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Jan 6th, 2015
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Question description

For the reaction

2NO + Cl2 " src=""> 2NOCl

Match the appropriate rate law to each postulated mechanism.
ARate = k[Cl2]2
BRate = k[Cl2]
CRate = k[NO]2[Cl2]
DRate = k[NO]2
ERate = k[NO][Cl2]2
FRate = k[NO][Cl2]
GRate = k[NO]
HRate = k[NO]2[Cl2]2
INone of the above

Cl2 2Cl slow
Cl + NO NOCl fast

NO + Cl2 NOCl2 fast equilibrium
2NOCl2 NOCl3 + NOCl slow
NOCl3 NOCl + Cl2 fast

NO + Cl2 NOCl2 fast equilibrium
NOCl2 + NO 2NOCl slow

NO + Cl2 NOCl + Cl slow
Cl + NO NOCl fast

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(Top Tutor) Daniel C.
School: University of Virginia

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Jan 6th, 2015
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