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Predict the structures of compounds (I) through (VI) and write the curved arrow mechanisms to justify their formation from their precursors. Write each mechanism on a separate sheet of paper.
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Prep: Predict the structures of compounds (1) through (VI)
and write the curved arrow mechanisms to justify their
formation from their precursors. Write each mechanism on a
separate sheet of paper.
(xs)
II
SOCI2
Br
Mg
I
1. CO2
anhydrous 2. H30+
ether
CH2OH (excess)
conc. H2SO4 (catalytic)
heat
1. CH3MgBr (2 eq.) in
anhydrous ether
2. H2O
1. LiAlH4 in
anhydrous ether
2. H30+
X = No mech
V
CH3OH (excess) PCC in
conc. H2SO4 (catalytic) dichloromethane
heat, Dean-Stark Trap
No mech
IV
VI
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