/2015
Supersedes Revision: 06/01/2015
Chronic Exposure Effects:
Reports have associated repeated and prolonged overexposure to solvents with
neurological and other physiological damage. Prolonged or repeated contact may cause
dermatitis. May cause jaundice; bone marrow damage; liver damage; anemia; and skin
irritation.
Medical Conditions Generally Diseases of the skin, eyes, liver, kidneys, central nervous system and respiratory
system.
Aggravated By Exposure:
3. COMPOSITION/INFORMATION ON INGREDIENTS
CAS #
Hazardous Components (Chemical Name)
Concentration
8052-41-3
Stoddard solvent {Mineral spirits; Aliphatic
Petroleum Distillates; White spirits}
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