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I need someone who can complete this practice exam and provide answers so I can make sure I am doing these problems correctly before my test.
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1. Arrange the following substances in the expected order of increasing boiling pt and give
the types of intermolecular forces in each. H2O, NH3, CH4, CH3CH3. (5pts)
2. Using figure 10.10 from your book, calculate the entropy change of vaporization of
water. (15pts)
3. At 25 °C and 2.00 atm, the solubility of CO2(g) in water is 0.0678 M. When air at 1 atm
and 25 °C is in equilibrium with water, Use Henry’s law to get the concentration of
dissolved CO2? The partial pressure of CO2 in air is approximately 4.0 x 10-4 atm.
(10pts)
1
4. The vapor pressure of benzene (C6H6) at 25°C is 95.1 mm Hg. What is the vapor
pressure of benzene above a solution in which 5.05 g of benzoic acid, C6H5COOH, is
dissolved in 245 g C6H6? Use Raoult’s law. (10pts)
5. Draw a picture showing hydrogen bonding between several molecules of water (2D is ok
here) (2pts)
6. What is the normal boiling pt in °C of ethanol if a solution prepared by dissolving 13.0 g
NaCl in 285 g of ethyl alcohol has a boiling pt of 79.1 °C? Assume complete
dissociation of NaCl. The Kb for ethanol is 1.22 (°C kg)/mol. (10pts)
2
7. The experimental dipole moment of BrCl is 0.518 D and the distance between atoms is
213.9 pm. What is the percent ionic character of the BrCl bond? (μ = Q x r) 1D = 3.336
x 10-30 Cm (5pts)
8. Ethyl alcohol, CH3CH2OH is miscible with water but 1-heptanol
CH3CH2CH2CH2CH2CH2CH2OH is only slightly miscible in water. Explain. (3pts)
9. Give the name of the packing, the name of the unit cell, and the number of atoms in the
unit cell for each of the following packing structures/unit cell diagrams. (9 pts)
(a)
3
(b)
(c)
10. Oxygen has a triple point at 54.3 K and 1.14 mm Hg and a critical point at 154.6 K and
49.77 atm. The density of the liquid is 1.14 g/cm3 and the density of the solid is 1.33
Pressure (atm)
g/cm3. Sketch a phase diagram labeling all points of interest (not to scale). (10pts)
Temperature (K)
11. At 500 K, the vapor pressure of Hg is 39.3 mm Hg. Use the Clausius-Clapeyron
equation to find the temperature at which the vapor pressure of mercury is 114.4 mm
Hg.
ΔHvap = 59.229 kJ/mol for Hg (10pts)
4
12. Express the following aqueous concentrations in the unit indicated: (6pts)
a. 0.0025 g KI/L water as ppm of KI
b. 0.0035% NaCl by mass as ppb NaCl
c. 2.40 ppm F-, as molarity of fluoride ion.
13. How many mL of ethanol, CH3CH2OH (d = 0.789 g/mL), must be mixed with 125 mL of
benzene, C6H6 (d = 0.879 g/mL) in order to produce a solution that is 0.0654 m ethanol?
(15 pts)
5
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Organic Chemistry lab; One Slide Research like poster on PowerPoint; subject is Synthesis of Acetaminophen
You are going to make a one slide research like poster on Synthesis of Acetaminophen. Follow instructions attached below. ...
Organic Chemistry lab; One Slide Research like poster on PowerPoint; subject is Synthesis of Acetaminophen
You are going to make a one slide research like poster on Synthesis of Acetaminophen. Follow instructions attached below. Experimental Methods- Synthesis of AcetaminophenThe reaction: In the fume hood, prepare a hot water bath in the fume hood using a stainless steel bowl, thermometer and hotplate. Heat the water in the bath to approximately 90°C -100°C.Attach a clamp to the vertical lattice support above the water bath to secure an Erlenmeyer flask. Set up a vacuum filtration apparatus on the other side of the fume hood using the red vacuum tubing, not the clear condenser tubing. Make sure to secure the filter flask to a vertical lattice support using a clamp. Also, remember to pre-weigh the filter paper that will be used.In a 50 mL Erlenmeyer flask, add ~ 3 g of 4-aminophenol, 8 mL of DI water, 3.5 mL of acetic anhydride, and a stir bar.Record the exact mass of 4-aminophenol as you'll need it when calculating the theoretical yield. Heat the Erlenmeyer flask containing the reaction mixture in the hot water bath for 5 minutes with gently stirring.Make sure to secure the Erlenmeyer flask using the clamp previously set up.Once 5 minutes as elapsed, remove the flask from the bath and place on the fume hood bench top. Allow the flask to cool to room temperature.While the reaction mixture flask is cooling, dump out the water bath and prepare an ice bath in the stainless steel bowl.Once cooled to room temperature, place the Erlenmeyer flask in the ice bath to force the product to crash out as a solid.Collecting the crude product:Using the vacuum filtration apparatus already assembled, vacuum filter the crude product making sure to wet the filter paper with DI water before beginning the filtration.A few small portions of cold water (~1-3 mL) may be utilized to aid in the transfer of the product from the Erlenmeyer to the Buchner funnel. Allow the crude product to air dry on the vacuum for 5 minutes.Once dried, mass the amount of crude product obtained and set aside a small amount of crude product for melting point analysis later.Recrystallization: Transfer the weighed crude product into a 50 mL Erlenmeyer flask (clean and dry the flask used in the initial reaction)Recrystallize the crude product using hot 50% methanol in water as the recrystallization solvent (the recrystallization solvent has already been prepared and can be found in the reagent fume hood).Use a plastic transfer pipette to transfer only enough hot recrystallization solvent to completely dissolve the crude product while the solvent is still hot.Add the solvent in small portions, one plastic transfer pipet at a time.This process should proceed quickly, as to not allow the solvent to cool.Approximately 3 mL of solvent will recrystallize 1 g of crude acetaminophen. Use this as a rough guide not a rule that is written in stone.Once dissolved, allow the solution to slowly cool down to room temperature by placing the Erlenmeyer on the fume hood bench top. Once cooled to room temperature, place the Erlenmeyer in an ice bath to maximize crystallization.Vacuum filter the recrystallized product making sure to wet the filter paper with DI water before beginning the filtration.A few small portions of cold water (~ 1-3 mL) may be utilized to aid in the transfer of the product from the Erlenmeyer to the Buchner funnel.Wash the filtered crystals with approximately two 3 mL portions of cold DI water.Allow the product to air dry on the vacuum for 15 minutes.It may be necessary to break up any chunks using a spatula but take care not to tear the underlying filter paper.Collecting the recrystallized product:Vacuum filter the recrystallized product making sure to wet the filter paper with DI water before beginning the filtration.A few small portions of cold water (~ 1-3 mL) may be utilized to aid in the transfer of the product from the Erlenmeyer to the Buchner funnel.Wash the filtered crystals with approximately two 3 mL portions of cold DI water.Allow the product to air dry on the vacuum for 15 minutes.It may be necessary to break up any chunks using a spatula but take care not to tear the underlying filter paper.Monitoring the progress of the reaction by TLC:Obtain a 15 mL plastic centrifuge tube, place 1-2 crystals of the recrystallized product in the tube and using acetone dilute the sample until the meniscus reaches the 2 mL mark on the tube.This can be done as soon as needed, do not wait for the recrystallized product to fully dry as this will not affect the TLC results.If this solution is too concentrated, the spot will streak on the TLC plate giving no discernable Rf.If this solution is too dilute, the spot will not be visible on the plate.Prepare a TLC plate, making 3 spot marks on the line-of-origin for the following:Standard product spot (already prepared at TLC spotting station)Standard starting material spot (already prepared at TLC spotting station)Recrystallized product spot.Spot each sample on the TLC plate remembering to visualize the spots using the UV lamp between each spot.Do not over spot the samples.Prepare the TLC solvent system using a 10 mL graduated cylinder. Dispense ethyl acetate to the 10 mL mark and then add 2 drops of conc. ammonium hydroxide. Transfer this to the TLC development chamber and completely mix the solvent system by swirling the solution in the beaker.Be very careful as to not directly have your face directly over the conc. ammonium hydroxide.Develop the TLC plate approximately 50 % -75 % up the plate, immediately mark the solvent front and visualize using the UV lamp. Sketch the TLC results in the lab notebook. Calculate the Rf for each component visible in the recrystallized product spot.Characterization:Once the recrystallized product has dried, weigh out the solid and calculate the percent yield for the reaction. Observe and record the melting point range for the crude and recrystallized product.Waste Disposal:All accumulated waste from the experiment must be disposed of as follows:Solids: Solid waste in reagent fume hood.Aqueous filtrate: Acid waste.Recrystallization solvent: non-halogenated.TLC development solution: non-halogenated.Melting point capillary tubes: glass disposal box.Draw the mechanism on https://chemdrawdirect.perkinelmer.cloud/js/sample... Data: You may choose how you wish to represent your data within the poster. Keep in mind that it is a visual representation, i.e. tables are better than text, when possible. etc.Make a one slide power point and convert it to a poster by clicking on design, slide size, a page set up window will pop up, click Custom for the slide sized for, and put the width 48 inches, and the height 36 inches. Let the zoom size 32% not 100%. The font has to be 34 Times New Roman. Experimental methods section is based on the experiment’s data conclusión. I Attached: 1)Follow instructions for Posters by reading the Poster Info attached carefully. USE ACS STYLE FOR REFERENCES THIS IS EXTREMELY IMPORTANT2) an experiment overview too of Synthesis of Acetaminophen 2) Calculating % yield; read it carefully if you don't know how to do it. 3) Couple of examples of previous students submissions, follow them throughly. DO NOT PLAGIARIZE. 4) The rubic for the experiment, make sure you read it carefully.
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NURS 300B SMSU Social Insurance and Public Assistance Discussion
Isabella is a 4-year-old girl who showed signs of a viral illness that did not seem to get better for 2 days. Her mother, ...
NURS 300B SMSU Social Insurance and Public Assistance Discussion
Isabella is a 4-year-old girl who showed signs of a viral illness that did not seem to get better for 2 days. Her mother, Sonia Ramirez, took her to a local walk-in clinic, where she was reassured that Isabella had a bad cold but would recover within a few days. She was given a teaching sheet about viral illnesses that, after getting home, she realized she could not understand. The next day, however, Isabella was barely responsive and had numerous dark purple spots. Her mother rushed her to a local emergency room. Isabella was intubated and airlifted via helicopter to a major medical center, where she was diagnosed with meningococcemia, a life-threatening infection.undefinedIsabella subsequently had bilateral amputations of her legs for gangrene secondary to poor perfusion. After a long hospitalization, she was transferred to a rehabilitation facility where she was fitted with prosthetic legs. Sonia quit her job to stay with Isabella throughout her illness and recovery. When Sonia quit her job, her insurance benefits ended, and she could not afford to pay for continuing insurance coverage.undefinedDiscuss all of the questions below: Isabella's health care bills were enormous. What is the role of private insurance in paying these bills? What is the role of public assistance?What is the role of the nurse in containing these costs? Do you feel that health literacy played a role in the patient’s outcome? If so, how?Do you think Sonia should have continued working through Isabella's illness in order to continue insurance coverage?Would you feel differently about who is accountable for paying the bills for caring for this patient if the patient had been a morbidly obese adult who lived with unhealthy eating and exercise habits?Is this a display of incivility?If so, what are some possible destructive consequences of this incivility, including the financial implications for the patient and rehabilitation facility?How could each of the following nursing roles advocate for Isabella: educator, manager, researcher, activist?How could the contemporary care delivery model of patient-centered care, used by an interdisciplinary team, effect the care and outcomes for Isabella?What is the RN’s role on that team?Discuss these questions as well:You are a nurse working in this rehabilitation facility. You have a peer in this facility who disagrees with your feelings about Isabella’s current employment decisions. This peers make derogatory, demeaning statements about your feelings for this situation.
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What was the runoff from precipitation on the property for areas with vegetation and roofed or paved
Field Study ReportQ 1.
What was the runoff from precipitation on the property for areas with vegetation and roofed or ...
What was the runoff from precipitation on the property for areas with vegetation and roofed or paved
Field Study ReportQ 1.
What was the runoff from precipitation on the property for areas with vegetation and roofed or paved areas over the past four months? What percent of total precipitation ran off of the property? Include data tables in your answer. Would you expect this percentage to be the same for the properties of other students in the class? Why or why not? What factors decide the percentage of runoff? Q 2.
Which way will runoff water flow from your property? Where will the runoff water collect and flow? Show the flow of runoff and streams with arrows on a topographic map.Q 3. Use the graph you made of weekly precipitation to answer the following questions. Include the graph with your answer. You do not need to include the graphs you printed out of stream gauge height and groundwater.How have the local stream gauge height and groundwater changed in the past seven days, if at all? What factors influenced the stream gauge height the most? What factors influenced groundwater levels the most?How have the local stream gauge height and groundwater changed in the past 120 days? What factors influenced the stream gauge height the most? What factors influenced groundwater levels the most?
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Organic Chemistry lab; One Slide Research like poster on PowerPoint; subject is Synthesis of Acetaminophen
You are going to make a one slide research like poster on Synthesis of Acetaminophen. Follow instructions attached below. ...
Organic Chemistry lab; One Slide Research like poster on PowerPoint; subject is Synthesis of Acetaminophen
You are going to make a one slide research like poster on Synthesis of Acetaminophen. Follow instructions attached below. Experimental Methods- Synthesis of AcetaminophenThe reaction: In the fume hood, prepare a hot water bath in the fume hood using a stainless steel bowl, thermometer and hotplate. Heat the water in the bath to approximately 90°C -100°C.Attach a clamp to the vertical lattice support above the water bath to secure an Erlenmeyer flask. Set up a vacuum filtration apparatus on the other side of the fume hood using the red vacuum tubing, not the clear condenser tubing. Make sure to secure the filter flask to a vertical lattice support using a clamp. Also, remember to pre-weigh the filter paper that will be used.In a 50 mL Erlenmeyer flask, add ~ 3 g of 4-aminophenol, 8 mL of DI water, 3.5 mL of acetic anhydride, and a stir bar.Record the exact mass of 4-aminophenol as you'll need it when calculating the theoretical yield. Heat the Erlenmeyer flask containing the reaction mixture in the hot water bath for 5 minutes with gently stirring.Make sure to secure the Erlenmeyer flask using the clamp previously set up.Once 5 minutes as elapsed, remove the flask from the bath and place on the fume hood bench top. Allow the flask to cool to room temperature.While the reaction mixture flask is cooling, dump out the water bath and prepare an ice bath in the stainless steel bowl.Once cooled to room temperature, place the Erlenmeyer flask in the ice bath to force the product to crash out as a solid.Collecting the crude product:Using the vacuum filtration apparatus already assembled, vacuum filter the crude product making sure to wet the filter paper with DI water before beginning the filtration.A few small portions of cold water (~1-3 mL) may be utilized to aid in the transfer of the product from the Erlenmeyer to the Buchner funnel. Allow the crude product to air dry on the vacuum for 5 minutes.Once dried, mass the amount of crude product obtained and set aside a small amount of crude product for melting point analysis later.Recrystallization: Transfer the weighed crude product into a 50 mL Erlenmeyer flask (clean and dry the flask used in the initial reaction)Recrystallize the crude product using hot 50% methanol in water as the recrystallization solvent (the recrystallization solvent has already been prepared and can be found in the reagent fume hood).Use a plastic transfer pipette to transfer only enough hot recrystallization solvent to completely dissolve the crude product while the solvent is still hot.Add the solvent in small portions, one plastic transfer pipet at a time.This process should proceed quickly, as to not allow the solvent to cool.Approximately 3 mL of solvent will recrystallize 1 g of crude acetaminophen. Use this as a rough guide not a rule that is written in stone.Once dissolved, allow the solution to slowly cool down to room temperature by placing the Erlenmeyer on the fume hood bench top. Once cooled to room temperature, place the Erlenmeyer in an ice bath to maximize crystallization.Vacuum filter the recrystallized product making sure to wet the filter paper with DI water before beginning the filtration.A few small portions of cold water (~ 1-3 mL) may be utilized to aid in the transfer of the product from the Erlenmeyer to the Buchner funnel.Wash the filtered crystals with approximately two 3 mL portions of cold DI water.Allow the product to air dry on the vacuum for 15 minutes.It may be necessary to break up any chunks using a spatula but take care not to tear the underlying filter paper.Collecting the recrystallized product:Vacuum filter the recrystallized product making sure to wet the filter paper with DI water before beginning the filtration.A few small portions of cold water (~ 1-3 mL) may be utilized to aid in the transfer of the product from the Erlenmeyer to the Buchner funnel.Wash the filtered crystals with approximately two 3 mL portions of cold DI water.Allow the product to air dry on the vacuum for 15 minutes.It may be necessary to break up any chunks using a spatula but take care not to tear the underlying filter paper.Monitoring the progress of the reaction by TLC:Obtain a 15 mL plastic centrifuge tube, place 1-2 crystals of the recrystallized product in the tube and using acetone dilute the sample until the meniscus reaches the 2 mL mark on the tube.This can be done as soon as needed, do not wait for the recrystallized product to fully dry as this will not affect the TLC results.If this solution is too concentrated, the spot will streak on the TLC plate giving no discernable Rf.If this solution is too dilute, the spot will not be visible on the plate.Prepare a TLC plate, making 3 spot marks on the line-of-origin for the following:Standard product spot (already prepared at TLC spotting station)Standard starting material spot (already prepared at TLC spotting station)Recrystallized product spot.Spot each sample on the TLC plate remembering to visualize the spots using the UV lamp between each spot.Do not over spot the samples.Prepare the TLC solvent system using a 10 mL graduated cylinder. Dispense ethyl acetate to the 10 mL mark and then add 2 drops of conc. ammonium hydroxide. Transfer this to the TLC development chamber and completely mix the solvent system by swirling the solution in the beaker.Be very careful as to not directly have your face directly over the conc. ammonium hydroxide.Develop the TLC plate approximately 50 % -75 % up the plate, immediately mark the solvent front and visualize using the UV lamp. Sketch the TLC results in the lab notebook. Calculate the Rf for each component visible in the recrystallized product spot.Characterization:Once the recrystallized product has dried, weigh out the solid and calculate the percent yield for the reaction. Observe and record the melting point range for the crude and recrystallized product.Waste Disposal:All accumulated waste from the experiment must be disposed of as follows:Solids: Solid waste in reagent fume hood.Aqueous filtrate: Acid waste.Recrystallization solvent: non-halogenated.TLC development solution: non-halogenated.Melting point capillary tubes: glass disposal box.Draw the mechanism on https://chemdrawdirect.perkinelmer.cloud/js/sample... Data: You may choose how you wish to represent your data within the poster. Keep in mind that it is a visual representation, i.e. tables are better than text, when possible. etc.Make a one slide power point and convert it to a poster by clicking on design, slide size, a page set up window will pop up, click Custom for the slide sized for, and put the width 48 inches, and the height 36 inches. Let the zoom size 32% not 100%. The font has to be 34 Times New Roman. Experimental methods section is based on the experiment’s data conclusión. I Attached: 1)Follow instructions for Posters by reading the Poster Info attached carefully. USE ACS STYLE FOR REFERENCES THIS IS EXTREMELY IMPORTANT2) an experiment overview too of Synthesis of Acetaminophen 2) Calculating % yield; read it carefully if you don't know how to do it. 3) Couple of examples of previous students submissions, follow them throughly. DO NOT PLAGIARIZE. 4) The rubic for the experiment, make sure you read it carefully.
BIO 230 Cuyamaca College Green Fluorescent Protein GFP Project Lab
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biology lab about the gfp and I'm gonna provide all the instruction and details. I will send all the Pdf that you need and the things that will help you go through the lab smoothly.
NURS 300B SMSU Social Insurance and Public Assistance Discussion
Isabella is a 4-year-old girl who showed signs of a viral illness that did not seem to get better for 2 days. Her mother, ...
NURS 300B SMSU Social Insurance and Public Assistance Discussion
Isabella is a 4-year-old girl who showed signs of a viral illness that did not seem to get better for 2 days. Her mother, Sonia Ramirez, took her to a local walk-in clinic, where she was reassured that Isabella had a bad cold but would recover within a few days. She was given a teaching sheet about viral illnesses that, after getting home, she realized she could not understand. The next day, however, Isabella was barely responsive and had numerous dark purple spots. Her mother rushed her to a local emergency room. Isabella was intubated and airlifted via helicopter to a major medical center, where she was diagnosed with meningococcemia, a life-threatening infection.undefinedIsabella subsequently had bilateral amputations of her legs for gangrene secondary to poor perfusion. After a long hospitalization, she was transferred to a rehabilitation facility where she was fitted with prosthetic legs. Sonia quit her job to stay with Isabella throughout her illness and recovery. When Sonia quit her job, her insurance benefits ended, and she could not afford to pay for continuing insurance coverage.undefinedDiscuss all of the questions below: Isabella's health care bills were enormous. What is the role of private insurance in paying these bills? What is the role of public assistance?What is the role of the nurse in containing these costs? Do you feel that health literacy played a role in the patient’s outcome? If so, how?Do you think Sonia should have continued working through Isabella's illness in order to continue insurance coverage?Would you feel differently about who is accountable for paying the bills for caring for this patient if the patient had been a morbidly obese adult who lived with unhealthy eating and exercise habits?Is this a display of incivility?If so, what are some possible destructive consequences of this incivility, including the financial implications for the patient and rehabilitation facility?How could each of the following nursing roles advocate for Isabella: educator, manager, researcher, activist?How could the contemporary care delivery model of patient-centered care, used by an interdisciplinary team, effect the care and outcomes for Isabella?What is the RN’s role on that team?Discuss these questions as well:You are a nurse working in this rehabilitation facility. You have a peer in this facility who disagrees with your feelings about Isabella’s current employment decisions. This peers make derogatory, demeaning statements about your feelings for this situation.
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Your Local Watershed
Lower Arkansas-Maumelle Watershed drains into lake Maumelle water body Counties and/or Cities that are part of Lower Arkan ...
Your Local Watershed
Lower Arkansas-Maumelle Watershed drains into lake Maumelle water body Counties and/or Cities that are part of Lower Arkansas-Maumelle Watershed
What was the runoff from precipitation on the property for areas with vegetation and roofed or paved
Field Study ReportQ 1.
What was the runoff from precipitation on the property for areas with vegetation and roofed or ...
What was the runoff from precipitation on the property for areas with vegetation and roofed or paved
Field Study ReportQ 1.
What was the runoff from precipitation on the property for areas with vegetation and roofed or paved areas over the past four months? What percent of total precipitation ran off of the property? Include data tables in your answer. Would you expect this percentage to be the same for the properties of other students in the class? Why or why not? What factors decide the percentage of runoff? Q 2.
Which way will runoff water flow from your property? Where will the runoff water collect and flow? Show the flow of runoff and streams with arrows on a topographic map.Q 3. Use the graph you made of weekly precipitation to answer the following questions. Include the graph with your answer. You do not need to include the graphs you printed out of stream gauge height and groundwater.How have the local stream gauge height and groundwater changed in the past seven days, if at all? What factors influenced the stream gauge height the most? What factors influenced groundwater levels the most?How have the local stream gauge height and groundwater changed in the past 120 days? What factors influenced the stream gauge height the most? What factors influenced groundwater levels the most?
5 pages
Quantum Mechanics Research22
The three applications which involve the use of Quantum Mechanics include MRI (Magnetic Resonance Imaging) scan, Lacers an ...
Quantum Mechanics Research22
The three applications which involve the use of Quantum Mechanics include MRI (Magnetic Resonance Imaging) scan, Lacers and Modern Electronics. These ...
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