Unit III BASIC JOB HAZARD ANALYSIS FORM Directions: List the steps involved in performing the process, and identify the potential hazards associated with each step. Steps to Perform the Work Process Hazards/Potential Hazards 1. 2. 3. 4. 5. 6. Prepare a two-page homework assignment summarizing your health hazard analysis and answer these questions from the Basic Job Hazard Analysis form. 1. What are the health hazards associated with the operation? 2. What are the primary exposure routes associated with each health hazard? 3. Are there any potential acute or chronic health effects for any of the health hazards you identified? 4. Are there any special hazards associated with any of the health hazards? You may use the Safety Data Sheets provided, information from the OSHA or NIOSH web sites, or any academic references from the Internet to answer the questions. SAFETY DATA SHEET Revision date 25-Apr-2015 Version 2 Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Product Code ALS5N0035 Product Name EARTH VEIN Other means of identification No information available Recommended use of the chemical and restrictions on use Paint, Coatings Details of the supplier of the safety data sheet See section 16 for more information The Valspar Corporation PO Box 1461 Minneapolis, MN 55440 E-mail address msds@valspar.com Emergency telephone number United States of America 1-888-345-5732 American Samoa, Guam, Northern Mariana Islands, Puerto Rico, U.S. Virgin Islands 1-800-255-3924 Section 2: HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label elements HAZARD STATEMENTS Not a dangerous substance or mixture according to the Globally Harmonized System (GHS) Product Code ALS5N0035 Page 1 / 8 AGHS - USA OSHA SDS PREVENTION Do not handle until all safety precautions have been read and understood. RESPONSE Get medical advice/attention if you feel unwell. Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Inhalation IF INHALED: Call a POISON CENTER or doctor if you feel unwell. Ingestion Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. STORAGE Store in a closed container. DISPOSAL Dispose of contents/containers in accordance with local regulations. HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) Not applicable. May form combustible dust concentrations in air. OTHER HAZARDS Not applicable. UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity. Section 3: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Carbon black Titanium dioxide CAS No 1333-86-4 13463-67-7 weight-% 1-3 0.1 - 0.3 *The exact percentage (concentration) of composition has been withheld as a trade secret. Section 4: FIRST AID MEASURES First Aid Measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Contact Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Inhalation IF INHALED: Call a POISON CENTER or doctor if you feel unwell. Ingestion Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Product Code ALS5N0035 Page 2 / 8 AGHS - USA OSHA SDS Treat symptomatically. Note to physicians Section 5: FIRE FIGHTING MEASURES Suitable extinguishing media Water spray (fog). Carbon dioxide (CO2). Alcohol resistant foam. Not to be used for safety reasons: Inert gas under high pressure (e.g. CO2), water jet Specific hazards arising from the chemical Burning produces heavy smoke. Fire may produce irritating and/or toxic gases. In the event of fire and/or explosion do not breathe fumes. Special protective equipment for fire-fighters Wear self-contained breathing apparatus and protective suit. Cool containers with flooding quantities of water until well after fire is out. Do not allow run-off from fire-fighting to enter drains or water courses. Section 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Remove all sources of ignition. Do not breathe dust. For emergency responders Use personal protection recommended in Section 8. Environmental precautions Do not allow into any sewer, on the ground or into any body of water. If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Dispose of waste product or used containers according to local regulations. Do not use a dry brush as dust clouds or static can be created. Contain and collect spillage with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Section 7: HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Precautions should be taken to prevent the formation of dusts in concentrations above flammable, explosive or occupational exposure limits. Operators should wear anti-static footwear and clothing and floors should be of the conducting type. Use personal protection recommended in Section 8. Comply with the health and safety at work laws. Prevent product from entering drains. General Hygiene Considerations Take off all contaminated clothing and wash it before reuse. Wash hands thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Conditions Keep/store only in original container. Store in accordance with local regulations. Keep unauthorized personnel away. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Incompatible materials Alcohols. Amines. Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Product Code ALS5N0035 Page 3 / 8 AGHS - USA OSHA SDS Control parameters Exposure Limits If S* appears in the OEL table, it indicates this chemical contains a skin notation. Chemical Name Carbon black 1333-86-4 ACGIH TLV TWA: 3 mg/m3 inhalable fraction OSHA PEL TWA: 3.5 mg/m3 Titanium dioxide 13463-67-7 TWA: 10 mg/m3 TWA: 15 mg/m3 total dust NIOSH IDLH IDLH: 1750 mg/m3 TWA: 3.5 mg/m3 TWA: 0.1 mg/m3 Carbon black in presence of Polycyclic aromatic hydrocarbons PAH IDLH: 5000 mg/m3 Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Provide local exhaust ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Do not breathe dust. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear suitable protective clothing. Care should be taken in the selection of protective clothing to ensure that inflammation and irritation of the skin at neck and wrists through contact with the powder are avoided. Hand Protection There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of chemicals. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on breakthrough time for specific gloves. The instructions and information provided by the glove manufacturer on use, storage, maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance or effectiveness of the glove may be reduced by physical / chemical damage and poor maintenance. Respiratory protection In case of inadequate ventilation wear respiratory protection. Thermal Protection No information available Section 9: PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Appearance Odor Color Odor Threshold pH value Melting point/freezing point Boiling point / boiling range flash point evaporation rate Flammability (solid, gas) Flammability Limit in Air Upper flammability limit: Lower flammability limit: Vapor Pressure vapor density Density (lbs per US gallon) powder No information available Odorless brown No information available No information available No information available No information available °C / °F 510 °C / 950 °F No information available No information available No information available No information available No information available No information available 10.28 Product Code ALS5N0035 Page 4 / 8 AGHS - USA OSHA SDS specific gravity Solubility(ies) Partition coefficient Autoignition temperature Decomposition temperature Kinematic viscosity Dynamic viscosity 1.23 No information available No information available No information available No information available No information available No information available Other information Section 10: STABILITY AND REACTIVITY Reactivity No information available. Chemical stability Stable under normal conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Alcohols. Amines. Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). Aldehydes. Section 11: TOXICOLOGICAL INFORMATION Information on likely routes of exposure Eye contact Not applicable Skin Contact Not applicable Ingestion Not applicable Inhalation Not applicable Numerical measures of toxicity - Component Information Chemical Name Carbon black 1333-86-4 Titanium dioxide 13463-67-7 Oral LD50 - Dermal LD50 - Inhalation LC50 - > 10000 mg/kg ( Rat ) - - Numerical measures of toxicity - Product Information UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity According to IARC, Volume 93, no significant exposure to primary particles of titanium dioxide is thought to occur from use in paints since the pigment is bound to other materials. According to IARC, Volume 93, no significant exposure to primary particles of carbon black is thought to occur from use in paints since the pigment is bound to other materials. ACGIH NTP OSHA Chemical Name IARC A3 X Carbon black Group 2B 1333-86-4 Product Code ALS5N0035 Page 5 / 8 AGHS - USA OSHA SDS Titanium dioxide 13463-67-7 X Group 2B ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen. IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans. OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present. Not applicable Skin corrosion/irritation Serious eye damage/eye irritation Not applicable Not applicable Skin sensitization Not applicable Respiratory sensitization Not applicable Germ cell mutagenicity Not applicable Carcinogenicity Not applicable Reproductive Toxicity Specific target organ toxicity (single Not applicable exposure) Not applicable Specific target organ toxicity (repeated exposure) Not applicable Aspiration hazard Section 12: ECOLOGICAL INFORMATION Ecotoxicity Environmental precautions Prevent product from entering drains. Persistence and degradability No information available Bioaccumulation No information available Mobility No information available No information available Other adverse effects Section 13: DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal. Empty containers must be scrapped or reconditioned. Section 14: TRANSPORT INFORMATION 14.1 UN/ID no 14.2 Proper shipping name DOT IMDG IATA Not regulated Not regulated Not regulated 14.3 Hazard Class 14.4 Packing Group 14.5 Environmental hazard Not applicable 14.6 Special Provisions 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available Section 15: REGULATORY INFORMATION International Inventories Product Code ALS5N0035 Page 6 / 8 AGHS - USA OSHA SDS TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL - Canadian Domestic Substances List US Federal Regulations SARA 311/312 Hazard Categories Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard No No No No No US State Regulations Rule 66 status of product Not photochemically reactive. U.S. EPA Label information EPA Pesticide registration number Not applicable U.S. State Right-to-Know Regulations Chemical Name Proprietary Non-Hazardous Ingredient - Proprietary CAS . . Proprietary Non-Hazardous Ingredient - Proprietary CAS . Proprietary Inert . Carbon black 1333-86-4 Iron oxide (Fe2O3) 1309-37-1 . . Section 16: OTHER INFORMATION HMIS Health hazards Flammability Physical hazards Personal Protection 0 1 0 X Supplier Address Valspar Coatings 10300 Claude Freeman Dr. Charlotte, NC 28262 704-548-2820 Valspar Powder Coatings 13129 Harland Dr. NE Covington, GA 30014 770-784-4140 Prepared By Product Stewardship Revision date Revision Note 25-Apr-2015 No information available Product Code ALS5N0035 Page 7 / 8 AGHS - USA OSHA SDS All components are listed or exempt from listing Not all components are listed or exempt from listing Disclaimer The information on this Safety Data Sheet (SDS) is based on the present state of our knowledge, current national legislation and guidelines. As the specific conditions of use of the product are outside the supplier's knowledge and control the user is responsible for ensuring that the requirements of relevant legislation are complied with. This SDS should not be construed as any guarantee of the technical performance or suitability for particular applications. UNLESS SUPPLIER AGREES OTHERWISE IN WRITING, SUPPLIER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. SUPPLIER WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. End of Safety Data Sheet Product Code ALS5N0035 Page 8 / 8 AGHS - USA OSHA SDS SAFETY DATA SHEET Klean Strip Paint Thinner Page: 1 Printed: 11/17/2015 Revision: 11/16/2015 Supersedes Revision: 06/01/2015 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: Company Name: Klean Strip Paint Thinner W. M. Barr 2105 Channel Avenue Memphis, TN 38113 Web site address: www.wmbarr.com Emergency Contact: Information: 3E 24 Hour Emergency Contact W.M. Barr Customer Service Phone Number: (901)775-0100 (800)451-8346 (800)398-3892 Intended Use: Paint, stain, and varnish thinning. Product Code: CKPT94402, GKPT94002B, DKPT94403CA, EKPT94401, GKPT94002, GKPT94002P, GKPT94002T, GKPT94400, GPT1KS, PA12779, QKPT94003, QKPT94203, QPT1KS, GKPTDP, EKPT94404 Additional Information This product is regulated by the United States Consumer Product Safety Commission and is subject to certain labeling requirements under the Federal Hazardous Substances Act. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS). The product label also includes other important information, including directions for use, and should always be read in its entirety prior to using the product. 2. HAZARDS IDENTIFICATION Flammable Liquids, Category 3 Acute Toxicity: Inhalation, Category 4 Skin Corrosion/Irritation, Category 2 Serious Eye Damage/Eye Irritation, Category 2B Germ Cell Mutagenicity, Category 1B Toxic To Reproduction, Category 2 Specific Target Organ Toxicity (single exposure), Category 3 Specific Target Organ Toxicity (repeated exposure), Category 2 Aspiration Toxicity, Category 1 GHS Signal Word: GHS Hazard Phrases: Danger H226: Flammable liquid and vapor. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H320: Causes eye irritation. H332: Harmful if inhaled. H336: May cause drowsiness or dizziness. H340: May cause genetic defects. H361: Suspected of damaging fertility or the unborn child. H373: May cause damage to Central Nervous System (CNS) through prolonged or repeated exposure. GHS Precaution Phrases: P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P242: Use only non-sparking tools. Licensed to W.M. Barr and Company GHS format SAFETY DATA SHEET Klean Strip Paint Thinner Page: 2 Printed: 11/17/2015 Revision: 11/16/2015 Supersedes Revision: 06/01/2015 P243: Take precautionary measures against static discharge. P260: Do not breathe gas/mist/vapors/spray. P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves/protective clothing/eye protection/face protection. P281: Use personal protective equipment as required. P235: Keep cool. GHS Response Phrases: P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+352: IF ON SKIN: Wash with plenty of soap and water. P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+313: IF exposed or concerned: Get medical attention/advice. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P314: Get medical attention/advice if you feel unwell. P321: Specific treatment see label. P331: Do NOT induce vomiting. P332+313: If skin irritation occurs, get medical advice/attention. P337+313: If eye irritation persists, get medical advice/attention. P362: Take off contaminated clothing and wash before re-use. P370+378: In case of fire, use dry chemical powder to extinguish. GHS Storage and Disposal Phrases: P403+233: Store container tightly closed in well-ventilated place. P405: Store locked up. P501: Dispose of contents/container according to local, state and federal regulations. Hazard Rating System: * HEALTH FLAMMABILITY PHYSICAL PPE 1 2 0 Flammability Instability 2 Health 1 0 HMIS: OSHA Regulatory Status: Special Hazard NFPA: This material is classified as hazardous under OSHA regulations. Potential Health Effects (Acute and Chronic): Inhalation Acute Exposure Effects: May cause dizziness; headache; watering of eyes; eye irritation; weakness; nausea; muscle twitches, and depression of central nervous system. Severe overexposure may cause convulsions; unconsciousness; and death. Intentional misuse of this product by deliberately concentrating and inhaling can be harmful or fatal. Skin Contact Acute Exposure Effects: May cause irritation; numbness in the fingers and arms; drying of skin; and dermatitis. May cause increased severity of symptoms listed under inhalation. Eye Contact Acute Exposure Effects: This material is an eye irritant. May cause irritation; burns; conjunctivitis of eyes; and corneal ulcerations of the eye. Vapors may irritate eyes. Ingestion Acute Exposure Effects: Harmful or fatal if swallowed. May cause nausea; weakness; muscle twitches; gastrointestinal irritation; and diarrhea. Severe overexposure may cause convulsions; unconsciousness; and death. Licensed to W.M. Barr and Company GHS format SAFETY DATA SHEET Klean Strip Paint Thinner Page: 3 Printed: 11/17/2015 Revision: 11/16/2015 Supersedes Revision: 06/01/2015 Chronic Exposure Effects: Reports have associated repeated and prolonged overexposure to solvents with neurological and other physiological damage. Prolonged or repeated contact may cause dermatitis. May cause jaundice; bone marrow damage; liver damage; anemia; and skin irritation. Medical Conditions Generally Diseases of the skin, eyes, liver, kidneys, central nervous system and respiratory system. Aggravated By Exposure: 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS # Hazardous Components (Chemical Name) Concentration 8052-41-3 Stoddard solvent {Mineral spirits; Aliphatic Petroleum Distillates; White spirits}
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