​Assignment for Transport of Dangerous Goods Module

Anonymous
timer Asked: Dec 20th, 2017
account_balance_wallet $75

Question description

Psychedelic Paints, Malahide, Co Dublin manufactures and distributes paint through out Ireland. They package paint in a variety of different packages from 1 litre to 25 litre. They use their own vehicle, haulage contractors and some customers collect direct from the warehouse in Malahide.

The paint has a flashpoint of 20C and a boiling point of 36C. The vapour pressure pressure at 50C is not more than 110KPa.

1. Classify the product.


2. The product is being packaged in 5 litre containers and four of these containers are put into a fiberboard box.

Detail what marks and labels should be put on the packaging.

3. The paint is packaged in 25 litre drums. A vehicle <7.5tonnes GVW is loaded with 100 drums for delivery to Ryan Painters, Clones Co Monaghan.

Detail the type of packaging which should be used

What marking and labels should be put on the packaging

What marking should be put on the vehicle.

Prepare a transport document.

What other documents should be carried on the vehicle.

What "equipment must be on board the vehicle.

List 8 on the spot fines which the carrier is liable.

4. A customer collects 300 litres of paint in his own vehicle.

Outline the details of any exemption which the customer can apply.

5. The company wants to transport the paint in bulk to a sister company in Cork.

What road tanker (code) should be specified.

What orange plates and placards should be displayed.

Complete an ADR application form for the tanker.

What is the maximum filling ratio

6. You are the DGSA for this company

Outline the areas you would cover in this report

Note: Answers must meet EUROPEAN COMMUNITIES (CARRIAGE OF DANGEROUS GOODS BY ROAD AND USE OF TRANSPORTABLE PRESSURE EQUIPMENT) REGULATIONS 2013, ADR VolumeI&II and DGSA Guide attached.

Note: Include references with each answer.

Guidance on the duties of a Dangerous Goods Safety Adviser (DGSA) Our vision: A country where worker safety, health and welfare and the safe management of chemicals are central to successful enterprise Published in June 2015 by the Health and Safety Authority, The Metropolitan Building James Joyce Street, Dublin 1. When to Appoint a DGSA This guidance is intended to inform Dangerous Goods Safety Advisers (DGSAs) and those undertakings which need to appoint a DGSA, about the roles and responsibilities of a DGSA. A DGSA has specific duties under the European Agreement Concerning the International Carriage of Dangerous Goods by Road (ADR), which will be detailed in this document. An undertaking may need to appoint a DGSA if it is involved in the following activities: • Consigning dangerous goods for transport including, including as appropriate, loading, packing and filling (consignors). • Operation of road vehicles carrying dangerous goods, including as appropriate, packing, loading, filling and unloading (carriers). The main legislation relating to the carriage of Dangerous Goods by Road in Ireland is as follows: A. The European Communities (Carriage of Dangerous Goods by Road and Use of Transportable Pressure Equipment) Regulations 2011 to 2015. These regulations implement the ADR in Ireland and provide for the administration and enforcement of ADR. For more information on the transport of dangerous goods in Ireland, please refer to the: Carriage of Dangerous Goods by Road section of the HSA website at www.hsa.ie B. ADR (European Agreement Concerning the International Carriage of Dangerous Goods by Road) 2015. This document is reviewed and amended every two years. DGSAs are required to inform themselves of the changes and advise their clients accordingly. Information on the ADR and reports on changes to the ADR may be accessed at the links below: http://www.unece.org/trans/danger/publi/adr/adr_e.html and the Main Changes Reports section of the HSA website at www.hsa.ie Guidance on the duties of a Dangerous Goods Safety Adviser (DGSA) 3 The ADR specifies the responsibilities of a Safety Adviser in Chapter 1.8.3 The core responsibilities of a Safety Adviser are as follows: • Advising undertakings on the safe transport of dangerous goods by road. • Monitoring the undertakings compliance with dangerous goods regulations. • Preparing an annual report about the activities of the undertaking related to the transport dangerous goods. • Investigating any accidents or infringements of regulations and preparing reports. • Monitoring the provision of training and advice to any staff involved in the transport of dangerous goods. The duties of those who accept the appointment of DGSA for an undertaking are mandatory. A DGSA or employer does not have the discretion to “cherry pick” the duties or roles which they must observe and fulfil. The role of a DGSA is such that fulfilling the responsibilities as detailed in the ADR attracts a legal duty of care for the DGSA. A regulatory body or competent authority in any of the EU or non-EU member states who are signatories to the ADR may require the identity of the DGSA acting for an undertaking. It is your duty as an undertaking involved in the carriage, loading or unloading of dangerous goods, or as an appointed DGSA, to comply in a timely fashion with any lawful request of any such regulatory body. Guidance for Undertakings You may decide to appoint a member of your own staff (suitably trained and qualified) to be a DGSA or you may choose to appoint externally. In appointing a DGSA it is recommended to make enquiries regarding the competence and experience of the prospective DGSA. Some DGSAs may be qualified in various different modes of transport (road, rail, sea, air) which may be relevant in your line of business. 4 If you are operating several sites or large complex organisation, you may need to appoint more than one DGSA. If this is the case, you must ensure that the activities of these advisers are adequately integrated and co-ordinated. You must also ensure that the responsibilities to prepare documents such as annual reports, accident records or safety plans are clearly defined so as to ensure compliance with the ADR. It is recommended to clarify such roles in writing. Upon receipt of written reports from audits, reviews and spot checks from your DGSA, it is your responsibility to address any matters requiring attention quickly and effectively. You must inform your DGSA of any accidents or incidents (including serious accidents and incidents listed in ADR 1.8.5) in a timely fashion, to enable the DGSA to conduct thorough investigation and submit a report (if required) to the regulatory authorities. There are instances where you may not be required to appoint a DGSA, for example: • Where the amounts of dangerous goods handled by your undertaking are so small or are so infrequently consigned, that the appointment of a DGSA would be unreasonable. • Where you structure your operation so as to avail of the exemptions permitted in the ADR, such as the exemption under ADR 1.1.3.6 known colloquially as the ‘load limit exemption’ or the ‘carrier exemption’. The assessment of whether or not you are required to legally appoint a DGSA should be carried out by a competent person and should be documented. Your particular circumstances should be reviewed periodically to ensure that the initial assumptions and criteria are still valid and applicable. However, where you do determine that you are not required to appoint a DGSA, if your enterprise carries out any activities involving the carriage of dangerous goods, it is highly recommended that you seek advice or guidance from a qualified DGSA from time to time as required. For guidance on the appointment of a DGSA, and in relation to your general responsibilities and duties of care under the regulations, please refer to the following documents available on the HSA website www.hsa.ie: Guidance on the appointment of a Dangerous Goods Safety Adviser (DGSA) Carriage of Dangerous Goods by Road: A Guide for Business Guidance on the duties of a Dangerous Goods Safety Adviser (DGSA) 5 Guidance for Dangerous Goods Safety Advisers Training and Competence To qualify as a DGSA, you must ensure that you have a vocational training certificate. A DGSA certificate is valid for 5 years and specifes the mode of transport. In Ireland the only certification available is for road transport, however certification for transport modes, such as rail, may be available outside Ireland. The Chartered Institute of Logistics and Transport (CILT) has been appointed by the HSA as the examination body for DGSA certification in Ireland. Vocational training certificates are issued by CILT to candidates who have successfully completed the approved examination. Irish certified DGSAs are recognised in other EU and non-EU states who are signatories to the ADR, and DGSAs certified in such states are recognised in Ireland. For more information on how to obtain DGSA certification, please refer to the CILT website at http://www.cilt.ie/. The Roles and Responsibilities of a DGSA In your position as an appointed DGSA, your roles and responsibilities will include, but may not be limited to, those listed below: 1. Monitor compliance and provide advice to the undertaking You must carry out spot checks, audits and review the various activities of the undertaking. You must communicate the results to the undertaking in writing and in a timely manner. It is the responsibility of the undertaking to address any matters requiring attention quickly and effectively. You may provide advice on various matters as required, for example on packaging provisions for specific dangerous goods, or in relation to the application of any ADR or national exemptions. For more detail see later in this guidance in the section entitled ‘Provision of Advice’. 6 2. Selection, purchasing and approval of vehicles You may be required to advise on, review and monitor the procedures of the undertaking with respect to the selection and purchasing of vehicles meeting the requirements of ADR Part 9, or the provision and renewal of certificates of approval for vehicles. 3. Safety Equipment and Transport Equipment You must advise on, review and monitor procedures with respect to checking the safety equipment and transport equipment used in the carriage of dangerous goods by road. All transport equipment should be subjected to regular general inspections, and certain equipment requires certification and may be subject to periodic inspection. Equipment that requires certification includes packaging (including IBCs), bulk containers, tanks and vehicles which transport such tanks. For more information regarding safety equipment, and transport equipment requiring certification, please refer to Sections 11 and 14 of our ADR guide for Business. 4. Training You must review and monitor the procedures for the provision of adequate training of personnel and the retention and maintenance of appropriate training records. ADR training must include general awareness training for staff involved in the consignment, packing, filling, loading, stowage, securing and unloading of dangerous goods in addition to function specific training and safety training in accordance with ADR Chapter 1.3. In addition, you must advise on and monitor requirements for driver vocational training (in accordance with ADR 8.2.2.8). 5. Emergency Procedures You must review and monitor the implementation of written emergency procedures in the event of an accident or incident during the carriage of dangerous goods by road, including loading and unloading operations. Guidance on the duties of a Dangerous Goods Safety Adviser (DGSA) 7 Procedures should consider at a minimum: • Incidents such as fires and explosions, road traffic accidents or loss of containment of dangerous goods • Foreseeable events such as breakdowns or a transport unit becoming immobilised for any reason • How the requirements for supervising vehicles as detailed in ADR 8.4 are achieved and complied with; for example, it may be necessary to identify possible secure locations on a route where a vehicle may be safely parked overnight 6. Accident and Incident investigation You must review and monitor procedures for the investigation of accidents, incidents and infringements. Note that you must comply with the reporting regime required by the Safety, Health and Welfare at Work (General Applications) Regulations 1993, S.I. No. 44 of 1993 Twelfth Schedule, Dangerous Occurrences. In the case of serious accidents or incidents (ADR 1.8.5), you must prepare a report according to the model in ADR 1.8.5.4. You should request that the undertaking informs you of such an event in a timely fashion, to facilitate adequate investigation and the preparation of a report, if required, for submission to the regulatory authorities. 7. Prevention of accidents, incidents or dangerous occurrences You must review and monitor the implementation of written procedures and measures to avoid the recurrence of accidents, incidents or serious infringements. Where appropriate, you must review and monitor procedures required to ensure compliance with any special requirements of national and international legislation regarding the use of third parties or sub-contractors with respect to the carriage of dangerous goods. You must review and monitor the undertakings mechanisms to ensure that personnel involved in the carriage, loading and unloading of dangerous goods are provided with detailed operating procedures (SOPs) and instructions to ensure compliance with the legislation in its entirety. 8 You must review and monitor the implementation of measures designed to ensure compliance with the duty of care imposed by the legislation. This must address the various aspects of the carriage of dangerous goods, including: • the loading and unloading of dangerous goods, • the provision and maintenance of all necessary documentation, • the marking, labelling and placarding of the vehicles, containers, tanks or packages as appropriate, and • the provision and maintenance of all safety equipment. You must review and monitor the written procedures to ensure that the loading, stowage, carriage and unloading of dangerous goods is in compliance with the best practice guidelines. It must be ensured that the loads do not shift, fall or lead to a loss of containment or put at risk other road users. For information sheets on load security and the international guidelines on safe load securing please refer to the load security section of the HSA website www.hsa.ie Where appropriate, you must review and monitor the preparation of the security plan in accordance with ADR 1.10.3.2 for those dangerous goods designated as ‘high consequence dangerous goods’. Provision of Advice You must advise the undertaking, who appoints you, on how to ensure compliance with the ADR with respect to: • the classification of dangerous goods, packing and tank provisions, • consignment procedures, and • exemptions (ADR, national exemptions). Guidance on the duties of a Dangerous Goods Safety Adviser (DGSA) 9 1. Classification of dangerous goods, packing and tank provisions Where appropriate, you must advise on the classification of dangerous goods in accordance with ADR Chapter 2.2. You should provide to the undertaking a written copy of all test results and the mechanism by which the classification process was carried out, for each of the dangerous goods addressed. You should provide written advice to the undertaking regarding the choice of suitable means of containment of dangerous goods. Such advice must provide adequate detail to ensure the purchase and appropriate use of packagings, tanks and containers for the various DG which they handle. Where appropriate you should provide written advice on all relevant packaging and tank provisions in accordance with ADR Part 4. Where the packages are not equipped with information required by ADR 6.1.2, you must ensure that a certificate of conformity is provided by a reliable manufacturer or supplier. It may be most suitable to provide the packaging code information as a spreadsheet, from which the undertaking may identify the appropriate codes for its particular application and activities. 2. Consignment Procedures You must provide written advice to the undertaking as to the requirements for compliance with the procedures for proper consignment of DG. Such advice should, where applicable, include details as to the following: • • 10 You should advise the undertaking on any applicable authorisations of consignments and advance notifications. Such authorisations may take the form of Competent Authority Exemptions, Approvals or Multilateral Agreements (MLAs). All current Authorisations are listed and available for download on the HSA website. The use of overpacks in accordance with ADR 5.1.2. • The marking and labelling of empty uncleaned packages, tanks, MEMU’s, vehicles and containers. • You must provide written advice as to the appropriate marking & labelling of packages, in accordance with ADR 5.2. Such advice should be provided in respect of each participant role that the undertaking fulfils. • You must provide written advice with respect to placarding and marking of containers, multiple-element gas containers (MEGCs), tanks and vehicles in accordance with ADR 5.3. • You must provide written advice as to the appropriate documentation as specified by the ADR Chapter 5.4. Such documentation must be maintained at the appropriate location within the undertaking for reference and presentation to an inspector on request. For more detailed guidance in relation to many of the provisions outlined above please refer to Sections 8-10 and Section 13 of our ADR Guide for Business. 3. ADR and National Exemptions You should advise the undertaking on the proper application of any relevant exemptions, including clear written guidance in relation to the application of any such exemption. Typically an undertaking may avail of exemptions related to: • the nature of the transport operation (ADR 1.1.3.1), • the carriage of gases (ADR 1.1.3.2), • the carriage of liquid fuels (ADR 1.1.3.3), • special provisions or to dangerous goods packed in limited or excepted quantities (ADR Chapters 3.3 - 3.5), • empty uncleaned packaging (ADR 1.1.3.5), and • quantities carried per transport unit (1.1.3.6) generally referred to as the “load limit" or "carriers exemption”. National exemptions apply to the carriage of dangerous goods within the state only and are provided for in the national regulations (Part 8). Competent Authority exemptions are generally temporary derogations for specific dangerous goods, and generally only apply to national transport (see ‘Authorisations’ above in the section on ‘consignment procedures’). They are usually initiated by the consignor or carrier, and must specify the nature, control measures, conditions and duration of the exemption. For more detailed guidance in relation to many of the provisions outlined above please refer to Section 5 of our ADR Guide for Business. Guidance on the duties of a Dangerous Goods Safety Adviser (DGSA) 11 Preparation and provision of Annual Reports You should prepare an annual report on the activities of the undertaking. The Annual Report must record in reasonable detail all activities in respect of the carriage of dangerous goods during the period in question. A template of the minimum necessary information is provided in Annex A. Information in the Annual Report The template provides the minimum information that is required in an adequate Annual Report (AR). The function of the AR is to capture the activities of the undertaking with respect to the ADR, and should achieve the following objectives: • Inform the management of the undertaking as to standard of compliance achieved during the period, with the aim of identifying opportunities for improvement and to ensure compliance with their duty of care under the ADR. • Provide recommendations with respect to areas which need improvement or corrective action. • Facilitate inspection and investigation by the regulatory authorities in the performance of their statutory duties in an efficient and effective manner. Records of annual reports must be held by the undertaking for 5 years and be readily available for review by an inspector. Any supporting documentation must also be available. • Provide details of the activities of the Safety Adviser; however, it is not merely a review of the activities of the Safety Adviser. • Detail the activities of the undertaking in its role as a participant under the provisions of the ADR. An undertaking may fulfil the role of several participants during the reporting period, and also may share some participant obligations with another undertaking. While the use of the attached template is not mandatory, you may find it useful to ensure that you provide enough detail to achieve compliance. It is critical to capture all the relevant detail in the report. Where an undertaking carries out spot checks, maintains checklists or carries out audits, the detail of these must be included in the report. It may be useful to use appendices for supporting data such as spreadsheets, tables or other required information. This will ensure that the report is reasonably concise and to facilitate the analysis of the information. 12 Provision of records for inspection The provision and maintenance of adequate records is a core part of the management of the carriage of dangerous goods by road. Any information captured in the annual report must be supported by relevant records, such as vocational training certification (DGSAs and drivers), audit records and completed inspection checklists and these records must be readily available for inspection by inspectors of the regulatory authorities during normal working hours. Where an undertaking operates multiple sites, records which are relevant to each specific site should be kept on location where possible, e.g. site training records, audits and schedule of work identified by site audits. The annual report itself may be held centrally as it is primarily for the company management but elements of it or documents referenced by it which are specific to a particular site should be available to management and staff on any given site. Records may be retained electronically. However, hard copies must be made available to an inspector on request. Guidance on the duties of a Dangerous Goods Safety Adviser (DGSA) 13 DGSA Annual Report- Template 1. Company Name: Address: Contact: Position: [Manager] Phone Numbers: Mobile: email: Fax: Nature of Business: 2. DGSA Name: Date of Appointment: Phone Number: Certificate Number: Mobile Number: Expiry Date: email: Mode/Classes: 3. Report Period: Indicate period covered by the report e.g. 01/01/2006 to 31/12/2006 Copied to: List the Names and positions of all recipients Additional Documentation: List associated documents/ appendices. 14 4. Dangerous Goods Provide details of all dangerous goods carried /consigned in the past 12 months, including quantity and class. A spreadsheet as an appendix could be used and referenced here. 5. Packaging Types Provide details of packaging types used and confirmation of suitability (for example,UN approvals, certificates of conformity) 6. Tanks / Tankers Give details of the tank / tanker types managed / operated. Provide details of periodic inspections and leakproofness tests carried out over the last 12 months. Indicate expiry dates for all other tanks / tankers. A suitable table could be used, see example below. Ref No. Tank Type and Expiry Date: Tank Code periodic inspections Expiry Date: Intermediate/ leakproofness tests Comments Guidance on the duties of a Dangerous Goods Safety Adviser (DGSA) 15 7. Fleet Details Provide details of company vehicles used to transport dangerous goods. Ref No. Registration Number Expiry Date: DoE Test Expiry Date: ADR Vehicle Approval Comments 8. Audits Provide details of audits carried out. Indicate deficiencies and recommendations arising from these audits during the period of the report. The inspections carried out by the regulatory authorities under the ADR are audits, and should be included in this section. 9. Accidents Provide details of accidents or incidents involving dangerous goods and, where relevant, incidents of the type mentioned in ADR 1.8.5 that occurred in the past 12 months. 10. Training Provide details of Training according to ADR 1.3 (DGSA, ADR Driver, and Dangerous Goods awareness, function specific and safety training for others involved in the carriage of dangerous goods). 16 11. Security Give details of activities carried out to meet the requirements of ADR 1.10 on Security, particularly the preparation of “Security Plans” where relevant. 12. Infringements Provide details of inspections / checks carried out by enforcement authorities and include details of improvement notices or fines imposed, and identify any actions taken by the participants to address the non-compliance issues identified. 13. Recommendations List any recommendations Signed: Dated: Guidance on the duties of a Dangerous Goods Safety Adviser (DGSA) 17 A country where worker safety, health and welfare and the safe management of chemicals are central to successful enterprise ISBN No: 978-1-84496-211-2 HSA0433
RSA/ADR 1 APPLICATION FOR ADR ROAD VEHICLE APPROVAL CERTIFICATE Before filling in this application, please see notes at rear. Consult with your DGSA if unclear about any aspect. (All relevant parts of this application must be completed, both for first and subsequent applications for all vehicles) PART 1 (To be completed by all applicants) ))applicants) 1. The Applicant Name: ________________________________________________ Tel No: ____________________ Company: _______________________________________________email:_____________________ Address: __________________________________________________________________________________ 2. The Vehicle (Please tick appropriate box(es) Is this the first application for this vehicle YES Vehicle Type Method of Carrying or Containing Load NO Rigid Drawbar Trailer Artic Tractor Semi-Trailer Box (closed) Body Fixed Tank Sheeted Body Tank Container/Demountable Battery Vehicle Tank/Portable Tank/MEGC Vac. operated Tank Vehicle Registration No/Trailer Mark: _______________________ Chassis No: ______________ (Please enclose the vehicle Licensing or Registration Certificate, or Trailer Card, as appropriate) Date of 1st Registration: ______________ D.G.V.W ________ TONNES D.G.C.W________TONNES Make____________________________ 3. Body/Tank Make/Number: _______________________ Vehicle Owner (To be completed by all applicants) Company: _________________________________________________________________________ Address: _________________________________________________________________________ ___________________________________________Company email:__________________________ 4. The Test Preferred Test Centre ____________________________ 5. Date/Time: ____________________ Applicant’s Declaration I declare that the information on this form is correct. I enclose Cheque/Postal Order for the amount of €91.50. I undertake to pay the remaining €93.01 directly to the test centre on the day of the test. Signed: _____________________ Name (BLOCK CAPITALS) _______________________________ Status (Transport Manager, etc) _________________________ Date ____________________________ PART II (To be completed by all applicants) 6. ADR CATEGORY FOR WHICH CERTIFICATION IS REQUIRED (Please tick the appropriate box(es)) B3 Certificate (Vehicle or trailer to be used in International or National Transport) I3 Certificate (Vehicle or trailer to be used in National Transport only) Vehicle category for which certification is required. Type EX/II For closed bodied or sheeted vehicles intended for the carriage of class 1 explosive substance and articles. Type EX/III For a vehicle intended for the carriage of explosives substances and articles (Class 1). Type FL For a vehicle intended for the carriage of liquids having a flash-point of not more than 60oC (with the exception of diesel fuel complying with standard EN 590: 2004, gas oil, and heating oil (light) – UN No. 1202 – with a flash-point as specified in standard EN 590: 2004) or flammable gases, in tank-containers, portable tanks or MEGCs of more than 3m3 capacity, fixed tanks or demountable tanks of more than 1 m3 capacity, or a battery-vehicle of more than 1m3 capacity intended for the carriage of flammable gases. Type OX For a vehicle intended for the carriage of hydrogen peroxide, stabilized or hydrogen peroxide, aqueous solution stabilized with more than 60 per cent hydrogen peroxide (Class 5.1, UN No. 2015) in tank-containers or portable tanks of more than 3 m3 capacity, fixed tanks or demountable tanks of more than 1 m3 capacity. Type AT For a vehicle, other than EX/III, FL or OX, intended for the carriage of dangerous goods in tank-containers, portable tanks or MEGCs of more than 3 m3 capacity, fixed tanks or demountable tanks of more than 1 m3 capacity or a battery vehicle of more than 1 m3 capacity other than an FL Vehicle. Do you intend carrying a) hydrogen? b) carbon disulphide? YES YES NO NO Is the tank made of reinforced plastic? YES NO TANK VEHICLE Please state tank code according to ADR Agreement 2011 Chapter 4.3 (Column 12 of Table A of Chapter3.2) Please state code for any special provisions relating to 6.8.4 of ADR Agreement 2011 (Column 13 of Table A of Chapter 3.2) TANK VEHICLE/BATTERY VEHICLE Is any of the substances to be carried classified with a “(+)” in Column 12 of Table A in Chapter 3.2 of the ADR Agreement 2011. YES NO If Yes, please state below the name of the substance, the UN number and the packing group number – SUBSTANCE UN NUMBER PACKING GROUP NUMBER ___________ ___________ _______________________ Note: “Demountable tanks” are tanks which cannot be removed from the carrying vehicles when loaded. “Tank containers” are tanks which are designed to be removed from the carrying vehicle when loaded for transfer to another vehicle or mode of transport. “Battery vehicles” are vehicles which carry an assembly of receptacles interconnected by a manifold and permanently maintained in a frame. EX II / EX III Do you intend to carry any goods of Class 1 compatibility group J YES 7. NO DOCUMENTATION The following documentation and/or declarations are required with the application. Failure to provide these could delay the application or lead to forfeiture of the fee. The RSA must at all times hold copies of valid and up to date documentation/declarations for every ADR vehicle. TYPE EX/II Cab/Body and, if applicable, sheet declaration(s). See parts VI, VII and VIII. N/A Cab declaration provided by vehicle manufacturer. Sheet declaration provided by manufacturer. Body Declaration 3 YES NO TYPE EX/III Brakes, Cab and body declarations. See parts III, VII and VIII. N/A YES NO Brake declaration provided by vehicle manufacturer. Cab declaration provided by vehicle manufacturer. Body declaration provided by manufacturer. TYPE FL Brake Declarations, Tank Approval Certificates and Combustion Heater Declaration. See parts III, IV and V. N/A YES NO Brake declaration provided by vehicle manufacturer. Tank Type Approval Certificate Tank Code and/or Product List provided. Tank Initial Approval Certificate. Tank Periodical Test Certificate. Tank Leakproofness Test Certificate. Combustion Heater Declaration TYPE OX Brake Declarations, Tank Type Approval Certificate, and Cab Declaration (if not fitted with cab screen). See parts III, IV, and VII. N/A Brake declaration provided by vehicle manufacturer. Tank Type Approval Certificate Tank Code and/or Product List provided. Tank Initial Approval Certificate. Tank Periodical Test Certificate Tank Leakproofness Test Certificate Cab Declaration provided by Vehicle Manufacturer. YES NO TYPE AT Brake Declaration, Tank Type Approval Certificate. See Parts III and IV. N/A Brake declaration provided by vehicle manufacturer. Tank Type Approval Certificate. Tank Code and/or Product List provided. Tank Initial Approval Certificate. Tank Periodical Test Certificate. Tank Leakproofness Test Certificate. . Tank Lining Annual Condition Certificate (only required if carrying Bromine) 5 YES NO PART III 8. Braking Requirements from Type EX/III, FL, OX and AT Vehicles A brake declaration completed by the manufacturer will be required for the following vehicles at the time of first application for ADR inspection in the Republic of Ireland. a) a motor vehicle with a maximum mass exceeding 16 tonnes. b) a motor vehicle authorised to draw a trailer exceeding 10 tonnes. c) a trailer with a maximum mass exceeding 10 tonnes. Vehicles registered before 1st April, 2002 and seeking certification for National Transport only (I3 Certificate) that are not fitted with anti-lock brakes and endurance braking do not require a brake declaration. DECLARATION – to be completed by manufacturer. NOTE: A separate declaration from the manufacturer is acceptable provided it clearly relates to the vehicle concerned. I declare that:- • In the case of a motor vehicle referred to in (a), (b) or (d) above the vehicle is equipped with an antilock braking system of category 1 according to UN ECE Regulations No. 13 Annex 13 or the corresponding provisions of Directive 71/320/EEC. • In the case of a vehicle referred to in (a), (b) or (d) above the vehicle is equipped with an endurance braking system (retarder) that fulfils the requirements of UN ECE Regulation No 13 Annex 5 (Type IIA test), or of the corresponding provisions of EEC Directive 71/320/EEC, with a laden vehicle mass comprising the laden mass of the motor vehicle and its authorised maximum towed mass but not exceeding a total of 44 tonnes. (Where a vehicle is not authorised to tow a trailer this should be clearly stated by the vehicle manufacturer). • In the case of a trailer referred to in (c) or (d) above the trailer is equipped with an antilock braking system of category A according to UN ECE Regulation No 13 Annex 13 or to the corresponding provisions of Directive 71/320/EEC. Signed: _____________________ Name (BLOCK CAPITALS) _______________________________ Company __________________________ Status _________________ Date _____________ The following declaration will be required from the owner for every ADR application relating to the types of vehicles referred to above. Declaration – to be completed by owner. I declare that no repairs or alterations have been carried out which will invalidate the manufacturer’s declaration, or which would affect the performance of either: a. the antilock braking system, or b. the endurance braking system Signed: _____________________ Name (BLOCK CAPITALS) _______________________________ Company __________________________ Status _________________ Date _____________ PART IV 9. Tank Certificates The application must provide as appropriate (depending on whether a B3 or an I3 is required) the following with the application: (Copies are acceptable but originals must be produced on the day of test). a. Tank Type Approval Certificate. b. Tank Code and/or Product List. c. Tank Initial Approval Certificate. d. Tank Periodical Test Certificate. e. Tank Leakproofness Test Certificate. f. Tank Lining Annual Condition Certificate (only applicable if carrying Bromine) PART V 10. COMBUSTION HEATER HEAT EXCHANGER DECLARATION (only applicable to type FL vehicles) A declaration completed by the manufacturer will be required at the time of first application for ADR inspection in the Republic of Ireland. DECLARATION – to be completed by vehicle or combustion heater manufacturer. NB Dealer declarations are not acceptable. NOTE: A separate declaration from the manufacturer is acceptable provided it clearly relates to the vehicle. I declare that:• The heat exchanger of the combustion heater fitted to the engine or cab of the type FL motor vehicle is resistant to the reduced after-running cycle of 40 seconds for the time of its normal use. Signed: _____________________ Name (BLOCK CAPITALS) _______________________________ Company __________________________ Status _________________ 7 Date _____________ PART V I II. Sheet Declaration For Type EX/II Sheeted Vehicles To be completed by the vehicle or sheet manufacturer or supplier. NOTE: A separate declaration from the vehicle or sheet manufacturer or supplier is acceptable provided it clearly relates to the vehicle. I declare that the sheet manufactured or supplied by …………………………………………………….. and if applicable marked with the following identification feature ……………………………………….. is resistant to tearing and is made of impermeable material and not readily flammable as proven by testing to the BI level in standard DIN 4102 or equivalent. Signed: _____________________ Name (BLOCK CAPITALS) _______________________________ Company __________________________ Status _________________ Date _____________ PART V II 12. Cab Declaration For All Type EX/II and EX/III Vehicles and those OX Vehicles Not Equipped With A Metal Shield Behind The Cab. Declaration(s) completed by the manufacturer (or modifier, if applicable) will be required for the following vehicles at the time of first application for ADR inspection in the Republic of Ireland. a. Type EX/II (explosives) b. Type EX/III (explosives) c. Type OX if not equipped with a metal shield behind the cab. Declaration – to be completed by manufacturer (or modifier, if applicable). Note: a separate declaration from the manufacturer/modifier is acceptable provided it clearly relates to the vehicle. I declare that: • • Only material not readily flammable is used in the construction of the driver’s cab. This provision will be deemed to be met if, in accordance with the procedure specified in ISO standard 3795:1989, samples of the following cab components have a burn rate not exceeding 100 mm/min: seat cushions, seat backs, safety belts, head lining, opening roofs, armrests, all trim panels including door, front, rear, and side panels, compartment shelves, head restraints, floor coverings, sun visors, curtains, shades, wheel housing covers, engine compartment covers, mattress covers and any other interior materials, including padding and crash-deployed elements, that are designed to absorb energy on contact by occupants in the event of a crash. Signed: _____________________ Name (BLOCK CAPITALS) ______________________________ Company: ___________________ Status: ____________________ Date:__________________ The following declaration will be required from the owner for every ADR application relating to the type of vehicle referred to above. DECLARATION – to be completed by owner I declare that no repairs, modifications or paintings of the cab have been carried out in such a manner as to invalidate the manufacturer’s/modifier’s declaration. Signed: _____________________ Name (BLOCK CAPITALS) ______________________________ Company: ___________________ Status: ____________________ 9 Date: __________________ PART V III 13. Body Declaration For Type EXII/EX/III Vehicles A declaration completed by the manufacturer will be required at the time of first application for ADR inspection in the Republic of Ireland. Declaration – to be completed by manufacturer. Note: a separate declaration from the manufacturer is acceptable provided it clearly relates to the vehicle. I declare that in the case of a Type EXII vehicle or trailer: • No materials have been used in the construction of the body which would be likely to form dangerous compounds with the substances carried. Signed: _____________________ Name (BLOCK CAPITALS) ______________________________ Company: ___________________ Status: ____________________ Date: __________________ I declare that in the case of a Type EXIII motor vehicle or trailer: • • • the body is solidly constructed of not readily flammable materials and the materials used for the lining are incapable of producing sparks. the insulating and heat resisting properties of the body are at least equivalent to those of a partition consisting of a metal outer wall lined with a layer of fire proofed wood 10mm thick, or the body is of a construction which ensure no flame penetration of the wall or hot spots of more than 120oc on the inner wall surface will occur within 15 minutes from the start of a fire likely to occur from the operation of the vehicle. No materials have been used in the construction of the body which would be likely to form dangerous compounds with the substances carried. Signed: _____________________ Name (BLOCK CAPITALS) ______________________________ Company: ___________________ Status: ____________________ Date: __________________ The following declaration will be required from the owner for every ADR application relating to the type EXII/EXIII vehicle. DECLARATION – to be completed by owner I declare that no repairs, modifications or painting of the body have been carried out in such a manner as to invalidate the manufacturer’s declaration. Signed: _____________________ Name (BLOCK CAPITALS) ______________________________ Company: ___________________ Status: ____________________ Date: __________________ Notes General 1. Applicants must ensure that the application form for an ADR examination is properly completed (e.g. tank code and special provisions code provided). You should consult your D.G.S.A. if in doubt about any aspect of the form. 2. Applications should be made as early as possible and not less than 10 working days before the inspection is required. Applications must be accompanied by copies only of the necessary declarations and in the case of tank vehicles by current tank certificates, a tank code and/or product list. Originals must be produced on the day of the examination. It will be necessary to have passed a roadworthiness test within forty days of the confirmed appointment date of the ADR examination. Evidence of this will be required to be presented in the form of a certificate of roadworthiness or a pass statement of result on the day of the ADR examination. 3. Separate applications must be made for each vehicle (i.e. motor vehicle, trailer or semitrailer) for which an ADR certificate is required. 4. Applications should be sent to, ADR Unit, Vehicle Standards Section, Road Safety Authority, Moy Valley Business Park, Primrose Hill, Ballina Co. Mayo. The application should be accompanied by a crossed cheque or postal order for €91.50 (payable to The Road Safety Authority). The remaining fee of €93.01 must be paid directly to the test centre on the day of the test. The payment of the test centre’s portion of the fee is a matter between you and the test centre. 5. In some vehicle types it may be necessary for vehicles to be presented with covers removed so that markings can be seen e.g. (battery master switch). 6. If you are not able to keep an appointment for an examination, let the inspection station know as soon as possible – fees may be forfeited for late cancellation or failure to attend. 7. If this is not the first application for this vehicle, a photocopy of both sides of the current or most recent ADR certificate must be enclosed with the application. 8. Following issue of a Certificate of Approval, the applicant should ensure that details on the issued certificate correspond with the approval requested in the application form. 9. Tank Vehicles a) Photocopies of the appropriate tank certificates should be sent with the application. However, the originals must be produced at the time of the examination. If an original has features which are not obvious on the copy and which leads to a change having to be made to the prepared (ADR) certificate, a retest fee may be payable before release of the new certificate. b) Before a B3 Approval Certificate can be processed, a copy of any previous B3 certificate issued for the vehicle must be sent to The Road Safety Authority. 11 c) A declaration stating that the tank has been purged and rendered safe for an ADR examination to be carried out must be presented at the test centre. 10. ADR Unit Contact Details: ADR Unit Vehicle Standards Section Road Safety Authority Moy Valley Business Park Primrose Hill Ballina Co. Mayo. Telephone: 096 25035 Email : adrtestapplication@rsa.ie
Copyright © United Nations, 2010. All rights reserved ECE/TRANS/215 (Vol.I) Economic Commission for Europe Committee on Inland Transport applicable as from 1 January 2011 European Agreement Concerning the International Carriage of Dangerous Goods by Road Volume I UNITED NATIONS New York and Geneva, 2010 Copyright © United Nations, 2010. All rights reserved NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ECE/TRANS/215 (Vol.I) Copyright © United Nations, 2010 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS PUBLICATION Sales No.: E.10.VIII.4 ISBN 978-92-1-139140-4 (complete set of 2 volumes) Volumes I and II not to be sold separately. Copyright © United Nations, 2010. All rights reserved FOREWORD General The European Agreement concerning the International Carriage of Dangerous Goods by Road (ADR) was done at Geneva on 30 September 1957 under the auspices of the United Nations Economic Commission for Europe, and it entered into force on 29 January 1968. The Agreement itself was amended by the Protocol amending article 14 (3) done at New York on 21 August 1975, which entered into force on 19 April 1985. According to article 2 of the Agreement, dangerous goods barred from carriage by Annex A shall not be accepted for international transport, while international transport of other dangerous goods shall be authorized subject to compliance with: - the conditions laid down in Annex A for the goods in question, in particular as regards their packaging and labelling; and - the conditions laid down in Annex B, in particular as regards the construction, equipment and operation of the vehicle carrying the goods in question. Nevertheless, according to article 4, each Contracting Party shall retain the right to regulate or prohibit, for reasons other than safety during carriage, the entry of dangerous goods into its territory. Contracting Parties also retain the right to arrange, by bilateral or multilateral agreements, that certain dangerous goods which are prohibited from carriage by Annex A be internationally carried, subject to certain conditions, on their territories, or that dangerous goods authorized to be carried internationally according to Annex A be carried on their territories under conditions less stringent than those specified in Annexes A and B. Annexes A and B have been regularly amended and updated since the entry into force of ADR. Structure of Annexes A and B The Working Party on the Transport of Dangerous Goods (WP.15) of the Economic Commission for Europe’s Committee on Inland Transport decided, at its fifty-first session (26-30 October 1992), to restructure Annexes A and B, on the basis of a proposal by the International Road Transport Union (TRANS/WP.15/124, paras. 100-108). The main objectives were to make the requirements more accessible and more user-friendly so that they could be applied more easily not only to international road transport operations under ADR, but also to domestic traffic in all European States through national or European Community legislation, and ultimately to ensure a consistent regulatory framework at European level. It was also considered necessary to identify more clearly the duties of the various participants in the transport chain, to group more systematically the requirements concerning these various participants, and to differentiate the legal requirements of ADR from the European or international standards that could be applied to meet such requirements. The structure is consistent with that of the United Nations Recommendations on the Transport of Dangerous Goods, Model Regulations, the International Maritime Dangerous Goods Code (IMDG Code) and the Regulations concerning the International Carriage of Dangerous Goods by Rail (RID). It has been split into nine parts, but still grouped under two annexes to align with the wording of article 2 of the Agreement itself. The layout is as follows: Annex A: General provisions and provisions concerning dangerous articles and substances Part 1 Part 2 Part 3 Part 4 General provisions Classification Dangerous goods list, special provisions and exemptions related to limited and excepted quantities Packing and tank provisions - iii - Copyright © United Nations, 2010. All rights reserved Part 5 Consignment procedures Part 6 Requirements for the construction and testing of packagings, intermediate bulk containers (IBCs), large packagings, tanks and bulk containers Part 7 Provisions concerning the conditions of carriage, loading, unloading and handling Annex B: Provisions concerning transport equipment and transport operations Part 8 Requirements for vehicle crews, equipment, operation and documentation Part 9 Requirements concerning the construction and approval of vehicles Part 1, which contains general provisions and definitions, is an essential part, since it contains all definitions for terms used throughout the other parts, and it defines precisely the scope and applicability of ADR, including the possibility of exemptions, as well as the applicability of other regulations. It also contains provisions concerning training, derogations and transitional measures, the respective safety obligations of the various participants in a chain of transport of dangerous goods, control measures, safety advisers, restrictions for the passage of vehicles carrying dangerous goods through road tunnels and transport of dangerous goods security. Central to the use of the restructured ADR is table A of Chapter 3.2 which contains the dangerous goods list in the numerical order of UN numbers. Once the UN number of a specific dangerous substance or article has been determined, the table provides cross-references to specific requirements to be applied for the carriage of that substance or article, and to the chapters or sections where these specific requirements may be found. Nevertheless, it should be borne in mind that the general requirements or class specific requirements of the various Parts have to be applied in addition to specific requirements, as relevant. An alphabetical index which indicates the UN number assigned to specific dangerous goods has been prepared by the secretariat and added as table B of Chapter 3.2 to facilitate the access to table A when the UN number is unknown. This table B is not an official part of ADR and has been added in the publication for easy reference only. When goods which are known or suspected to be dangerous cannot be found by name in any of tables A or B, they have to be classified in accordance with Part 2, which contains all relevant procedures and criteria to determine whether such goods are deemed to be dangerous or not and which UN number should be assigned. Applicable texts This version ("2011 ADR") takes into account all new amendments adopted by WP.15 in 2008, 2009 and 2010, circulated under the symbols ECE/TRANS/WP.15/204 and -/Corr.1 and ECE/TRANS/WP.15/204/Add.1, which, subject to acceptance by the Contracting Parties in accordance with article 14(3) of the Agreement, should enter into force on 1 January 2011. Nevertheless, due to the transitional measures provided for in 1.6.1.1 of Annex A, the previous version ("2009 ADR") may continue to be used until 30 June 2011. - iv - Copyright © United Nations, 2010. All rights reserved Territorial applicability ADR is an Agreement between States, and there is no overall enforcing authority. In practice, highway checks are carried out by Contracting Parties, and non-compliance may then result in legal action by national authorities against offenders in accordance with their domestic legislation. ADR itself does not prescribe any penalties. At the time of publishing, the Contracting Parties are Albania, Andorra, Austria, Azerbaijan, Belarus, Belgium, Bosnia and Herzegovina, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Ireland, Italy, Kazakhstan, Latvia, Liechtenstein, Lithuania, Luxembourg, Malta, Moldova, Montenegro, Morocco, Netherlands, Norway, Poland, Portugal, Romania, Russian Federation, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, The former Yugoslav Republic of Macedonia, Tunisia, Turkey, Ukraine and United Kingdom. ADR applies to transport operations performed on the territory of at least two of the above-mentioned Contracting Parties. In addition, it should be noted that, in the interest of uniformity and free trading across the European Union (EU), Annexes A and B of ADR have also been adopted by EU Member States as the basis for regulation of the carriage of dangerous goods by road within and between their territories (Directive 2008/68/EC of the European Parliament and of the Council of 24 September 2008 on the inland transport of dangerous goods, as amended). A number of non-EU countries have also adopted Annexes A and B of ADR as the basis for their national legislation. Additional practical information Any query concerning the application of ADR should be directed to the relevant competent authority. Additional information may be found on the UNECE Transport Division website on the following page: http://www.unece.org/trans/danger/danger.htm This website is regularly updated and contains the following information: - General information on ADR: http://www.unece.org/trans/danger/publi/adr/adr_e.html - Agreement (without annexes): http://www.unece.org/trans/danger/publi/adr/adr_agreement.htm - Protocol of signature: http://www.unece.org/trans/danger/publi/adr/adr_protocol.htm - Present status of ADR: http://www.unece.org/trans/danger/publi/adr/legalinst_53_TDG_ADR.html - Depositary notifications: http://www.unece.org/trans/danger/publi/adr/depnot_e.html - Country information (Competent Authorities, notifications): http://www.unece.org/trans/danger/publi/adr/country-info_e.htm - Linguistic versions (ADR, instructions in writing): http://www.unece.org/trans/danger/publi/adr/adr_linguistic_e.htm - Multilateral agreements: http://www.unece.org/trans/danger/multi/multi.htm - ADR 2011 (files): http://www.unece.org/trans/danger/publi/adr/adr2011/11ContentsE.html - ADR 2009 (files): http://www.unece.org/trans/danger/publi/adr/adr2009/09ContentsE.html - ADR 2009 (amendments): http://www.unece.org/trans/danger/publi/adr/adr2009_amend.htm - Previous versions (files and amendments) - Publication details and Corrigenda: http://www.unece.org/trans/danger/publi/adr/pubdet.htm -v- Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved TABLE OF CONTENTS VOLUME I Page Annex A Part 1 European Agreement concerning the international carriage of dangerous goods by road ............................................................................................ xv Protocol of signature ........................................................................................................ xxi General provisions and provisions concerning dangerous substances and articles .............................................................................................................. 1 General provisions ........................................................................................................... 3 Chapter 1.1 Scope and applicability ..................................................................... 5 Structure .............................................................................................. Scope ................................................................................................... Exemptions .......................................................................................... Applicability of other regulations ....................................................... 5 5 6 11 Definitions and units of measurement ............................................. 15 Definitions ........................................................................................... Units of measurement ......................................................................... 15 36 Training of persons involved in the carriage of dangerous goods ............................................................................ 39 Scope and applicability ....................................................................... Nature of the training .......................................................................... Documentation .................................................................................... 39 39 40 Safety obligations of the participants .............................................. 41 General safety measures ...................................................................... Obligations of the main participants ................................................... Obligations of the other participants ................................................... 41 41 43 Derogations ........................................................................................ 47 Temporary derogations ....................................................................... (Reserved) ........................................................................................... 47 47 Transitional measures ....................................................................... 49 General ................................................................................................ Pressure receptacles and receptacles for Class 2 ................................. Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles ................................................................................... Tank-containers, portable tanks and MEGCs ..................................... Vehicles ............................................................................................... Class 7 ................................................................................................. 49 50 1.1.1 1.1.2 1.1.3 1.1.4 Chapter 1.2 1.2.1 1.2.2 Chapter 1.3 1.3.1 1.3.2 1.3.3 Chapter 1.4 1.4.1 1.4.2 1.4.3 Chapter 1.5 1.5.1 1.5.2 Chapter 1.6 1.6.1 1.6.2 1.6.3 1.6.4 1.6.5 1.6.6 - vii - 51 55 58 59 Copyright © United Nations, 2010. All rights reserved Table of contents (cont'd) Page Chapter 1.7 1.7.1 1.7.2 1.7.3 1.7.4 1.7.5 1.7.6 Chapter 1.8 1.8.1 1.8.2 1.8.3 1.8.4 61 Scope and application ......................................................................... Radiation protection programme ......................................................... Quality assurance ................................................................................ Special arrangement ............................................................................ Radioactive material possessing other dangerous properties ........................................................................... Non-compliance ................................................................................... 61 62 63 64 64 64 Checks and other support measures to ensure compliance with safety requirements .............................................. 65 Administrative controls of dangerous goods ....................................... Mutual administrative support ............................................................ Safety adviser ...................................................................................... List of competent authorities and bodies designated by them .............................................................................. Notifications of occurrences involving dangerous goods ................... Administrative controls for application of the conformity assessments, periodic inspections, intermediate inspections and exceptional checks described in 1.8.7 ................................................................................. Procedures for conformity assessment and periodic inspection........... Procedures for conformity assessment of gas cartridges...................... 65 65 66 Transport restrictions by the competent authorities ..................... 93 Tunnel restrictions ............................................................................... 93 Security provisions ............................................................................. 97 General provisions ............................................................................... Security training................................................................................... Provisions for high consequence dangerous goods.............................. 97 97 97 Classification .............................................................................................................. 101 Chapter 2.1 General provisions ............................................................................ 103 Introduction.......................................................................................... Principles of classification ................................................................... Classification of substances, including solutions and mixtures (such as preparations and wastes), not mentioned by name................. Classification of samples...................................................................... 103 104 105 111 Class specific provisions ................................................................... 113 Class 1 Explosive substances and articles ......................................... Class 2 Gases..................................................................................... Class 3 Flammable liquids ................................................................ Class 4.1 Flammable solids, self-reactive substances and solid desensitized explosives ......................................... Class 4.2 Substances liable to spontaneous combustion ...................... 113 141 150 1.8.5 1.8.6 1.8.7 1.8.8 Chapter 1.9 1.9.5 Chapter 1.10 1.10.1 1.10.2 1.10.3 Part 2 General provisions concerning Class 7 ............................................ 2.1.1 2.1.2 2.1.3 2.1.4 Chapter 2.2 2.2.1 2.2.2 2.2.3 2.2.41 2.2.42 - viii - 72 72 79 81 88 155 166 Copyright © United Nations, 2010. All rights reserved Table of contents (cont'd) Page 2.2.43 2.2.51 2.2.52 Class 4.3 Substances which, in contact with water, emit flammable gases............................................................ Class 5.1 Oxidizing substances ............................................................ Class 5.2 Organic peroxides................................................................. 170 173 177 2.2.61 2.2.62 2.2.7 2.2.8 2.2.9 Class 6.1 Toxic substances................................................................... Class 6.2 Infectious substances ............................................................ Class 7 Radioactive material ............................................................. Class 8 Corrosive substances ............................................................ Class 9 Miscellaneous dangerous substances and articles................. 195 208 215 247 252 Test methods ...................................................................................... 269 General ................................................................................................. Exudation test for blasting explosives of Type A ................................ Tests relating to nitrated cellulose mixtures of Class 4.1..................... Tests relating to flammable liquids of Classes 3, 6.1 and 8 ................. Test for determining fluidity ................................................................ Classification of organometallic substances in Classes 4.2 and 4.3..... 269 269 271 272 274 277 Dangerous goods list, special provisions and exemptions related to limited and excepted quantities ...................................................................................... 279 Chapter 3.1 General ............................................................................................... 281 Introduction.......................................................................................... Proper shipping name........................................................................... Solutions or mixtures ........................................................................... 281 281 283 Dangerous goods list ......................................................................... 285 Table A: Dangerous Goods List........................................................... Table B: Alphabetic index of substances and articles of ADR ........... 293 560 Chapter 2.3 2.3.0 2.3.1 2.3.2 2.3.3 2.3.4 2.3.5 Part 3 3.1.1 3.1.2 3.1.3 Chapter 3.2 3.2.1 3.2.2 - ix - Copyright © United Nations, 2010. All rights reserved TABLE OF CONTENTS VOLUME II Page Annex A (cont’d) General provisions and provisions concerning dangerous substances and articles .............................................................................................................. 1 Part 3 (cont’d) Dangerous goods list, special provisions and exemptions related to limited and excepted quantities ................................................................................... 3 Chapter 3.3 Special provisions applicable to certain articles or substances ...................................................................................... 5 Dangerous goods packed in limited quantities ........................................................................... 39 Dangerous goods packed in excepted quantities ............................ 43 Packing and tank provisions ........................................................................................... 47 Chapter 3.4 Chapter 3.5 Part 4 Chapter 4.1 Use of packagings, including intermediate bulk containers (IBCs) and large packagings .......................................... 49 Use of portable tanks and UN multiple-element gas containers (MEGCs) ............................... 183 Use of fixed tanks (tank-vehicles), demountable tanks, tank-containers and tank swap bodies with shells made of metallic materials, and battery-vehicles and multiple-element gas containers (MEGCs) ..................................... 207 Use of fibre-reinforced plastics (FRP) tanks, fixed tanks (tank-vehicles), demountable tanks, tank containers and tank swap bodies ........................................................................ 231 Chapter 4.5 Use of vacuum operated waste tanks ............................................... 233 Chapter 4.6 (Reserved) ........................................................................................... 235 Chapter 4.7 Use of mobile explosives manufacturing units (MEMUs) ............. 237 Consignment procedures ................................................................................................. 239 Chapter 5.1 General provisions ............................................................................ 241 Chapter 5.2 Marking and labelling ...................................................................... 249 Chapter 5.3 Placarding and marking of containers, MEGCs, MEMUs, 261 tank-containers, portable tanks and vehicles ................................. 261 Chapter 5.4 Documentation .................................................................................. 271 Chapter 5.5 Special provisions .............................................................................. 291 Chapter 4.2 Chapter 4.3 Chapter 4.4 Part 5 -x- Copyright © United Nations, 2010. All rights reserved Table of contents (cont'd) Page Part 6 Requirements for the construction and testing of packagings, intermediate bulk container (IBCs), large packagings, tanks and bulk containers .......................... Chapter 6.1 Chapter 6.2 Chapter 6.3 Chapter 6.4 Chapter 6.5 Chapter 6.6 Chapter 6.7 Chapter 6.8 Chapter 6.9 Chapter 6.10 Chapter 6.11 Chapter 6.12 293 Requirements for the construction and testing of packagings .......................................................................................... 295 Requirements for the construction and testing of pressure receptacles, aerosol dispensers, small receptacles containing gas (gas cartridges) and fuel cell cartridges containing liquefied flammable gas ..................................................................................... 327 Requirements for the construction and testing of packagings for Class 6.2 infectious substances of Category A ....... 365 Requirements for the construction, testing and approval of packages and material of Class 7 ................................ 373 Requirements for the construction and testing of intermediate bulk containers (IBCs) ........................................... 399 Requirements for the construction and testing of large packagings ................................................................................ 425 Requirements for the design, construction, inspection and testing of portable tanks and UN multiple-element gas containers (MEGCs) ............................... 435 Requirements for the construction, equipment, type approval, inspections and tests, and marking of fixed tanks (tank-vehicles), demountable tanks and tank-containers and tank swap bodies, with shells made of metallic materials, and battery-vehicles and multiple element gas containers (MEGCs) ..................................... 493 Requirements for the design, construction, equipment, type approval, testing and marking of fibre-reinforced plastics (FRP) fixed tanks (tank-vehicles), demountable tanks, tank-containers and tank swap bodies........... 537 Requirements for the construction, equipment, type approval, inspection and marking of vacuum-operated waste tanks ......................................................................................... 545 Requirements for the design, construction, inspection and testing of bulk containers .......................................................... 549 Requirements for the construction, equipment, type approval, inspections and tests, and marking of tanks, bulk containers and special compartments for explosives of mobile explosives manufacturing units (MEMUs) ....................................................... 553 - xi - Copyright © United Nations, 2010. All rights reserved Table of contents (cont'd) Page Part 7 Annex B Part 8 Provisions concerning the conditions of carriage, loading, unloading and handling .............................................................................................................. 557 Chapter 7.1 General provisions ............................................................................ 559 Chapter 7.2 Provisions concerning carriage in packages ................................... 561 Chapter 7.3 Provisions concerning carriage in bulk ........................................... 565 Chapter 7.4 Provisions concerning carriage in tanks ......................................... 571 Chapter 7.5 Provisions concerning loading, unloading and handling ...................................................................................... 573 Provisions concerning transport equipment and transport operations ........................................................................................................ 589 Requirements for vehicle crews, equipment, operation and documentation .............................................................................................................. 591 Chapter 8.1 General requirements concerning transport units and equipment on board ................................................................... 593 Requirements concerning the training of the vehicle crew .............................................................................. 597 Miscellaneous requirements to be complied with by the vehicle crew ................................................................................. 605 Chapter 8.4 Requirements concerning the supervision of vehicles..................... 607 Chapter 8.5 Additional requirements relating to particular classes or substances ...................................................................................... 609 Road tunnel restrictions for the passage of vehicles carrying Dangerous goods ............................................................................... 615 Requirements concerning the construction and approval of vehicles ......................... 617 Chapter 8.2 Chapter 8.3 Chapter 8.6 Part 9 Chapter 9.1 Chapter 9.2 Chapter 9.3 Chapter 9.4 Scope, definitions and requirements for the approval of vehicles ........................................................................... 619 Requirements concerning the construction of vehicles ............................................................................................... 625 Additional requirements concerning complete or completed EX/II or EX/III vehicles intended for the carriage of explosive substances and articles (Class 1) in packages ................. 635 Additional requirements concerning the construction of the bodies of complete or completed vehicles intended for the carriage of dangerous goods in packages (other than EX/II and EX/III vehicles) ........................................... 637 - xii - Copyright © United Nations, 2010. All rights reserved Table of contents (cont'd) Page Chapter 9.5 Chapter 9.6 Chapter 9.7 Chapter 9.8 Additional requirements concerning the construction of the bodies of complete or completed vehicles intended for the carriage of dangerous solids in bulk ................................... 639 Additional requirements concerning complete or completed vehicles intended for the carriage of temperature controlled substances ................................................... 641 Additional requirements concerning fixed tanks (tank-vehicles), battery-vehicles and complete or completed vehicles used for the carriage of dangerous goods in demountable tanks with a capacity greater than 1 m3 or in tank-containers, portable tanks or MEGCs of a capacity greater than 3 m3 (EX/III, FL, OX and AT vehicles) ... 643 Additional requirements concerning complete and Completed MEMUs .......................................................................... 647 - xiii - Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR) THE CONTRACTING PARTIES, DESIRING to increase the safety of international transport by road, HAVE AGREED as follows: Article 1 For the purpose of this Agreement, (a) the term "vehicle" shall mean motor vehicles, articulated vehicles, trailers and semi-trailers, as defined in article 4 of the Convention on Road Traffic of 19 September 1949, other than vehicles belonging to or under the orders of the armed forces of a Contracting Party; (b) the term "dangerous goods" shall mean those substances and articles the international carriage by road of which is prohibited by, or authorized only on certain conditions by, Annexes A and B; (c) the term "international transport" shall mean any transport operation performed on the territory of at least two Contracting Parties by vehicles defined in (a) above. Article 2 Subject to the provisions of article 4, paragraph 3, dangerous goods barred from carriage by Annex A 1. shall not be accepted for international transport. 2. International transport of other dangerous goods shall be authorized subject to compliance with: (a) the conditions laid down in Annex A for the goods in question, in particular as regards their packaging and labelling, and (b) the conditions laid down in Annex B, in particular as regards the construction, equipment and operation of the vehicle carrying the goods in question, subject to the provisions of article 4, paragraph 2. Article 3 The Annexes to this Agreement shall form an integral part thereof. Article 4 Each Contracting Party shall retain the right to regulate or prohibit, for reasons other than safety during 1. carriage, the entry of dangerous goods into its territory. 2. Vehicles in service on the territory of a Contracting Party at the time of entry into force of this Agreement or brought into service on such territory within two months after its entry into force shall be allowed, for a period of three years from such entry into force, to perform the international transport of dangerous goods even if their construction and equipment do not entirely conform to the requirements laid down in Annex B for the transport operation in question. Under special clauses of Annex B, however, this period may be reduced. - xv - Copyright © United Nations, 2010. All rights reserved 3. The Contracting Parties shall retain the right to arrange, by special bilateral or multilateral agreements, that certain of the dangerous goods which under this Agreement are barred from all international transport may, subject to certain conditions, be accepted for international transport on their territories, or that dangerous goods which under this Agreement are acceptable for international transport only on specified conditions may be accepted for international transport on their territories under conditions less stringent than those laid down in the Annexes to this Agreement. The special bilateral or multilateral agreements referred to in this paragraph shall be communicated to the Secretary-General of the United Nations, who shall communicate them to the Contracting Parties which are not signatories to the said agreements. Article 5 The transport operations to which this Agreement applies shall remain subject to national or international regulations applicable in general to road traffic, international road transport and international trade. Article 6 Countries members of the Economic Commission for Europe and countries admitted to the Commission 1. in a consultative capacity under paragraph 8 of the Commission's terms of reference may become Contracting Parties to this Agreement. (a) by signing it; (b) by ratifying it after signing it subject to ratification; (c) by acceding to it. 2. Such countries as may participate in certain activities of the Economic Commission for Europe in accordance with paragraph 11 of the Commission's terms of reference may become Contracting Parties to this Agreement by acceding to it after its entry into force. 3. The Agreement shall be open for signature until 15 December 1957. Thereafter, it shall be open for accession. 4. Ratification or accession shall be effected by the depositing of an instrument with the Secretary-General of the United Nations. Article 7 This agreement shall enter into force one month after the date on which the number of countries 1. mentioned in article 6, paragraph 1, which have signed it without reservation of ratification or have deposited their instruments of ratification or accession has reached a total of five. However, the Annexes thereto shall not apply until six months after the entry into force of the Agreement itself. 2. For any country ratifying or acceding to this Agreement after five of the countries referred to in article 6, paragraph 1, have signed it without reservation of ratification or have deposited their instruments of ratification or accession, this Agreement shall enter into force one month after the said country has deposited its instrument of ratification or accession and the Annexes thereto shall apply for the said country either on the same date, if they are already in force by that date, or, if they are not in force by that date, on the date on which they apply under the provisions of paragraph 1 of this article. Article 8 Any contracting Party may denounce this Agreement by so notifying the Secretary-General of the 1. United Nations. 2. Denunciation shall take effect twelve months after the date of receipt by the Secretary-General of the notification of denunciation. - xvi - Copyright © United Nations, 2010. All rights reserved Article 9 This Agreement shall cease to have effect if, after its entry into force, the number of Contracting Parties 1. is less than five during twelve consecutive months. 2. In the event of the conclusion of a worldwide agreement for the regulation of the transport of dangerous goods, any provision of this Agreement which is contrary to any provision of the said worldwide agreement shall, from the date on which the latter enters into force, automatically cease to apply to relations between the Parties to this Agreement which become parties to the worldwide agreement, and shall automatically be replaced by the relevant provision of the said worldwide agreement. Article 10 Any country may, at the time of signing this Agreement without reservation of ratification or of 1. depositing its instrument of ratification or accession or at any time thereafter, declare by notification addressed to the Secretary-General of the United Nations that this Agreement shall extend to all or any of the territories for the international relations of which it is responsible. The Agreement and the annexes thereto shall extend to the territory or territories named in the notification one month after it is received by the Secretary-General. 2. Any country which has made a declaration under paragraph 1 of this article extending this Agreement to any territory for whose international relations it is responsible may denounce the Agreement separately in respect of the said territory in accordance with the provisions of article 8. Article 11 Any dispute between two or more Contracting Parties concerning the interpretation or application of 1. this Agreement shall so far as possible be settled by negotiation between them. 2. Any dispute which is not settled by negotiation shall be submitted to arbitration if any one of the Contracting Parties in dispute so requests and shall be referred accordingly to one or more arbitrators selected by agreement between the Parties in dispute. If within three months from the date of the request for arbitration the Parties in dispute are unable to agree on the selection of an arbitrator or arbitrators, any of those Parties may request the Secretary-General of the United Nations to nominate a single arbitrator to whom the dispute shall be referred for decision. 3. The decision of the arbitrator or arbitrators appointed under paragraph 2 of this article shall be binding on the Contracting Parties in dispute. Article 12 Each Contracting Party may, at the time of signing, ratifying, or acceding to, this Agreement, declare 1. that it does not consider itself bound by article 11. Other Contracting Parties shall not be bound by article 11 in respect of any Contracting Party which has entered such a reservation. 2. Any Contracting Party having entered a reservation as provided for in paragraph 1 of this article may at any time withdraw such reservation by notifying the Secretary-General of the United Nations. Article 13 After this Agreement has been in force for three years, any Contracting Party may, by notification to 1. the Secretary-General of the United Nations, request that a conference be convened for the purpose of reviewing the text of the Agreement. The Secretary-General shall notify all Contracting Parties of the request and a review conference shall be convened by the Secretary-General if, within a period of four months following the date of notification by the Secretary-General, not less than one-fourth of the Contracting Parties notify him of their concurrence with the request. - xvii - Copyright © United Nations, 2010. All rights reserved 2. If a conference is convened in accordance with paragraph 1 of this article, the Secretary-General shall notify all the Contracting Parties and invite them to submit within a period of three months such proposals as they may wish the Conference to consider. The Secretary-General shall circulate to all Contracting Parties the provisional agenda for the conference, together with the texts of such proposals, at least three months before the date on which the conference is to meet. 3. The Secretary-General shall invite to any conference convened in accordance with this article all countries referred to in article 6, paragraph 1, and countries which have become Contracting Parties under article 6, paragraph 2. Article 141 1. Independently of the revision procedure provided for in article 13, any Contracting Party may propose one or more amendments to the Annexes to this Agreement. To that end it shall transmit the text thereof to the Secretary-General of the United Nations. The Secretary-General may also propose amendments to the Annexes to this Agreement for the purpose of ensuring concordance between those Annexes and other international agreements concerning the carriage of dangerous goods. 2. The Secretary-General shall transmit any proposal made under paragraph 1 of this article to all Contracting Parties and inform thereof the other countries referred to in article 6, paragraph 1. 3. Any proposed amendment to the Annexes shall be deemed to be accepted unless, within three months from the date on which the Secretary-General circulates it, at least one-third of the Contracting Parties, or five of them if one-third exceeds that figure, have given the Secretary-General written notification of their objection to the proposed amendment. If the amendment is deemed to be accepted, it shall enter into force for all the Contracting Parties, on the expiry of a further period of three months, except in the following cases: (a) In cases where similar amendments have been or are likely to be made to the other international agreements referred to in paragraph 1 of this article, the amendment shall enter into force on the expiry of a period the duration of which shall be determined by the Secretary-General in such a way as to allow, wherever possible, the simultaneous entry into force of the amendment and those that have been made or are likely to be made to such other agreements; such period shall not, however, be of less than one month's duration; (b) The Contracting Party submitting the proposed amendment may specify in its proposal, for the purpose of entry into force of the amendment, should it be accepted, a period of more than three months' duration. 4. The Secretary-General shall, as soon as possible, notify all Contracting Parties and all the countries referred to in article 6, paragraph 1, of any objection which may be received from the Contracting Parties to a proposed amendment. 5. If the proposed amendment to the Annexes is not deemed to be accepted, but if at least one Contracting Party other than the Contracting Party which proposed the amendment has given the Secretary-General written notification of its agreement to the proposal, a meeting of all the Contracting Parties and all the countries referred to in article 6, paragraph 1, shall be convened by the Secretary-General within three months after the expiry of the period of three months within which, under paragraph 3 of this article, notification must be given of objection to the amendment. The Secretary-General may also invite to such meeting representatives of: (a) 1 intergovernmental organizations which are concerned with transport matters; Note by the Secretariat: The text of Article 14, paragraph 3 incorporates a modification which entered into force on 19 April 1985 in accordance with a Protocol transmitted to Contracting Parties under cover of Depositary Notification C.N.229.1975.TREATIES-8 of 18 September 1975. - xviii - Copyright © United Nations, 2010. All rights reserved (b) international non-governmental organizations whose activities are directly related to the transport of dangerous goods in the territories of the Contracting Parties. 6. Any amendment adopted by more than half the total number of Contracting Parties at a meeting convened in accordance with paragraph 5 of this article shall enter into force for all Contracting Parties in accordance with the procedure agreed at such meeting by the majority of the Contracting Parties attending it. Article 15 In addition to the notifications provided for in articles 13 and 14, the Secretary-General of the United Nations shall notify the countries referred to in article 6, paragraph 1, and the countries which have become Contracting Parties under article 6, paragraph 2, of (a) signatures, ratifications and accessions in accordance with article 6; (b) the dates on which this Agreement and the Annexes thereto enter into force in accordance with article 7; (c) denunciations in accordance with article 8; (d) the termination of the Agreement in accordance with article 9; (e) notifications and denunciations received in accordance with article 10; (f) declarations and notifications received in accordance with article 12, paragraphs 1 and 2; (g) the acceptance and date of entry into force of amendments in accordance with article 14, paragraphs 3 and 6. Article 16 The Protocol of Signature of this Agreement shall have the same force, effect and duration as the 1. Agreement itself, of which it shall be considered to be an integral part. 2. No reservation to this Agreement, other than those entered in the Protocol of Signature and those made in accordance with article 12, shall be permitted. Article 17 After 15 December 1957, the original of this Agreement shall be deposited with the Secretary-General of the United Nations, who shall transmit certified true copies thereof to each of the countries referred to in article 6, paragraph 1. - xix - Copyright © United Nations, 2010. All rights reserved IN WITNESS WHEREOF the undersigned, being duly authorized thereto, have signed this Agreement. DONE at Geneva, this thirtieth day of September one thousand nine hundred and fifty-seven, in a single copy, in the English and French languages for the text of the Agreement proper, and in the French language for the Annexes, each text being equally authentic for the Agreement proper. The Secretary-General of the United Nations is requested to prepare an authoritative translation of the Annexes in the English language and attach it to the certified true copies referred to in article 17. - xx - Copyright © United Nations, 2010. All rights reserved PROTOCOL OF SIGNATURE - xxi - Copyright © United Nations, 2010. All rights reserved PROTOCOL OF SIGNATURE TO THE EUROPEAN AGREEMENT ON THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR) On proceeding to sign the European Agreement on the International Carriage of Dangerous Goods by Road (ADR) the undersigned, duly authorized, 1. CONSIDERING that the conditions governing the carriage of dangerous goods by sea to or from the United Kingdom differ basically from those set forth in Annex A to ADR and that it is impossible to modify them so as to conform to the latter in the near future; HAVING REGARD to the undertaking given by the United Kingdom to submit as an amendment to the said Annex A a special appendix containing special provisions for road-sea carriage of dangerous goods between the Continent and the United Kingdom; HAVE AGREED that, until the entry into force of such special appendix, dangerous goods carried under ADR to or from the United Kingdom shall comply with the provisions of Annex A to ADR and also with the United Kingdom conditions for the carriage of dangerous goods by sea; 2. TAKE NOTE OF a declaration by the representative of France to the effect that the Government of the French Republic reserves the right, notwithstanding the provisions of article 4, paragraph 2, to refuse to allow vehicles in service on the territory of another Contracting Party, whatever the date on which they were put into service, to be used for the carriage of dangerous goods on French territory unless such vehicles comply either with the conditions laid down for such carriage in Annex B or with the conditions laid down for the carriage of the goods in question in the French regulations governing the carriage of dangerous goods by road; 3. RECOMMEND that, before submission in accordance with article 14, paragraph 1, or article 13, paragraph 2, proposed amendments to this Agreement or its Annexes shall as far as possible first be discussed at meetings of experts of the Contracting Parties and, if necessary, of the other countries mentioned in article 6, paragraph 1, of the Agreement and of the international organizations mentioned in article 14, paragraph 5, of the Agreement. - xxii - Copyright © United Nations, 2010. All rights reserved ANNEX A GENERAL PROVISIONS AND PROVISIONS CONCERNING DANGEROUS SUBSTANCES AND ARTICLES -1- Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved PART 1 General provision -3- Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved CHAPTER 1.1 SCOPE AND APPLICABILITY 1.1.1 Structure Annexes A and B of ADR are grouped into nine parts. Annex A consists of Parts 1 to 7, and Annex B of Parts 8 and 9. Each part is subdivided into chapters and each chapter into sections and sub-sections. Within each part the number of the part is included with the numbers of the chapters, sections and sub-sections, for example Part 4, Chapter 2, Section 1 is numbered "4.2.1". 1.1.2 Scope 1.1.2.1 For the purposes of Article 2 of ADR, Annex A specifies: 1.1.2.2 (a) Dangerous goods which are barred from international carriage; (b) Dangerous goods which are authorized for international carriage and the conditions attaching to them (including exemptions) particularly with regard to: - classification of goods, including classification criteria and relevant test methods; - use of packagings (including mixed packing); - use of tanks (including filling); - consignment procedures (including marking and labelling of packages and placarding and marking of means of transport as well as documentation and information required); - provisions concerning the construction, testing and approval of packagings and tanks; - use of means of transport (including loading, mixed loading and unloading). Annex A contains certain provisions which, according to Article 2 of ADR, pertain to Annex B or to both Annexes A and B, as follows: 1.1.1 1.1.2.3 1.1.2.4 1.1.3.1 1.1.3.6 1.1.4 1.1.4.5 Chapter 1.2 Chapter 1.3 Chapter 1.4 Chapter 1.5 Chapter 1.6 Chapter 1.8 Structure (Scope of Annex B) Exemptions related to the nature of the transport operation Exemptions related to quantities carried per transport unit Applicability of other regulations Carriage other than by road Definitions and units of measurements Training of persons involved in the carriage of dangerous goods Safety obligations of the participants Derogations Transitional measures Checks and other support measures to ensure compliance with safety requirements -5- Copyright © United Nations, 2010. All rights reserved Chapter 1.9 Chapter 1.10 Chapter 3.1 Chapter 3.2 1.1.2.3 Transport restrictions by the competent authorities Security provisions General Columns (1), (2), (14), (15) and (19) (application of provisions of Parts 8 and 9 to individual substances or articles). For the purposes of Article 2 of ADR, Annex B specifies the conditions regarding the construction, equipment and operation of vehicles carrying dangerous goods authorized for carriage: - requirements for vehicle crews, equipment, operation and documentation; - requirements concerning the construction and approval of vehicles. 1.1.2.4 In Article 1(c) of ADR, the word "vehicles" need not refer to one and the same vehicle. An international transport operation may be performed by several different vehicles provided that the operation takes place on the territory of at least two Contracting Parties to ADR between the consignor and the consignee indicated in the transport document. 1.1.3 Exemptions 1.1.3.1 Exemptions related to the nature of the transport operation The provisions laid down in ADR do not apply to: (a) The carriage of dangerous goods by private individuals where the goods in question are packaged for retail sale and are intended for their personal or domestic use or for their leisure or sporting activities provided that measures have been taken to prevent any leakage of contents in normal conditions of carriage. When these goods are flammable liquids carried in refillable receptacles filled by, or for, a private individual, the total quantity shall not exceed 60 litres per receptacle and 240 litres per transport unit. Dangerous goods in IBCs, large packagings or tanks are not considered to be packaged for retail sale; (b) The carriage of machinery or equipment not specified in this Annex and which happen to contain dangerous goods in their internal or operational equipment, provided that measures have been taken to prevent any leakage of contents in normal conditions of carriage; (c) The carriage undertaken by enterprises which is ancillary to their main activity, such as deliveries to or returns from building or civil engineering sites, or in relation to surveying, repairs and maintenance, in quantities of not more than 450 litres per packaging and within the maximum quantities specified in 1.1.3.6. Measures shall be taken to prevent any leakage of contents in normal conditions of carriage. These exemptions do not apply to Class 7. Carriage undertaken by such enterprises for their supply or external or internal distribution does not fall within the scope of this exemption; (d) The carriage undertaken by the competent authorities for the emergency response or under their supervision, insofar as such carriage is necessary in relation to the emergency response, in particular carriage undertaken: - by breakdown vehicles carrying vehicles which have been involved in accidents or have broken down and contain dangerous goods; or -6- Copyright © United Nations, 2010. All rights reserved - to contain and recover the dangerous goods involved in an incident or accident and move them to the nearest appropriate safe place; (e) Emergency transport intended to save human lives or protect the environment provided that all measures are taken to ensure that such transport is carried out in complete safety; (f) The carriage of uncleaned empty static storage vessels which have contained gases of Class 2, groups A, O or F, substances of Class 3 or Class 9 belonging to packing group II or III or pesticides of Class 6.1 belonging to packing group II or III, subject to the following conditions: - All openings with the exception of pressure relief devices (when fitted) are hermetically closed; - Measures have been taken to prevent any leakage of contents in normal conditions of carriage; and - The load is fixed in cradles or crates or other handling devices or to the vehicle or container in such a way that they will not become loose or shift during normal conditions of carriage. This exemption does not apply to static storage vessels which have contained desensitized explosives or substances the carriage of which is prohibited by ADR. NOTE: For radioactive material, see 1.7.1.4. 1.1.3.2 Exemptions related to the carriage of gases The provisions laid down in ADR do not apply to the carriage of: (a) Gases contained in the tanks of a vehicle, performing a transport operation and destined for its propulsion or for the operation of any of its equipment (e.g. refrigerating equipment); (b) Gases contained in the fuel tanks of vehicles transported. The fuel cock between gas tank and engine shall be closed and the electric contact open; (c) Gases of Groups A and O (according to 2.2.2.1), if the pressure of the gas in the receptacle or tank at a temperature of 20 °C does not exceed 200 kPa (2 bar) and if the gas is not a liquefied or a refrigerated liquefied gas. This includes every kind of receptacle or tank, e.g. also parts of machinery and apparatus; (d) Gases contained in the equipment used for the operation of the vehicle (e.g. fire extinguishers), including in spare parts (e.g. inflated pneumatic tyres); this exemption also applies to inflated pneumatic tyres carried as a load; (e) Gases contained in the special equipment of vehicles and necessary for the operation of this special equipment during transport (cooling systems, fish-tanks, heaters, etc.) as well as spare receptacles for such equipment or uncleaned empty exchange receptacles, transported in the same transport unit; (f) Gases contained in foodstuffs (except UN 1950), including carbonated beverages; (g) Gases contained in balls intended for use in sports; and -7- Copyright © United Nations, 2010. All rights reserved (h) 1.1.3.3 Gases contained in light bulbs provided they are packaged so that the projectile effects of any rupture of the bulb will be contained within the package. Exemptions related to the carriage of liquid fuels The provisions laid down in ADR do not apply to the carriage of: (a) Fuel contained in the tanks of a vehicle performing a transport operation and destined for its propulsion or for the operation of any of its equipment. The fuel may be carried in fixed fuel tanks, directly connected to the vehicle’s engine and/or auxiliary equipment, which comply with the pertinent legal provisions, or may be carried in portable fuel containers (such as jerricans). The total capacity of the fixed tanks shall not exceed 1500 litres per transport unit and the capacity of a tank fitted to a trailer shall not exceed 500 litres. A maximum of 60 litres per transport unit may be carried in portable fuel containers. These restrictions shall not apply to vehicles operated by the emergency services; (b) 1.1.3.4 Fuel contained in the tanks of vehicles or of other means of conveyance (such as boats) which are carried as a load, where it is destined for their propulsion or the operation of any of their equipment. Any fuel cocks between the engine or equipment and the fuel tank shall be closed during carriage unless it is essential for the equipment to remain operational. Where appropriate, the vehicles or other means of conveyance shall be loaded upright and secured against falling. Exemptions related to special provisions or to dangerous goods packed in limited or excepted quantities NOTE: For radioactive material, see 1.7.1.4. 1.1.3.4.1 Certain special provisions of Chapter 3.3 exempt partially or totally the carriage of specific dangerous goods from the requirements of ADR. The exemption applies when the special provision is referred to in Column (6) of Table A of Chapter 3.2 against the dangerous goods entry concerned. 1.1.3.4.2 Certain dangerous goods may be subject to exemptions provided that the conditions of Chapter 3.4 are met. 1.1.3.4.3 Certain dangerous goods may be subject to exemptions provided that the conditions of Chapter 3.5 are met. 1.1.3.5 Exemptions related to empty uncleaned packagings Empty uncleaned packagings (including IBCs and large packagings) which have contained substances of Classes 2, 3, 4.1, 5.1, 6.1, 8 and 9 are not subject to the conditions of ADR if adequate measures have been taken to nullify any hazard. Hazards are nullified if adequate measures have been taken to nullify all hazards of Classes 1 to 9. 1.1.3.6 Exemptions related to quantities carried per transport unit 1.1.3.6.1 For the purposes of this sub-section, dangerous goods are assigned to transport categories 0, 1, 2, 3, or 4, as indicated in Column (15) of Table A of Chapter 3.2. Empty uncleaned packagings having contained substances assigned to transport category "0" are also assigned to transport category "0". Empty uncleaned packagings having contained substances assigned to a transport category other than "0" are assigned to transport category "4". -8- Copyright © United Nations, 2010. All rights reserved 1.1.3.6.2 Where the quantity of dangerous goods carried on a transport unit does not exceed the values indicated in column (3) of the table in 1.1.3.6.3 for a given transport category (when the dangerous goods carried in the transport unit belong to the same category) or the value calculated in accordance with 1.1.3.6.4 (when the dangerous goods carried in the transport unit belong to different transport categories), they may be carried in packages in one transport unit without application of the following provisions: - - Chapter 1.10, except for Class 1 explosives of Division 1.4 of UN Nos. 0104, 0237, 0255, 0267, 0289, 0361, 0365, 0366, 0440, 0441, 0455, 0456 and 0500; Chapter 5.3; Section 5.4.3; Chapter 7.2, except for V5 and V8 of 7.2.4; CV1 of 7.5.11; Part 8 except for 8.1.2.1 (a), 8.1.4.2 to 8.1.4.5, 8.2.3, 8.3.3, 8.3.4, 8.3.5, Chapter 8.4, S1(3) and (6), S2(1), S4, S14 to S21 and S24 of Chapter 8.5; Part 9. -9- Copyright © United Nations, 2010. All rights reserved 1.1.3.6.3 Transport category Substances or articles packing group or classification code/group or UN No. (1) 0 (2) 1.1A/1.1L/1.2L/1.3L and UN No. 0190 UN No. 3343 Substances belonging to packing group I UN Nos. 1183, 1242, 1295, 1340, 1390, 1403, 1928, 2813, 2965, 2968, 2988, 3129, 3130, 3131, 3134, 3148, 3396, 3398 and 3399 Class 5.1: UN No. 2426 Class 6.1: UN Nos. 1051, 1600, 1613, 1614, 2312, 3250 and 3294 Class 6.2: UN Nos. 2814 and 2900 Class 7: UN Nos. 2912 to 2919, 2977, 2978 and 3321 to 3333 Class 8: UN No. 2215 (MALEIC ANHYDRIDE, MOLTEN) Class 9: UN Nos. 2315, 3151, 3152 and 3432 and apparatus containing such substances or mixtures and empty uncleaned packagings, except those classified under UN No. 2908, having contained substances classified in this transport category. Substances and articles belonging to packing group I and not classified in transport category 0 and substances and articles of the following classes: Class 1: 1.1B to 1.1J a /1.2B to 1.2J/1.3C/1.3G/1.3H/1.3J/1.5D a Class 2: groups T, TC a, TO, TF, TOC a and TFC aerosols: groups C, CO, FC, T, TF, TC, TO, TFC and TOC Class 4.1: UN Nos. 3221 to 3224 and 3231 to 3240 Class 5.2: UN Nos. 3101 to 3104 and 3111 to 3120 Substances or articles belonging to packing group II and not classified in transport categories 0, 1 or 4 and substances of the following classes: Class 1: 1.4B to 1.4G and 1.6N Class 2: group F aerosols: group F Class 4.1: UN Nos. 3225 to 3230 Class 5.2: UN Nos. 3105 to 3110 Class 6.1: substances and articles belonging to packing group III Class 9: UN No. 3245 Substances and articles belonging to packing group III and not classified in transport categories 0, 2 or 4 and substances and articles of the following classes: Class 2: groups A and O aerosols: groups A and O Class 3: UN No. 3473 Class 4.3: UN No. 3476 Class 8: UN Nos. 2794, 2795, 2800, 3028 and 3477 Class 9: UN Nos. 2990 and 3072 Class 1: 1.4S Class 4.1: UN Nos. 1331, 1345, 1944, 1945, 2254 and 2623 Class 4.2: UN Nos. 1361 and 1362 packing group III Class 7: UN Nos. 2908 to 2911 Class 9: UN No. 3268 and empty, uncleaned packagings having contained dangerous goods, except for those classified in transport category 0 1 2 3 4 a Where the dangerous goods carried in the transport unit belong to the same category, the maximum total quantity per transport unit is indicated in column (3) of the table below. Class 1: Class 3: Class 4.2: Class 4.3: Maximum total quantity per transport unit (3) 0 20 333 1 000 unlimited For UN Nos. 0081, 0082, 0084, 0241, 0331, 0332, 0482, 1005 and 1017, the total maximum quantity per transport unit shall be 50 kg. - 10 - Copyright © United Nations, 2010. All rights reserved In the above table, "maximum total quantity per transport unit" means: 1.1.3.6.4 - For articles, gross mass in kilograms (for articles of Class 1, net mass in kilograms of the explosive substance; for dangerous goods in machinery and equipment specified in this Annex, the total quantity of dangerous goods contained therein in kilograms or litres as appropriate); - For solids, liquefied gases, refrigerated liquefied gases and dissolved gases, net mass in kilograms; - For liquids and compressed gases, nominal capacity of receptacles (see definition in 1.2.1) in litres. Where dangerous goods of different transport categories are carried in the same transport unit, the sum of: - The quantity of substances and articles of transport category 1 multiplied by "50"; - The quantity of substances and articles of transport category 1 referred to in Note a to the table in 1.1.3.6.3 multiplied by "20"; - The quantity of substances and articles of transport category 2 multiplied by "3"; and - The quantity of substances and articles of transport category 3; shall not exceed "1 000". 1.1.3.6.5 For the purposes of this sub-section, dangerous goods exempted in accordance with 1.1.3.2 to 1.1.3.5 shall not be taken into account. 1.1.3.7 Exemptions related to the carriage of lithium batteries The provisions laid down in ADR do not apply to: (a) Lithium batteries installed in a vehicle, performing a transport operation and destined for its propulsion or for the operation of any of its equipment; (b) Lithium batteries contained in equipment for the operation of this equipment used or intended for use during carriage (e.g. a laptop). 1.1.4 Applicability of other regulations 1.1.4.1 (Reserved) 1.1.4.2 Carriage in a transport chain including maritime or air carriage 1.1.4.2.1 Packages, containers, portable tanks and tank-containers, which do not entirely meet the requirements for packing, mixed packing, marking, labelling of packages or placarding and orange plate marking, of ADR, but are in conformity with the requirements of the IMDG Code or the ICAO Technical Instructions shall be accepted for carriage in a transport chain including maritime or air carriage subject to the following conditions: (a) If the packages are not marked and labelled in accordance with ADR, they shall bear markings and danger labels in accordance with the requirements of the IMDG Code or the ICAO Technical Instructions; - 11 - Copyright © United Nations, 2010. All rights reserved (b) The requirements of the IMDG Code or the ICAO Technical Instructions shall be applicable to mixed packing within a package; (c) For carriage in a transport chain including maritime carriage, if the containers, portable tanks or tank-containers are not marked and placarded in accordance with Chapter 5.3 of this Annex, they shall be marked and placarded in accordance with Chapter 5.3 of the IMDG Code. In such case, only 5.3.2.1.1 of this Annex is applicable to the marking of the vehicle itself. For empty, uncleaned portable tanks and tank-containers, this requirement shall apply up to and including the subsequent transfer to a cleaning station. This derogation does not apply in the case of goods classified as dangerous goods in classes 1 to 9 of ADR and considered as non-dangerous goods according to the applicable requirements of the IMDG Code or the ICAO Technical Instructions. 1.1.4.2.2 Transport units composed of a vehicle or vehicles other than those carrying containers, portable tanks or tank containers as provided for in 1.1.4.2.1 (c), which are not placarded in accordance with the provisions of 5.3.1 of ADR but which are marked and placarded in accordance with Chapter 5.3 of the IMDG Code, shall be accepted for carriage in a transport chain including maritime transport provided that the orange-coloured plate marking provisions of 5.3.2 of ADR are complied with. 1.1.4.2.3 For carriage in a transport chain including maritime or air carriage, the information required under 5.4.1 and 5.4.2 and under any special provision of Chapter 3.3 may be substituted by the transport document and information required by the IMDG Code or the ICAO Technical Instructions respectively provided that any additional information required by ADR is also included. NOTE: For carriage in accordance with 1.1.4.2.1, see also 5.4.1.1.7. For carriage in containers, see also 5.4.2. 1.1.4.3 Use of IMO type portable tanks approved for maritime transport IMO type portable tanks (types 1, 2, 5 and 7) which do not meet the requirements of Chapters 6.7 or 6.8, but which have been built and approved before 1 January 2003 in accordance with the provisions (including transitional provisions) of the IMDG Code (Amdt. 29-98) may be used until 31 December 2009 provided they are found to meet the applicable inspection and test provisions of the IMDG Code (Amdt. 29-98) and that the instructions referred to in Columns (12) and (14) of Chapter 3.2 of the IMDG Code (Amdt. 33-06) are fully complied with. They may continue to be used after 31 December 2009 if they meet the applicable inspection and test provisions of the IMDG Code, but provided that the instructions of Columns (10) and (11) of Chapter 3.2 of ADR and of Chapter 4.2 are complied with. 1 1.1.4.4 1 (Reserved) The International Maritime Organization (IMO) has issued "Guidance on the Continued Use of Existing IMO Type Portable Tanks and Road Tank Vehicles for the Transport of Dangerous Goods" as circular DSC.1/Circ.12 and Corrigenda. The text of this guidance can be found on the IMO website at: www.imo.org. - 12 - Copyright © United Nations, 2010. All rights reserved 1.1.4.5 Carriage other than by road 1.1.4.5.1 If the vehicle carrying out a transport operation subject to the requirements of ADR is conveyed over a section of the journey otherwise than by road haulage, then any national or international regulations which, on the said section, govern the carriage of dangerous goods by the mode of transport used for conveying the road vehicle shall alone be applicable to the said section of the journey. 1.1.4.5.2 In the cases referred to in 1.1.4.5.1 above, the involved ADR Contracting Parties may agree to apply the requirements of ADR to the section of a journey where a vehicle is conveyed otherwise than by road haulage, supplemented, if they consider it necessary, by additional requirements, unless such agreements between the involved ADR Contracting Parties would contravene clauses of the international conventions governing the carriage of dangerous goods by the mode of transport used for conveying the road vehicle on the said section of the journey, e.g. the International Convention for the Safety of Life at Sea (SOLAS), to which these ADR Contacting Parties would also be contracting parties. These agreements shall be notified by the Contracting Party which has taken the initiative thereof to the Secretariat of the United Nations Economic Commission for Europe which shall bring them to the attention of the Contracting Parties. 1.1.4.5.3 In cases where a transport operation subject to the provisions of ADR is likewise subject over the whole or a part of the road journey to the provisions of an international convention which regulates the carriage of dangerous goods by a mode of transport other than road carriage by virtue of clauses extending the applicability of that convention to certain motorvehicle services, then the provisions of that international convention shall apply over the journey in question concurrently with those of ADR which are not incompatible with them; the other clauses of ADR shall not apply over the journey in question. - 13 - Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved CHAPTER 1.2 DEFINITIONS AND UNITS OF MEASUREMENT 1.2.1 Definitions NOTE: This section contains all general or specific definitions. For the purposes of ADR: A "ADN" means the European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways; "Aerosol or aerosol dispenser" means any non-refillable receptacle meeting the requirements of 6.2.6, made of metal, glass or plastics and containing a gas, compressed, liquefied or dissolved under pressure, with or without a liquid, paste or powder, and fitted with a release device allowing the contents to be ejected as solid or liquid particles in suspension in a gas, as a foam, paste or powder or in a liquid state or in a gaseous state; "Animal material" means animal carcasses, animal body parts, or animal foodstuffs; "Applicant" means, in the case of conformity assessment, the manufacturer or its authorised representative in a country Contracting Party. In the case of periodic inspections, intermediate inspections and exceptional checks, applicant means the testing facility, the operator or their authorised representative in a country Contracting Party; NOTE: Exceptionally a third party (for instance an operator in accordance with the definition of 1.2.1) may apply for the conformity assessment. "Approval" Multilateral approval, for the carriage of Class 7 material, means approval by the relevant competent authority of the country of origin of the design or shipment, as applicable, and by the competent authority of each country through or into which the consignment is to be carried; Unilateral approval, for the carriage of Class 7 material, means an approval of a design which is required to be given by the competent authority of the country of origin of the design only. If the country of origin is not a Contracting Party to ADR, the approval shall require validation by the competent authority of the first Contracting Party to ADR reached by the consignment (see 6.4.22.6); "ASTM" means the American Society for Testing and Materials (ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA, 19428-2959, United States of America); - 15 - Copyright © United Nations, 2010. All rights reserved B "Bag" means a flexible packaging made of paper, plastics film, textiles, woven material or other suitable material; "Battery-vehicle" means a vehicle containing elements which are linked to each other by a manifold and permanently fixed to a transport unit. The following elements are considered to be elements of a battery-vehicle: cylinders, tubes, bundles of cylinders (also known as frames), pressure drums as well as tanks destined for the carriage of gases as defined in 2.2.2.1.1 with a capacity of more than 450 litres; "Body" (for all categories of IBC other than composite IBCs) means the receptacle proper, including openings and closures, but does not include service equipment; "Box" means a packaging with complete rectangular or polygonal faces, made of metal, wood, plywood, reconstituted wood, fibreboard, plastics or other suitable material. Small holes for purposes of ease of handling or opening or to meet classification requirements, are permitted as long as they do not compromise the integrity of the packaging during carriage; "Bulk containers" means containment systems (including any liner or coating) intended for the carriage of solid substances which are in direct contact with the containment system. Packagings, intermediate bulk containers (IBCs), large packagings and tanks are not included. Bulk containers are: - of a permanent character and accordingly strong enough to be suitable for repeated use; - specially designed to facilitate the carriage of goods by one or more modes of carriage without intermediate reloading; - fitted with devices permitting its ready handling; - of a capacity of not less than 1.0 m3; Examples of bulk containers are containers, offshore bulk containers, skips, bulk bins, swap bodies, trough-shaped containers, roller containers, load compartments of vehicles; "Bundle of cylinders" means an assembly of cylinders that are fastened together and which are interconnected by a manifold and carried as a unit. The total water capacity shall not exceed 3 000 litres except that bundles intended for the carriage of toxic gases of Class 2 (groups starting with letter T according to 2.2.2.1.3) shall be limited to 1 000 litres water capacity; C "Calculation pressure" means a theoretical pressure at least equal to the test pressure which, according to the degree of danger exhibited by the substance being carried, may to a greater or lesser degree exceed the working pressure. It is used solely to determine the thickness of the walls of the shell, independently of any external or internal reinforcing device (see also "Discharge pressure", "Filling pressure", "Maximum working pressure (gauge pressure)" and "Test pressure"); NOTE: For portable tanks, see Chapter 6.7. - 16 - Copyright © United Nations, 2010. All rights reserved "Capacity of shell or shell compartment" for tanks, means the total inner volume of the shell or shell compartment expressed in litres or cubic metres. When it is impossible to completely fill the shell or the shell compartment because of its shape or construction, this reduced capacity shall be used for the determination of the degree of filling and for the marking of the tank; "Cargo transport unit" means a vehicle, a container, a tank-container, portable tank or a MEGC; NOTE: This definition applies only for the application of special provision 302 of Chapter 3.3 and of Chapter 5.5. "Carriage" means the change of place of dangerous goods, including stops made necessary by transport conditions and including any period spent by the dangerous goods in vehicles, tanks and containers made necessary by traffic conditions before, during and after the change of place. This definition also covers the intermediate temporary storage of dangerous goods in order to change the mode or means of transport (transshipment). This shall apply provided that transport documents showing the place of dispatch and the place of reception are presented on request and provided that packages and tanks are not opened during intermediate storage, except to be checked by the competent authorities; "Carriage in bulk" means the carriage of unpackaged solids or articles in vehicles or containers. The term does not apply to packaged goods nor to substances carried in tanks; "Carrier" means the enterprise which carries out the transport operation with or without a transport contract; "CGA" means the Compressed Gas Association (CGA, 4221 Walney Road, 5th Floor, Chantilly VA 20151-2923, United States of America); "CIM" means the Uniform Rules Concerning the Contract of International Carriage of Goods by Rail (Appendix B to the Convention concerning International Carriage by Rail (COTIF)), as amended; "Closed container", see "Container"; "Closed vehicle" means a vehicle having a body capable of being closed; "Closure" means a device which closes an opening in a receptacle; "CMR" means the Convention on the Contract for the International Carriage of Goods by Road (Geneva, 19 May 1956), as amended; "Collective entry" means an entry for a well defined group of substances or articles (see 2.1.1.2, B, C and D); "Combination packaging" means a combination of packagings for transport purposes, consisting of one or more inner packagings secured in an outer packing in accordance with 4.1.1.5; NOTE: The "inners" of "combination packagings" are always termed "inner packagings" and not "inner receptacles". A glass bottle is an example of such an "inner packaging". - 17 - Copyright © United Nations, 2010. All rights reserved "Combustion heater" means a device directly using liquid or gaseous fuel and not using the waste heat from the engine used for propulsion of the vehicle; "Competent authority" means the authority or authorities or any other body or bodies designated as such in each State and in each specific case in accordance with domestic law; "Compliance assurance" (radioactive material) means a systematic programme of measures applied by a competent authority which is aimed at ensuring that the requirements of ADR are met in practice; "Composite IBC with plastics inner receptacle" means an IBC comprising structural equipment in the form of a rigid outer casing encasing a plastics inner receptacle together with any service or other structural equipment. It is so constructed that the inner receptacle and outer casing once assembled form, and are used as, an integrated single unit to be filled, stored, transported or emptied as such; NOTE: "Plastics material", when used in connection with inner receptacles for composite IBCs, is taken to include other polymeric materials such as rubber. "Composite packaging (plastics material)" is a packaging consisting of an inner plastics receptacle and an outer packaging (made of metal, fibreboard, plywood, etc.). Once assembled such a packaging remains thereafter an inseparable unit; it is filled, stored, despatched and emptied as such; NOTE: See NOTE under "Composite packagings (glass, porcelain or stoneware)". "Composite packaging (glass, porcelain or stoneware)" is a packaging consisting of an inner glass, porcelain or stoneware receptacle and an outer packaging (made of metal, wood, fibreboard, plastics material, expanded plastics material, etc.). Once assembled, such a packaging remains thereafter an inseparable unit; it is filled, stored, despatched and emptied as such; NOTE: The "inners" of "composite packagings" are normally termed "inner receptacles". For example, the "inner" of a 6HA1 (composite packaging, plastics material) is such an "inner receptacle" since it is normally not designed to perform a containment function without its "outer packaging" and is not therefore an "inner packaging". "Confinement system", for the carriage of Class 7 material, means the assembly of fissile material and packaging components specified by the designer and agreed to by the competent authority as intended to preserve criticality safety; "Conformity assessment" means the process of verifying the conformity of a product according to the provisions of sections 1.8.6 and 1.8.7 related to type approval, supervision of manufacture and initial inspection and testing; "Consignee" means the consignee according to the contract for carriage. If the consignee designates a third party in accordance with the provisions applicable to the contract for carriage, this person shall be deemed to be the consignee within the meaning of ADR. If the transport operation takes place without a contract for carriage, the enterprise which takes charge of the dangerous goods on arrival shall be deemed to be the consignee; "Consignment" means any package or packages, or load of dangerous goods, presented by a consignor for carriage; - 18 - Copyright © United Nations, 2010. All rights reserved "Consignor" means the enterprise which consigns dangerous goods either on its own behalf or for a third party. If the transport operation is carried out under a contract for carriage, consignor means the consignor according to the contract for carriage; "Container" means an article of transport equipment (lift van or other similar structure): - of a permanent character and accordingly strong enough to be suitable for repeated use; - specially designed to facilitate the carriage of goods, by one or more means of transport, without breakage of load; - fitted with devices permitting its ready stowage and handling, particularly when being transloaded from one means of transport to another; - so designed as to be easy to fill and empty; - having an internal volume of not less than 1 m3, except for containers for the carriage of radioactive material. In addition: "Small container" means a container which has either any overall outer dimension (length, width or height) less than 1.5 m, or an internal volume of not more than 3 m3; "Large container" means (a) A container which does not meet the definition of a small container; (b) In the meaning of the CSC, a container of a size such that the area enclosed by the four outer bottom corners is either (i) at least 14 m2 (150 square feet); or (ii) at least 7 m2 (75 square feet) if fitted with top corner fittings; "Closed container" means a totally enclosed container having a rigid roof, rigid side walls, rigid end walls and a floor. The term includes containers with an opening roof where the roof can be closed during transport; "Open container" means an open top container or a platform based container; "Sheeted container" means an open container equipped with a sheet to protect the goods loaded; A "swap body" is a container which, in accordance with EN 283:1991 has the following characteristics: - from the point of view of mechanical strength, it is only built for carriage on a wagon or a vehicle on land or by roll-on roll-of ship; - it cannot be stacked; - it can be removed from vehicles by means of equipment on board the vehicle and on its own supports, and can be reloaded; - 19 - Copyright © United Nations, 2010. All rights reserved NOTE: The term "container" does not cover conventional packagings, IBCs, tank-containers or vehicles. Nevertheless, a container may be used as a packaging for the carriage of radioactive material. "Containment system", for the carriage of Class 7 material, means the assembly of components of the packaging specified by the designer as intended to retain the radioactive material during carriage; "Control temperature" means the maximum temperature at which the organic peroxide or the self-reactive substance can be safely carried; "Conveyance" means, for carriage by road or by rail, a vehicle or a wagon; "Criticality safety index (CSI) assigned to a package, overpack or container containing fissile material", for the carriage of Class 7 material, means a number which is used to provide control over the accumulation of packages, overpacks or containers containing fissile material; "CSC" means the International Convention for Safe Containers (Geneva, 1972) as amended and published by the International Maritime Organization (IMO), London; "Crate" means an outer packaging with incomplete surfaces; "Critical temperature" means the temperature above which the substance cannot exist in the liquid state; "Cryogenic receptacle" means a transportable thermally insulated pressure receptacle for refrigerated liquefied gases of a water capacity of not more than 1 000 litres (see also "Open cryogenic receptacle"); "Cylinder" means a transportable pressure receptacle of a water capacity not exceeding 150 litres (see also "Bundle of cylinders"); D "Dangerous goods" means those substances and articles the carriage of which is prohibited by ADR, or authorized only under the conditions prescribed therein; "Dangerous reaction" means: (a) Combustion or evolution of considerable heat; (b) Evolution of flammable, asphyxiant, oxidizing or toxic gases; (c) The formation of corrosive substances; (d) The formation of unstable substances; or (e) Dangerous rise in pressure (for tanks only); "Demountable tank" means a tank, other than a fixed tank, a portable tank, a tank-container or an element of a battery-vehicle or a MEGC which has a capacity of more than 450 litres, is not designed for the carriage of goods without breakage of load, and normally can only be handled when it is empty; "Design", for the carriage of Class 7 material, means the description of special form radioactive material, low dispersible radioactive material, package or packaging which enables such an item to be fully identified. The description may include specifications, - 20 - Copyright © United Nations, 2010. All rights reserved engineering drawings, reports demonstrating compliance with regulatory requirements, and other relevant documentation; "Discharge pressure" means the maximum pressure actually built up in the tank when it is being discharged under pressure (see also "Calculation pressure", "Filling pressure", "Maximum working pressure (gauge pressure)" and "Test pressure"); "Drum" means a flat-ended or convex-ended cylindrical packaging made out of metal, fibreboard, plastics, plywood or other suitable materials. This definition also includes packagings of other shapes, e.g. round, taper-necked packagings or pail-shaped packagings. Wooden barrels and jerricans are not covered by this definition; E "EC Directive" means provisions decided by the competent institutions of the European Community and which are binding, as to the result to be achieved, upon each Member State to which it is addressed, but shall leave to the national authorities the choice of form and methods; "ECE Regulation" means a regulation annexed to the Agreement concerning the adoption of uniform technical prescriptions for wheeled vehicles equipment and parts which can be fitted and or used on wheeled vehicles and the conditions for reciprocal recognition of approvals granted on the basis of these prescriptions (1958 Agreement, as amended); "Emergency temperature" means the temperature at which emergency procedures shall be implemented in the event of loss of temperature control; "EN" (standard) means a European standard published by the European Committee for Standardization (CEN) (CEN, Avenue Marnix 17, B-1000 Brussels); "Enterprise" means any natural person, any legal person, whether profit-making or not, any association or group of persons without legal personality, whether profit-making or not, or any official body, whether it has legal personality itself or is dependent upon an authority that has such personality; "Exclusive use", for the carriage of Class 7 material, means the sole use, by a single consignor, of a vehicle or of a large container, in respect of which all initial, intermediate and final loading and unloading is carried out in accordance with the directions of the consignor or consignee; F "Fibreboard IBC" means a fibreboard body with or without separate top and bottom caps, if necessary an inner liner (but no inner packagings), and appropriate service and structural equipment; "Filler" means any enterprise which loads dangerous goods into a tank (tank-vehicle, demountable tank, portable tank or tank-container) and/or into a vehicle, large container or small container for carriage in bulk, or into a battery-vehicle or MEGC; "Filling pressure" means the maximum pressure actually built up in the tank when it is being filled under pressure (see also "Calculation pressure", "Discharge pressure", "Maximum working pressure (gauge pressure)" and "Test pressure"); "Filling ratio" means the ratio of the mass of gas to the mass of water at 15 °C that would fill completely a pressure receptacle fitted ready for use; - 21 - Copyright © United Nations, 2010. All rights reserved "Fixed tank" means a tank having a capacity of more than 1 000 litres which is permanently attached to a vehicle (which then becomes a tank-vehicle) or is an integral part of the frame of such vehicle; "Flammable component" (for aerosols) means flammable liquids, flammable solids or flammable gases and gas mixtures as defined in Notes 1 to 3 of sub-section 31.1.3 of Part III of the Manual of Tests and Criteria. This designation does not cover pyrophoric, self-heating or water-reactive substances. The chemical heat of combustion shall be determined by one of the following methods ASTM D 240, ISO/FDIS 13943:1999 (E/F) 86.1 to 86.3 or NFPA 30B; "Flash-point" means the lowest temperature of a liquid at which its vapours form a flammable mixture with air; "Flexible IBC" means a body constituted of film, woven fabric or any other flexible material or combinations thereof, and if necessary, an inner coating or liner, together with any appropriate service equipment and handling devices; "Fuel cell" means an electrochemical device that converts the chemical energy of a fuel to electrical energy, heat and reaction products; "Fuel cell engine" means a device used to power equipment and which consists of a fuel cell and its fuel supply, whether integrated with or separate from the fuel cell, and includes all appurtenances necessary to fulfil its function; "Full load" means any load originating from one consignor for which the use of a vehicle or of a large container is exclusively reserved and all operations for the loading and unloading of which are carried out in conformity with the instructions of the consignor or of the consignee; NOTE: The corresponding term for Class 7 is "exclusive use". G "Gas" means a substance which: (a) At 50 °C has a vapour pressure greater than 300 kPa (3 bar); or (b) Is completely gaseous at 20 °C under standard pressure of 101.3 kPa; "Gas cartridge", see "Small receptacle containing gas"; "GHS" means the third revised edition of the Globally Harmonized System of Classification and Labelling of Chemicals, published by the United Nations as document ST/SG/AC.10/30/Rev.3; H "Handling device" (for flexible IBCs) means any sling, loop, eye or frame attached to the body of the IBC or formed from the continuation of the IBC body material; "Hermetically closed tank" means a tank intended for the carriage of liquid substances with a calculation pressure of at least 4 bar or intended for the carriage of solid substances (powdery or granular) regardless of its calculation pressure, the openings of which are hermetically closed and which: - 22 - Copyright © United Nations, 2010. All rights reserved - is not equipped with safety valves, bursting discs, other similar safety devices or vacuum valves; or - is not equipped with safety valves, bursting discs or other similar safety devices, but is equipped with vacuum valves, in accordance with the requirements of 6.8.2.2.3; or - is equipped with safety valves preceded by a bursting disc according to 6.8.2.2.10, but is not equipped with vacuum valves; or - is equipped with safety valves preceded by a bursting disc according to 6.8.2.2.10 and vacuum valves, in accordance with the requirements of 6.8.2.2.3; I "IAEA" means the International Atomic Energy Agency (IAEA), (IAEA, P.O. Box 100 – A 1400 Vienna); "IBC", see "Intermediate bulk container"; "ICAO" means the International Civil Aviation Organization (ICAO, 999 University Street, Montreal, Quebec H3C 5H7, Canada); "ICAO Technical Instructions" means the Technical Instructions for the Safe Transport of Dangerous Goods by Air, which complement Annex 18 to the Chicago Convention on International Civil Aviation (Chicago 1944), published by the International Civil Aviation Organization (ICAO) in Montreal; "IMDG Code" means the International Maritime Dangerous Goods Code, for the implementation of Chapter VII, Part A, of the International Convention for the Safety of Life at Sea, 1974 (SOLAS Convention), published by the International Maritime Organization (IMO), London; "IMO" means the International Maritime Organization (IMO, 4 Albert Embankment, London SE1 7SR, United Kingdom); "Inner packaging" means a packaging for which an outer packaging is required for carriage; "Inner receptacle" means a receptacle which requires an outer packaging in order to perform its containment function; "Inspection body" means an independent inspection and testing body approved by the competent authority; "Intermediate bulk container" (IBC) means a rigid, or flexible portable packaging, other than those specified in Chapter 6.1, that: (a) Has a capacity of: (i) not more than 3 m3 for solids and liquids of packing groups II and III; (ii) not more than 1.5 m3 for solids of packing group I when packed in flexible, rigid plastics, composite, fibreboard and wooden IBCs; (iii) not more than 3 m3 for solids of packing group I when packed in metal IBCs; (iv) not more than 3 m3 for radioactive material of Class 7; - 23 - Copyright © United Nations, 2010. All rights reserved (b) Is designed for mechanical handling; (c) Is resistant to the stresses produced in handling and transport as determined by the tests specified in Chapter 6.5; (see also "Composite IBC with plastics inner receptacle", "Fibreboard IBC", "Flexible IBC", "Metal IBC", "Rigid plastics IBC" and "Wooden IBC"). NOTE 1: Portable tanks or tank-containers that meet the requirements of Chapter 6.7 or 6.8 respectively are not considered to be intermediate bulk containers (IBCs). NOTE 2: Intermediate bulk containers (IBCs) which meet the requirements of Chapter 6.5 are not considered to be containers for the purposes of ADR. "Remanufactured IBC" means a metal, rigid plastics or composite IBC that: (a) Is produced as a UN type from a non-UN type; or (b) Is converted from one UN design type to another UN design type. Remanufactured IBCs are subject to the same requirements of ADR that apply to new IBCs of the same type (see also design type definition in 6.5.6.1.1); "Repaired IBC" means a metal, rigid plastics or composite IBC that, as a result of impact or for any other cause (e.g. corrosion, embrittlement or other evidence of reduced strength as compared to the design type) is restored so as to conform to the design type and to be able to withstand the design type tests. For the purposes of ADR, the replacement of the rigid inner receptacle of a composite IBC with a receptacle conforming to the original design type from the same manufacturer is considered repair. However, routine maintenance of rigid IBCs is not considered repair. The bodies of rigid plastics IBCs and the inner receptacles of composite IBCs are not repairable. Flexible IBCs are not repairable unless approved by the competent authority; "Routine maintenance of flexible IBCs" means the routine performance on plastics or textile flexible IBCs of operations, such as: (a) Cleaning; or (b) Replacement of non-integral components, such as non-integral liners and closure ties, with components conforming to the original manufacturer's specification; provided that these operations do not adversely affect the containment function of the flexible IBC or alter the design type. "Routine maintenance of rigid IBCs" means the routine performance on metal, rigid plastics or composite IBCs of operations such as: (a) Cleaning; (b) Removal and reinstallation or replacement of body closures (including associated gaskets), or of service equipment, conforming to the original manufacturer’s specifications, provided that the leaktightness of the IBC is verified; or (c) Restoration of structural equipment not directly performing a dangerous goods containment or discharge pressure retention function so as to conform to the design type (e.g. the straightening of legs or lifting attachments) provided that the containment function of the IBC is not affected; - 24 - Copyright © United Nations, 2010. All rights reserved "Intermediate packaging" means a packaging placed between inner packagings or articles, and an outer packaging; "ISO" (standard) means an international standard published by the International Organization for Standardization (ISO) (ISO - 1, rue de Varembé. CH-1204 Geneva 20); J "Jerrican" means a metal or plastics packaging of rectangular or polygonal cross-section with one or more orifices; L "Large container ", see "Container"; "Large packaging" means a packaging consisting of an outer packaging which contains articles or inner packagings and which (a) Is designed for mechanical handling; (b) Exceeds 400 kg net mass or 450 litres capacity but has a volume of not more than 3 m3; "Leakproofness test" means a test to determine the leakproofness of a tank, a packaging or an IBC and of the equipment and closure devices; NOTE: For portable tanks, see Chapter 6.7. "Light-gauge metal packaging" means a packaging of circular, elliptical, rectangular or polygonal cross-section (also conical) and taper-necked and pail-shaped packaging made of metal, having a wall thickness of less than 0.5 mm (e.g. tinplate), flat or convex bottomed and with one or more orifices, which is not covered by the definitions for drums or jerricans; "Liner" means a tube or bag inserted into a packaging, including large packagings or IBCs, but not forming an integral part of it, including the closures of its openings; "Liquid" means a substance which at 50 °C has a vapour pressure of not more than 300 kPa (3 bar), which is not completely gaseous at 20 °C and 101.3 kPa, and which (a) Has a melting point or initial melting point of 20 °C or less at a pressure of 101.3 kPa; or (b) Is liquid according to the ASTM D 4359-90 test method; or (c) Is not pasty according to the criteria applicable to the test for determining fluidity (penetrometer test) described in 2.3.4; NOTE: "Carriage in the liquid state", for the purpose of tank requirements, means: - Carriage of liquids according to the above definition; or - Solids handed over for carriage in the molten state. "Loader" means any enterprise which: (a) Loads packaged dangerous goods, small containers or portable tanks into or onto a vehicle or a container; or (b) Loads a container, bulk-container, MEGC, tank-container or portable tank onto a vehicle. - 25 - Copyright © United Nations, 2010. All rights reserved M "Manual of Tests and Criteria" means the fifth revised edition of the Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, published by the United Nations (ST/SG/AC.10/11/Rev.5); "Mass of package" means gross mass of the package unless otherwise stated. The mass of containers and tanks used for the carriage of goods is not included in the gross mass; "Maximum capacity" means the maximum inner volume of receptacles or packagings including intermediate bulk containers (IBCs) and large packagings expressed in cubic metres or litres; "Maximum net mass" means the maximum net mass of contents in a single packaging or maximum combined mass of inner packagings and the contents thereof expressed in kilograms; "Maximum normal operating pressure", for the carriage of Class 7 material, means the maximum pressure above atmospheric pressure at mean sea-level that would develop in the containment system in a period of one year under the conditions of temperature and solar radiation corresponding to environmental conditions in the absence of venting, external cooling by an ancillary system, or operational controls during carriage; "Maximum permissible gross mass" (a) (for all categories of IBCs other than flexible IBCs) means the mass of the IBC and any service or structural equipment together with the maximum net mass; (b) (for tanks) means the tare of the tank and the heaviest load authorized for carriage; NOTE: For portable tanks, see Chapter 6.7. "Maximum permissible load" (for flexible IBCs) means the maximum net mass for which the IBC is intended and which it is authorized to carry; "Maximum working pressure (gauge pressure)" means the highest of the following three pressures: (a) The highest effective pressure allowed in the tank during filling (maximum filling pressure allowed); (b) The highest effective pressure allowed in the tank during discharge (maximum discharge pressure allowed); and (c) The effective gauge pressure to which the tank is subjected by its contents (including such extraneous gases as it may contain) at the maximum working temperature. Unless the special requirements prescribed in Chapter 4.3 provide otherwise, the numerical value of this working pressure (gauge pressure) shall not be lower than the vapour pressure (absolute pressure) of the filling substance at 50 °C. For tanks equipped with safety valves (with or without bursting disc) other than tanks for the carriage of compressed, liquefied or dissolved gases of Class 2, the maximum working pressure (gauge pressure) shall however be equal to the prescribed opening pressure of such safety valves. - 26 - Copyright © United Nations, 2010. All rights reserved (See also "Calculation pressure", "Discharge pressure", "Filling pressure" and "Test pressure"); NOTE 1: For portable tanks, see Chapter 6.7. NOTE 2: For closed cryogenic receptacles, see NOTE to 6.2.1.3.6.5. "MEGC", see "Multiple-element gas container"; "Member of a vehicle crew" means a driver or any other person accompanying the driver for safety, security, training or operational reasons; "MEMU", see "Mobile explosives manufacturing unit"; "Metal hydride storage system" means a single complete hydrogen storage system, including a receptacle, metal hydride, pressure relief device, shut-off valve, service equipment and internal components used for the carriage of hydrogen only; "Metal IBC" means a metal body together with appropriate service and structural equipment; "Mild steel" means a steel having a minimum tensile strength between 360 N/mm2 and 440 N/mm2; NOTE: For portable tanks, see Chapter 6.7. "Mobile explosives manufacturing unit" (MEMU) means a unit, or a vehicle mounted with a unit, for manufacturing and charging explosives from dangerous goods that are not explosives. The unit consists of various tanks and bulk containers and process equipment as well as pumps and related equipment. The MEMU may have special compartments for packaged explosives; NOTE: Even though the definition of MEMU includes the expression "manufacturing and charging explosives" the requirements for MEMUs apply only to carriage and not to manufacturing and charging of explosives. "Multiple-element gas container" (MEGC) means a unit containing elements which are linked to each other by a manifold and mounted on a frame. The following elements are considered to be elements of a multiple-element gas container: cylinders, tubes, pressure drums and bundles of cylinders as well as tanks for the carriage of gases as defined in 2.2.2.1.1 having a capacity of more than 450 litres; NOTE: For UN MEGCs, see Chapter 6.7. N "Nominal capacity of the receptacle" means the nominal volume of the dangerous substance contained in the receptacle expressed in litres. For compressed gas cylinders the nominal capacity shall be the water capacity of the cylinder; "N.O.S. entry (not otherwise specified entry)" means a collective entry to which substances, mixtures, solutions or articles may be assigned if they: (a) Are not mentioned by name in Table A of Chapter 3.2; and (b) Exhibit chemical, physical and/or dangerous properties corresponding to the Class, classification code, packing group and the name and description of the n.o.s. entry; - 27 - Copyright © United Nations, 2010. All rights reserved O "Offshore bulk container" means a bulk container specially designed for repeated use for carriage to, from and between offshore facilities. An offshore bulk container is designed and constructed in accordance with the guidelines for the approval of offshore containers handled in open seas specified by the International Maritime Organization (IMO) in document MSC/Circ.860; "Open container", see "Container"; "Open cryogenic receptacle" means a transportable thermally insulated receptacle for refrigerated liquefied gases maintained at atmospheric pressure by continuous venting of the refrigerated liquefied gas; "Open vehicle" means a vehicle the platform of which has no superstructure or is merely provided with side boards and a tailboard; "Outer packaging" means the outer protection of the composite or combination packaging together with any absorbent materials, cushioning and any other components necessary to contain and protect inner receptacles or inner packagings; "Overpack" means an enclosure used (by a single consignor in the case of Class 7) to contain one or more packages, consolidated into a single unit easier to handle and stow during carriage; Examples of overpacks: (a) A loading tray such as a pallet, on which several packages are placed or stacked and secured by a plastics strip, shrink or stretch wrapping or other appropriate means; or (b) An outer protective packaging such as a box or a crate; P "Package" means the complete product of the packing operation, consisting of the packaging or large packaging or IBC and its contents prepared for dispatch. The term includes receptacles for gases as defined in this section as well as articles which, because of their size, mass or configuration may be carried unpackaged or carried in cradles, crates or handling devices. Except for the carriage of radioactive material, the term does not apply to goods which are carried in bulk, nor to substances carried in tanks; NOTE: For radioactive material, see 2.2.7.2, 4.1.9.1.1 and Chapter 6.4. "Packaging" means one or more receptacles and any other components or materials necessary for the receptacles to perform their containment and other safety functions (see also "Combination packaging", "Composite packaging (plastics material)", "Composite packaging (glass, porcelain or stoneware)", "Inner packaging", "Intermediate bulk container (IBC)", "Intermediate packaging", "Large packaging", "Light-gauge metal packaging", "Outer packaging", "Reconditioned packaging", "Remanufactured packaging", "Reused packaging", "Salvage packaging" and "Sift-proof packaging"); "Packer" means any enterprise which puts dangerous goods into packagings, including large packagings and intermediate bulk containers (IBCs) and, where necessary, prepares packages for carriage; - 28 - Copyright © United Nations, 2010. All rights reserved "Packing group" means a group to which, for packing purposes, certain substances may be assigned in accordance with their degree of danger. The packing groups have the following meanings which are explained more fully in Part 2: Packing group I: Substances presenting high danger; Packing group II: Substances presenting medium danger; and Packing group III: Substances presenting low danger; NOTE: Certain articles containing dangerous goods are assigned to a packing group. "Portable tank" means a multimodal tank having, when used for the carriage of gases as defined in 2.2.2.1.1, a capacity of more than 450 litres in accordance with the definitions in Chapter 6.7 or the IMDG Code and indicated by a portable tank instruction (T-Code) in Column (10) of Table A of Chapter 3.2; "Portable tank operator", see "Tank-container/portable tank operator"; "Pressure drum" means a welded transportable pressure receptacle of a water capacity exceeding 150 litres and of not more than1 000 litres, (e.g. cylindrical receptacles equipped with rolling hoops, spheres on skids);" "Pressure receptacle" means a collective term that includes cylinders, tubes, pressure drums, closed cryogenic receptacles, metal hydride storage systems and bundles of cylinders; "Pressurized gas cartridge", see "Aerosol or aerosol dispenser"; "Protected IBC" (for metal IBCs) means an IBC provided with additional protection against impact, the protection taking the form of, for example, a multi-layer (sandwich) or doublewall construction, or a frame with a metal lattice-work casing; Q "Quality assurance" means a systematic programme of controls and inspections applied by any organization or body which is aimed at providing confidence that the safety prescriptions in ADR are met in practice; R "Radiation level", for the carriage of Class 7 material, means the corresponding dose rate expressed in millisieverts per hour; "Radioactive contents", for the carriage of Class 7 material, mean the radioactive material together with any contaminated or activated solids, liquids, and gases within the packaging; "Receptacle" (Class 1) includes boxes, bottles, cans, drums, jars and tubes, including any means of closure used in the inner or intermediate packaging; "Receptacle" means a containment vessel for receiving and holding substances or articles, including any means of closing. This definition does not apply to shells (see also "Cryogenic receptacle", "Inner receptacle", "Pressure receptacle", "Rigid inner receptacle" and "Gas cartridge"); - 29 - Copyright © United Nations, 2010. All rights reserved "Reconditioned packaging" means in particular (a) (b) Metal drums that are: (i) cleaned to original materials of construction, with all former contents, internal and external corrosion, and external coatings and labels removed; (ii) restored to original shape and contour, with chimes (if any) straightened and sealed and all non-integral gaskets replaced; and (iii) inspected after cleaning but before painting, with rejection of packagings with visible pitting, significant reduction in the material thickness, metal fatigue, damaged threads or closures or other significant defects; Plastics drums and jerricans that: (i) are cleaned to original materials of construction, with all former contents, external coatings and labels removed; (ii) have all non-integral gaskets replaced; and (iii) are inspected after cleaning with rejection of packagings with visible damage such as tears, creases or cracks, or damaged threads or closures or other significant defects; "Recycled plastics material" means material recovered from used industrial packagings that has been cleaned and prepared for processing into new packagings; "Reel" (Class 1) means a device made of plastics, wood, fibreboard, metal or other suitable material comprising a central spindle with, or without, side walls at each end of the spindle. Articles and substances can be wound onto the spindle and may be retained by side walls; "Reference steel" means a steel with a tensile strength of 370 N/mm2 and an elongation at fracture of 27%; "Remanufactured IBC", see "Intermediate Bulk Container (IBC)"; "Remanufactured large packaging" means a metal or rigid plastics large packaging that: (a) Is produced as a UN type from a non-UN type; or (b) Is converted from one UN design type to another UN design type. Remanufactured large packagings are subject to the same requirements of ADR that apply to new large packagings of the same type (see also design type definition in 6.6.5.1.2); "Remanufactured packaging" means in particular (a) Metal drums that: (i) are produced as a UN type complying with the requirements of Chapter 6.1 from a non-UN type; (ii) are converted from one UN type complying with the requirements of Chapter 6.1 to another UN type; or (iii) undergo the replacement of integral structural components (such as nonremovable heads); - 30 - Copyright © United Nations, 2010. All rights reserved (b) Plastics drums that: (i) are converted from one UN type to another UN type (e.g. 1H1 to 1H2); or (ii) undergo the replacement of integral structural components. Remanufactured drums are subject to the requirements of Chapter 6.1 which apply to new drums of the same type; "Repaired IBC", see "Intermediate Bulk Container (IBC)"; "Reused large packaging" means a large packaging to be refilled which has been examined and found free of defects affecting the ability to withstand the performance tests; the term includes those which are refilled with the same or similar compatible contents and are carried within distribution chains controlled by the consignor of the product; "Reused packaging" means a packaging which has been examined and found free of defects affecting the ability to withstand the performance tests. The term includes those which are refilled with the same or similar compatible contents and are carried within distribution chains controlled by the consignor of the product; "RID" means Regulations concerning the International Carriage of Dangerous Goods by Rail (Appendix C of COTIF (Convention concerning international carriage by rail)); "Rigid inner receptacle" (for composite IBCs) means a receptacle which retains its general shape when empty without its closures in place and without benefit of the outer casing. Any inner receptacle that is not "rigid" is considered to be "flexible"; "Rigid plastics IBC" means a rigid plastics body, which may have structural equipment together with appropriate service equipment; "Routine maintenance of flexible IBCs", see "Intermediate Bulk Container (IBC)"; "Routine maintenance of rigid IBCs", see "Intermediate Bulk Container (IBC)"; S "Safety valve" means a spring-loaded device which is activated automatically by pressure the purpose of which is to protect the tank against unacceptable excess internal pressure; "SADT" see "Self-accelerating decomposition temperature"; "Salvage packaging" means a special packaging into which damaged, defective or leaking dangerous goods packages, or dangerous goods that have spilled or leaked are placed for purposes of carriage for recovery or disposal; "Self-accelerating decomposition temperature" (SADT), means the lowest temperature at which self-accelerating decomposition may occur with substance in the packaging as used during carriage. Provisions for determining the SADT and the effects of heating under confinement are contained in Part II of the Manual of Tests and Criteria; "Service equipment" (a) Of the tank means filling and emptying, venting, safety, heating and heat insulating devices and measuring instruments; - 31 - Copyright © United Nations, 2010. All rights reserved (b) Of the elements of a battery-vehicle or of a MEGC means filling and emptying devices, including the manifold, safety devices and measuring instruments; (c) Of an IBC means the filling and discharge devices and any pressure-relief or venting, safety, heating and heat insulating devices and measuring instruments; NOTE: For portable tanks, see Chapter 6.7. "Settled pressure" means the pressure of the contents of a pressure receptacle in thermal and diffusive equilibrium; "Sheeted container", see "Container"; "Sheeted vehicle" means an open vehicle provided with a sheet to protect the load; "Shell" means the sheathing containing the substance (including the openings and their closures); NOTE 1: This definition does not apply to receptacles. NOTE 2: For portable tanks, see Chapter 6.7. "Sift-proof packaging" means a packaging impermeable to dry contents, including fine solid material produced during carriage; "Small container", see "Container"; "Small receptacle containing gas (gas cartridge)" means a non-refillable receptacle meeting the relevant requirements of 6.2.6 containing, under pressure, a gas or a mixture of gases. It may be fitted with a valve; "Solid" means: (a) A substance with a melting point or initial melting point of more than 20 °C at a pressure of 101.3 kPa; or (b) A substance which is not liquid according to the ASTM D 4359-90 test method or which is pasty according to the criteria applicable to the test for determining fluidity (penetrometer test) described in 2.3.4; "Structural equipment" (a) For tanks of a tank-vehicle or demountable tank, means the external or internal reinforcing, fastening, protective or stabilizing members of the shell; (b) For tanks of a tank-container, means the external or internal reinforcing, fastening, protective or stabilizing members of the shell; (c) For elements of a battery-vehicle or an MEGC means the external or internal reinforcing, fastening, protective or stabilizing members of the shell or receptacle; (d) For IBCs other than flexible IBCs means the reinforcing, fastening, handling, protective or stabilizing members of the body (including the base pallet for composite IBCs with plastics inner receptacle); NOTE: For portable tanks, see Chapter 6.7. "Swap body", see "Container"; - 32 - Copyright © United Nations, 2010. All rights reserved T "Tank" means a shell, including its service and structural equipment. When used alone, the term tank means a tank-container, portable tank, demountable tank or fixed tank as defined in this Part, including tanks forming elements of battery-vehicles or MEGCs (see also "Demountable tank", "Fixed tank", "Portable tank" and "Multiple-element gas container"); NOTE: For portable tanks, see 6.7.4.1. "Tank-container" means an article of transport equipment meeting the definition of a container, and comprising a shell and items of equipment, including the equipment to facilitate movement of the tank-container without significant change of attitude, used for the carriage of gases, liquid, powdery or granular substances and, when used for the carriage of gases as defined in 2.2.2.1.1, having a capacity of more than 0.45 m3 (450 litres); NOTE: IBCs which meet the requirements of Chapter 6.5 are not considered to be tankcontainers. "Tank-container/portable tank operator" means any enterprise in whose name the tankcontainer/portable tank is registered; "Tank record" means a file containing all the important technical information concerning a tank, a battery-vehicle or a MEGC, such as certificates referred to in 6.8.2.3, 6.8.2.4 and 6.8.3.4; "Tank swap body" is considered to be a tank-container; "Tank-vehicle" means a vehicle built to carry liquids, gases or powdery or granular substances and comprising one or more fixed tanks. In addition to the vehicle proper, or the units of running gear used in its stead, a tank-vehicle comprises one or more shells, their items of equipment and the fittings for attaching them to the vehicle or to the running-gear units; "Technical name" means a recognized chemical name, if relevant a biological name, or other name currently used in scientific and technical handbooks, journals and texts (see 3.1.2.8.1.1); "Test pressure" means the required pressure applied during a pressure test for initial or periodic inspection (see also "Calculation pressure", "Discharge pressure", "Filling pressure" and "Maximum working pressure (gauge pressure)"); NOTE: For portable tanks, see Chapter 6.7. "Through or into", for the carriage of Class 7 material, means through or into the countries in which a consignment is carried but specifically excludes countries "over" which a consignment is carried by air provided that there are no scheduled stops in those countries; "Transport index (TI) assigned to a package, overpack or container, or to unpackaged LSA-I or SCO-I", for the carriage of Class 7 material, means a number which is used to provide control over radiation exposure; "Transport unit" means a motor vehicle without an attached trailer, or a combination consisting of a motor vehicle and an attached trailer; "Tray" (Class 1) means a sheet of metal, plastics, fibreboard or other suitable material which is placed in the inner, intermediate or outer packaging and achieves a close-fit in such - 33 - Copyright © United Nations, 2010. All rights reserved packaging. The surface of the tray may be shaped so that packagings or articles can be inserted, held secure and separated from each other; "Tube" (Class 2) means a seamless transportable pressure receptacle of a water capacity exceeding 150 litres and of not more than 3 000 litres; U "UIC" means the International Union of Railways (UIC, 16 rue Jean Rey, F-75015 Paris, France); "UNECE" means the United Nations Economic Commission for Europe (UNECE, Palais des Nations, 8-14 avenue de la Paix, CH-1211 Geneva 10, Switzerland); "Undertaking", see "Enterprise"; "Unloader" means any enterprise which: (a) Removes a container, bulk-container, MEGC, tank-container or portable tank from a vehicle; or (b) Unloads packaged dangerous goods, small containers or portable tanks out of or from a vehicle or a container; or (c) Discharges dangerous goods from a tank (tank-vehicle, demountable tank, portable tank or tank-container) or from a battery-vehicle, MEMU or MEGC or from a vehicle, large container or small container for carriage in bulk or a bulk-container; "UN Model Regulations" means the Model Regulations annexed to the sixteenth revised edition of the Recommendations on the Transport of Dangerous Goods published by the United Nations (ST/SG/AC.10/1/Rev.16); "UN number" means the four-figure identification number of the substance or article taken from the UN Model Regulations; V "Vacuum-operated waste tank" means a fixed tank, demountable tank, tank-container or tank swap body primarily used for the carriage of dangerous wastes, with special constructional features and/or equipment to facilitate the loading and unloading of wastes as specified in Chapter 6.10. A tank which fully complies with the requirements of Chapter 6.7 or 6.8 is not considered to be a vacuum-operated waste tank; "Vacuum valve" means a spring-loaded device which is activated automatically by pressure the purpose of which is to protect the tank against unacceptable negative internal pressure; "Vehicle" see "Battery-vehicle", "Closed vehicle", "Open vehicle", "Sheeted vehicle" and "Tank-vehicle"; W "Wastes" means substances, solutions, mixtures or articles for which no direct use is envisaged but which are transported for reprocessing, dumping, elimination by incineration or other methods of disposal; - 34 - Copyright © United Nations, 2010. All rights reserved "Wooden barrel" means a packaging made of natural wood, of round cross-section, having convex walls, consisting of staves and heads and fitted with hoops; "Wooden IBC" means a rigid or collapsible wooden body, together with an inner liner (but no inner packaging) and appropriate service and structural equipment; "Working pressure" means the settled pressure of a compressed gas at a reference temperature of 15 °C in a full pressure receptacle; NOTE: For tanks, see "Maximum working pressure". "Woven plastics" (for flexible IBCs) means a material made from stretch tapes or monofilaments of suitable plastics material. - 35 - Copyright © United Nations, 2010. All rights reserved 1.2.2 Units of measurement 1.2.2.1 The following units of measurement a are applicable in ADR: SI Unit b Measurement of Length Area Volume Time m (metre) m2 (square metre) m3 (cubic metre) s (second) Mass kg (kilogram) Mass density Temperature Temperature difference Force Pressure kg/m3 K (kelvin) K (kelvin) N (newton) Pa (pascal) Stress Work Energy Quantity of heat Power Kinematic viscosity Dynamic viscosity Activity Dose equivalent N/m2 a Acceptable alternative unit l c (litre) min (minute) h (hour) d (day) g (gram) t (ton) kg/l °C (degree Celsius) °C (degree Celsius) bar (bar) N/mm2 kWh (kilowatt hours) J (joule) eV (electronvolt) mm2/s mPa.s W (watt) m2/s Pa.s Bq (becquerel) Sv (sievert) Relationship between units 1 l = 10-3 m3 1 min = 60 s 1 h = 3 600 s 1 d = 86 400 s 1g = 10-3 kg 1 t = 103 kg 1 kg/l = 103 kg/m3 0 °C = 273.15 K 1 °C = 1 K 1 N = 1 kg.m/s2 1 Pa = 1 N/m2 1 bar = 105 Pa 1 N/mm2 = 1 MPa 1 kWh = 3.6 MJ 1 J = 1 N.m = 1 W.s 1 eV = 0.1602 Η 10-18J 1 W = 1 J/s = 1 N.m/s 1 mm2/s = 10-6 m2/s 1 mPa.s = 10-3 Pa.s The following round figures are applicable for the conversion of the units hitherto used into SI Units. Force 1 kg 1N = = 9.807 N 0.102 kg Pressure 1 Pa 1 bar 1 kg/cm2 1 torr = = = = 1 N/m2 105 Pa 9.807 × 104 Pa 1.33 × 102 Pa Stress 1 kg/mm2 1 N/mm2 = 9.807 N/mm2 = 0.102 kg/mm2 = = = = 10-5 bar 1.02 kg/cm2 0.9807 bar 1.33 × 10-3 bar = = = = 1.02 × 10-5 kg/cm2 750 torr 736 torr 1.36 × 10-3 kg/cm2 = 0.75 × 10-2 torr Energy, Work, Quantity of heat 1J = 1 N.m 1 kWh = 3.6 × 106 J 1 kgm = 9.807 J 1 kcal = 4.19 × 103 J = = = = 0.278 × 10-6 kWh 367 × 103 kgm 2.72 × 10-6 kWh 1.16 × 10-3 kWh = = = = 0.102 kgm 860 kcal 2.34 × 10-3 kcal 427 kgm = 0.239 × 10-3 kcal Power 1W = 1 kgm/s = 1 kcal/h = = = = 0.86 kcal/h 8.43 kcal/h 0.119 kgm/s = = = 10 P (poise) 0.1 N.s/m2 9.807 N.s/m2 0.102 kgm/s 9.807 W 1.16 W Dynamic viscosity 1 Pa.s = 1 N.s/m2 1P = 0.1 Pa.s 1 kg.s/m2 = 9.807 Pa.s Kinematic viscosity 1 m2/s = 104 St (Stokes) 1 St = 10-4 m2/s = = = - 36 - 0.102 kg.s/m2 1.02 × 10-2 kg.s/m2 98.07 P Copyright © United Nations, 2010. All rights reserved b The International System of Units (SI) is the result of decisions taken at the General Conference on Weights and Measures (Address: Pavillon de Breteuil, Parc de St-Cloud, F-92 310 Sèvres). c The abbreviation "L" for litre may also be used in place of the abbreviation "l" when a typewriter cannot distinguish between figure "1" and letter "l". The decimal multiples and sub-multiples of a unit may be formed by prefixes or symbols, having the following meanings, placed before the name or symbol of the unit: Factor 1 000 000 000 000 000 000 1 000 000 000 000 000 1 000 000 000 000 1 000 000 000 1 000 000 1 000 100 10 0.1 0.01 0.001 0.000 001 0.000 000 001 0.000 000 000 001 0.000 000 000 000 001 0.000 000 000 000 000 001 = 1018 = 1015 = 1012 = 109 = 106 = 103 = 102 = 101 = 10-1 = 10-2 = 10-3 = 10-6 = 10-9 = 10-12 = 10-15 = 10-18 quintillion quadrillion trillion billion million thousand hundred ten tenth hundredth thousandth millionth billionth trillionth quadrillionth quintillionth Prefix Symbol exa peta tera giga mega kilo hecto deca deci centi milli micro nano pico femto atto E P T G M k h da d c m μ n p f a NOTE: 109 billion is United Nations usage in English. By analogy, so is 10-9 = 1 billionth. 1.2.2.2 Unless expressly stated otherwise, the sign "%" in ADR represents: (a) In the case of mixtures of solids or of liquids, and also in the case of solutions and of solids wetted by a liquid, a percentage mass based on the total mass of the mixture, the solution or the wetted solid; (b) In the case of mixtures of compressed gases, when filled by pressure, the proportion of the volume indicated as a percentage of the total volume of the gaseous mixture, or, when filled by mass, the proportion of the mass indicated as a percentage of the total mass of the mixture; (c) In the case of mixtures of liquefied gases and dissolved gases, the proportion of the mass indicated as a percentage of the total mass of the mixture. 1.2.2.3 Pressures of all kinds relating to receptacles (such as test pressure, internal pressure, safety valve opening pressure) are always indicated in gauge pressure (pressure in excess of atmospheric pressure); however, the vapour pressure of substances is always expressed in absolute pressure. 1.2.2.4 Where ADR specifies a degree of filling for receptacles, this is always related to a reference temperature of the substances of 15 °C, unless some other temperature is indicated. - 37 - Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved CHAPTER 1.3 TRAINING OF PERSONS INVOLVED IN THE CARRIAGE OF DANGEROUS GOODS 1.3.1 Scope and applicability Persons employed by the participants referred to in Chapter 1.4, whose duties concern the carriage of dangerous goods, shall be trained in the requirements governing the carriage of such goods appropriate to their responsibilities and duties. Employees shall be trained in accordance with 1.3.2 before assuming responsibilities and shall only perform functions, for which required training has not yet been provided, under the direct supervision of a trained person. Training requirements specific to security of dangerous goods in Chapter 1.10 shall also be addressed. NOTE 1: With regard to the training for the safety adviser, see 1.8.3. NOTE 2: With regard to the training of the vehicle crew, see Chapter 8.2. NOTE 3: For training with regard to Class 7, see also 1.7.2.5. NOTE 4: The training shall be effected before taking on responsibilities concerning the carriage of dangerous goods. 1.3.2 Nature of the training The training shall take the following form, appropriate to the responsibility and duties of the individual concerned. 1.3.2.1 General awareness training Personnel shall be familiar with the general requirements of the provisions for the carriage of dangerous goods. 1.3.2.2 Function-specific training Personnel shall be trained, commensurate directly with their duties and responsibilities in the requirements of the regulations concerning the carriage of dangerous goods. Where the carriage of dangerous goods involves a multimodal transport operation, the personnel shall be aware of the requirements concerning other transport modes. 1.3.2.3 Safety training Commensurate with the degree of risk of injury or exposure arising from an incident involving the carriage of dangerous goods, including loading and unloading, personnel shall be trained in the hazards and dangers presented by dangerous goods. The training provided shall aim to make personnel aware of the safe handling and emergency response procedures. 1.3.2.4 The training shall be periodically supplemented with refresher training to take account of changes in regulations. - 39 - Copyright © United Nations, 2010. All rights reserved 1.3.3 Documentation Records of training received according to this Chapter shall be kept by the employer and made available to the employee or competent authority, upon request. Records shall be kept by the employer for a period of time established by the competent authority. Records of training shall be verified upon commencing a new employment. - 40 - Copyright © United Nations, 2010. All rights reserved CHAPTER 1.4 SAFETY OBLIGATIONS OF THE PARTICIPANTS 1.4.1 General safety measures 1.4.1.1 The participants in the carriage of dangerous goods shall take appropriate measures according to the nature and the extent of foreseeable dangers, so as to avoid damage or injury and, if necessary, to minimize their effects. They shall, in all events, comply with the requirements of ADR in their respective fields. 1.4.1.2 When there is an immediate risk that public safety may be jeopardized, the participants shall immediately notify the emergency services and shall make available to them the information they require to take action. 1.4.1.3 ADR may specify certain of the obligations falling to the various participants. If a Contracting Party considers that no lessening of safety is involved, it may in its domestic legislation transfer the obligations falling to a specific participant to one or several other participants, provided that the obligations of 1.4.2 and 1.4.3 are met. These derogations shall be communicated by the Contracting Party to the Secretariat of the United Nations Economic Commission for Europe which will bring them to the attention of the Contracting Parties. The requirements of 1.2.1, 1.4.2 and 1.4.3 concerning the definitions of participants and their respective obligations shall not affect the provisions of domestic law concerning the legal consequences (criminal nature, liability, etc.) stemming from the fact that the participant in question is e.g. a legal entity, a self-employed worker, an employer or an employee. 1.4.2 Obligations of the main participants NOTE 1: Several participants to which safety obligations are assigned in this section may be one and the same enterprise. Also, the activities and the corresponding safety obligations of a participant can be assumed by several enterprises. NOTE 2: For radioactive material, see also 1.7.6. 1.4.2.1 Consignor 1.4.2.1.1 The consignor of dangerous goods is required to hand over for carriage only consignments which conform to the requirements of ADR. In the context of 1.4.1, he shall in particular: (a) Ascertain that the dangerous goods are classified and authorized for carriage in accordance with ADR; (b) Furnish the carrier with information and data and, if necessary, the required transport documents and accompanying documents (authorizations, approvals, notifications, certificates, etc.), taking into account in particular the requirements of Chapter 5.4 and of the tables in Part 3; (c) Use only packagings, large packagings, intermediate bulk containers (IBCs) and tanks (tank-vehicles, demountable tanks, battery-vehicles, MEGCs, portable tanks and tankcontainers) approved for and suited to the carriage of the substances concerned and bearing the markings prescribed by ADR; - 41 - Copyright © United Nations, 2010. All rights reserved (d) Comply with the requirements on the means of dispatch and on forwarding restrictions; (e) Ensure that even empty uncleaned and not degassed tanks (tank-vehicles, demountable tanks, battery-vehicles, MEGCs, portable tanks and tank-containers) or empty uncleaned vehicles and large and small bulk containers are appropriately marked and labelled and that empty uncleaned tanks are closed and present the same degree of leakproofness as if they were full. 1.4.2.1.2 If the consignor uses the services of other participants (packer, loader, filler, etc.), he shall take appropriate measures to ensure that the consignment meets the requirements of ADR. He may, however, in the case of 1.4.2.1.1 (a), (b), (c) and (e), rely on the information and data made available to him by other participants. 1.4.2.1.3 When the consignor acts on behalf of a third party, the latter shall inform the consignor in writing that dangerous goods are involved and make available to him all the information and documents he needs to perform his obligations. 1.4.2.2 Carrier 1.4.2.2.1 In the context of 1.4.1, where appropriate, the carrier shall in particular: (a) Ascertain that the dangerous goods to be carried are authorized for carriage in accordance with ADR; (b) Ascertain that all information prescribed in ADR related to the dangerous goods to be carried has been provided by the consignor before carriage, that the prescribed documentation is on board the transport unit or if electronic data processing (EDP) or if electronic data interchange (EDI) techniques are used instead of paper documentation, that data is available during transport in a manner at least equivalent to that of paper documentation; (c) Ascertain visually that the vehicles and loads have no obvious defects, leakages or cracks, missing equipment, etc.; (d) Ascertain that the date of the next test for tank-vehicles, battery-vehicles, demountable tanks, portable tanks, tank-containers and MEGCs has not expired; NOTE: Tanks, battery-vehicles and MEGCs may however be carried after the expiry of this date under the conditions of 4.1.6.10 (in the case of battery-vehicles and MEGCs containing pressure receptacles as elements), 4.2.4.4, 4.3.2.4.4, 6.7.2.19.6, 6.7.3.15.6 or 6.7.4.14.6. (e) verify that the vehicles are not overloaded; (f) ascertain that the danger labels and markings prescribed for the vehicles have been affixed; (g) ascertain that the equipment prescribed in the written instructions for the driver is on board the vehicle. Where appropriate, this shall be done on the basis of the transport documents and accompanying documents, by a visual inspection of the vehicle or the containers and, where appropriate, the load. - 42 - Copyright © United Nations, 2010. All rights reserved 1.4.2.2.2 The carrier may, however, in the case of 1.4.2.2.1 (a), (b), (e) and (f), rely on information and data made available to him by other participants. 1.4.2.2.3 If the carrier observes an infringement of the requirements of ADR, in accordance with 1.4.2.2.1, he shall not forward the consignment until the matter has been rectified. 1.4.2.2.4 If, during the journey, an infringement which could jeopardize the safety of the operation is observed, the consignment shall be halted as soon as possible bearing in mind the requirements of traffic safety, of the safe immobilisation of the consignment, and of public safety. The transport operation may only be continued once the consignment complies with applicable regulations. The competent authority(ies) concerned by the rest of the journey may grant an authorization to pursue the transport operation. In case the required compliance cannot be achieved and no authorization is granted for the rest of the journey, the competent authority(ies) shall provide the carrier with the necessary administrative assistance. The same shall apply in case the carrier informs this/these competent authority(ies) that the dangerous nature of the goods carried was not communicated to him by the consignor and that he wishes, by virtue of the law applicable in particular to the contract of carriage, to unload, destroy or render the goods harmless. 1.4.2.2.5 (Reserved) 1.4.2.3 Consignee 1.4.2.3.1 The consignee has the obligation not to defer acceptance of the goods without compelling reasons and to verify, after unloading, that the requirements of ADR concerning him have been complied with. 1.4.2.3.2 If, in the case of a container, this verification brings to light an infringement of the requirements of ADR, the consignee shall return the container to the carrier only after the infringement has been remedied. 1.4.2.3.3 If the consignee makes use of the services of other participants (unloader, cleaner, decontamination facility, etc.) he shall take appropriate measures to ensure that the requirements of 1.4.2.3.1 and 1.4.2.3.2 of ADR have been complied with. 1.4.3 Obligations of the other participants A non-exhaustive list of the other participants and their respective obligations is given below. The obligations of the other participants flow from section 1.4.1 above insofar as they know or should have known that their duties are performed as part of a transport operation subject to ADR. 1.4.3.1 Loader 1.4.3.1.1 In the context of 1.4.1, the loader has the following obligations in particular: (a) He shall hand the dangerous goods over to the carrier only if they are authorized for carriage in accordance with ADR; (b) He shall, when handing over for carriage packed dangerous goods or uncleaned empty packagings, check whether the packaging is damaged. He shall not hand over a package the packaging of which is damaged, especially if it is not leakproof, and there are leakages or the possibility of leakages of the dangerous substance, until the damage has been repaired; this obligation also applies to empty uncleaned packagings; - 43 - Copyright © United Nations, 2010. All rights reserved (c) He shall, when loading dangerous goods in a vehicle, or a large or small container, comply with the special requirements concerning loading and handling; (d) He shall, after loading dangerous goods into a container comply with the requirements concerning danger markings conforming to Chapter 5.3; (e) He shall, when loading packages, comply with the prohibitions on mixed loading taking into account dangerous goods already in the vehicle or large container and requirements concerning the separation of foodstuffs, other articles of consumption or animal feedstuffs. 1.4.3.1.2 The loader may, however, in the case of 1.4.3.1.1 (a), (d) and (e), rely on information and data made available to him by other participants. 1.4.3.2 Packer In the context of 1.4.1, the packer shall comply with in particular: 1.4.3.3 (a) The requirements concerning packing conditions, or mixed packing conditions; and (b) When he prepares packages for carriage, the requirements concerning marking and labelling of the packages. Filler In the context of 1.4.1, the filler has the following obligations in particular: (a) He shall ascertain prior to the filling of tanks that both they and their equipment are technically in a satisfactory condition; (b) He shall ascertain that the date of the next test for tank-vehicles, battery-vehicles, demountable tanks, portable tanks, tank-containers and MEGCs has not expired; (c) He shall only fill tanks with the dangerous goods authorized for carriage in those tanks; (d) He shall, in filling the tank, comply with the requirements concerning dangerous goods in adjoining compartments; (e) He shall, during the filling of the tank, observe the maximum permissible degree of filling or the maximum permissible mass of contents per litre of capacity for the substance being filled; (f) He shall, after filling the tank, check the leakproofness of the closing devices; (g) He shall ensure that no dangerous residue of the filling substance adheres to the outside of the tanks filled by him; (h) He shall, in preparing the dangerous goods for carriage, ensure that the orange plates and placards or labels prescribed are affixed on the tanks, on the vehicles and on the large and small containers for carriage in bulk in accordance with the requirements; (i) (Reserved); (j) He shall, when filling vehicles or containers with dangerous goods in bulk, ascertain that the relevant provisions of Chapter 7.3 are complied with. - 44 - Copyright © United Nations, 2010. All rights reserved 1.4.3.4 Tank-container/portable tank operator In the context of 1.4.1, the tank-container/portable tank operator shall in particular: (a) Ensure compliance with the requirements for construction, equipment, tests and marking; (b) Ensure that the maintenance of shells and their equipment is carried out in such a way as to ensure that, under normal operating conditions, the tank-container/portable tank satisfies the requirements of ADR until the next inspection; (c) Have an exceptional check made when the safety of the shell or its equipment is liable to be impaired by a repair, an alteration or an accident. 1.4.3.5 and 1.4.3.6 1.4.3.7 (Reserved) Unloader NOTE: In this sub-section, unloading covers removal, unloading and discharging as indicated in the definition of unloader in 1.2.1. 1.4.3.7.1 1.4.3.7.2 In the context of 1.4.1, the unloader shall in particular: (a) Ascertain that the correct goods are unloaded by comparing the relevant information on the transport document with the information on the package, container, tank, MEMU, MEGC or vehicle; (b) Before and during unloading, check whether the packagings, the tank, the vehicle or container have been damaged to an extent which would endanger the unloading operation. If this is the case, ascertain that unloading is not carried out until appropriate measures have been taken; (c) Comply with all relevant requirements concerning unloading; (d) Immediately following the unloading of the tank, vehicle or container: (i) Remove any dangerous residues which have adhered to the outside of the tank, vehicle or container during the process of unloading; and (ii) Ensure the closure of valves and inspection openings; (e) Ensure that the prescribed cleaning and decontamination of the vehicles or containers is carried out; and (f) Ensure that the containers once completely unloaded, cleaned and decontaminated, no longer display danger markings conforming to Chapter 5.3. If the unloader makes use of the services of other participants (cleaner, decontamination facility, etc.) he shall take appropriate measures to ensure that the requirements of ADR have been complied with. - 45 - Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved CHAPTER 1.5 DEROGATIONS 1.5.1 Temporary derogations 1.5.1.1 In accordance with Article 4, paragraph 3 of ADR, the competent authorities of the Contracting Parties may agree directly among themselves to authorize certain transport operations in their territories by temporary derogation from the requirements of ADR, provided that safety is not compromised thereby. The authority which has taken the initiative with respect to the temporary derogation shall notify such derogations to the Secretariat of the United Nations Economic Commission for Europe which shall bring them to the attention of the Contracting Parties 1. NOTE: "Special arrangement" in accordance with 1.7.4 is not considered to be a temporary derogation in accordance with this section. 1.5.1.2 The period of validity of the temporary derogation shall not be more than five years from the date of its entry into force. The temporary derogation shall automatically cease as from the date of the entry into force of a relevant amendment to ADR. 1.5.1.3 Transport operations on the basis of temporary derogations shall constitute transport operations in the sense of ADR. 1.5.2 (Reserved) 1 Note by the Secretariat: The special agreements concluded under this Chapter may be consulted on the web site of the Secretariat of the United Nations Economic Commission for Europe (http://www.unece.org/trans/danger/danger.htm). - 47 - Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved CHAPTER 1.6 TRANSITIONAL MEASURES 1.6.1 General 1.6.1.1 Unless otherwise provided, the substances and articles of ADR may be carried until 30 June 2011 in accordance with the requirements of ADR applicable up to 31 December 2010. 1.6.1.2 (Deleted) 1.6.1.3 Substances and articles of Class 1, belonging to the armed forces of a Contracting Party, that were packaged prior to 1 January 1990 in accordance with the requirements of ADR in effect at that time may be carried after 31 December 1989 provided the packagings maintain their integrity and are declared in the transport document as military goods packaged prior to 1 January 1990. The other requirements applicable as from 1 January 1990 for this class shall be complied with. 1.6.1.4 Substances and articles of Class 1 that were packaged between 1 January 1990 and 31 December 1996 in accordance with the requirements of ADR in effect at that time may be carried after 31 December 1996, provided the packagings maintain their integrity and are declared in the transport document as goods of Class 1 packaged between 1 January 1990 and 31 December 1996. 1.6.1.5 (Reserved) 1.6.1.6 Intermediate bulk containers (IBCs) manufactured before 1 January 2003 in accordance with the requirements of marginal 3612 (1) applicable up to 30 June 2001 and which do not conform to the requirements of 6.5.2.1.1 regarding the height of letters, numerals and symbols applicable as from 1 July 2001 may continue to be used. 1.6.1.7 Type approvals for drums, jerricans and composite packagings made of high or medium molecular mass polyethylene issued before 1 July 2005 in accordance with the requirements of 6.1.5.2.6 in force up to 31 December 2004, but which are not in accordance with the requirements of 4.1.1.19, continue to be valid until 31 December 2009. Any such packagings manufactured and marked on the basis of these type approvals may be used until the end of their period of use determined in 4.1.1.15. 1.6.1.8 Existing orange-coloured plates which meet the requirements of sub-section 5.3.2.2 applicable up to 31 December 2004 may continue to be used provided that the requirements of 5.3.2.2.1 and 5.3.2.2.2 that the plate, numbers and letters shall remain affixed irrespective of the orientation of the vehicle are met. 1.6.1.9 (Deleted) 1.6.1.10 Lithium cells and batteries manufactured before 1 July 2003 which had been tested in accordance with the requirements applicable until 31 December 2002 but which had not been tested in accordance with the requirements applicable as from 1 January 2003, and appliances containing such lithium cells or batteries, may continue to be carried up to 30 June 2013 if all the other applicable requirements are fulfilled. 1.6.1.11 Type approvals for drums, jerricans and composite packagings made of high or medium molecular mass polyethylene, and for high molecular mass polyethylene IBCs, issued before 1 July 2007 in accordance with the requirements of 6.1.6.1 (a) in force up to 31 December 2006, but which are not in accordance with the requirements of 6.1.6.1 (a) applicable as from 1 January 2007, continue to be valid. - 49 - Copyright © United Nations, 2010. All rights reserved 1.6.1.12 and 1.6.1.13 (Deleted) 1.6.1.14 IBCs manufactured before 1 January 2011 and conforming to a design type which has not passed the vibration test of 6.5.6.13 or which was not required to meet the criteria of 6.5.6.9.5 (d) at the time it was subjected to the drop test, may still be used. 1.6.1.15 IBCs manufactured, remanufactured or repaired before 1 January 2011 need not be marked with the maximum permitted stacking load in accordance with 6.5.2.2.2. Such IBCs, not marked in accordance with 6.5.2.2.2, may still be used after 31 December 2010 but must be marked in accordance with 6.5.2.2.2 if they are remanufactured or repaired after that date. 1.6.1.16 Animal material affected by pathogens included in Category B, other than those which would be assigned to Category A if they were in culture (see 2.2.62.1.12.2), may be carried in accordance with provisions determined by the competent authority until 31 December 2014 1. 1.6.1.17 and 1.6.1.18 (Deleted) 1.6.1.19 The provisions of 2.2.9.1.10.3 and 2.2.9.1.10.4 concerning the classification of environmentally hazardous substances applicable until 31 December 2010 may be applied until 31 December 2013. 1.6.1.20 Notwithstanding the requirements of Chapter 3.4 applicable as from 1 January 2011, dangerous goods packed in limited quantities, other than those which are assigned figure "0" in column (7a) of Table A of Chapter 3.2, may continue to be carried until 30 June 2015 in accordance with the provisions of Chapter 3.4 in force up to 31 December 2010. However, in such a case, the provisions of 3.4.12 to 3.4.15 in force as from 1 January 2011 may be applied as from 1 January 2011. For the purposes of the application of the last sentence of 3.4.13 (b), if the container carried is marked with the mark required in paragraph 3.4.12 applicable until 31 December 2010, the transport unit may be marked with the mark required in paragraph 3.4.15 applicable as from 1 January 2011.. 1.6.1.21 Contracting Parties may continue to issue training certificates for drivers conforming to the model applicable until 31 December 2010, instead of those conforming to the requirements of 8.2.2.8.5, until 31 December 2012. Such certificates may continue in use to the end of their five year validity. 1.6.1.22 Inner receptacles of composite IBCs manufactured before 1 July 2011 and marked in accordance with the requirements of 6.5.2.2.4 in force up to 31 December 2010 may still be used. 1.6.2 Pressure receptacles and receptacles for Class 2 1.6.2.1 Receptacles built before 1 January 1997 and which do not conform to the requirements of ADR applicable as from 1 January 1997, but the carriage of which was permitted under the requirements of ADR applicable up to 31 December 1996, may continue to be transported after that date if the periodic test requirements in packing instructions P200 and P203 are complied with. 1 Regulations for dead infected animals are contained e.g. in Regulation (EC) No. 1774/2002 of the European Parliament and of the Council of 3 October 2002 laying down health rules concerning animal byproducts not intended for human consumption (Official Journal of the European Communities, No. L 273 of 10.10.2002, p. 1). - 50 - Copyright © United Nations, 2010. All rights reserved 1.6.2.2 Cylinders in accordance with the definition in 1.2.1 which were submitted to an initial inspection or periodic inspection before 1 January 1997 may be transported empty and uncleaned without a label until the date of the next refilling or the next periodic inspection. 1.6.2.3 Receptacles intended for the carriage of Class 2 substances constructed before 1 January 2003, may continue to bear, after 1 January 2003, the markings conforming to the requirements applicable until 31 December 2002. 1.6.2.4 Pressure receptacles designed and constructed in accordance with technical codes no longer recognized according to 6.2.5 may still be used. 1.6.2.5 Pressure receptacles and their closures designed and constructed in accordance with standards applicable at the time of their construction (see 6.2.4) according to the provisions of ADR which were applicable at that time may still be used unless restricted by a specific transitional measure. 1.6.2.6 Pressure receptacles for substances other than those of Class 2, built before 1 July 2009 in accordance with the requirements of 4.1.4.4 in force up to 31 December 2008, but which do not conform to the requirements of 4.1.3.6 applicable as from 1 January 2009, may continue to be used provided that the requirements of 4.1.4.4 in force up to 31 December 2008 are complied with. 1.6.2.7 Contracting Parties may continue to apply the requirements of 6.2.1.4.1 to 6.2.1.4.4 applicable until 31 December 2008 instead of those of 1.8.6, 1.8.7, 6.2.2.10, 6.2.3.6 to 6.2.3.8 until 30 June 2011. 1.6.2.8 Type approvals for pressure receptacles issued before 1 July 2011 shall be reviewed and brought into conformity with the provisions of 1.8.7.2.4 before 1 January 2013. 1.6.2.9 The provisions of packing instruction P200 (10), special packing provision v of 4.1.4.1 applicable until 31 December 2010 may be applied by Contracting Parties to ADR to cylinders constructed before 1 January 2015. 1.6.2.10 Refillable welded steel cylinders for the carriage of gases of UN Nos. 1011, 1075, 1965, 1969 or 1978, granted 15 year intervals for periodic inspection in accordance with packing instruction P200 (10), special packing provision v of 4.1.4.1 as applicable until 31 December 2010 by the competent authority of the country (countries) of carriage, may continue to be periodically inspected according to those provisions. 1.6.2.11 Contracting Parties need not apply the requirements of 1.8.6, 1.8.7 or 1.8.8 for the conformity assessment of gas cartridges before 1 January 2013. In this case, gas cartridges constructed and prepared for carriage before 1 January 2013 may still be carried after this date, provided all the other applicable provisions of ADR are met. 1.6.3 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles 1.6.3.1 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles built before the entry into force of the requirements applicable as from 1 October 1978 may be kept in service if the equipment of the shell meets the requirements of Chapter 6.8. The thickness of the shell wall, except in the case of shells intended for the carriage of refrigerated liquefied gases of Class 2, shall be appropriate to a calculation pressure of not less than 0.4 MPa (4 bar) (gauge pressure) in the case of mild steel or of not less than 200 kPa (2 bar) (gauge pressure) in the case of aluminium and aluminium alloys. For other than circular cross-sections of tanks, the diameter to be used as a basis for calculation shall be that of a circle whose area is equal to that of the actual cross-section of the tank. - 51 - Copyright © United Nations, 2010. All rights reserved 1.6.3.2 The periodic tests for fixed tanks (tank-vehicles), demountable tanks and battery-vehicles kept in service under these transitional requirements shall be conducted in accordance with the requirements of 6.8.2.4 and 6.8.3.4 and with the pertinent special requirements for the various classes. Unless the earlier requirements prescribed a higher test pressure, a test pressure of 200 kPa (2 bar) (gauge pressure) shall suffice for aluminium shells and aluminium alloy shells. 1.6.3.3 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles which meet the transitional requirements in 1.6.3.1 and 1.6.3.2 may be used until 30 September 1993 for the carriage of the dangerous goods for which they have been approved. This transitional period shall not apply to fixed tanks (tank-vehicles), demountable tanks and battery-vehicles intended for the carriage of substances of Class 2, or to fixed tanks (tank-vehicles), demountable tanks and battery-vehicles whose wall thickness and items of equipment meet the requirements of Chapter 6.8. 1.6.3.4 (a) Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles constructed before 1 May 1985 in accordance with the requirements of ADR in force between 1 October 1978 and 30 April 1985 but not conforming to the requirements applicable as from 1 May 1985 may continue to be used after that date; (b) Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles, constructed between 1 May 1985 and the entry into force of the requirements applicable as from 1 January 1988 which do not conform to those requirements but were constructed according to the requirements of ADR in force until that date, may continue to be used after that date. 1.6.3.5 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles, constructed before 1 January 1993 in accordance with the requirements in force up to 31 December 1992 but which do not conform to the requirements applicable as from 1 January 1993 may still be used. 1.6.3.6 (a) Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles constructed between 1 January 1978 and 31 December 1984, if used after 31 December 2004, shall conform to the requirements of marginal 211 127 (5), applicable as from 1 January 1990, concerning shell thickness and protection against damage; (b) Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles constructed between 1 January 1985 and 31 December 1989, if used after 31 December 2010, shall conform to the requirements of marginal 211 127 (5), applicable as from 1 January 1990, concerning shell thickness and protection against damage. 1.6.3.7 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles constructed before 1 January 1999 in accordance with the requirements in force up to 31 December 1998 but which do not, however, conform to the requirements applicable as from 1 January 1999 may still be used. 1.6.3.8 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles intended for the carriage of substances of Class 2, which were built prior to 1 January 1997, may carry markings conforming to the requirements applicable up to 31 December 1996, until the next periodic test. When, because of amendments to ADR, some proper shipping names of gases have been modified, it is not necessary to modify the names on the plate or on the shell itself (see 6.8.3.5.2 or 6.8.3.5.3), provided that the names of the gases on the fixed tanks (tank-vehicles), demountable tanks and battery-vehicles or on the plates (see 6.8.3.5.6 (b) or (c)) are adapted at the first periodic test thereafter. - 52 - Copyright © United Nations, 2010. All rights reserved 1.6.3.9 and 1.6.3.10 (Reserved) 1.6.3.11 Fixed tanks (tank-vehicles) and demountable tanks constructed before 1 January 1997 in accordance with the requirements in force up to 31 December 1996 but which do not, however, conform to the requirements of marginals 211 332 and 211 333 applicable as from 1 January 1997, may still be used. 1.6.3.12 (Reserved) 1.6.3.13 (Deleted) 1.6.3.14 (Reserved) 1.6.3.15 Fixed tanks (tank-vehicles) and demountable tanks constructed before 1 July 2007 in accordance with the requirements in force up to 31 December 2006 but which do not, however, conform to the requirements of 6.8.2.2.3 applicable as from 1 January 2007 may continue to be used until the next periodic inspection. 1.6.3.16 For fixed tanks (tank-vehicles), demountable tanks and battery-vehicles constructed before 1 January 2007 which do not conform to the requirements of 4.3.2, 6.8.2.3, 6.8.2.4 and 6.8.3.4 concerning the tank record, the retention of files for the tank record shall start at the latest at the next periodic inspection. 1.6.3.17 Fixed tanks (tank-vehicles) and demountable tanks intended for the carriage of substances of Class 3, packing group I having a vapour pressure of not more than 175 kPa (1.75 bar) (absolute) at 50 °C, constructed before 1 July 2007 in accordance with the requirements applicable up to 31 December 2006, to which tank code L1.5BN had been assigned in accordance with the requirements applicable up to 31 December 2006, may continue to be used for the carriage of the substances mentioned above, until 31 December 2018. 1.6.3.18 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles constructed before 1 January 2003 in accordance with the requirements in force up to 30 June 2001, but which do not, however, conform to the requirements applicable as from 1 July 2001, may still be used provided that the assignment to the relevant tank code has been carried out. 1.6.3.19 Fixed tanks (tank-vehicles) and demountable tanks constructed before 1 January 2003 in accordance with the requirements of 6.8.2.1.21 in force up to 31 December 2002 but which do not, however, conform to the requirements applicable as from 1 January 2003 may still be used. 1.6.3.20 Fixed tanks (tank-vehicles) and demountable tanks constructed before 1 July 2003 in accordance with the requirements in force up to 31 December 2002 but which do not, however, conform to the requirements of 6.8.2.1.7 applicable as from 1 January 2003 and special provision TE15 of 6.8.4 (b) applicable from 1 January 2003 to 31 December 2006 may still be used. 1.6.3.21 (Deleted) 1.6.3.22 to 1.6.3.24 (Reserved) 1.6.3.25 The type of the test ("P" or "L") required by 6.8.2.5.1 need not be added to the tank plate until the first test after 1 January 2007 is performed. 1.6.3.26 Fixed tanks (tank-vehicles) and demountable tanks constructed before 1 January 2007 in accordance with the requirements in force up to 31 December 2006 but which do not, - 53 - Copyright © United Nations, 2010. All rights reserved however, conform to the requirements applicable as from 1 January 2007 regarding the marking of the external design pressure in accordance with 6.8.2.5.1, may still be used. 1.6.3.27 to 1.6.3.29 (Reserved) 1.6.3.30 Vacuum-operated waste fixed tanks (tank-vehicles) and demountable tanks constructed before 1 July 2005 in accordance with the requirements applicable up to 31 December 2004 but which do not conform to the requirements of 6.10.3.9 applicable as from 1 January 2005, may still be used. 1.6.3.31 Fixed tanks (tank-vehicles), demountable tanks and tanks forming elements of batteryvehicles designed and constructed in accordance with a technical code which was recognized at the time of their construction according to the provisions of 6.8.2.7 which were applicable at that time may still be used. 1.6.3.32 Fixed tanks (tank vehicles) and demountable tanks constructed before 1 July 2007 in accordance with the requirements in force up to 31 December 2006, equipped with manhole cover assemblies in accordance with the provisions of standard EN 13317:2002 referred to in the table of paragraph 6.8.2.6, applicable until 31 December 2006, including those of the figure and table B.2 of annex B of the said standard which are no longer accepted as from 1 January 2007, or the material of which does not meet the requirements of EN 13094:2004, paragraph 5.2, may still be used. 1.6.3.33 When the shell of a fixed tank (tank-vehicle) or demountable tank was already divided by partitions or surge plates into sections of not more than 7 500 litres capacity before 1 January 2009, the capacity of the shell need not be supplemented with the symbol "S" in the particulars required by 6.8.2.5.1 until the next periodic inspection according to 6.8.2.4.2 is performed. 1.6.3.34 Notwithstanding the provisions of 4.3.2.2.4, fixed tanks (tank-vehicles) and demountable tanks intended for the carriage of liquefied gases or refrigerated liquefied gases, which meet the applicable construction requirements of ADR but which were divided, before 1 July 2009, by partitions or surge plates into sections of more than 7 500 litres capacity may still be filled to more than 20% and less than 80% of their capacity. 1.6.3.35 Contracting Parties need not apply the requirements of 1.8.6, 1.8.7 and 6.8.4 TA4 and TT9 before 1 July 2011. 1.6.3.36 Fixed tanks (tank-vehicles) intended for the carriage of liquefied non-toxic flammable gases constructed before 1 July 2011 and which are equipped with non-return valves instead of internal stop-valves and which do not conform to the requirements of 6.8.3.2.3, may still be used. 1.6.3.37 Type approvals for fixed tanks (tank-vehicles), demountable tanks and battery-vehicles issued before 1 July 2011 shall be reviewed and brought into conformity with the provisions of 1.8.7.2.4 or 6.8.2.3.3 before 1 January 2013. 1.6.3.38 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles designed and constructed in accordance with standards applicable at the time of their construction (see 6.8.2.6 and 6.8.3.6) according to the provisions of ADR which were applicable at that time may still be used unless restricted by a specific transitional measure. 1.6.3.39 Fixed tanks (tank-vehicles) and demountable tanks constructed before 1 July 2011 in accordance with the requirements of 6.8.2.2.3 in force up to 31 December 2010 but which do not, however, conform to the requirements of 6.8.2.2.3, third paragraph, concerning the position of the flame trap or flame arrester may still be used. - 54 - Copyright © United Nations, 2010. All rights reserved 1.6.3.40 For toxic by inhalation substances of UN Nos. 1092, 1238, 1239, 1244, 1251, 1510, 1580, 1810, 1834, 1838, 2474, 2486, 2668, 3381, 3383, 3385, 3387 and 3389, the tank code specified in column (12) of Table A of Chapter 3.2 applicable up to 31 December 2010 may continue to be applied until 31 December 2016 for fixed tanks (tank-vehicles) and demountable tanks constructed before 1 July 2011. 1.6.3.41 to 1.6.3.49 1.6.3.50 (Reserved) Fibre-reinforced plastics (FRP) tanks FRP tanks which have been constructed before 1 July 2002 in conformity with a design type approved before 1 July 2001 in accordance with the requirements of Appendix B.1c which were in force until 30 June 2001 may continue to be used until the end of their lifetime provided that all the requirements in force up to 30 June 2001 have been and continue to be complied with. However, as from 1 July 2001, no new design type may be approved in accordance with the requirements in force until 30 June 2001. 1.6.4 Tank-containers, portable tanks and MEGCs 1.6.4.1 Tank-containers constructed before 1 January 1988 in accordance with the requirements in force up to 31 December 1987 but which do not, however, conform to the requirements applicable as from 1 January 1988, may still be used. 1.6.4.2 Tank-containers constructed before 1 January 1993 in accordance with the requirements in force up to 31 December 1992 but which do not, however, conform to the requirements applicable as from 1 January 1993, may still be used. 1.6.4.3 Tank-containers constructed before 1 January 1999 in accordance with the requirements in force up to 31 December 1998 but which do not, however, conform to the requirements applicable as from 1 January 1999, may still be used. 1.6.4.4 (Reserved) 1.6.4.5 When, because of amendments to ADR, some proper shipping names of gases have been modified, it is not necessary to modify the names on the plate or on the shell itself (see 6.8.3.5.2 or 6.8.3.5.3), provided that the names of the gases on the tank-containers and MEGCs or on the plates [see 6.8.3.5.6 (b) or (c)] are adapted at the first periodic test thereafter. 1.6.4.6 Tank-containers constructed before 1 January 2007 in accordance with the requirements in force up to 31 December 2006 but which do not, however, conform to the requirements applicable as from 1 January 2007 regarding the marking of the external design pressure in accordance with 6.8.2.5.1, may still be used. 1.6.4.7 Tank-containers constructed before 1 January 1997 in accordance with the requirements in force up to 31 December 1996 but which do not, however, conform to the requirements of marginals 212 332 and 212 333 applicable as from 1 January 1997, may still be used. 1.6.4.8 (Reserved) 1.6.4.9 Tank-containers and MEGCs designed and constructed in accordance with a technical code which was recognized at the time of their construction according to the provisions of 6.8.2.7 which were applicable at that time may still be used. - 55 - Copyright © United Nations, 2010. All rights reserved 1.6.4.10 (Deleted) 1.6.4.11 (Reserved) 1.6.4.12 Tank-containers and MEGCs constructed before 1 January 2003 in accordance with the requirements applicable up to 30 June 2001, but which do not, however, conform to the requirements applicable as from 1 July 2001, may still be used. However, they shall be marked with the relevant tank code and if applicable the relevant alphanumeric codes of special provisions TC and TE in accordance with 6.8.4. 1.6.4.13 Tank-containers constructed before 1 July 2003 in accordance with the requirements in force up to 31 December 2002 but which do not, however, conform to the requirements of 6.8.2.1.7 applicable as from 1 January 2003 and special provision TE15 of 6.8.4 (b) applicable from 1 January 2003 to 31 December 2006 may still be used. 1.6.4.14 (Reserved) 1.6.4.15 The type of the test ("P" or "L") required by 6.8.2.5.1 need not be added to the tank plate until the first test after 1 January 2007 is performed. 1.6.4.16 (Deleted) 1.6.4.17 Tank-containers constructed before 1 July 2007 in accordance with the requirements in force up to 31 December 2006 but which do not conform to the requirements of 6.8.2.2.3 applicable as from 1 January 2007 may continue to be used until the next periodic inspection. 1.6.4.18 For tank-containers and MEGCs constructed before 1 January 2007 which do not conform to the requirements of 4.3.2, 6.8.2.3, 6.8.2.4 and 6.8.3.4 concerning the tank record, the retention of files for the tank record shall start at the latest at the next periodic inspection. 1.6.4.19 Tank-containers intended for the carriage of substances of Class 3, packing group I having a vapour pressure of not more than 175 kPa (1.75 bar) (absolute) at 50 °C, constructed before 1 July 2007 in accordance with the requirements applicable up to 31 December 2006, to which tank code L1.5BN had been assigned in accordance with the requirements applicable up to 31 December 2006, may continue to be used for the carriage of the substances mentioned above until 31 December 2016. 1.6.4.20 Vacuum-operated waste tank-containers constructed before 1 July 2005 in accordance with the requirements applicable up to 31 December 2004 but which do not conform to the requirements of 6.10.3.9 applicable as from 1 January 2005, may still be used. 1.6.4.21 to 1.6.4.29 (Reserved) 1.6.4.30 Portable tanks and UN MEGCs which do not meet the design requirements applicable as from 1 January 2007 but which have been constructed according to a design approval certificate which has been issued before 1 January 2008 may continue to be used. 1.6.4.31 For substances where TP35 is assigned in column (11) of Table A of Chapter 3.2, portable tank instruction T14 prescribed in ADR applicable up to 31 December 2008 may continue to be applied until 31 December 2014. - 56 - Copyright © United Nations, 2010. All rights reserved 1.6.4.32 When the shell of a tank-container was already divided by partitions or surge plates into sections of not more than 7 500 litres capacity before 1 January 2009, the capacity of the shell need not be supplemented with the symbol "S" in the particulars required by 6.8.2.5.1 until the next periodic inspection according to 6.8.2.4.2 is performed. 1.6.4.33 Notwithstanding the provisions of 4.3.2.2.4, tank-containers intended for the carriage of liquefied gases or refrigerated liquefied gases, which meet the applicable construction requirements of ADR but which were divided, before 1 July 2009, by partitions or surge plates into sections of more than 7 500 litres capacity may still be filled to more than 20% and less than 80% of their capacity. 1.6.4.34 Contracting Parties need not apply the requirements of 1.8.6, 1.8.7 and 6.8.4 TA4 and TT9 before 1 July 2011. 1.6.4.35 Type approvals for tank-containers and MEGCs issued before 1 July 2011 shall be reviewed and brought into conformity with the provisions of 1.8.7.2.4 or 6.8.2.3.3 before 1 January 2013. 1.6.4.36 For substances where TP37 is assigned in column (11) of Table A of Chapter 3.2, the portable tank instruction prescribed in ADR applicable up to 31 December 2010 may continue to be applied until 31 December 2016. 1.6.4.37 Portable tanks and MEGCs manufactured before 1 January 2012, that conform to the marking requirements of 6.7.2.20.1, 6.7.3.16.1, 6.7.4.15.1 or 6.7.5.13.1 applicable up to 31 December 2010, as relevant, may continue to be used if they comply with all other relevant requirements of ADR applicable as from 1 January 2011 including, when applicable, the requirement of 6.7.2.20.1 (g) for marking the symbol "S" on the plate when the shell or the compartment is divided by surge plates into sections of not more than 7 500 litres capacity. When the shell, or the compartment, was already divided by surge plates into sections of not more than 7 500 litres capacity before 1 January 2012, the capacity of the shell, or respectively of the compartment, need not be supplemented with the symbol "S" until the next periodic inspection or test according to 6.7.2.19.5 is performed. 1.6.4.38 Portable tanks manufactured before 1 January 2014 need not be marked with the portable tank instruction as required in 6.7.2.20.2, 6.7.3.16.2 and 6.7.4.15.2 until the next periodic inspection and test. 1.6.4.39 Tank-containers and MEGCs designed and constructed in accordance with standards applicable at the time of their construction (see 6.8.2.6 and 6.8.3.6) according to the provisions of ADR which were applicable at that time may still be used unless restricted by a specific transitional measure. 1.6.4.40 Tank-containers constructed before 1 July 2011 in accordance with the requirements of 6.8.2.2.3 in force up to 31 December 2010 but which do not, however, conform to the requirements of 6.8.2.2.3, third paragraph, concerning the position of the flame trap or flame arrester may still be used. 1.6.4.41 For toxic by inhalation substances of UN Nos. 1092, 1238, 1239, 1244, 1251, 1510, 1580, 1810, 1834, 1838, 2474, 2486, 2668, 3381, 3383, 3385, 3387 and 3389, the tank code specified in column (12) of Table A of Chapter 3.2 applicable up to 31 December 2010 may continue to be applied until 31 December 2016 for tank-containers constructed before 1 July 2011. - 57 - Copyright © United Nations, 2010. All rights reserved 1.6.5 Vehicles 1.6.5.1 and 1.6.5.2 (Reserved) 1.6.5.3 (Deleted) 1.6.5.4 As regards the construction of EX/II, EX/III, FL, OX and AT vehicles, the requirements of Part 9 in force up to 31 December 2010 may be applied until 31 March 2012. 1.6.5.5 Vehicles registered or entering into service before 1 January 2003 the electric equipment of which does not comply with the requirements of 9.2.2, 9.3.7 or 9.7.8 but complies with the requirements applicable until 30 June 2001 may still be used. 1.6.5.6 (Deleted) 1.6.5.7 Complete or completed vehicles which have been type-approved before 31 December 2002 according to ECE Regulation No. 105 2 as amended by the 01 series of amendments or the corresponding provisions of Directive 98/91/EC 3 and which do not comply with the requirements of Chapter 9.2 but comply with the requirements applicable to the construction of base vehicles (marginals 220 100 to 220 540 of Appendix B.2) applicable until 30 June 2001 may continue to be approved and used provided they are first registered or they entered into service before 1 July 2003. 1.6.5.8 EX/II and EX/III vehicles which have been first approved before 1 July 2005 and which comply with the requirements of Part 9 in force up to 31 December 2004 but which do not however conform to the requirements applicable as from 1 January 2005 may still be used. 1.6.5.9 Tank-vehicles with fixed tanks with a capacity of more than 3 m3 intended for the carriage of dangerous goods in the liquid or molten state tested with a pressure of less than 4 bar, which do not comply with the requirements of 9.7.5.2, first registered (or which entered into service if the registration is not mandatory) before 1 July 2004, may still be used. 1.6.5.10 Certificates of approval which conform to the model shown in 9.1.3.5 applicable up to 31 December 2006 and those which conform to the model shown in 9.1.3.5 applicable from 1 January 2007 to 31 December 2008 may continue to be used. 1.6.5.11 MEMUs which have been constructed and approved before 1 July 2009 in accordance with the provisions of national law but which do not, however, conform to the construction and approval requirements applicable as from 1 January 2009 may be used with the approval of the competent authorities in the countries of use. 1.6.5.12 EX/III and FL vehicles registered or entering into service before 1 April 2012, the electrical connections of which do not comply with the requirements of 9.2.2.6.3, but comply with the requirements applicable until 31 December 2010, may still be used. 1.6.5.13 Trailers first registered (or which entered into service if registration was not mandatory) before 1 July 1995 equipped with anti-lock braking system in conformity with ECE Regulation No. 13, 06 series of amendments but which do not comply with the technical requirements for category A anti-lock braking system may still be used. 2 ECE Regulation No. 105 (Uniform provisions concerning the approval of vehicles intended for the carriage of dangerous goods with regard to their specific constructional features). 3 Directive 98/91/EC of the European Parliament and of the Council of 14 December 1998 relating to motor vehicles and their trailers intended for the transport of dangerous goods by road and amending Directive 70/156/EEC relating to the type approval of motor vehicles and their trailers (Official Journal of the European Communities No. L 011 of 16 January 1999, pp. 0025-0036). - 58 - Copyright © United Nations, 2010. All rights reserved 1.6.6 Class 7 1.6.6.1 Packages not requiring competent authority approval of design under the 1985 and 1985 (as amended 1990) editions of IAEA Safety Series No. 6 Excepted packages, Industrial packages Type IP-1, Type IP-2 and Type IP-3 and Type A packages that did not require approval of design by the competent authority and which meet the requirements of the 1985 or 1985 (as amended 1990) Editions of IAEA Regulations for the Safe Transport of Radioactive Material (IAEA Safety Series No. 6) may continue to be used subject to the mandatory programme of quality assurance in accordance with the requirements of 1.7.3 and the activity limits and material restrictions of 2.2.7.2.2, 2.2.7.2.4.1, 2.2.7.2.4.4, 2.2.7.2.4.5, 2.2.7.2.4.6, special provision 336 of Chapter 3.3 and 4.1.9.3. Any packaging modified, unless to improve safety, or manufactured after 31 December 2003, shall meet the requirements of ADR. Packages prepared for carriage not later than 31 December 2003 under the 1985 or 1985 (as amended 1990) Editions of IAEA Safety Series No. 6 may continue in transport. Packages prepared for carriage after this date shall meet the requirements of ADR. 1.6.6.2 Packages approved under the 1973, 1973 (as amended), 1985 and 1985 ( as amended 1990) editions of IAEA Safety Series No. 6 1.6.6.2.1 Packagings manufactured to a package design approved by the competent authority under the provisions of the 1973 or 1973 (as amended) Editions of IAEA Safety Series No. 6 may continue to be used, subject to: multilateral approval of package design, the mandatory programme of quality assurance in accordance with the applicable requirements of 1.7.3 and the activity limits and material restrictions of 2.2.7.2.2, 2.2.7.2.4.1, 2.2.7.2.4.4, 2.2.7.2.4.5, 2.2.7.2.4.6, special provision 337 of Chapter 3.3 and 4.1.9.3. No new manufacture of such packaging shall be permitted to commence. Changes in the design of the packaging or in the nature or quantity of the authorized radioactive contents which, as determined by the competent authority, would significantly affect safety shall require that the requirements of ADR be met. A serial number according to the provision of 5.2.1.7.5 shall be assigned to and marked on the outside of each packaging. 1.6.6.2.2 Packagings manufactured to a package design approved by the competent authority under the provisions of the 1985 or 1985 (as amended 1990) Editions of IAEA Safety Series No. 6 may continue to be used, subject to: the multilateral approval of package design; the mandatory programme of quality assurance in accordance with the requirements of 1.7.3 and the activity limits and material restrictions of 2.2.7.2.2, 2.2.7.2.4.1, 2.2.7.2.4.4, 2.2.7.2.4.5, 2.2.7.2.4.6, special provision 337 of Chapter 3.3 and 4.1.9.3. Changes in the design of the packaging or in the nature or quantity of the authorized radioactive contents which, as determined by the competent authority, would significantly affect safety shall require that the requirements of these Regulations be met. All packagings for which manufacture begins after 31 December 2006 shall meet the requirements of ADR. 1.6.6.3 Special form radioactive material approved under the 1973, 1973 (as amended), 1985 and 1985 (as amended 1990) Editions of IAEA Safety Series No. 6 Special form radioactive material manufactured to a design which had received unilateral approval by the competent authority under the 1973, 1973 (as amended), 1985 or 1985 (as amended 1990) Editions of IAEA Safety Series No. 6 may continue to be used when in compliance with the mandatory programme of quality assurance in accordance with the applicable requirements of 1.7.3. All special form radioactive material manufactured after 31 December 2003 shall meet the requirements of ADR. - 59 - Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved CHAPTER 1.7 GENERAL PROVISIONS CONCERNING CLASS 7 1.7.1 Scope and application NOTE 1: In the event of accidents or incidents during the carriage of radioactive material, emergency provisions, as established by relevant national and/or international organizations, shall be observed to protect persons, property and the environment. Appropriate guidelines for such provisions are contained in "Planning and Preparing for Emergency Response to Transport Accidents Involving Radioactive Material", Safety Standard Series No. TS-G-1.2 (ST-3), IAEA, Vienna (2002). NOTE 2: Emergency procedures shall take into account the formation of other dangerous substances that may result from the reaction between the contents of a consignment and the environment in the event of an accident. 1.7.1.1 ADR establishes standards of safety which provide an acceptable level of control of the radiation, criticality and thermal hazards to persons, property and the environment that are associated with the carriage of radioactive material. These standards are based on the IAEA Regulations for the Safe Transport of Radioactive Material, 2009 edition, Safety Standards Series No. TS-R-1, IAEA, Vienna (2009). Explanatory material can be found in "Advisory Material for the IAEA Regulations for the Safe Transport of Radioactive Material (2005 Edition)", Safety Standard Series No. TS-G-1.1 (Rev.1), IAEA, Vienna (2008). 1.7.1.2 The objective of ADR is to establish requirements that shall be satisfied to ensure safety and to protect persons, property and the environment from the effects of radiation in the carriage of radioactive material. This protection is achieved by requiring: (a) Containment of the radioactive contents; (b) Control of external radiation levels; (c) Prevention of criticality; and (d) Prevention of damage caused by heat. These requirements are satisfied firstly by applying a graded approach to contents limits for packages and vehicles and to performance standards applied to package designs depending upon the hazard of the radioactive contents. Secondly, they are satisfied by imposing requirements on the design and operation of packages and on the maintenance of packagings, including a consideration of the nature of the radioactive contents. Finally, they are satisfied by requiring administrative controls including, where appropriate, approval by competent authorities. 1.7.1.3 ADR applies to the carriage of radioactive material by road including carriage which is incidental to the use of the radioactive material. Carriage comprises all operations and conditions associated with and involved in the movement of radioactive material; these include the design, manufacture, maintenance and repair of packaging, and the preparation, consigning, loading, carriage including in-transit storage, unloading and receipt at the final destination of loads of radioactive material and packages. A graded approach is applied to the performance standards in ADR that are characterized by three general severity levels: - 61 - Copyright © United Nations, 2010. All rights reserved 1.7.1.4 (a) Routine conditions of carriage (incident free); (b) Normal conditions of carriage (minor mishaps); (c) Accident conditions of carriage. The provisions laid down in ADR do not apply to the carriage of: (a) Radioactive material that is an integral part of the means of transport; (b) Radioactive material moved within an establishment which is subject to appropriate safety regulations in force in the establishment and where the movement does not involve public roads or railways; (c) Radioactive material implanted or incorporated into a person or live animal for diagnosis or treatment; (d) Radioactive material in consumer products which have received regulatory approval, following their sale to the end user; (e) Natural material and ores containing naturally occurring radionuclides which are either in their natural state, or have only been processed for purposes other than for extraction of the radionuclides, and which are not intended to be processed for use of these radionuclides provided the activity concentration of the material does not exceed 10 times the values specified in 2.2.7.2.2.1 (b), or calculated in accordance with 2.2.7.2.2.2 to 2.2.7.2.2.6; (f) Non-radioactive solid objects with radioactive substances present on any surfaces in quantities not in excess of the limit set out in the definition for "contamination" in 2.2.7.1.2. 1.7.1.5 Specific provisions for the carriage of excepted packages 1.7.1.5.1 Excepted packages which may contain radioactive material in limited quantities, instruments, manufactured articles and empty packagings as specified in 2.2.7.2.4.1 shall be subject only to the following provisions of Parts 5 to 7: (a) The applicable provisions specified in 5.1.2, 5.1.3.2, 5.1.4, 5.1.5.4, 5.2.1.9 and 7.5.11 CV33 (5.2); (b) The requirements for excepted packages specified in 6.4.4; and (c) If the excepted package contains fissile material, one of the fissile exceptions provided by 2.2.7.2.3.5 shall apply and the requirement of 6.4.7.2 shall be met. 1.7.1.5.2 Excepted packages are subject to the relevant provisions of all other parts of ADR. 1.7.2 Radiation protection programme 1.7.2.1 The carriage of radioactive material shall be subject to a Radiation protection programme which shall consist of systematic arrangements aimed at providing adequate consideration of radiation protection measures. 1.7.2.2 Doses to persons shall be below the relevant dose limits. Protection and safety shall be optimized in order that the magnitude of individual doses, the number of persons exposed, - 62 - Copyright © United Nations, 2010. All rights reserved and the likelihood of incurring exposure shall be kept as low as reasonably achievable, economic and social factors being taken into account within the restriction that the doses to individuals be subject to dose constraints. A structured and systematic approach shall be adopted and shall include consideration of the interfaces between carriage and other activities. 1.7.2.3 The nature and extent of the measures to be employed in the programme shall be related to the magnitude and likelihood of radiation exposures. The programme shall incorporate the requirements in 1.7.2.2, 1.7.2.4, 1.7.2.5 and 7.5.11 CV33 (1.1). Programme documents shall be available, on request, for inspection by the relevant competent authority. 1.7.2.4 For occupational exposures arising from transport activities, where it is assessed that the effective dose: (a) Is likely to be between 1 mSv and 6 mSv in a year, a dose assessment programme via work place monitoring or individual monitoring shall be conducted; (b) Is likely to exceed 6 mSv in a year, individual monitoring shall be conducted. When individual monitoring or work place monitoring is conducted, appropriate records shall be kept. NOTE: For occupational exposures arising from transport activities, where it is assessed that the effective dose is most unlikely to exceed 1 mSv in a year, no special work patterns, detailed monitoring, dose assessment programmes or individual record keeping need be required. 1.7.2.5 Workers (see 7.5.11, CV33 Note 3) shall be appropriately trained in radiation protection including the precautions to be observed in order to restrict their occupational exposure and the exposure of other persons who might be affected by their actions. 1.7.3 Quality assurance Quality assurance programmes based on international, national or other standards acceptable to the competent authority shall be established and implemented for the design, manufacture, testing, documentation, use, maintenance and inspection of all special form radioactive material, low dispersible radioactive material and packages and for carriage and in-transit storage operations to ensure compliance with the relevant provisions of ADR. Certification that the design specification has been fully implemented shall be available to the competent authority. The manufacturer, consignor or user shall be prepared to provide facilities for competent authority inspection during manufacture and use and to demonstrate to any cognizant competent authority that: (a) The manufacturing methods and materials used are in accordance with the approved design specifications; and (b) All packagings are periodically inspected and, as necessary, repaired and maintained in good condition so that they continue to comply with all relevant requirements and specifications, even after repeated use. Where competent authority approval is required, such approval shall take into account and be contingent upon the adequacy of the quality assurance programme. - 63 - Copyright © United Nations, 2010. All rights reserved 1.7.4 Special arrangement 1.7.4.1 Special arrangement shall mean those provisions, approved by the competent authority, under which consignments which do not satisfy all the requirements of ADR applicable to radioactive material may be transported. NOTE: Special arrangement is not considered to be a temporary derogation in accordance with 1.5.1. 1.7.4.2 Consignments for which conformity with any provision applicable to Class 7 is impracticable shall not be transported except under special arrangement. Provided the competent authority is satisfied that conformity with the Class 7 provisions of ADR is impracticable and that the requisite standards of safety established by ADR have been demonstrated through alternative means the competent authority may approve special arrangement transport operations for single or a planned series of multiple consignments. The overall level of safety in carriage shall be at least equivalent to that which would be provided if all the applicable requirements had been met. For international consignments of this type, multilateral approval shall be required. 1.7.5 Radioactive material possessing other dangerous properties In addition to the radioactive and fissile properties, any subsidiary risk of the contents of the package, such as explosiveness, flammability, pyrophoricity, chemical toxicity and corrosiveness, shall also be taken into account in the documentation, packing, labelling, marking, placarding, stowage, segregation and carriage, in order to be in compliance with all relevant provisions for dangerous goods of ADR. 1.7.6 Non-compliance 1.7.6.1 In the event of a non-compliance with any limit in ADR applicable to radiation level or contamination, (a) (b) The consignor shall be informed of the non-compliance by: (i) the carrier if the non-compliance is identified during carriage; or (ii) the consignee if the non-compliance is identified at receipt; The carrier, consignor or consignee, as appropriate shall: (i) take immediate steps to mitigate the consequences of the non-compliance; (ii) investigate the non-compliance and its causes, circumstances and consequences; (iii) take appropriate action to remedy the causes and circumstances that led to the non-compliance and to prevent a recurrence of similar circumstances that led to the non-compliance; and (iv) communicate to the competent authority(ies) on the causes of the noncompliance and on corrective or preventive actions taken or to be taken; and (c) The communication of the non-compliance to the consignor and competent authority(ies), respectively, shall be made as soon as practicable and it shall be immediate whenever an emergency exposure situation has developed or is developing. - 64 - Copyright © United Nations, 2010. All rights reserved CHAPTER 1.8 CHECKS AND OTHER SUPPORT MEASURES TO ENSURE COMPLIANCE WITH SAFETY REQUIREMENTS 1.8.1 Administrative controls of dangerous goods 1.8.1.1 The competent authorities of the Contracting Parties may, on their national territory, at any time, conduct spot checks to verify whether the requirements concerning the carriage of dangerous goods have been met including, in accordance with 1.10.1.5, those concerning security measures. These checks shall, however, be made without endangering persons, property or the environment and without major disruption of road services. 1.8.1.2 Participants in the carriage of dangerous goods (Chapter 1.4) shall, without delay, in the context of their respective obligations, provide the competent authorities and their agents with the necessary information for carrying out the checks. 1.8.1.3 The competent authorities may also, for the purposes of carrying out checks on the premises of the enterprises participating in the carriage of dangerous goods (Chapter 1.4), make inspections, consult the necessary documents and remove samples of dangerous goods or packagings for examination, provided that safety is not jeopardized thereby. The participants in the carriage of dangerous goods (Chapter 1.4) shall also make the vehicles or parts of vehicles and the equipment and installations accessible for the purpose of checking where this is possible and reasonable. They may, if they deem necessary, designate a person from the enterprise to accompany the representative of the competent authority. 1.8.1.4 If the competent authorities observe that the requirements of ADR have not been met, they may prohibit a consignment or interrupt a transport operation until the defects observed are rectified, or they may prescribe other appropriate measures. Immobilization may take place on the spot or at another place selected by the authorities for safety reasons. These measures shall not cause a major disruption in road services. 1.8.2 Mutual administrative support 1.8.2.1 The Contracting Parties shall agree on mutual administrative support for the implementation of ADR. 1.8.2.2 When a Contracting Party has reasons to observe that the safety of the carriage of dangerous goods on its territory is compromised as a result of very serious or repeated infringements by an enterprise which has its headquarters on the territory of another Contracting Party, it shall notify the competent authorities of this Contracting Party of such infringements. The competent authorities of the Contracting Party on the territory of which the very serious or repeated infringements were observed may request the competent authorities of the Contracting Party on the territory of which the enterprise has its headquarters to take appropriate measures against the offender(s). The transmission of data referring to persons shall not be permitted unless it is necessary for the prosecution of very serious or repeated infringements. 1.8.2.3 The authorities notified shall communicate to the competent authorities of the Contracting Party on the territory of which the infringements were observed, the measures which have, if necessary, been taken with respect to the enterprise. - 65 - Copyright © United Nations, 2010. All rights reserved 1.8.3 Safety adviser 1.8.3.1 Each undertaking, the activities of which include the carriage, or the related packing, loading, filling or unloading, of dangerous goods by road shall appoint one or more safety advisers for the carriage of dangerous goods, responsible for helping to prevent the risks inherent in such activities with regard to persons, property and the environment. 1.8.3.2 The competent authorities of the Contracting Parties may provide that these requirements shall not apply to undertakings: 1.8.3.3 (a) The activities of which concern quantities in each transport unit smaller than those referred to in 1.1.3.6, 1.7.1.4 and in Chapters 3.3, 3.4 and 3.5; or (b) The main or secondary activities of which are not the carriage or the related loading or unloading of dangerous goods but which occasionally engage in the national carriage or the related loading or unloading of dangerous goods posing little danger or risk of pollution. The main task of the adviser shall be, under the responsibility of the head of the undertaking, to seek by all appropriate means and by all appropriate action, within the limits of the relevant activities of that undertaking, to facilitate the conduct of those activities in accordance with the requirements applicable and in the safest possible way. With regard to the undertaking’s activities, the adviser has the following duties in particular: - monitoring compliance with the requirements governing the carriage of dangerous goods; - advising his undertaking on the carriage of dangerous goods; - preparing an annual report to the management of his undertaking or a local public authority, as appropriate, on the undertaking's activities in the carriage of dangerous goods. Such annual reports shall be preserved for five years and made available to the national authorities at their request. The adviser's duties also include monitoring the following practices and procedures relating to the relevant activities of the undertaking: - the procedures for compliance with the requirements governing the identification of dangerous goods being transported; - the undertaking's practice in taking account, when purchasing means of transport, of any special requirements in connection with the dangerous goods being transported; - the procedures for checking the equipment used in connection with the carriage, loading or unloading of dangerous goods; - the proper training of the undertaking's employees and the maintenance of records of such training; - the implementation of proper emergency procedures in the event of any accident or incident that may affect safety during the carriage, loading or unloading of dangerous goods; - 66 - Copyright © United Nations, 2010. All rights reserved - investigating and, where appropriate, preparing reports on serious accidents, incidents or serious infringements recorded during the carriage, loading or unloading of dangerous goods; - the implementation of appropriate measures to avoid the recurrence of accidents, incidents or serious infringements; - the account taken of the legal prescriptions and special requirements associated with the carriage of dangerous goods in the choice and use of sub-contractors or third parties; - verification that employees involved in the carriage, loading or unloading of dangerous goods have detailed operational procedures and instructions; - the introduction of measures to increase awareness of the risks inherent in the carriage, loading and unloading of dangerous goods; - the implementation of verification procedures to ensure the presence on board the means of transport of the documents and safety equipment which must accompany transport and the compliance of such documents and equipment with the regulations; - the implementation of verification procedures to ensure compliance with the requirements governing loading and unloading; - the existence of the security plan indicated in 1.10.3.2. 1.8.3.4 The adviser may also be the head of the undertaking, a person with other duties in the undertaking, or a person not directly employed by that undertaking, provided that that person is capable of performing the duties of adviser. 1.8.3.5 Each undertaking concerned shall, on request, inform the competent authority or the body designated for that purpose by each Contracting Party of the identity of its adviser. 1.8.3.6 Whenever an accident affects persons, property or the environment or results in damage to property or the environment during carriage, loading or unloading carried out by the undertaking concerned, the adviser shall, after collecting all the relevant information, prepare an accident report to the management of the undertaking or to a local public authority, as appropriate. That report shall not replace any report by the management of the undertaking which might be required under any other international or national legislation. 1.8.3.7 An adviser shall hold a vocational training certificate, valid for transport by road. That certificate shall be issued by the competent authority or the body designated for that purpose by each Contracting Party. 1.8.3.8 To obtain a certificate, a candidate shall undergo training and pass an examination approved by the competent authority of the Contracting Party. 1.8.3.9 The main aims of the training shall be to provide candidates with sufficient knowledge of the risks inherent in the carriage of dangerous goods, of the laws, regulations and administrative provisions applicable to the modes of transport concerned and of the duties listed in 1.8.3.3. 1.8.3.10 The examination shall be organized by the competent authority or by an examining body designated by the competent authority. The examining body shall not be a training provider. - 67 - Copyright © United Nations, 2010. All rights reserved The examining body shall be designated in writing. This approval may be of limited duration and shall be based on the following criteria: 1.8.3.11 - competence of the examining body; - specifications of the form of the examinations the examining body is proposing; - measures intended to ensure that examinations are impartial; - independence of the body from all natural or legal persons employing safety advisers. The aim of the examination is to ascertain whether candidates possess the necessary level of knowledge to carry out the duties incumbent upon a safety adviser as listed in 1.8.3.3, for the purpose of obtaining the certificate prescribed in sub-section 1.8.3.7, and it shall cover at least the following subjects: (a) Knowledge of the types of consequences which may be caused by an accident involving dangerous goods and knowledge of the main causes of accidents; (b) Requirements under national law, international conventions and agreements, with regard to the following in particular: - classification of dangerous goods (procedure for classifying solutions and mixtures, structure of the list of substances, classes of dangerous goods and principles for their classification, nature of dangerous goods transported, physical, chemical and toxicological properties of dangerous goods); - general packing provisions, provisions for tanks and tank-containers (types, code, marking, construction, initial and periodic inspection and testing); - marking and labelling, placarding and orange plates marking (marking and labelling of packages, placing and removal of placards and orange plates); - particulars in transport documents (information required); - method of consignment and restrictions on dispatch (full load, carriage in bulk, carriage in intermediate bulk containers, carriage in containers, carriage in fixed or demountable tanks); - transport of passengers; - prohibitions and precautions relating to mixed loading; - segregation of goods; - limitation of the quantities carried and quantities exemptions; - handling and stowage (loading and unloading - filling ratios -, stowage and segregation); - cleaning and/or degassing before loading and after unloading; - crews, vocational training; - vehicle documents (transport documents, instructions in writing, vehicle approval certificate, driver training certificate, copies of any derogations, other documents); - 68 - Copyright © United Nations, 2010. All rights reserved - instructions in writing (implementation of the instructions and crew protection equipment); - supervision requirements (parking); - traffic regulations and restrictions; - operational discharges or accidental leaks of pollutants; - requirements relating to transport equipment. 1.8.3.12 Examinations 1.8.3.12.1 The examination shall consist of a written test which may be supplemented by an oral examination. 1.8.3.12.2 The use in the written test of documentation other than international or national regulations is not permitted. 1.8.3.12.3 Electronic media may be used only if provided by the examining body. There shall be no means of a candidate introducing further data to the electronic media provided; the candidate may only answer the questions posed. 1.8.3.12.4 The written test shall consist of two parts: (a) (b) Candidates shall receive a questionnaire. It shall include at least 20 open questions covering at least the subjects mentioned in the list in 1.8.3.11. However, multiple choice questions may be used. In this case, two multiple choice questions count as one open question. Amongst these subjects particular attention shall be paid to the following subjects: - general preventive and safety measures; - classification of dangerous goods; - general packing provisions, including tanks, tank-containers, tank-vehicles, etc.; - danger markings and labels; - information in transport document; - handling and stowage; - crew, vocational training; - vehicle documents and transport certificates; - instructions in writing; - requirements concerning transport equipment; Candidates shall undertake a case study in keeping with the duties of the adviser referred to in 1.8.3.3, in order to demonstrate that they have the necessary qualifications to fulfil the task of adviser. - 69 - Copyright © United Nations, 2010. All rights reserved 1.8.3.13 The Contracting Parties may decide that candidates who intend working for undertakings specializing in the carriage of certain types of dangerous goods need only be questioned on the substances relating to their activities. These types of goods are: - Class 1; - Class 2; - Class 7; - Classes 3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1, 6.2, 8 and 9; - UN Nos. 1202, 1203, 1223, 3475, and aviation fuel classified under UN Nos. 1268 or 1863. The certificate prescribed in 1.8.3.7 shall clearly indicate that it is only valid for one type of the dangerous goods referred to in this sub-section and on which the adviser has been questioned under the conditions defined in 1.8.3.12. Certificates of training as safety advisers issued before 1 January 2009 for UN Nos. 1202, 1203 and 1223 are also valid for UN No. 3475 and aviation fuel classified under UN Nos. 1268 or 1863. 1.8.3.14 The competent authority or the examining body shall keep a running list of the questions that have been included in the examination. 1.8.3.15 The certificate prescribed in 1.8.3.7 shall take the form laid down in 1.8.3.18 and shall be recognized by all Contracting Parties. 1.8.3.16 Validity and renewal of certificates 1.8.3.16.1 The certificate shall be valid for five years. The period of the validity of a certificate shall be extended from the date of its expiry for five years at a time where, during the year before its expiry, its holder has passed an examination. The examination shall be approved by the competent authority. 1.8.3.16.2 The aim of the examination is to ascertain that the holder has the necessary knowledge to carry out the duties set out in 1.8.3.3. The knowledge required is set out in 1.8.3.11 (b) and shall include the amendments to the regulations introduced since the award of the last certificate. The examination shall be held and supervised on the same basis as in 1.8.3.10 and 1.8.3.12 to 1.8.3.14. However, holders need not undertake the case study specified in 1.8.3.12.4 (b). 1.8.3.17 (Deleted) - 70 - Copyright © United Nations, 2010. All rights reserved 1.8.3.18 Form of certificate Certificate of training as safety adviser for the transport of dangerous goods Certificate No: .................................................................................................................................................. Distinguishing sign of the State issuing the certificate: .................................................................................... Surname: ........................................................................................................................................................... Forename(s): ..................................................................................................................................................... Date and place of birth: .................................................................................................................................... Nationality: ....................................................................................................................................................... Signature of holder: .......................................................................................................................................... Valid until ............... for undertakings which transport dangerous goods and for undertakings which carry out related loading or unloading: □ by road □ by rail □ by inland waterway Issued by: .......................................................................................................................................................... Date: ......................................................................... Signature: ................................................................... Extended until: ......................................................... By: .............................................................................. Date: ......................................................................... Signature: ................................................................... - 71 - Copyright © United Nations, 2010. All rights reserved 1.8.4 List of competent authorities and bodies designated by them The Contracting Parties shall communicate to the Secretariat of the United Nations Economic Commission for Europe the addresses of the authorities and bodies designated by them which are competent in accordance with national law to implement ADR, referring in each case to the relevant requirement of ADR and giving the addresses to which the relevant applications should be made. The Secretariat of the United Nations Economic Commission for Europe shall establish a list on the basis of the information received and shall keep it up-to-date. It shall communicate this list and the amendments thereto to the Contracting Parties. 1.8.5 Notifications of occurrences involving dangerous goods 1.8.5.1 If a serious accident or incident takes place during loading, filling, carriage or unloading of dangerous goods on the territory of a Contracting Party, the loader, filler, carrier or consignee, respectively, shall ascertain that a report conforming to the model prescribed in 1.8.5.4 is made to the competent authority of the Contracting Party concerned. 1.8.5.2 The Contracting Party shall in turn, if necessary, make a report to the Secretariat of the United Nations Economic Commission for Europe with a view to informing the other Contracting Parties. 1.8.5.3 An occurrence subject to report in accordance with 1.8.5.1 has occurred if dangerous goods were released or if there was an imminent risk of loss of product, if personal injury, material or environmental damage occurred, or if the authorities were involved and one or more of the following criteria has/have been met: Personal injury means an occurrence in which death or injury directly relating to the dangerous goods carried has occurred, and where the injury (a) Requires intensive medical treatment; (b) Requires a stay in hospital of at least one day; or (c) Results in the inability to work for at least three consecutive days. Loss of product means the release of dangerous goods (a) Of transport category 0 or 1 in quantities of 50 kg / 50 l or more; (b) Of transport category 2 in quantities of 333 kg / 333 l or more; or (c) Of transport category 3 or 4 in quantities of 1 000 kg / 1 000 l or more. The loss of product criterion also applies if there was an imminent risk of loss of product in the above-mentioned quantities. As a rule, this has to be assumed if, owing to structural damage, the means of containment is no longer suitable for further carriage or if, for any other reason, a sufficient level of safety is no longer ensured (e.g. owing to distortion of tanks or containers, overturning of a tank or fire in the immediate vicinity). If dangerous goods of Class 6.2 are involved, the obligation to report applies without quantity limitation. - 72 - Copyright © United Nations, 2010. All rights reserved In occurrences involving Class 7 material, the criteria for loss of product are: (a) Any release of radioactive material from the packages; (b) Exposure leading to a breach of the limits set out in the regulations for protection of workers and members of the public against ionizing radiation (Schedule II of IAEA Safety Series No. 115 – "International Basic Safety Standards for Protection Against Ionizing Radiation and for Safety of Radiation Sources"); or (c) Where there is reason to believe that there has been a significant degradation in any package safety function (containment, shielding, thermal protection or criticality) that may have rendered the package unsuitable for continued carriage without additional safety measures. NOTE: See the requirements of 7.5.11 CV33 (6) for undeliverable consignments. Material damage or environmental damage means the release of dangerous goods, irrespective of the quantity, where the estimated amount of damage exceeds 50,000 Euros. Damage to any directly involved means of carriage containing dangerous goods and to the modal infrastructure shall not be taken into account for this purpose. Involvement of authorities means the direct involvement of the authorities or emergency services during the occurrence involving dangerous goods and the evacuation of persons or closure of public traffic routes (roads/railways) for at least three hours owing to the danger posed by the dangerous goods. If necessary, the competent authority may request further relevant information. 1.8.5.4 Model for report on occurrences during the carriage of dangerous goods - 73 - Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved Report on occurrences during the carriage of dangerous goods in accordance with RID/ADR section 1.8.5 Carrier/Railway infrastructure operator: ............................................................................................................................…………………………………………. Address: ............................................................................................................................................................….………………… Contact name: .......................................………… Telephone: ............................ Fax: ................................…….…. (The competent authority shall remove this cover sheet before forwarding the report) - 75 - Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved 1. Mode □ Rail □ Road Wagon number (optional) Vehicle registration (optional) .........................................................……………………… ............................................................…………………... 2. Date and location of occurrence Year: ………………….. Month: …………………. Rail □ Station □ Shunting/marshalling yard □ Loading/unloading/transhipment site Location / Country: …………………………………… or □ Open line: Description of line: …………………………………… Kilometres: ………………………………….………... Day: …………………. Time: …………………………... Road □ Built-up area □ Loading/unloading/transhipment site □ Open road Location / Country: ……………………………….… 3. Topography □ Gradient/incline □ Tunnel □ Bridge/Underpass □ Crossing 4. Particular weather conditions □ Rain □ Snow □ Ice □ Fog □ Thunderstorm □ Storm Temperature: ..... °C 5. Description of occurrence □ Derailment/Leaving the road □ Collision □ Overturning/Rolling over □ Fire □ Explosion □ Loss □ Technical fault Additional description of occurrence: ..........................................................................................................................................…………………....................... ............................................................................................................................................................................................. ............................................................................................................................................................................................. ............................................................................................................................................................................................. ............................................................................................................................................................................................. ............................................................................................................................................................................................. ............………………………………………………………………………………………………………………….… ………………………………………………………………………………………………………………………….… ……………………………………………………………………………………………………………………………. - 77 - Copyright © United Nations, 2010. All rights reserved 6. Dangerous goods involved UN Number (1) Class Packing Estimated quantity of Group loss of products (kg or l) (2) Means of containment (3) Means of containment material Type of failure of means of containment (4) For dangerous goods assigned to collective entries to (2) For Class 7, indicate values according to the criteria in which special provision 274 applies, also the technical 1.8.5.3. name shall be indicated. (3) (4) Indicate the appropriate number Indicate the appropriate number 1 Packaging 1 Loss 2 IBC 2 Fire 3 Large packaging 3 Explosion 4 Small container 4 Structural failure 5 Wagon 6 Vehicle 7 Tank-wagon 8 Tank-vehicle 9 Battery-wagon 10 Battery-vehicle 11 Wagon with demountable tanks 12 Demountable tank 13 Large container 14 Tank-container 15 MEGC 16 Portable tank 7. Cause of occurrence (if clearly known) □ Technical fault □ Faulty load securing □ Operational cause (rail operation) □ Other: ............................................................................................................................................................................................. ...............................................................................................................................................…………………………….. ……………………………………………………………………………………………………………………………. 8. Consequences of occurrence Personal injury in connection with the dangerous goods involved: □ Deaths (number: ......) □ Injured (number: ......) (1) Loss of product: □ Yes □ No □ Imminent risk of loss of product Material/Environmental damage: □ Estimated level of damage ≤ 50,000 Euros □ Estimated level of damage > 50,000 Euros Involvement of authorities: □ Yes □ Evacuation of persons for a duration of at least three hours caused by the dangerous goods involved □ Closure of public traffic routes for a duration of at least three hours caused by the dangerous goods involved □ No If necessary, the competent authority may request further relevant information. - 78 - Copyright © United Nations, 2010. All rights reserved 1.8.6 Administrative controls for application of the conformity assessments, periodic inspections, intermediate inspections and exceptional checks described in 1.8.7 1.8.6.1 Approval of inspection bodies The competent authority may approve inspection bodies for conformity assessments, periodic inspections, intermediate inspections, exceptional checks and surveillance of the inhouse inspection service as specified in 1.8.7. 1.8.6.2 Operational obligations for the competent authority, its delegate or inspection body 1.8.6.2.1 The competent authority, its delegate or inspection body shall carry out conformity assessments, periodic inspections, intermediate inspections and exceptional checks in a proportionate manner, avoiding unnecessary burdens. The competent authority, its delegate or inspection body shall perform its activities taking into consideration the size, the sector and the structure of the undertakings involved, the relative complexity of the technology and the serial character of production. 1.8.6.2.2 Nevertheless the competent authority, its delegate or inspection body shall respect the degree of rigour and the level of protection required for the compliance of the transportable pressure equipment by the provisions of parts 4 and 6 as applicable. 1.8.6.2.3 Where a competent authority, its delegate or inspection body finds out that requirements laid down in parts 4 or 6 have not been met by the manufacturer, it shall require the manufacturer to take appropriate corrective measures and it shall not issue any type approval certificate or certificate of conformity. 1.8.6.3 Information obligation Contracting Parties to ADR shall publish their national procedures for the assessment, appointment and monitoring of inspection bodies and of any changes to that information. 1.8.6.4 Delegation of inspection tasks NOTE: In-house inspection services according to 1.8.7.6 are not covered by 1.8.6.4. 1.8.6.4.1 Where an inspection body uses the services of any other entity (e.g. subcontractor, subsidiary), to carry out specific tasks connected with the conformity assessment, periodic inspection, intermediate inspection or exceptional checks, this entity shall be included in the accreditation of the inspection body, or it shall be accredited separately. The inspection body shall ensure that this entity meets the requirements set out for the tasks given to it with the same level of competence and safety as laid down for inspection bodies (see 1.8.6.8) and the inspection body shall monitor it. The inspection body shall inform the competent authority about the above mentioned arrangements. 1.8.6.4.2 The inspection body shall take full responsibility for the tasks performed by such entities wherever the tasks are performed by them. 1.8.6.4.3 The inspection body shall not delegate the whole task of conformity assessment, periodic inspection, intermediate inspection or exceptional checks. In any case, the assessment and the issue of certificates shall be carried out by the inspection body itself. 1.8.6.4.4 Activities shall not be delegated without the agreement of the applicant. - 79 - Copyright © United Nations, 2010. All rights reserved 1.8.6.4.5 The inspection body shall keep at the disposal of the competent authority the relevant documents concerning the assessment of the qualifications and the work carried out by the above mentioned entities. 1.8.6.5 Information obligations for inspection bodies Any inspection body shall inform the competent authority, which had approved it, of the following: (a) Except when the provisions of 1.8.7.2.4 apply, any refusal, restriction, suspension or withdrawal of type approval certificates; (b) Any circumstance(s) affecting the scope of and conditions for the approval as granted by the competent authority; (c) Any request for information on conformity assessment activities performed which they have received from competent authorities monitoring compliance according to 1.8.1 or 1.8.6.6; (d) On request, conformity assessment activities performed within the scope of their approval and any other activity performed, including delegation of tasks. 1.8.6.6 The competent authority shall ensure the monitoring of the inspection bodies and shall revoke or restrict the approval given, if it notes that an approved body is no longer in compliance with the approval and the requirements of 1.8.6.8 or does not follow the procedures specified in the provisions of ADR. 1.8.6.7 If the approval of the inspection body is revoked or restricted or if the inspection body ceased activity, the competent authority shall take the appropriate steps to ensure that the files are either processed by another inspection body or kept available. 1.8.6.8 The inspection body shall: (a) Have a staff with an organisational structure, capable, trained, competent and skilled, to satisfactorily perform its technical functions; (b) Have access to suitable and adequate facilities and equipment; (c) Operate in an impartial manner and be free from any influence which could prevent it from doing so; (d) Ensure commercial confidentiality of the commercial and proprietary activities of the manufacturer and other bodies; (e) Maintain clear demarcation between actual inspection body functions and unrelated functions; (f) Have a documented quality system; (g) Ensure that the tests and inspections specified in the relevant standard and in ADR are performed; and (h) Maintain an effective and appropriate report and record system in accordance with 1.8.7 and 1.8.8. - 80 - Copyright © United Nations, 2010. All rights reserved The inspection body shall additionally be accredited according to the standard EN ISO/IEC 17020:2004, as specified in 6.2.2.10, 6.2.3.6 and TA4 and TT9 of 6.8.4. An inspection body starting a new activity may be approved temporarily. Before temporary designation, the competent authority shall ensure that the inspection body meets the requirements of the standard EN ISO/IEC 17020:2004. The inspection body shall be accredited in its first year of activity to be able to continue this new activity. 1.8.7 Procedures for conformity assessment and periodic inspection NOTE: In this section, "relevant body" means a body assigned in 6.2.2.10 when certifying UN pressure receptacles, in 6.2.3.6 when approving non-UN pressure receptacles and in special provisions TA4 and TT9 of 6.8.4. 1.8.7.1 General provisions 1.8.7.1.1 The procedures in section 1.8.7 shall be applied according to 6.2.3.6 when approving nonUN pressure receptacles and according to TA4 and TT9 of 6.8.4 when approving tanks, battery-vehicles and MEGCs. The procedures in section 1.8.7 may be applied according to the table in 6.2.2.10 when certifying UN pressure receptacles. 1.8.7.1.2 Each application for (a) The type approval in accordance with 1.8.7.2 or; (b) The supervision of manufacture in accordance with 1.8.7.3 and the initial inspection and test in accordance with 1.8.7.4; or (c) The periodic inspection, intermediate inspection and exceptional checks in accordance with 1.8.7.5 shall be lodged by the applicant with a single competent authority, its delegate or an approved inspection body of his choice. 1.8.7.1.3 1.8.7.1.4 The application shall include: (a) The name and address of the applicant; (b) For conformity assessment where the applicant is not the manufacturer, the name and address of the manufacturer; (c) A written declaration that the same application has not been lodged with any other competent authority, its delegate or inspection body; (d) The relevant technical documentation specified in 1.8.7.7; (e) A statement allowing the competent authority, its delegate or inspection body access for inspection purposes to the locations of manufacture, inspection, testing and storage and providing it with all necessary information. Where the applicant can demonstrate to the satisfaction of the competent authority or its delegated inspection body conformity with 1.8.7.6 the applicant may establish an in-house inspection service which may perform part or all of the inspections and tests when specified in 6.2.2.10 or 6.2.3.6. - 81 - Copyright © United Nations, 2010. All rights reserved 1.8.7.1.5 Design type approval certificates and certificates of conformity - including the technical documentation - shall be retained by the manufacturer or by the applicant for the type approval, if he is not the manufacturer, and by the inspection body, who issued the certificate, for a period of at least 20 years starting from the last date of production of products of the same type. 1.8.7.1.6 When a manufacturer or owner intends to cease operation, he shall send the documentation to the competent authority. The competent authority shall then retain the documentation for the rest of the period specified in 1.8.7.1.5. 1.8.7.2 Type approval Type approvals authorise the manufacture of pressure receptacles, tanks, battery-vehicles or MEGCs within the period of validity of that approval. 1.8.7.2.1 1.8.7.2.2 The applicant shall: (a) In the case of pressure receptacles, place at the disposal of the relevant body representative samples of the production envisaged. The relevant body may request further samples if required by the test programme; (b) In the case of tanks, battery-vehicles or MEGCs, give access to the prototype for type testing. The relevant body shall: (a) Examine the technical documentation specified in 1.8.7.7.1 to verify that the design is in accordance with the relevant provisions of ADR, and the prototype or the prototype lot has been manufactured in conformity with the technical documentation and is representative of the design; (b) Perform the examinations and witness the tests specified in ADR, to determine that the provisions have been applied and fulfilled, and the procedures adopted by the manufacturer meet the requirements; (c) Check the certificate(s) issued by the materials manufacturer(s) against the relevant provisions of ADR; (d) As applicable, approve the procedures for the permanent joining of parts or check that they have been previously approved, and verify that the staff undertaking the permanent joining of parts and the non-destructive tests are qualified or approved; (e) Agree with the applicant the location and testing facilities where the examinations and necessary tests are to be carried out. The relevant body shall issue a type-examination report to the applicant. 1.8.7.2.3 Where the type satisfies all applicable provisions, the competent authority, its delegate or the inspection body, shall issue a type approval certificate to the applicant. This certificate shall contain: (a) The name and address of the issuer; (b) The name and address of the manufacturer and of the applicant when the applicant is not the manufacturer; - 82 - Copyright © United Nations, 2010. All rights reserved (c) A reference to the version of ADR and standards used for the type examination; (d) Any requirements resulting from the examination; (e) The necessary data for identification of the type and variation, as defined by the relevant standard; (f) The reference to the type examination report(s); and (g) The maximum period of validity of the type approval. A list of the relevant parts of the technical documentation shall be annexed to the certificate (see 1.8.7.7.1). 1.8.7.2.4 The type approval shall be valid for a maximum of ten years. If within that period the relevant technical requirements of ADR (including referenced standards) have changed so that the approved type is no longer in conformity with them, the relevant body which issued the type approval shall withdraw it and inform the holder of the type approval. NOTE: For the ultimate dates for withdrawal of existing type approvals, see column (5) of the tables in 6.2.4 and 6.8.2.6 or 6.8.3.6 as appropriate. If a type approval has expired or has been withdrawn, the manufacture of the pressure receptacles, tanks, battery-vehicles or MEGCs according to that type approval is no longer authorised. In such a case, the relevant provisions concerning the use, periodic inspection and intermediate inspection of pressure receptacles, tanks, battery-vehicles or MEGCs contained in the type approval which has expired or has been withdrawn shall continue to apply to these pressure receptacles, tanks, battery-vehicles or MEGCs constructed before the expiry or the withdrawal if they may continue to be used. They may continue to be used as long as they remain in conformity with the requirements of ADR. If they are no longer in conformity with the requirements of ADR they may continue to be used only if such use is permitted by relevant transitional measures in Chapter 1.6. Type approvals may be renewed by a complete review and assessment for conformity with the provisions of ADR applicable at the date of renewal. Renewal is not permitted after a type approval has been withdrawn. Interim amendments of an existing type approval (e.g. for pressure receptacles minor amendments such as the addition of further sizes or volumes not affecting conformity, or for tanks see 6.8.2.3.2) do not extend or modify the original validity of the certificate. NOTE: The review and assessment of conformity can be done by a body other than the one which issued the original type approval. The issuing body shall keep all documents for the type approval (see 1.8.7.7.1) for the whole period of validity including its renewals if granted. 1.8.7.3 Supervision of manufacture 1.8.7.3.1 The manufacturing process shall be subject to a survey by the relevant body to ensure the product is produced in conformity with the provisions of the type approval. - 83 - Copyright © United Nations, 2010. All rights reserved 1.8.7.3.2 The applicant shall take all the necessary measures to ensure that the manufacturing process complies with the applicable provisions of ADR and of the type approval certificate and its annexes. 1.8.7.3.3 The relevant body shall: (a) Verify the conformity with the technical documentation specified in 1.8.7.7.2; (b) Verify that the manufacturing process produces products in conformity with the requirements and the documentation which apply to it; (c) Verify the traceability of materials and check the material certificate(s) against the specifications; (d) As applicable, verify that the personnel undertaking the permanent joining of parts and the non-destructive tests are qualified or approved; (e) Agree with the applicant on the location where the examinations and necessary tests are to be carried out; and (f) Record the results of its survey. 1.8.7.4 Initial inspection and tests 1.8.7.4.1 The applicant shall: 1.8.7.4.2 (a) Affix the marks specified in ADR; and (b) Supply to the relevant body the technical documentation specified in 1.8.7.7. The relevant body shall: (a) Perform the necessary examinations and tests in order to verify that the product is manufactured in accordance with the type approval and the relevant provisions; (b) Check the certificates supplied by the manufacturers of service equipment against the service equipment; (c) Issue an initial inspection and test report to the applicant relating to the detailed tests and verifications carried out and the verified technical documentation; (d) Draw up a written certificate of conformity of the manufacture and affix its registered mark when the manufacture satisfies the provisions; and (e) Check if the type approval remains valid after provisions of ADR (including referenced standards) relevant to the type approval have changed. The certificate in (d) and report in (c) may cover a number of items of the same type (group certificate or report). 1.8.7.4.3 The certificate shall contain as a minimum: (a) The name and address of the relevant body; (b) The name and address of the manufacturer and the name and address of the applicant, if not the manufacturer; - 84 - Copyright © United Nations, 2010. All rights reserved (c) A reference to the version of the ADR and standards used for the initial inspections and tests; (d) The results of the inspections and tests; (e) The data for identification of the inspected product(s), at least the serial number or for non refillable cylinders the batch number; and (f) The type approval number. 1.8.7.5 Periodic inspection, intermediate inspection and exceptional checks 1.8.7.5.1 The relevant body shall: 1.8.7.5.2 (a) Perform the identification and verify the conformity with the documentation; (b) Carry out the inspections and witness the tests in order to check that the requirements are met; (c) Issue reports of the results of the inspections and tests, which may cover a number of items; and (d) Ensure that the required marks are applied. Reports of periodic inspections and tests of pressure receptacles shall be retained by the applicant at least until the next periodic inspection. NOTE: For tanks, see provisions for tank records in 4.3.2.1.7. 1.8.7.6 Surveillance of the applicant’s in-house inspection service 1.8.7.6.1 The applicant shall: 1.8.7.6.2 (a) Implement an in-house inspection service with a quality system for inspections and tests documented in 1.8.7.7.5 and subject to surveillance; (b) Fulfil the obligations arising out of the quality system as approved and to ensure that it remains satisfactory and efficient; (c) Appoint trained and competent personnel for the in-house inspection service; and (d) Affix the registered mark of the inspection body where appropriate. The inspection body shall carry out an initial audit. If satisfactory the inspection body shall issue an authorisation for a period not exceeding three years. The following provisions shall be met: (a) This audit shall confirm that the inspections and tests performed on the product are in compliance with the requirements of ADR; (b) The inspection body may authorise the in-house inspection service of the applicant to affix the registered mark of the inspection body to each approved product; (c) The authorisation may be renewed after a satisfactory audit in the last year prior to the expiry. The new period of validity shall begin with the date of expiry of the authorisation; and - 85 - Copyright © United Nations, 2010. All rights reserved (d) 1.8.7.6.3 The auditors of the inspection body shall be competent to carry out the assessment of conformity of the product covered by the quality system. The inspection body shall carry out periodic audits within the duration of the authorisation to make sure that the applicant maintains and applies the quality system. The following provisions shall be met: (a) A minimum of two audits shall be carried out in a 12 month period; (b) The inspection body may require additional visits, training, technical changes, modifications of the quality system, restrict or prohibit the inspections and tests to be done by the applicant; (c) The inspection body shall assess any changes in the quality system and decide whether the modified quality system will still satisfy the requirements of the initial audit or whether a full reassessment is required; (d) The auditors of the inspection body shall be competent to carry out the assessment of conformity of the product covered by the quality system; and (e) The inspection body shall provide the applicant with a visit or audit report and, if a test has taken place, with a test report. 1.8.7.6.4 In cases of non conformity with the relevant requirements the inspection body shall ensure that corrective measures are taken. If corrective measures are not taken in due time, the inspection body shall suspend or withdraw the permission for the in-house inspection service to carry out its activities. The notice of suspension or withdrawal shall be transmitted to the competent authority. A report shall be provided to the applicant giving detailed reasons for the decisions taken by the inspection body. 1.8.7.7 Documents The technical documentation shall enable an assessment to be made of conformity with the relevant requirements. 1.8.7.7.1 Documents for type approval The applicant shall provide as appropriate: (a) The list of standards used for the design and manufacture; (b) A description of the type including all variations; (c) The instructions according to the relevant column of table A of Chapter 3.2 or a list of dangerous goods to be transported for dedicated products; (d) A general assembly drawing or drawings; (e) The detailed drawings, including the dimensions used for the calculations, of the product, the service equipment, the structural equipment, the marking and/or the labelling necessary to verify the conformity; (f) The calculation notes, results and conclusions; (g) The list of the service equipment with the relevant technical data and information on the safety devices including the calculation of the relief capacity if relevant; - 86 - Copyright © United Nations, 2010. All rights reserved 1.8.7.7.2 (h) The list of material requested in the standard for manufacture used for every part, subpart, lining, service and structural equipment and the corresponding material specifications or the corresponding declaration of conformity to ADR; (i) The approved qualification of permanent joining process; (j) The description of the heat treatment process(es); and (k) The procedures, descriptions and records of all relevant tests listed in the standards or ADR for the type approval and for the manufacture. Documents for the supervision of manufacture The applicant shall make available as appropriate: 1.8.7.7.3 (a) The documents listed in 1.8.7.7.1; (b) A copy of the type approval certificate; (c) The manufacturing procedures including test procedures; (d) The manufacturing records; (e) The approved qualifications of permanent joining operators; (f) The approved qualifications of the non destructive test operators; (g) The reports of the destructive and non destructive tests; (h) The heat treatment records; and (i) The calibration records. Documents for initial inspection and tests The applicant shall make available as appropriate: 1.8.7.7.4 (a) The documents listed in 1.8.7.7.1 and 1.8.7.7.2; (b) The material certificates of the product and any sub-parts; (c) The declarations of conformity and material certificates of the service equipment; and (d) A declaration of conformity including the description of the product and all the variations adopted from the type approval. Documents for periodic inspections, intermediate inspections and exceptional checks The applicant shall make available as appropriate: (a) For pressure receptacles, the documents specifying special requirements when the manufacturing and periodic inspections and tests standards so require; (b) For tanks: (i) the tank record; and (ii) one or more of the documents mentioned in 1.8.7.7.1 to 1.8.7.7.3. - 87 - Copyright © United Nations, 2010. All rights reserved 1.8.7.7.5 Documents for the assessment of in-house inspection service The applicant for in-house inspection service shall make available the quality system documentation as appropriate: 1.8.7.8 (a) The organisational structure and responsibilities; (b) The relevant inspection and test, quality control, quality assurance and process operation instructions, and systematic actions that will be used; (c) The quality records, such as inspection reports, test data, calibration data and certificates; (d) The management reviews to ensure the effective operation of the quality system arising from the audits in accordance with 1.8.7.6; (e) The process describing how customer and regulation requirements are met; (f) The process for control of documents and their revision; (g) The procedures for dealing with non-conforming products; and (h) The training programmes and qualification procedures for relevant personnel. Products manufactured, approved, inspected and tested according to standards The requirements of 1.8.7.7 are considered to have been complied with if the following standards, as relevant, are applied: Applicable subsection and paragraph 1.8.7.7.1 to 1.8.7.7.4 1.8.8 References Title of the document EN 12972:2007 Tanks for transport of dangerous goods - Testing, inspection and marking of metallic tanks Procedures for conformity assessment of gas cartridges When assessing the conformity of gas cartridges, one of the following procedures shall be applied: (a) The procedure in section 1.8.7 for non-UN pressure receptacles, with the exception of 1.8.7.5; or (b) The procedure in sub-sections 1.8.8.1 to 1.8.8.7. 1.8.8.1 General provisions 1.8.8.1.1 The supervision of manufacture shall be carried out by an Xa body and the tests as required in 6.2.6 shall be carried out either by that Xa body or by an IS-body approved by that Xa body; for definition of Xa and IS bodies see definitions in 6.2.3.6.1. Conformity assessment shall be carried out by the competent authority, its delegate or its approved inspection body of a Contracting Party to ADR. - 88 - Copyright © United Nations, 2010. All rights reserved 1.8.8.1.2 By the application of 1.8.8, the applicant shall demonstrate, ensure and declare on his sole responsibility the conformity of gas cartridges with the provisions of 6.2.6 and all further applicable provisions of ADR. 1.8.8.1.3 The applicant shall (a) Carry out a design type examination of each type of gas cartridges (including materials to be used and variations of that type, e.g. volumes, pressures, drawings and closing and release devices) according to 1.8.8.2; (b) Operate an approved quality system for design, manufacture, inspection and testing according to 1.8.8.3; (c) Operate an approved testing regime according to 1.8.8.4 for the tests required in 6.2.6; (d) Apply for the approval of his quality system for supervision of manufacture and for testing to one Xa body of his choice of the Contracting Party; if the applicant is not established in a Contracting Party he shall apply to one Xa body of a Contracting Party prior to first transport into a Contracting Party; (e) If the gas cartridge is finally assembled from parts manufactured by the applicant by one or more other enterprise(s), provide written instructions how to assemble and fill the gas cartridges to meet the provisions of his type examination certificate. 1.8.8.1.4 Where the applicant and enterprises assembling or filling gas cartridges according to the instructions of the applicant, can demonstrate to the satisfaction of the Xa body conformity with the provisions of 1.8.7.6 excluding 1.8.7.6.1 (d) and 1.8.7.6.2 (b), they may establish an in-house inspection service which may perform part or all of the inspections and tests specified in 6.2.6. 1.8.8.2 Design type examination 1.8.8.2.1 The applicant shall establish a technical documentation for each type of gas cartridges including the technical standard(s) applied. If he chooses to apply a standard not referenced in 6.2.6, he shall add the standard applied to the documentation. 1.8.8.2.2 The applicant shall retain the technical documentation together with samples of that type at the disposal of the Xa body during production and afterwards for a period of minimum five years starting from the last date of production of gas cartridges according to that type examination certificate. 1.8.8.2.3 The applicant shall after careful examination issue a design type certificate which shall be valid for a maximum period of ten years; he shall add this certificate to the documentation. This certificate authorises him to produce gas cartridges of that type for that period. 1.8.8.2.4 If within that period the relevant technical requirements of ADR (including referenced standards) have changed so that the design type is no longer in conformity with them, the applicant shall withdraw his type examination certificate and inform the Xa body. 1.8.8.2.5 The applicant may after careful and complete review reissue the certificate for another period of maximum ten years. - 89 - Copyright © United Nations, 2010. All rights reserved 1.8.8.3 Supervision of manufacture 1.8.8.3.1 The procedure of design type examination as well as the manufacturing process shall be subject to a survey by the Xa body to ensure the type certified by the applicant and the product as produced are in conformity with the provisions of the design type certificate and the applicable provisions of ADR. If 1.8.8.1.3 (e) applies, the assembling and filling enterprises shall be included in that procedure. 1.8.8.3.2 The applicant shall take all the necessary measures to ensure that the manufacturing process complies with the applicable provisions of ADR and of his design type certificate and its annexes. If 1.8.8.1.3 (e) applies, the assembling and filling enterprises shall be included in that procedure. 1.8.8.3.3 The Xa body shall: (a) Verify the conformity of the design type examination of the applicant and conformity of the type of gas cartridges with the technical documentation specified in 1.8.8.2; (b) Verify that the manufacturing process produces products in conformity with the requirements and the documentation which apply to it; if the gas cartridge is finally assembled from parts manufactured by the applicant by one or more enterprise(s), the Xa body shall also verify that the gas cartridges are in full conformity with all applicable provisions after final assembly and filling and that the instructions of the applicant are correctly applied; (c) Verify that the personnel undertaking the permanent joining of parts and the tests are qualified or approved; (d) Record the results of its surveys. 1.8.8.3.4 If the findings of the Xa body show non-conformity of the design type certificate of the applicant or the manufacturing process, he shall require appropriate corrective measures or withdrawal of the certificate from the applicant. 1.8.8.4 Leakproofness test 1.8.8.4.1 The applicant and enterprises finally assembling and filling gas cartridges according to the instructions of the applicant shall: (a) Carry out the tests required in 6.2.6; (b) Record the test results; (c) Issue a certificate of conformity only for gas cartridges, which are in full compliance with the provisions of his design type examination and the applicable provisions of ADR and have successfully passed the tests as required in 6.2.6; (d) Retain the documentation as specified in 1.8.8.7 during production and afterwards for a period of minimum five years from the last date of production of gas cartridges belonging to one type approval for inspection by the Xa body at random intervals; (e) Affix a durable and legible mark identifying the type of gas cartridge, the applicant and the date of production or batch number; where due to limited available space the mark cannot be fully applied to the body of the gas cartridge, he shall affix a durable tag with this information to the gas cartridge or place it together with a gas cartridge in an inner packaging. - 90 - Copyright © United Nations, 2010. All rights reserved 1.8.8.4.2 1.8.8.4.3 The Xa body shall: (a) Perform the necessary examinations and tests at random intervals, but at least shortly after starting of manufacture of a type of gas cartridges and thereafter at least once every three years, in order to verify that the procedure for design type examination of the applicant as well as that the manufacture and testing of the product are carried out in accordance with the design type certificate and the relevant provisions; (b) Check the certificates supplied by the applicant; (c) Carry out the tests as required in 6.2.6 or approve the program of testing and the inhouse inspection service to carry out the tests. The certificate shall contain as a minimum: (a) The name and address of the applicant and, when the final assembly is not carried out by the applicant but by an enterprise or enterprises in accordance with the written instructions of the applicant, the name(s) and address(es) of these enterprises; (b) A reference to the version of ADR and the standard(s) used for manufacture and tests; (c) The result of inspections and tests; (d) The data for the marking as required in 1.8.8.4.1 (e). 1.8.8.5 (Reserved) 1.8.8.6 Surveillance of the in-house inspection service When the applicant or enterprise assembling or filling gas cartridges has established an inhouse inspection service, the provisions of 1.8.7.6 excluding 1.8.7.6.1 (d) and 1.8.7.6.2 (b) shall be applied. The enterprise assembling or filling gas cartridges shall comply with the provisions relevant to the applicant. 1.8.8.7 Documents The provisions of 1.8.7.7.1, 1.8.7.7.2, 1.8.7.7.3 and 1.8.7.7.5 shall be applied. - 91 - Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved CHAPTER 1.9 TRANSPORT RESTRICTIONS BY THE COMPETENT AUTHORITIES 1.9.1 In accordance with Article 4, paragraph 1 of ADR, the entry of dangerous goods into the territory of Contracting Parties may be subject to regulations or prohibitions imposed for reasons other than safety during carriage. Such regulations or prohibitions shall be published in an appropriate form. 1.9.2 Subject to the provisions of 1.9.3, a Contracting Party may apply to vehicles engaged in the international carriage of dangerous goods by road on its territory certain additional provisions not included in ADR, provided that those provisions do not conflict with Article 2, paragraph 2 of the Agreement, and are contained in its domestic legislation applying equally to vehicles engaged in the domestic carriage of dangerous goods by road on the territory of that Contracting Party. 1.9.3 Additional provisions falling within the scope of 1.9.2 are as follows: (a) Additional safety requirements or restrictions concerning vehicles using certain structures such as bridges, vehicles using combined transport modes such as ferries or trains, or vehicles entering or leaving ports or other transport terminals; (b) Requirements for vehicles to follow prescribed routes to avoid commercial or residential areas, environmentally sensitive areas, industrial zones containing hazardous installations or roads presenting severe physical hazards; (c) Emergency requirements regarding routeing or parking of vehicles carrying dangerous goods resulting from extreme weather conditions, earthquake, accident, industrial action, civil disorder or military hostilities; (d) Restrictions on movement of dangerous goods traffic on certain days of the week or year. 1.9.4 The competent authority of the Contracting Party applying on its territory any additional provisions within the scope of 1.9.3 (a) and (d) above shall notify the secretariat of the United Nations Economic Commission for Europe of the additional provisions, which secretariat shall bring them to the attention of the Contracting Parties1. 1.9.5 Tunnel restrictions NOTE: Provisions concerning restrictions for the passage of vehicles through road tunnels are also included in Chapter 8.6. 1.9.5.1 General provisions When applying restrictions to the passage of vehicles carrying dangerous goods through tunnels, the competent authority shall assign the road tunnel to one of the tunnel categories defined in 1.9.5.2.2. Account should be taken of the tunnel characteristics, risk assessment including availability and suitability of alternative routes and modes and traffic management considerations. The same tunnel may be assigned to more than one tunnel category, e.g. depending on the hours of the day, or the day of the week etc. 1 A General Guideline for the Calculation of Risks in the Transport of Dangerous Goods by Road may be consulted on the website of the secretariat of the United Nations Economic Commission for Europe (http://www.unece.org/trans/danger/danger.htm). - 93 - Copyright © United Nations, 2010. All rights reserved 1.9.5.2 Categorization 1.9.5.2.1 The categorization shall be based on the assumption that in tunnels there are three major dangers which may cause numerous victims or serious damage to the tunnel structure: 1.9.5.2.2 (a) Explosions; (b) Release of toxic gas or volatile toxic liquid; (c) Fires. The five tunnel categories are the following: Tunnel category A: No restrictions for the transport of dangerous goods; Tunnel category B: Restriction for dangerous goods which may lead to a very large explosion; The following dangerous goods are considered to fulfil this criterion2: Class 1: Class 3: Class 4.1: Compatibility groups A and L; Classification code D (UN Nos. 1204, 2059, 3064, 3343, 3357 and 3379); Classification codes D and DT; and Self-reactive substances, type B (UN Nos. 3221, 3222, 3231 and 3232); Class 5.2: Organic peroxides, type B (UN Nos. 3101, 3102, 3111 and 3112). When the total net explosive mass per transport unit is greater than 1000 kg: Class 1: Divisions 1.1, 1.2 and 1.5 (except compatibility groups A and L). When carried in tanks: Class 2: Classification codes F, TF and TFC; Class 4.2: Packing group I; Class 4.3: Packing group I; Class 5.1: Packing group I. Class 6.1: UN No. 1510 Tunnel category C: Restriction for dangerous goods which may lead to a very large explosion, a large explosion or a large toxic release; The following dangerous goods are considered to fulfil this criterion2: 2 - the dangerous goods restricted in tunnel category B, and - the following dangerous goods: The assessment is based on the intrinsic dangerous properties of the goods, the type of containment and the quantity carried. - 94 - Copyright © United Nations, 2010. All rights reserved Class 1: Divisions 1.1, 1.2 and 1.5 (except compatibility groups A and L); and Division 1.3 (compatibility groups H and J); Class 7: UN Nos. 2977 and 2978. When the net explosive mass per transport unit is greater than 5000 kg: Class 1: Division 1.3 (compatibility groups C and G). When carried in tanks: Class 2: Classification codes 2A, 2O, 3A and 3O, and classification codes containing the letter T only or letter groups TC, TO and TOC Class 3: Packing group I for classification codes FC, FT1, FT2 and FTC; Class 6.1: Packing group I, except UN No. 1510 Class 8: Packing group I for classification codes CT1, CFT and COT. Tunnel category D: Restriction for dangerous goods which may lead to a very large explosion, to a large explosion, to a large toxic release or to a large fire; The following dangerous goods are considered to fulfil this criterion2: - the dangerous goods restricted in tunnel category C, and - the following dangerous goods: Class 1: Class 2: Class 4.1: Division 1.3 (compatibility groups C and G); Classification codes F, FC, T, TF, TC, TO, TFC and TOC; Self-reactive substances, types C, D, E and F; and UN Nos. 2956, 3241, 3242 and 3251; Class 5.2: Organic peroxides, types C, D, E and F; Class 6.1: Packing group I for classification codes TF1, TFC and TFW; and Toxic by inhalation entries for which special provision 354 is assigned in column (6) of Table A of Chapter 3.2 and toxic by inhalation entries of UN Nos. 3381 to 3390; Class 8: Packing group I for classification codes CT1, CFT and COT; Class 9: Classification codes M9 and M10. When carried in bulk or in tanks: Class 3 Class 4.2: Packing group II; Class 4.3: Packing group II; Class 6.1: Packing group II; and Packing group III for classification code TF2; Class 8: Packing group I for classification codes CF1, CFT and CW1; and Packing group II for classification codes CF1 and CFT Class 9: Classification codes M2 and M3. Tunnel category E: Restriction for all dangerous goods other than UN Nos. 2919, 3291, 3331, 3359 and 3373. 2 The assessment is based on the intrinsic dangerous properties of the goods, the type of containment and the quantity carried. - 95 - Copyright © United Nations, 2010. All rights reserved NOTE: For the dangerous goods assigned to UN Nos. 2919 and 3331, restrictions to the passage through tunnels may, however, be part of the special arrangement approved by the competent authority(ies) on the basis of 1.7.4.2. 1.9.5.3 Provisions for road signs and notification of restrictions 1.9.5.3.1 Contracting Parties shall indicate tunnel prohibitions and alternative routes by means of signs and signals. 1.9.5.3.2 For this purpose, they may use signs C, 3h and D, 10a, 10b and 10c and signals according to the Vienna Convention on Road Signs and Signals (Vienna, 1968) and the European Agreement supplementing the Convention on Road Signs and Signals (Geneva, 1971) as interpreted by the Resolution on Road Signs and Signals (R.E.2) of the UNECE Inland Transport Committee Principal Working Party on Road Transport, as amended. 1.9.5.3.3 In order to facilitate international understanding of signs, the system of signs and signals prescribed in the Vienna Convention is based on the use of shapes, and colours characteristic of each class of signs and wherever possible, on the use of graphic symbols rather than inscriptions. Where Contracting Parties consider it necessary to modify the signs and symbols prescribed, the modifications made shall not alter their essential characteristics. Where Contracting Parties do not apply the Vienna Convention, the prescribed signs and symbols may be modified, provided that the modifications made shall not alter their essential intent. 1.9.5.3.4 Traffic signs and signals intended to prohibit access of vehicles carrying dangerous goods to road tunnels shall be affixed at a place where the choice of alternative routes is possible. 1.9.5.3.5 When access to tunnels is restricted or alternative routes are prescribed, the signs shall be displayed with additional panels as follows: No sign: no restriction Sign with additional panel bearing the letter B: applies to vehicles carrying dangerous goods not allowed in tunnels of category B; Sign with additional panel bearing the letter C: applies to vehicles carrying dangerous goods not allowed in tunnels of category C; Sign with additional panel bearing the letter D: applies to vehicles carrying dangerous goods not allowed in tunnels of category D; Sign with additional panel bearing the letter E: applies to vehicles carrying dangerous goods not allowed in tunnels of category E. 1.9.5.3.6 Tunnel restrictions shall not apply when dangerous goods are carried in accordance with 1.1.3 1.9.5.3.7 Restrictions shall be published officially and made publicly available. Contracting Parties shall notify the secretariat of UNECE of such restrictions and the secretariat shall make this information publicly available on its website. 1.9.5.3.8 When Contracting Parties apply specific operating measures designed to reduce the risks and related to some or all vehicles using tunnels, such as declaration before entering or passage in convoys escorted by accompanying vehicles, such operating measures shall be published officially and made publicly available. - 96 - Copyright © United Nations, 2010. All rights reserved CHAPTER 1.10 SECURITY PROVISIONS NOTE: For the purposes of this Chapter, security means measures or precautions to be taken to minimise theft or misuse of dangerous goods that may endanger persons, property or the environment. 1.10.1 General provisions 1.10.1.1 All persons engaged in the carriage of dangerous goods shall consider the security requirements set out in this Chapter commensurate with their responsibilities. 1.10.1.2 Dangerous goods shall only be offered for carriage to carriers that have been appropriately identified. 1.10.1.3 Areas within temporary storage terminals, temporary storage sites, vehicle depots, berthing areas and marshalling yards used for the temporary storage during carriage of dangerous goods shall be properly secured, well lit and, where possible and appropriate, not accessible to the general public. 1.10.1.4 Each member of a vehicle crew shall carry with them means of identification, which includes their photograph, during carriage of dangerous goods. 1.10.1.5 Safety inspections in accordance with 1.8.1 and 7.5.1.1 shall cover appropriate security measures. 1.10.1.6 The competent authority shall maintain up-to-date registers of all valid training certificates for drivers stipulated in 8.2.1 issued by it or by any recognized organization. 1.10.2 Security training 1.10.2.1 The training and the refresher training specified in Chapter 1.3 shall also include elements of security awareness. The security refresher training need not be linked to regulatory changes only. 1.10.2.2 Security awareness training shall address the nature of security risks, recognising security risks, methods to address and reduce such risks and actions to be taken in the event of a security breach. It shall include awareness of security plans (if appropriate) commensurate with the responsibilities and duties of individuals and their part in implementing security plans. 1.10.2.3 Such training shall be provided or verified upon employment in a position involving dangerous goods transport and shall be periodically supplemented with refresher training. 1.10.2.4 Records of all security training received shall be kept by the employer and made available to the employee or competent authority, upon request. Records shall be kept by the employer for a period of time established by the competent authority. 1.10.3 Provisions for high consequence dangerous goods 1.10.3.1 "High consequence dangerous goods" are those which have the potential for misuse in a terrorist incident and which may, as a result, produce serious consequences such as mass casualties or mass destruction. The list of high consequence dangerous goods is provided in Table 1.10.5. - 97 - Copyright © United Nations, 2010. All rights reserved 1.10.3.2 Security plans 1.10.3.2.1 Carriers, consignors and other participants specified in 1.4.2 and 1.4.3 engaged in the carriage of high consequence dangerous goods (see Table 1.10.5) shall adopt, implement and comply with a security plan that addresses at least the elements specified in 1.10.3.2.2. 1.10.3.2.2 The security plan shall comprise at least the following elements: (a) Specific allocation of responsibilities for security to competent and qualified persons with appropriate authority to carry out their responsibilities; (b) Records of dangerous goods or types of dangerous goods concerned; (c) Review of current operations and assessment of security risks, including any stops necessary to the transport operation, the keeping of dangerous goods in the vehicle, tank or container before, during and after the journey and the intermediate temporary storage of dangerous goods during the course of intermodal transfer or transhipment between units as appropriate; (d) Clear statement of measures that are to be taken to reduce security risks, commensurate with the responsibilities and duties of the participant, including: - training; - security policies (e.g. response to employee/employment verification, etc.); - operating practices (e.g. choice/use of routes where known, access to dangerous goods in intermediate temporary storage (as defined in (c)), proximity to vulnerable infrastructure etc.); - equipment and resources that are to be used to reduce security risks; higher threat conditions, new (e) Effective and up to date procedures for reporting and dealing with security threats, breaches of security or security incidents; (f) Procedures for the evaluation and testing of security plans and procedures for periodic review and update of the plans; (g) Measures to ensure the physical security of transport information contained in the security plan; and (h) Measures to ensure that the distribution of information relating to the transport operation contained in the security plan is limited to those who need to have it. Such measures shall not preclude the provision of information required elsewhere in ADR. NOTE: Carriers, consignors and consignees should co-operate with each other and with competent authorities to exchange threat information, apply appropriate security measures and respond to security incidents. 1.10.3.3 Devices, equipment or arrangements to prevent the theft of the vehicle carrying high consequence dangerous goods (see Table 1.10.5) and its cargo, shall be applied and measures taken to ensure that these are operational and effective at all times. The application of these protective measures shall not jeopardize emergency response. NOTE: When appropriate and already fitted, the use of transport telemetry or other tracking methods or devices should be used to monitor the movement of high consequence dangerous goods (see Table 1.10.5). - 98 - Copyright © United Nations, 2010. All rights reserved 1.10.4 In accordance with the provisions of 1.1.3.6, the requirements of 1.10.1, 1.10.2, 1.10.3 and 8.1.2.1 (d) do not apply when the quantities carried in packages on a transport unit do not exceed those referred to in 1.1.3.6.3, except for UN Nos. 0104, 0237, 0255, 0267, 0289, 0361, 0365, 0366, 0440, 0441, 0455, 0456 and 0500 (see first indent of 1.1.3.6.2). In addition, the requirements of 1.10.1, 1.10.2, 1.10.3 and 8.1.2.1 (d) do not apply when the quantities carried in tanks or in bulk on a transport unit do not exceed those referred to in 1.1.3.6.3. 1.10.5 High consequence dangerous goods are those listed in the table below and carried in quantities greater than those indicated therein. Table 1.10.5: List of high consequence dangerous goods Class Division Substance or article Tank (l) c 1 1.1 1.2 1.3 1.4 1.5 2 3 4.1 4.2 4.3 5.1 6.1 6.2 7 8 a b c d Quantity Bulk (kg) d Packages (kg) 0 0 0 0 a a Explosives a a Explosives a a Compatibility group C explosives a a Explosives of UN Nos. 0104, 0237, 0255, 0267, 0289, 0361, 0365, 0366, 0440, 0441, 0455, 0456 and 0500 a 0 Explosives 0 a b Flammable gases (classification codes including only 3000 the letter F) a 0 Toxic gases (classification codes including letters T, 0 TF, TC, TO, TFC or TOC) excluding aerosols b a Flammable liquids of packing groups I and II 3000 a 0 Desensitized explosives 0 a a 0 Desensitized explosives a b Packing group I substances 3000 a b Packing group I substances 3000 a b Oxidizing liquids of packing group I 3000 b Perchlorates, ammonium nitrate, ammonium nitrate 3000 3000 fertilisers and ammonium nitrate emulsions or suspensions or gels a 0 Toxic substances of packing group I 0 a 0 0 Infectious substances of Category A (UN Nos. 2814 and 2900, except for animal material) Radioactive material 3000 A1 (special form) or 3000 A2, as applicable, in Type B(U), B(M) or C packages a b Corrosive substances of packing group I 3000 Not relevant. The provisions of 1.10.3 do not apply, whatever the quantity is. A value indicated in this column is applicable only if carriage in tanks is authorized, in accordance with Chapter 3.2, Table A, column (10) or (12). For substances that are not authorized for carriage in tanks, the instruction in this column is not relevant. A value indicated in this column is applicable only if carriage in bulk is authorized, in accordance with Chapter 3.2, Table A, column (10) or (17). For substances that are not authorized for carriage in bulk, the instruction in this column is not relevant. - 99 - Copyright © United Nations, 2010. All rights reserved 1.10.6 1 For radioactive material, the provisions of this Chapter are deemed to be complied with when the provisions of the Convention on Physical Protection of Nuclear Material1 and the IAEA circular on "The Physical Protection of Nuclear Material and Nuclear Facilities"2 are applied. INFCIRC/274/Rev.1, IAEA, Vienna (1980). INFCIRC/225/Rev.4 (Corrected), IAEA, Vienna (1999). See also "Guidance and Considerations for the Implementation of INFCIRC/225/Rev.4, the Physical Protection of Nuclear Material and Nuclear Facilities, IAEA-TECDOC-967/Rev.1. - 100 2 Copyright © United Nations, 2010. All rights reserved PART 2 Classification - 101 - Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved CHAPTER 2.1 GENERAL PROVISIONS 2.1.1 Introduction 2.1.1.1 The classes of dangerous goods according to ADR are the following: Class 1 Class 2 Class 3 Class 4.1 Class 4.2 Class 4.3 Class 5.1 Class 5.2 Class 6.1 Class 6.2 Class 7 Class 8 Class 9 2.1.1.2 Explosive substances and articles Gases Flammable liquids Flammable solids, self-reactive substances and solid desensitized explosives Substances liable to spontaneous combustion Substances which, in contact with water, emit flammable gases Oxidizing substances Organic peroxides Toxic substances Infectious substances Radioactive material Corrosive substances Miscellaneous dangerous substances and articles Each entry in the different classes has been assigned a UN number. The following types of entries are used: A. Single entries for well defined substances or articles including entries for substances covering several isomers, e.g.: UN No. 1090 UN No. 1104 UN No. 1194 B. Generic entries for a well defined group of substances or articles, which are not n.o.s. entries, e.g.: UN No. 1133 UN No. 1266 UN No. 2757 UN No. 3101 C. ADHESIVES PERFUMERY PRODUCTS CARBAMATE PESTICIDE, SOLID, TOXIC ORGANIC PEROXIDE TYPE B, LIQUID Specific n.o.s. entries covering a group of substances or articles of a particular chemical or technical nature, not otherwise specified, e.g.: UN No. 1477 UN No. 1987 D. ACETONE AMYL ACETATES ETHYL NITRITE SOLUTION NITRATES, INORGANIC, N.O.S. ALCOHOLS, N.O.S. General n.o.s. entries covering a group of substances or articles having one or more dangerous properties, not otherwise specified, e.g.: UN No. 1325 UN No. 1993 FLAMMABLE SOLID, ORGANIC, N.O.S. FLAMMABLE LIQUID, N.O.S. The entries defined under B., C. and D. are defined as collective entries. - 103 - Copyright © United Nations, 2010. All rights reserved 2.1.1.3 For packing purposes, substances other than those of Classes 1, 2, 5.2, 6.2 and 7, and other than self-reactive substances of Class 4.1 are assigned to packing groups in accordance with the degree of danger they present: Packing group I: Substances presenting high danger; Packing group II: Substances presenting medium danger; Packing group III: Substances presenting low danger. The packing group(s) to which a substance is assigned is (are) indicated in Table A of Chapter 3.2. 2.1.2 Principles of classification 2.1.2.1 The dangerous goods covered by the heading of a class are defined on the basis of their properties according to sub-section 2.2.x.1 of the relevant class. Assignment of dangerous goods to a class and a packing group is made according to the criteria mentioned in the same sub-section 2.2.x.1. Assignment of one or several subsidiary risk(s) to a dangerous substance or article is made according to the criteria of the class or classes corresponding to those risks, as mentioned in the appropriate sub-section(s) 2.2.x.1. 2.1.2.2 All dangerous goods entries are listed in Table A of Chapter 3.2 in the numerical order of their UN Number. This table contains relevant information on the goods listed, such as name, class, packing group(s), label(s) to be affixed, packing and carriage provisions 1. 2.1.2.3 A substance may contain technical impurities (for example those deriving from the production process) or additives for stability or other purposes that do not affect their classification. However, a substance mentioned by name, i.e. listed as a single entry in Table A of Chapter 3.2, containing technical impurities or additives for stability or other purposes affecting its classification shall be considered a solution or mixture (see 2.1.3.3). 2.1.2.4 Dangerous goods which are listed or defined in sub-section 2.2.x.2 of each class are not to be accepted for carriage. 2.1.2.5 Goods not mentioned by name, i.e. goods not listed as single entries in Table A of Chapter 3.2 and not listed or defined in one of the above-mentioned sub-sections 2.2.x.2 shall be assigned to the relevant class in accordance with the procedure of section 2.1.3. In addition, the subsidiary risk (if any) and the packing group (if any) shall be determined. Once the class, subsidiary risk (if any) and packing group (if any) have been established the relevant UN number shall be determined. The decision trees in sub-sections 2.2.x.3 (list of collective entries) at the end of each class indicate the relevant parameters for selecting the relevant collective entry (UN number). In all cases the most specific collective entry covering the properties of the substance or article shall be selected, according to the hierarchy indicated in 2.1.1.2 by the letters B, C and D respectively. If the substance or article cannot be classified under entries of type B or C according to 2.1.1.2, then, and only then shall it be classified under an entry of type D. 2.1.2.6 On the basis of the test procedures of Chapter 2.3 and the criteria set out in sub-sections 2.2.x.1 of classes when it is so specified, it may be determined that a substance, solution or mixture of a certain class, mentioned by name in Table A of Chapter 3.2, does not meet the criteria of that class. In such a case, the substance, solution or mixture is deemed not to belong to that class. Note by the Secretariat: An alphabetic list of these entries has been prepared by the secretariat and is reproduced in Table B of Chapter 3.2. This table is not an official part of the ADR. 1 - 104 - Copyright © United Nations, 2010. All rights reserved 2.1.2.7 For the purposes of classification, substances with a melting point or initial melting point of 20 °C or lower at a pressure of 101.3 kPa shall be considered to be liquids. A viscous substance for which a specific melting point cannot be determined shall be subjected to the ASTM D 4359-90 test or to the test for determining fluidity (penetrometer test) prescribed in 2.3.4. 2.1.3 Classification of substances, including solutions and mixtures (such as preparations and wastes), not mentioned by name 2.1.3.1 Substances including solutions and mixtures not mentioned by name shall be classified according to their degree of danger on the basis of the criteria mentioned in sub-section 2.2.x.1 of the various classes. The danger(s) presented by a substance shall be determined on the basis of its physical and chemical characteristics and physiological properties. Such characteristics and properties shall also be taken into account when such experience leads to a more stringent assignment. 2.1.3.2 A substance not mentioned by name in Table A of Chapter 3.2 presenting a single hazard shall be classified in the relevant class under a collective entry listed in sub-section 2.2.x.3 of that class. 2.1.3.3 A solution or mixture composed of a single predominant substance mentioned by name in Table A of Chapter 3.2 and one or more substances not subject to ADR or traces of one or more substances mentioned by name in Table A of Chapter 3.2, shall be assigned the UN number and proper shipping name of the predominant substance mentioned by name in Table A of Chapter 3.2 unless: (a) The solution or mixture is mentioned by name in Table A of Chapter 3.2; (b) The name and description of the substance mentioned by name in Table A of Chapter 3.2 specifically indicate that they apply only to the pure substance; (c) The class, classification code, packing group, or physical state of the solution or mixture is different from that of the substance mentioned by name in Table A of Chapter 3.2; or (d) The hazard characteristics and properties of the solution or mixture necessitate emergency response measures that are different from those required for the substance mentioned by name in Table A of Chapter 3.2. In those other cases, except the one described in (a), the solution or mixture shall be classified as a substance not mentioned by name in the relevant class under a collective entry listed in sub-section 2.2.x.3 of that class taking account of the subsidiary risks presented by that solution or mixture, if any, unless the solution or mixture does not meet the criteria of any class, in which case it is not subject to ADR. 2.1.3.4 Solutions and mixtures containing substances belonging to one of the entries mentioned in 2.1.3.4.1 or 2.1.3.4.2 shall be classified in accordance with the provisions of these paragraphs. 2.1.3.4.1 Solutions and mixtures containing one of the following substances mentioned by name shall always be classified under the same entry as the substance they contain, provided they do not have the hazard characteristics as indicated in 2.1.3.5.3: - 105 - Copyright © United Nations, 2010. All rights reserved - Class 3 UN No. 1921 PROPYLENEIMINE, STABILIZED; UN No. 3064 NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin; - Class 6.1 UN No. 1051 HYDROGEN CYANIDE, STABILIZED, containing less than 3% water; UN No. 1185 ETHYLENEIMINE, STABILIZED; UN No. 1259 NICKEL CARBONYL; UN No. 1613 HYDROCYANIC ACID, AQUEOUS SOLUTION (HYDROGEN CYANIDE, AQUEOUS SOLUTION), with not more than 20% hydrogen cyanide; UN No. 1614 HYDROGEN CYANIDE, STABILIZED, containing not more than 3% water and absorbed in a porous inert material; UN No. 1994 IRON PENTACARBONYL; UN No. 2480 METHYL ISOCYANATE; UN No. 2481 ETHYL ISOCYANATE; UN No. 3294 HYDROGEN CYANIDE, SOLUTION IN ALCOHOL, with not more than 45% hydrogen cyanide; - Class 8 UN No. 1052 HYDROGEN FLUORIDE, ANHYDROUS; UN No. 1744 BROMINE or UN No. 1744 BROMINE SOLUTION; UN No. 1790 HYDROFLUORIC ACID with more than 85% hydrogen fluoride; UN No. 2576 PHOSPHORUS OXYBROMIDE, MOLTEN; 2.1.3.4.2 Solutions and mixtures containing a substance belonging to one of the following entries of Class 9: UN No. 2315 POLYCHLORINATED BIPHENYLS, LIQUID; UN No. 3151 POLYHALOGENATED BIPHENYLS, LIQUID; UN No. 3151 POLYHALOGENATED TERPHENYLS, LIQUID; UN No. 3152 POLYHALOGENATED BIPHENYLS, SOLID; UN No. 3152 POLYHALOGENATED TERPHENYLS, SOLID; or UN No. 3432 POLYCHLORINATED BIPHENYLS, SOLID shall always be classified under the same entry of Class 9 provided that: - they do not contain any additional dangerous component other than components of packing group III of classes 3, 4.1, 4.2, 4.3, 5.1, 6.1 or 8; and - they do not have the hazard characteristics as indicated in 2.1.3.5.3. 2.1.3.5 Substances not mentioned by name in Table A of Chapter 3.2, having more than one hazard characteristic and solutions or mixtures containing several dangerous substances shall be classified under a collective entry (see 2.1.2.5) and packing group of the appropriate class in accordance with their hazard characteristics. Such classification according to the hazard characteristics shall be carried out as follows: 2.1.3.5.1 The physical and chemical characteristics and physiological properties shall be determined by measurement or calculation and the substance, solution or mixture shall be classified according to the criteria mentioned in sub-section 2.2.x.1 of the various classes. 2.1.3.5.2 If this determination is not possible without disproportionate cost or effort (as for some kinds of wastes), the substance, solution or mixture shall be classified in the class of the component presenting the major hazard. - 106 - Copyright © United Nations, 2010. All rights reserved 2.1.3.5.3 If the hazard characteristics of the substance, solution or mixture fall within more than one class or group of substances listed below then the substance, solution or mixture shall be classified in the class or group of substances corresponding to the major hazard on the basis of the following order of precedence: (a) Material of Class 7 (apart from radioactive material in excepted packages for which special provision 290 of Chapter 3.3 applies, where the other hazardous properties take precedence); (b) Substances of Class 1; (c) Substances of Class 2; (d) Liquid desensitized explosives of Class 3; (e) Self-reactive substances and solid desensitized explosives of Class 4.1; (f) Pyrophoric substances of Class 4.2; (g) Substances of Class 5.2; (h) Substances of Class 6.1 or Class 3 which, on the basis of their inhalation toxicity, are to be classified under Packing group I (Substances meeting the classification criteria of Class 8 and having an inhalation toxicity of dust and mist (LC50) in the range of Packing group I and a toxicity through oral ingestion or dermal contact only in the range of Packing group III or less, shall be allocated to Class 8); (i) Infectious substances of Class 6.2. 2.1.3.5.4 If the hazard characteristics of the substance fall within more than one class or group of substances not listed in 2.1.3.5.3 above, the substance shall be classified in accordance with the same procedure but the relevant class shall be selected according to the precedence of hazards table in 2.1.3.10. 2.1.3.5.5 If the substance to be carried is a waste, with a composition that is not precisely known, its assignment to a UN number and packing group in accordance with 2.1.3.5.2 may be based on the consignor’s knowledge of the waste, including all available technical and safety data as requested by safety and environmental legislation in force 2. In case of doubt, the highest danger level shall be taken. If however, on the basis of the knowledge of the composition of the waste and the physical and chemical properties of the identified components, it is possible to demonstrate that the properties of the waste do not correspond to the properties of the packing group I level, the waste may be classified by default in the most appropriate n.o.s. entry of packing group II. This procedure may not be used for wastes containing substances mentioned in 2.1.3.5.3, substances of Class 4.3, substances of the case mentioned in 2.1.3.7 or substances which are not accepted for carriage in accordance with 2.2.x.2. Such legislation is for instance the Commission Decision 2000/532/EC of 3 May 2000 replacing Decision 94/3/EC establishing a list of wastes pursuant to Article 1(a) of Council Directive 75/442/EEC on waste (replaced by the Directive 2006/12/EC of the European Parliament and of the Council (Official Journal of the European Union No. L 114 of 27 April 2006, page 9)) and Council Decision 94/904/EC establishing a list of hazardous wastes pursuant to Article 1(4) of Council Directive 91/689/EEC on hazardous wastes (Official Journal of the European Communities No. L 226 of 6 September 2000, page 3). 2 - 107 - Copyright © United Nations, 2010. All rights reserved 2.1.3.6 The most specific applicable collective entry (see 2.1.2.5) shall always be used, i.e. a general n.o.s. entry shall only be used if a generic entry or a specific n.o.s. entry cannot be used. 2.1.3.7 Solutions and mixtures of oxidizing substances or substances with an oxidizing subsidiary risk may have explosive properties. In such a case they are not to be accepted for carriage unless they meet the requirements for Class 1. 2.1.3.8 Substances of classes 1 to 9, other than those assigned to UN Nos. 3077 or 3082, meeting the criteria of 2.2.9.1.10 are additionally to their hazards of classes 1 to 9 considered to be environmentally hazardous substances. Other substances meeting the criteria of 2.2.9.1.10 are to be assigned to UN Nos. 3077 or 3082 as appropriate. 2.1.3.9 Wastes that do not meet the criteria for classification in classes 1 to 9 but are covered by the Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and their Disposal may be carried under UN Nos. 3077 or 3082. - 108 - Copyright © United Nations, 2010. All rights reserved 2.1.3.10 Class and packing group Table of precedence of hazards 4.1, II 4.1, III 4.2, II 4.2, III 4.3, I 4.3, II 4.3, III 5.1, I 5.1, II 5.1, III 6.1, I DERMAL 6.1, I ORAL 6.1, II 6.1, III 8, I 8, II 8, III 9 SOL LIQ 4.1 3, I SOL LIQ 4.1 3, I SOL LIQ 4.2 3, I SOL LIQ 4.2 3, I 4.3, I 4.3, I 4.3, I SOL LIQ 5.1, I 3, I SOL LIQ 5.1, I 3, I SOL LIQ 5.1, I 3, I 3, I 3, I 3, I 3, I 3, I 3, I 3, I 3, I 3, II SOL LIQ 4.1 3, II SOL LIQ 4.1 3, II SOL LIQ 4.2 3, II SOL LIQ 4.2 3, II 4.3, I 4.3, II 4.3, II SOL LIQ 5.1, I 3, I SOL LIQ 5.1, II 3, II SOL LIQ 5.1, II 3, II 3, I 3, I 3, II 3, II 8, I 3, II 3, II 3, II 3, III SOL LIQ 4.1 3, II SOL LIQ 4.1 3, III SOL LIQ 4.2 3, II SOL LIQ 4.2 3, III 4.3, I 4.3, II 4.3, III SOL LIQ SOL LIQ SOL LIQ 5.1, I 3, I 5.1, II 3, II 5.1, III 3, III 6.1, I 6.1, I 6.1, II 3, III a 8, I 8, II 3, III 3, III 4.1, II 4.2, II 4.2, II 4.3, I 4.3, II 4.3, II 5.1, I 4.1, II 4.1, II 6.1, I 6.1, I SOL LIQ 4.1, II 6.1, II SOL LIQ 4.1, II 6.1, II 8, I SOL LIQ 4.1, II 8, II SOL 4.1, II LIQ 8, II 4.1, II 4.1, III 4.2, II 4.2, III 4.3, I 4.3, II 4.3, III 5.1, I 4.1, II 4.1, III 6.1, I 6.1, I 6.1, II SOL LIQ 4.1, III 6.1, III 8, I 8, II SOL 4.1, III LIQ 8, III 4.1, III 4.2, II 4.3, I 4.3, II 4.3, II 5.1, I 4.2, II 4.2, II 6.1, I 6.1, I 4.2, II 4.2, II 8, I 4.2, II 4.2, II 4.2, II 4.2, III 4.3, I 4.3, II 4.3, III 5.1, I 5.1, II 4.2, III 6.1, I 6.1, I 6.1, II 4.2, III 8, I 8, II 4.2, III 4.2, III 4.3, I 5.1, I 4.3, I 4.3, I 6.1, I 4.3, I 4.3, I 4.3, I 4.3, I 4.3, I 4.3, I 4.3, I 4.3, II 5.1, I 4.3, II 4.3, II 6.1, I 4.3, I 4.3, II 4.3, II 8, I 4.3, II 4.3, II 4.3, II 4.3, III 5.1, I 5.1, II 4.3, III 6.1, I 6.1, I 6.1, II 4.3, III 8, I 8, II 4.3, III 4.3, III 3, I - 109 - 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, II 6.1, I 5.1, I 5.1, II 5.1, II 8, I 5.1, II 5.1, II 5.1, II 5.1, III 6.1, I 6.1, I 6.1, II 5.1, III 8, I 8, II 5.1, III 5.1, III 6.1, I 6.1, I 6.1, I 6.1, I 6.1, I 6.1, I 6.1, II 6.1, II 6.1, II 6.1, II 6.1, II 6.1, II 6.1, II 8, III 6.1, III 6.1, I DERMAL 6.1, I ORAL SOL 6.1, I SOL 6.1, I 6.1, II INHAL SOL LIQ 6.1, I 8, I 6.1, II DERMAL 6.1, II ORAL SOL LIQ SOL 6.1, I 8, I 6.1, II 8.1 SOL 6.1, II 6.1, III 8, I SOL = LIQ = DERMAL = ORAL = INHAL = a Class 6.1 for pesticides Solid substances and mixtures Liquid substances, mixtures and solutions Dermal toxicity Oral toxicity Inhalation toxicity LIQ 8, I LIQ 8, I 8, I LIQ 8, II LIQ 8, II 8, II 8, I 8, II 8, II 8, III 8, III Copyright © United Nations, 2010. All rights reserved NOTE 1: Examples to explain the use of the table Classification of a single substance Description of the substance to be classified: An amine not mentioned by name meeting the criteria for Class 3, packing group II as well as those for Class 8, packing group I. Procedure: The intersection of line 3 II with column 8 I gives 8 I. This amine has therefore to be classified in Class 8 under: UN No. 2734 AMINES LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or UN No. 2734 POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. packing group I Classification of a mixture Description of the mixture to be classified: Mixture consisting of a flammable liquid classified in Class 3, packing group III, a toxic substance in Class 6.1, packing group II and a corrosive substance in Class 8, packing group I. Procedure: The intersection of line 3 III with column 6.1 II gives 6.1 II. The intersection of line 6.1 II with column 8 I gives 8 I LIQ. This mixture not further defined has therefore to be classified in Class 8 under: UN No. 2922 CORROSIVE LIQUID, TOXIC, N.O.S. packing group I. NOTE 2: Examples for the classification of mixtures and solutions under a class and a packing group: A phenol solution of Class 6.1, (II), in benzene of Class 3, (II) is to be classified in Class 3, (II); this solution is to be classified under UN No. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S., Class 3, (II), by virtue of the toxicity of the phenol. A solid mixture of sodium arsenate of Class 6.1, (II) and sodium hydroxide of Class 8, (II) is to be classified under UN No. 3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S., in Class 6.1 (II). A solution of crude or refined naphthalene of Class 4.1, (III) in petrol of Class 3, (II), is to be classified under UN No. 3295 HYDROCARBONS, LIQUID, N.O.S. in Class 3, (II). A mixture of hydrocarbons of Class 3, (III), and of polychlorinated biphenyls (PCB) of Class 9, (II), is to be classified under UN No. 2315 POLYCHLORINATED BIPHENYLS LIQUID or UN No. 3432 POLYCHLORINATED BIPHENYLS SOLID in Class 9, (II). A mixture of propyleneimine of Class 3, and polychlorinated biphenyls (PCB) of Class 9, (II), is to be classified under UN No. 1921 PROPYLENEIMINE, INHIBITED in Class 3. - 110 - Copyright © United Nations, 2010. All rights reserved 2.1.4 Classification of samples 2.1.4.1 When the class of a substance is uncertain and it is being carried for further testing, a tentative class, proper shipping name and UN number shall be assigned on the basis of the consignor's knowledge of the substance and application of: (a) the classification criteria of Chapter 2.2; and (b) the requirements of this Chapter. The most severe packing group possible for the proper shipping name chosen shall be used. Where this provision is used the proper shipping name shall be supplemented with the word "SAMPLE" (e.g., "FLAMMABLE LIQUID, N.O.S., SAMPLE"). In certain instances, where a specific proper shipping name is provided for a sample of a substance considered to meet certain classification criteria (e.g., GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, UN No. 3167) that proper shipping name shall be used. When an N.O.S. entry is used to carry the sample, the proper shipping name need not be supplemented with the technical name as required by special provision 274 of Chapter 3.3. 2.1.4.2 Samples of the substance shall be carried in accordance with the requirements applicable to the tentative assigned proper shipping name provided: (a) The substance is not considered to be a substance not accepted for carriage by sub-sections 2.2.x.2 of Chapter 2.2 or by Chapter 3.2; (b) The substance is not considered to meet the criteria for Class 1 or considered to be an infectious substance or a radioactive material; (c) The substance is in compliance with 2.2.41.1.15 or 2.2.52.1.9 if it is a self-reactive substance or an organic peroxide, respectively; (d) The sample is carried in a combination packaging with a net mass per package not exceeding 2.5 kg; and (e) The sample is not packed together with other goods. - 111 - Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved CHAPTER 2.2 CLASS SPECIFIC PROVISIONS 2.2.1 Class 1 2.2.1.1 Criteria 2.2.1.1.1 The heading of Class 1 covers: (a) Explosive substances and articles Explosive substances: solid or liquid substances (or mixtures of substances) capable by chemical reaction of producing gases at such a temperature and pressure and at such a speed as to cause damage to the surroundings. Pyrotechnic substances: substances or mixtures of substances designed to produce an effect by heat, light, sound, gas or smoke or a combination of these as the result of non-detonating self-sustaining exothermic chemical reactions; NOTE 1: Substances which are not themselves explosive but which may form an explosive mixture of gas, vapour or dust are not substances of Class 1. NOTE 2: Also excluded from Class 1 are: water- or alcohol-wetted explosives of which the water or alcohol content exceeds the limits specified and those containing plasticizers - these explosives are assigned to Class 3 or Class 4.1 - and those explosives which, on the basis of their predominant hazard, are assigned to Class 5.2. (b) Explosive articles: articles containing one or more explosive or pyrotechnic substances; NOTE: Devices containing explosive or pyrotechnic substances in such small quantity or of such a character that their inadvertent or accidental ignition or initiation during carriage would not cause any manifestation external to the device by projection, fire, smoke, heat or loud noise are not subject to the requirements of Class 1. (c) Substances and articles not mentioned above which are manufactured with a view to producing a practical effect by explosion or a pyrotechnic effect. For the purposes of Class 1, the following definition applies: Phlegmatized means that a substance (or "phlegmatizer") has been added to an explosive to enhance its safety in handling and carriage. The phlegmatizer renders the explosive insensitive, or less sensitive, to the following actions: heat, shock, impact, percussion or friction. Typical phlegmatizing agents include, but are not limited to: wax, paper, water, polymers (such as chlorofluoropolymers), alcohol and oils (such as petroleum jelly and paraffin). 2.2.1.1.2 Any substance or article having or suspected of having explosive properties shall be considered for assignment to Class 1 in accordance with the tests, procedures and criteria prescribed in Part I, Manual of Tests and Criteria. A substance or article assigned to Class 1 can only be accepted for carriage when it has been assigned to a name or n.o.s. entry listed in Table A of Chapter 3.2 and meets the criteria of the Manual of Tests and Criteria. - 113 - Copyright © United Nations, 2010. All rights reserved 2.2.1.1.3 The substances and articles of Class 1 shall be assigned to a UN Number and a name or n.o.s. entry listed in Table A of Chapter 3.2. Interpretation of the names of substances and articles in Table A of Chapter 3.2 shall be based upon the glossary in 2.2.1.1.8. Samples of new or existing explosive substances or articles carried for purposes including: testing, classification, research and development quality control, or as a commercial sample, other than initiating explosive, may be assigned to UN No. 0190 SAMPLES, EXPLOSIVE. The assignment of explosive substances and articles not mentioned by name as such in Table A of Chapter 3.2 to an n.o.s entry of Class 1 or UN No. 0190 SAMPLES, EXPLOSIVE as well as the assignment of certain substances the carriage of which is subject to a specific authorization by the competent authority according to the special provisions referred to in Column (6) of Table A of Chapter 3.2 shall be made by the competent authority of the country of origin. This competent authority shall also approve in writing the conditions of carriage of these substances and articles. If the country of origin is not a Contracting Party to ADR, the classification and the conditions of carriage shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. 2.2.1.1.4 Substances and articles of Class 1 shall have been assigned to a division in accordance with 2.2.1.1.5 and to a compatibility group in accordance with 2.2.1.1.6. The division shall be based on the results of the tests described in 2.3.0 and 2.3.1 applying the definitions in 2.2.1.1.5. The compatibility group shall be determined in accordance with the definitions in 2.2.1.1.6. The classification code shall consist of the division number and the compatibility group letter. 2.2.1.1.5 Definition of divisions Division 1.1 Substances and articles which have a mass explosion hazard (a mass explosion is an explosion which affects almost the entire load virtually instantaneously). Division 1.2 Substances and articles which have a projection hazard but not a mass explosion hazard. Division 1.3 Substances and articles which have a fire hazard and either a minor blast hazard or a minor projection hazard or both, but not a mass explosion hazard: (a) combustion of which gives rise to considerable radiant heat; or (b) which burn one after another, producing minor blast or projection effects or both. Division 1.4 Substances and articles which present only a slight risk of explosion in the event of ignition or initiation during carriage. The effects are largely confined to the package and no projection of fragments of appreciable size or range is to be expected. An external fire shall not cause virtually instantaneous explosion of almost the entire contents of the package. Division 1.5 Very insensitive substances having a mass explosion hazard which are so insensitive that there is very little probability of initiation or of transition from burning to detonation under normal conditions of carriage. As a minimum requirement they must not explode in the external fire test. - 114 - Copyright © United Nations, 2010. All rights reserved Division 1.6 Extremely insensitive articles which do not have a mass explosion hazard. The articles contain only extremely insensitive detonating substances and demonstrate a negligible probability of accidental initiation or propagation. NOTE: The risk from articles of Division 1.6 is limited to the explosion of a single article. 2.2.1.1.6 Definition of compatibility groups of substances and articles A Primary explosive substance. B Article containing a primary explosive substance and not having two or more effective protective features. Some articles, such as detonators for blasting, detonator assemblies for blasting and primers, cap-type, are included, even though they do not contain primary explosives. C Propellant explosive substance or other deflagrating explosive substance or article containing such explosive substance. D Secondary detonating explosive substance or black powder or article containing a secondary detonating explosive substance, in each case without means of initiation and without a propelling charge, or article containing a primary explosive substance and having two or more effective protective features. E Article containing a secondary detonating explosive substance, without means of initiation, with a propelling charge (other than one containing a flammable liquid or gel or hypergolic liquids). F Article containing a secondary detonating explosive substance with its own means of initiation, with a propelling charge (other than one containing a flammable liquid or gel or hypergolic liquids) or without a propelling charge. G Pyrotechnic substance, or article containing a pyrotechnic substance, or article containing both an explosive substance and an illuminating, incendiary, tear- or smoke-producing substance (other than a water-activated article or one which contains white phosphorus, phosphides, a pyrophoric substance, a flammable liquid or gel or hypergolic liquids). H Article containing both an explosive substance and white phosphorus. J Article containing both an explosive substance and a flammable liquid or gel. K Article containing both an explosive substance and a toxic chemical agent. L Explosive substance or article containing an explosive substance and presenting a special risk (e.g. due to water activation or the presence of hypergolic liquids, phosphides or a pyrophoric substance) necessitating isolation of each type. N Articles containing only extremely insensitive detonating substances. S Substance or article so packed or designed that any hazardous effects arising from accidental functioning are confined within the package unless the package has been degraded by fire, in which case all blast or projection effects are limited to the extent that they do not significantly hinder or prevent fire-fighting or other emergency response efforts in the immediate vicinity of the package. - 115 - Copyright © United Nations, 2010. All rights reserved NOTE 1: Each substance or article, packed in a specified packaging, may be assigned to one compatibility group only. Since the criterion of compatibility group S is empirical, assignment to this group is necessarily linked to the tests for assignment of a classification code. NOTE 2: Articles of compatibility groups D and E may be fitted or packed together with their own means of initiation provided that such means have at least two effective protective features designed to prevent an explosion in the event of accidental functioning of the means of initiation. Such articles and packages shall be assigned to compatibility groups D or E. NOTE 3: Articles of compatibility groups D and E may be packed together with their own means of initiation, which do not have two effective protective features (i.e. means of initiation assigned to compatibility group B), provided that they comply with mixed packing provision MP21 of Section 4.1.10. Such packages shall be assigned to compatibility groups D or E. NOTE 4: Articles may be fitted or packed together with their own means of ignition provided that the means of ignition cannot function during normal conditions of carriage. NOTE 5: Articles of compatibility groups C, D and E may be packed together. Such packages shall be assigned to compatibility group E. 2.2.1.1.7 Assignment of fireworks to divisions 2.2.1.1.7.1 Fireworks shall normally be assigned to divisions 1.1, 1.2, 1.3, and 1.4 on the basis of test data derived from Test Series 6 of the Manual of Tests and Criteria. However, since the range of such articles is very extensive and the availability of test facilities may be limited, assignment to divisions may also be made in accordance with the procedure in 2.2.1.1.7.2. 2.2.1.1.7.2 Assignment of fireworks to UN Nos. 0333, 0334, 0335 and 0336 may be made on the basis of analogy, without the need for Test Series 6 testing, in accordance with the default fireworks classification table in 2.2.1.1.7.5. Such assignment shall be made with the agreement of the competent authority. Items not specified in the table shall be classified on the basis of test data derived from Test Series 6. NOTE 1: The addition of other types of fireworks to column 1 of the table in 2.2.1.1.7.5 shall only be made on the basis of full test data submitted to the UN Sub-Committee of Experts on the Transport of Dangerous Goods for consideration. NOTE 2: Test data derived by competent authorities which validates, or contradicts the assignment of fireworks specified in column 4 of the table in 2.2.1.1.7.5 to divisions in column 5 should be submitted to the UN Sub-Committee of Experts on the Transport of Dangerous Goods for information. 2.2.1.1.7.3 Where fireworks of more than one division are packed in the same package, they shall be classified on the basis of the most dangerous division unless test data derived from Test Series 6 indicate otherwise. 2.2.1.1.7.4 The classification shown in the table in 2.2.1.1.7.5 applies only for articles packed in fibreboard boxes (4G). - 116 - Copyright © United Nations, 2010. All rights reserved 2.2.1.1.7.5 Default fireworks classification table 1 NOTE 1: References to percentages in the table, unless otherwise stated, are to the mass of all pyrotechnic substances (e.g. rocket motors, lifting charge, bursting charge and effect charge). NOTE 2: "Flash composition" in this table refers to pyrotechnic substances in powder form or as pyrotechnic units as presented in the fireworks, that are used to produce an aural effect, or used as a bursting charge or lifting charge, unless the time taken for the pressure rise is demonstrated to be more than 8 ms for 0.5 g of pyrotechnic substance in the HSL Flash Composition Test in Appendix 7 of the Manual of Tests and Criteria. NOTE 3: Dimensions in mm refer to: - for spherical and peanut shells the diameter of the sphere of the shell; for cylinder shells the length of the shell; for a shell in mortar, Roman candle, shot tube firework or mine the inside diameter of the tube comprising or containing the firework; for a bag mine or cylinder mine, the inside diameter of the mortar intended to contain the mine. This table contains a list of firework classifications which may be used in the absence of Test Series 6 data (see 2.2.1.1.7.2). - 117 - 1 Copyright © United Nations, 2010. All rights reserved Type Includes: / Synonym: Definition Specification Classification Shell, spherical or cylindrical Spherical display shell: aerial shell, colour shell, dye shell, multi-break shell, multi-effect shell, nautical shell, parachute shell, smoke shell, star shell; report shell: maroon, salute, sound shell, thunderclap, aerial shell kit Device with or without propellant charge, with delay fuse and bursting charge, pyrotechnic unit(s) or loose pyrotechnic substance and designed to be projected from a mortar All report shells 1.1G Colour shell: ≥ 180 mm 1.1G Colour shell: < 180 mm with > 25% flash composition, as loose powder and/or report effects 1.1G Colour shell: < 180 mm with ≤ 25% flash composition, as loose powder and/or report effects 1.3G Colour shell: ≤ 50 mm, or ≤ 60 g pyrotechnic substance, with ≤ 2% flash composition as loose powder and/or report effects 1.4G - 118 - Peanut shell Device with two or more spherical aerial shells in a common wrapper propelled by the same propellant charge with separate external delay fuses The most hazardous spherical aerial shell determines the classification Preloaded mortar, shell in mortar Assembly comprising a spherical or cylindrical shell inside a mortar from which the shell is designed to be projected All report shells 1.1G Colour shell: ≥ 180 mm 1.1G Colour shell: > 25% flash composition as loose powder and/or report effects 1.1G Colour shell: > 50 mm and < 180 mm 1.2G Colour shell: ≤ 50 mm, or ≤ 60 g pyrotechnic substance, with ≤ 25% flash composition as loose powder and/or report effects 1.3G Copyright © United Nations, 2010. All rights reserved Classification Type Includes: / Synonym: Definition Specification Shell, spherical or cylindrical Shell of shells (spherical) Device without propellant charge, with delay fuse and bursting charge, containing report shells and inert materials and designed to be projected from a mortar > 120 mm 1.1G Device without propellant charge, with delay fuse and bursting charge, containing report shells ≤ 25g flash composition per report unit, with ≤ 33% flash composition and ≥ 60% inert materials and designed to be projected from a mortar ≤ 120 mm 1.3G Device without propellant charge, with delay fuse and bursting charge, containing colour shells and/or pyrotechnic units and designed to be projected from a mortar > 300 mm 1.1G Device without propellant charge, with delay fuse and bursting charge, containing colour shells ≤ 70mm and/or pyrotechnic units, with ≤ 25% flash composition and ≤ 60% pyrotechnic substance and designed to be projected from a mortar > 200 mm and ≤ 300 mm 1.3G Device with propellant charge, with delay fuse and bursting charge, containing colour shells ≤ 70 mm and/or pyrotechnic units, with ≤ 25% flash composition and ≤ 60% pyrotechnic substance and designed to be projected from a mortar ≤ 200 mm 1.3G Assembly including several elements either containing the same type or several types each corresponding to one of the types of fireworks listed in this table, with one or two points of ignition The most hazardous firework type determines the classification (cont'd) (Reference to percentages for shell of shells are to the gross mass of the fireworks article) - 119 Battery/ combination Barrage, bombardos, cakes, finale box, flowerbed, hybrid, multiple tubes, shell cakes, banger batteries, flash banger batteries Copyright © United Nations, 2010. All rights reserved Classification Type Includes: / Synonym: Definition Specification Roman candle Exhibition candle, candle, bombettes Tube containing a series of pyrotechnic units consisting of alternate pyrotechnic substance, propellant charge, and transmitting fuse ≥ 50 mm inner diameter, containing flash composition, or < 50 mm with > 25% flash composition 1.1G ≥ 50 mm inner diameter, containing no flash composition 1.2G < 50 mm inner diameter and ≤ 25% flash composition 1.3G ≤ 30 mm inner diameter, each pyrotechnic unit ≤ 25 g and ≤ 5% flash composition 1.4G ≤ 30 mm inner diameter and pyrotechnic unit > 25 g, or > 5% and ≤ 25% flash composition 1.3G ≤ 30 mm inner diameter, pyrotechnic unit ≤ 25 g and ≤ 5% flash composition 1.4G Flash composition effects only 1.1G Flash composition > 25% of the pyrotechnic substance 1.1G > 20 g pyrotechnic substance and flash composition ≤ 25% 1.3G ≤ 20 g pyrotechnic substance, black powder bursting charge and ≤ 0.13 g flash composition per report and ≤ 1 g in total 1.4G Shot tube Single shot Roman candle, small preloaded mortar Tube containing a pyrotechnic unit consisting of pyrotechnic substance, propellant charge with or without transmitting fuse - 120 Rocket Avalanche rocket, signal rocket, whistling rocket, bottle rocket, sky rocket, missile type rocket, table rocket Tube containing pyrotechnic substance and/or pyrotechnic units, equipped with stick(s) or other means for stabilization of flight, and designed to be propelled into the air Copyright © United Nations, 2010. All rights reserved Classification Type Includes: / Synonym: Definition Specification Mine Pot-a-feu, ground mine, bag mine, cylinder mine Tube containing propellant charge and pyrotechnic units and designed to be placed on the ground or to be fixed in the ground. The principal effect is ejection of all the pyrotechnic units in a single burst producing a widely dispersed visual and/or aural effect in the air or: > 25% flash composition, as loose powder and/ or report effects 1.1G ≥ 180 mm and ≤ 25% flash composition, as loose powder and/ or report effects 1.1G < 180 mm and ≤ 25% flash composition, as loose powder and/ or report effects 1.3G ≤ 150 g pyrotechnic substance, containing ≤ 5% flash composition as loose powder and/ or report effects. Each pyrotechnic unit ≤ 25 g, each report effect < 2g; each whistle, if any, ≤ 3 g 1.4G Cloth or paper bag or cloth or paper cylinder containing propellant charge and pyrotechnic units, designed to be placed in a mortar and to function as a mine - 121 - Fountain Sparkler Volcanos, gerbs, showers, lances, Bengal fire, flitter sparkle, cylindrical fountains, cone fountains, illuminating torch Non-metallic case containing pressed or consolidated pyrotechnic substance producing sparks and flame ≥ 1 kg pyrotechnic substance 1.3G < 1 kg pyrotechnic substance 1.4G Handheld sparklers, non-handheld sparklers, wire sparklers Rigid wire partially coated (along one end) with slow burning pyrotechnic substance with or without an ignition tip Perchlorate based sparklers: > 5 g per item or > 10 items per pack 1.3G Perchlorate based sparklers: ≤ 5 g per item and ≤ 10 items per pack; 1.4G Nitrate based sparklers: ≤ 30 g per item Copyright © United Nations, 2010. All rights reserved Type Includes: / Synonym: Definition Specification Bengal stick Dipped stick Non-metallic stick partially coated (along one end) with slow-burning pyrotechnic substance and designed to be held in the hand Perchlorate based items: > 5 g per item or > 10 items per pack Perchlorate based items: ≤ 5 g per item and ≤ 10 items per pack; nitrate based items: ≤ 30 g per item Throwdowns and snaps may contain up to 1.6 mg of silver fulminate; snaps and party poppers may contain up to 16 mg of potassium chlorate/red phosphorous mixture; other articles may contain up to 5 g of pyrotechnic substance, but no flash composition Pyrotechnic substance per item > 20 g, containing ≤ 3% flash composition as report effects, or whistle composition ≤ 5 g Pyrotechnic substance per item ≤ 20 g, containing ≤ 3% flash composition as report effects, or whistle composition ≤ 5 g ≥ 1 kg total pyrotechnic substance, no report effect, each whistle (if any) ≤ 25 g and ≤ 50 g whistle composition per wheel < 1 kg total pyrotechnic substance, no report effect, each whistle (if any) ≤ 5 g and ≤ 10 g whistle composition per wheel Table bombs, throwdowns, crackling granules, smokes, fog, snakes, glow worm, serpents, snaps, party poppers Device designed to produce very limited visible and/ or audible effect which contains small amounts of pyrotechnic and/or explosive composition. Spinner Aerial spinner, helicopter, chaser, ground spinner Non-metallic tube or tubes containing gas- or spark-producing pyrotechnic substance, with or without noise producing composition, with or without aerofoils attached - 122 - Low hazard fireworks and novelties Wheels Catherine wheels, Saxon Assembly including drivers containing pyrotechnic substance and provided with a means of attaching it to a support so that it can rotate Classification 1.3 G 1.4G 1.4G 1.3G 1.4G 1.3G 1.4G Copyright © United Nations, 2010. All rights reserved Classification Type Includes: / Synonym: Definition Specification Aerial wheel Flying Saxon, UFO's, rising crown Tubes containing propellant charges and sparksflame- and/or noise producing pyrotechnic substances, the tubes being fixed to a supporting ring > 200 g total pyrotechnic substance or > 60 g pyrotechnic substance per driver, ≤ 3% flash composition as report effects, each whistle (if any) ≤ 25 g and ≤ 50 g whistle composition per wheel 1.3G ≤ 200 g total pyrotechnic substance and ≤ 60 g pyrotechnic substance per driver, ≤ 3% flash composition as report effects, each whistle (if any) ≤ 5 g and ≤ 10 g whistle composition per wheel 1.4G - 123 - Selection pack Display selection box, display selection pack, garden selection box, indoor selection box; assortment A pack of more than one type each corresponding to one of the types of fireworks listed in this table The most hazardous firework type determines the classification Firecracker Celebration cracker, celebration roll, string cracker Assembly of tubes (paper or cardboard) linked by a pyrotechnic fuse, each tube intended to produce an aural effect Each tube ≤ 140 mg of flash composition or ≤ 1 g black powder 1.4G Banger Salute, flash banger, lady cracker Non-metallic tube containing report composition intended to produce an aural effect > 2 g flash composition per item 1.1G ≤ 2 g flash composition per item and ≤ 10 g per inner packaging 1.3G ≤ 1 g flash composition per item and ≤ 10 g per inner packaging or ≤ 10 g black powder per item 1.4G Copyright © United Nations, 2010. All rights reserved 2.2.1.1.8 Glossary of names NOTE 1: The descriptions in the glossary are not intended to replace the test procedures, nor to determine the hazard classification of a substance or article of Class 1. Assignment to the correct division and a decision on whether Compatibility Group S is appropriate shall be based on testing of the product in accordance with the Manual of Tests and Criteria, Part I or by analogy with similar products which have already been tested and assigned in accordance with the procedures of the Manual of Tests and Criteria. NOTE 2: The figures given after the names refer to the relevant UN numbers (Column 1 of Table A of Chapter 3.2). For the classification code, see 2.2.1.1.4. AIR BAG INFLATORS or AIR BAG MODULES or SEAT-BELT PRETENSIONERS: UN No. 0503 Articles which contain pyrotechnic substances and are used as life-saving vehicle airbags or seat-belts. AMMUNITION, ILLUMINATING, with or without burster, expelling charge or propelling charge: UN Nos. 0171, 0254, 0297 Ammunition designed to produce a single source of intense light for lighting up an area. The term includes illuminating cartridges, grenades and projectiles; and illuminating and target identification bombs. NOTE: The following articles: CARTRIDGES, SIGNAL; SIGNAL DEVICES HAND; SIGNALS, DISTRESS; FLARES, AERIAL; FLARES, SURFACE are not included in this definition. They are listed separately. AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge: UN No. 0247 Ammunition containing liquid or gelatinous incendiary substance. Except when the incendiary substance is an explosive per se, it also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge: UN Nos. 0243, 0244 Ammunition containing white phosphorus as incendiary substance. It also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge: UN Nos. 0009, 0010, 0300 Ammunition containing incendiary composition. Except when the composition is an explosive per se, it also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. AMMUNITION, PRACTICE: UN Nos. 0362, 0488 Ammunition without a main bursting charge, containing a burster or expelling charge. Normally it also contains a fuze and a propelling charge. NOTE: GRENADES, PRACTICE are not included in this definition. They are listed separately. - 124 - Copyright © United Nations, 2010. All rights reserved AMMUNITION, PROOF: UN No. 0363 Ammunition containing pyrotechnic substances, used to test the performance or strength of new ammunition, weapon components or assemblies. AMMUNITION, SMOKE, WHITE PHOSPHORUS, with burster, expelling charge or propelling charge: UN Nos. 0245, 0246 Ammunition containing white phosphorus as a smoke-producing substance. It also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. The term includes grenades, smoke. AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge: UN Nos. 0015, 0016, 0303 Ammunition containing a smoke-producing substance such as chlorosulphonic acid mixture or titanium tetrachloride; or a smoke-producing pyrotechnic composition based on hexachloroethane or red phosphorus. Except when the substance is an explosive per se, the ammunition also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. The term includes grenades, smoke. NOTE: SIGNALS, SMOKE are not included in this definition. They are listed separately. AMMUNITION, TEAR-PRODUCING, with burster, expelling charge or propelling charge: UN Nos. 0018, 0019, 0301 Ammunition containing a tear-producing substance. It also contains one or more of the following: a pyrotechnic substance; a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES EEI): UN No. 0486 Articles containing only extremely insensitive detonating substances (EIDS) which demonstrate a negligible probability of accidental initiation or propagation under normal conditions of transport, and which have passed Test Series 7. ARTICLES, PYROPHORIC: UN No. 0380 Articles which contain a pyrophoric substance (capable of spontaneous ignition when exposed to air) and an explosive substance or component. The term excludes articles containing white phosphorus. ARTICLES, PYROTECHNIC, for technical purposes: UN Nos. 0428, 0429, 0430, 0431, 0432 Articles which contain pyrotechnic substances and are used for technical purposes such as heat generation, gas generation, theatrical effects, etc. NOTE: The following articles: all ammunition; CARTRIDGES, SIGNAL; CUTTERS, CABLE, EXPLOSIVE; FIREWORKS; FLARES, AERIAL; FLARES, SURFACE; RELEASE DEVICES, EXPLOSIVE; RIVETS, EXPLOSIVE; SIGNAL DEVICES, HAND; SIGNALS, DISTRESS; SIGNALS, RAILWAY TRACK, EXPLOSIVES; SIGNALS, SMOKE are not included in this definition. They are listed separately. - 125 - Copyright © United Nations, 2010. All rights reserved BLACK POWDER (GUNPOWDER), COMPRESSED (GUNPOWDER), IN PELLETS: UN No. 0028 or BLACK POWDER Substance consisting of a pelletized form of black powder. BLACK POWDER (GUNPOWDER), granular or as meal: UN No. 0027 Substance consisting of an intimate mixture of charcoal or other carbon and either potassium nitrate or sodium nitrate, with or without sulphur. BOMBS, WITH FLAMMABLE LIQUID, with bursting charge: UN Nos. 0399, 0400 Articles which are dropped from aircraft, consisting of a tank filled with inflammable liquid and bursting charge. BOMBS, PHOTO-FLASH: UN No. 0038 Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a charge of detonating explosive without means of initiation or with means of initiation containing two or more effective protective features. BOMBS, PHOTO-FLASH: UN No. 0037 Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a charge of detonating explosive with means of initiation not containing two or more effective protective features. BOMBS, PHOTO-FLASH: UN Nos. 0039, 0299 Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a photo-flash composition. BOMBS with bursting charge: UN Nos. 0034; 0035 Explosive articles which are dropped from aircraft, without means of initiation or with means of initiation containing two or more effective protective features. BOMBS with bursting charge: UN Nos. 0033, 0291 Explosive articles which are dropped from aircraft, with means of initiation not containing two or more effective protective features. BOOSTERS WITH DETONATOR: UN Nos. 0225, 0268 Articles consisting of a charge of detonating explosive with means of initiation. They are used to increase the initiating power of detonators or detonating cord. BOOSTERS without detonator: UN Nos. 0042, 0283 Articles consisting of a charge of detonating explosive without means of initiation. They are used to increase the initiating power of detonators or detonating cord. BURSTERS, explosive: UN No. 0043 Articles consisting of a small charge of explosive used to open projectiles or other ammunition in order to disperse their contents. - 126 - Copyright © United Nations, 2010. All rights reserved CARTRIDGES, FLASH: UN Nos. 0049, 0050 Articles consisting of a casing, a primer and flash powder, all assembled in one piece ready for firing. CARTRIDGES FOR WEAPONS, BLANK: UN Nos. 0326, 0413, 0327, 0338, 0014 Ammunition consisting of a closed cartridge case with a centre or rim fire primer and a charge of smokeless or black powder but no projectile. It produces a loud noise and is used for training, saluting, propelling charge, starter pistols, etc. The term includes ammunition, blank. CARTRIDGES FOR WEAPONS, INERT PROJECTILE: UN Nos. 0328, 0417, 0339, 0012 Ammunition consisting of a projectile without bursting charge but with a propelling charge with or without a primer. The articles may include a tracer, provided that the predominant hazard is that of the propelling charge. CARTRIDGES FOR WEAPONS with bursting charge: UN Nos. 0006, 0321, 0412 Ammunition consisting of a projectile with a bursting charge without means of initiation or with means of initiation containing two or more effective protective features; and a propelling charge with or without a primer. The term includes fixed (assembled) ammunition, semi-fixed (partially assembled) ammunition and separate loading ammunition when the components are packed together. CARTRIDGES FOR WEAPONS with bursting charge: UN Nos. 0005, 0007, 0348 Ammunition consisting of a projectile with a bursting charge with means of initiation not containing two or more effective protective features; and a propelling charge with or without a primer. The term includes fixed (assembled) ammunition, semi-fixed (partially assembled) ammunition and separate loading ammunition when the components are packed together. CARTRIDGES, OIL WELL: UN Nos. 0277, 0278 Articles consisting of a thin casing of fibreboard, metal or other material containing only propellant powder which projects a hardened projectile to perforate an oil well casing. NOTE: CHARGES, SHAPED are not included in this definition. They are listed separately. CARTRIDGES, POWER DEVICE: UN Nos. 0275, 0276, 0323, 0381 Articles designed to accomplish mechanical actions. They consist of a casing with a charge of deflagrating explosive and a means of ignition. The gaseous products of the deflagration produce inflation, linear or rotary motion or activate diaphragms, valves or switches or project fastening devices or extinguishing agents. CARTRIDGES, SIGNAL: UN Nos. 0054, 0312, 0405 Articles designed to fire coloured flares or other signals from signal pistols, etc. CARTRIDGES, SMALL ARMS: UN Nos. 0417, 0339, 0012 Ammunition consisting of a cartridge case fitted with a centre or rim fire primer and containing both a propelling charge and solid projectile. They are designed to be fired in - 127 - Copyright © United Nations, 2010. All rights reserved weapons of calibre not larger than 19.1 mm. Shot-gun cartridges of any calibre are included in this description. NOTE: CARTRIDGES, SMALL ARMS, BLANK, are not included in this definition. They are listed separately. Some military small arms cartridges are not included in this definition. They are listed under CARTRIDGES FOR WEAPONS, INERT PROJECTILE. CARTRIDGES, SMALL ARMS, BLANK: UN Nos. 0014, 0327, 0338 Ammunition consisting of a closed cartridge case with a centre or rim fire primer and a charge of smokeless or black powder. The cartridge cases contain no projectiles. The cartridges are designed to be fired from weapons with a calibre of at most 19.1 mm and serve to produce a loud noise and are used for training, saluting, propelling charge, starter pistols, etc. CASES, CARTRIDGE, EMPTY, WITH PRIMER: UN Nos. 0379; 0055 Articles consisting of a cartridge case made from metal, plastics or other non-inflammable material, in which the only explosive component is the primer. CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER: UN Nos. 0447, 0446 Articles consisting of a cartridge case made partly or entirely from nitrocellulose. CHARGES, BURSTING, PLASTICS BONDED: UN Nos. 0457, 0458, 0459, 0460 Articles consisting of a charge of detonating explosive, plastics bonded, manufactured in a specific form without a casing and without means of initiation. They are designed as components of ammunition such as warheads. CHARGES, DEMOLITION: UN No. 0048 Articles containing a charge of a detonating explosive in a casing of fibreboard, plastics, metal or other material. The articles are without means of initiation or with means of initiation containing two or more effective protective features. NOTE: The following articles: BOMBS; MINES; PROJECTILES are not included in this definition. They are listed separately. CHARGES, DEPTH: UN No. 0056 Articles consisting of a charge of detonating explosive contained in a drum or projectile without means of initiation or with means of initiation containing two or more effective protective features. They are designed to detonate under water. CHARGES, EXPLOSIVE, COMMERCIAL without detonator: UN Nos. 0442, 0443, 0444, 0445 Articles consisting of a charge of detonating explosive without means of initiation, used for explosive welding, jointing, forming and other metallurgical processes. CHARGES, PROPELLING, FOR CANNON: UN Nos. 0242, 0279, 0414 Charges of propellant in any physical form for separate-loading ammunition for cannon. - 128 - Copyright © United Nations, 2010. All rights reserved CHARGES, PROPELLING: UN Nos. 0271, 0272, 0415, 0491 Articles consisting of a charge of a propellant charge in any physical form, with or without a casing, as a component of rocket motors or for reducing the drag of projectiles. CHARGES, SHAPED, without detonator: UN Nos. 0059, 0439, 0440, 0441 Articles consisting of a casing containing a charge of detonating explosive with a cavity lined with rigid material, without means of initiation. They are designed to produce a powerful, penetrating jet effect. CHARGES, SHAPED, FLEXIBLE, LINEAR: UN Nos. 0237, 0288 Articles consisting of a V-shaped core of a detonating explosive clad by a flexible sheath. CHARGES, SUPPLEMENTARY, EXPLOSIVE: UN No. 0060 Articles consisting of a small removable booster placed in the cavity of a projectile between the fuze and the bursting charge. COMPONENTS, EXPLOSIVE TRAIN, N.O.S.: UN Nos. 0382, 0383, 0384, 0461 Articles containing an explosive designed to transmit detonation or deflagration within an explosive train. CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge: UN Nos. 0248, 0249 Articles whose functioning depends upon physico-chemical reaction of their contents with water. CORD, DETONATING, flexible: UN Nos. 0065, 0289 Article consisting of a core of detonating explosive enclosed in spun fabric and a plastics or other covering. The covering is not necessary if the spun fabric is sift-proof. CORD (FUSE) DETONATING, metal clad: UN Nos. 0102, 0290 Article consisting of a core of detonating explosive clad by a soft metal tube with or without protective covering. CORD (FUSE) DETONATING, MILD EFFECT, metal clad: UN No. 0104 Article consisting of a core of detonating explosive clad by a soft metal tube with or without a protective covering. The quantity of explosive substance is so small that only a mild effect is manifested outside the cord. CORD, IGNITER: UN No. 0066 Article consisting of textile yarns covered with black powder or another fast burning pyrotechnic composition and of a flexible protective covering; or it consists of a core of black powder surrounded by a flexible woven fabric. It burns progressively along its length with an external flame and is used to transmit ignition from a device to a charge or primer. - 129 - Copyright © United Nations, 2010. All rights reserved CUTTERS, CABLE, EXPLOSIVE: UN No. 0070 Articles consisting of a knife-edged device which is driven by a small charge of deflagrating explosive into an anvil. DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting: UN Nos. 0360, 0361, 0500 Non-electric detonators assembled with and activated by such means as safety fuse, shock tube, flash tube or detonating cord. They may be of instantaneous design or incorporate delay elements. Detonating relays incorporating detonating cord are included. DETONATORS, ELECTRIC for blasting: UN Nos. 0030, 0255, 0456 Articles specially designed for the initiation of blasting explosives. These detonators may be constructed to detonate instantaneously or may contain a delay element. Electric detonators are activated by an electric current. DETONATORS FOR AMMUNITION: UN Nos. 0073, 0364, 0365, 0366 Articles consisting of a small metal or plastics tube containing explosives such as lead azide, PETN or combinations of explosives. They are designed to start a detonation train. DETONATORS, NON-ELECTRIC for blasting: UN Nos. 0029, 0267, 0455 Articles specially designed for the initiation of blasting explosives. These detonators may be constructed to detonate instantaneously or may contain a delay element. Non-electric detonators are activated by such means as shock tube, flash tube, safety fuse, other igniferous device or flexible detonating cord. Detonating relays without detonating cord are included. EXPLOSIVE, BLASTING, TYPE A: UN No. 0081 Substances consisting of liquid organic nitrates such as nitroglycerine or a mixture of such ingredients with one or more of the following: nitrocellulose; ammonium nitrate or other inorganic nitrates; aromatic nitro-derivatives, or combustible materials, such as wood-meal and aluminium powder. They may contain inert components such as kieselguhr, and additives such as colouring agents and stabilizers. Such explosives shall be in powdery, gelatinous or elastic form. The term includes dynamite; gelatine, blasting and gelatine dynamites. EXPLOSIVE, BLASTING, TYPE B: UN Nos. 0082, 0331 Substances consisting of (a) a mixture of ammonium nitrate or other inorganic nitrates with an explosive such as trinitrotoluene, with or without other substances such as wood-meal and aluminium powder; or (b) a mixture of ammonium nitrate or other inorganic nitrates with other combustible substances which are not explosive ingredients. In both cases they may contain inert components such as kieselguhr, and additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine, similar liquid organic nitrates or chlorates. - 130 - Copyright © United Nations, 2010. All rights reserved EXPLOSIVE, BLASTING, TYPE C: UN No. 0083 Substances consisting of a mixture of either potassium or sodium chlorate or potassium, sodium or ammonium perchlorate with organic nitro-derivatives or combustible materials such as wood-meal or aluminium powder or a hydrocarbon. They may contain inert components such as kieselguhr and additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine or similar liquid organic nitrates. EXPLOSIVE, BLASTING, TYPE D: UN No. 0084 Substances consisting of a mixture of organic nitrated compounds and combustible materials such as hydrocarbons and aluminium powder. They may contain inert components such as kieselguhr and additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine, similar liquid organic nitrates, chlorates and ammonium nitrate. The term generally includes plastic explosives. EXPLOSIVES, BLASTING, TYPE E: UN Nos. 0241, 0332 Substances consisting of water as an essential ingredient and high proportions of ammonium nitrate or other oxidizers, some or all of which are in solution. The other constituents may include nitro-derivatives such as trinitrotoluene, hydrocarbons or aluminium powder. They may contain inert components such as kieselguhr and additives such as colouring agents and stabilizers. The term includes explosives, emulsion, explosives, slurry and explosives, watergel. FIREWORKS: UN Nos. 0333, 0334, 0335, 0336, 0337 Pyrotechnic articles designed for entertainment. FLARES, AERIAL: UN Nos. 0093, 0403, 0404, 0420, 0421; Articles containing pyrotechnic substances which are designed to be dropped from an aircraft to illuminate, identify, signal or warn. FLARES, SURFACE: UN Nos. 0092, 0418, 0419 Articles containing pyrotechnic substances which are designed for use on the surface to illuminate, identify, signal or warn. FLASH POWDER: UN Nos. 0094, 0305 Pyrotechnic substance which, when ignited, produces an intense light. FRACTURING DEVICES, EXPLOSIVE without detonator, for oil wells: UN No. 0099 Articles consisting of a charge of detonating explosive contained in a casing without means of initiation. They are used to fracture the rock around a drill shaft to assist the flow of crude oil from the rock. FUSE, IGNITER, tubular, metal clad: UN No. 0103 Article consisting of a metal tube with a core of deflagrating explosive. - 131 - Copyright © United Nations, 2010. All rights reserved FUSE, NON-DETONATING: UN No. 0101 Article consisting of cotton yarns impregnated with fine black powder (quickmatch). It burns with an external flame and is used in ignition trains for fireworks, etc. FUSE, SAFETY: UN No. 0105 Article consisting of a core of fine grained black powder surrounded by a flexible woven fabric with one or more protective outer coverings. When ignited, it burns at a predetermined rate without any external explosive effect. FUZES, DETONATING: UN Nos. 0106, 0107, 0257, 0367 Articles with explosive components designed to produce a detonation in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to initiate the detonation. They generally incorporate protective features. FUZES, DETONATING with protective features: UN Nos. 0408, 0409, 0410 Articles with explosive components designed to produce a detonation in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to initiate the detonation. The detonating fuze must incorporate two or more effective protective features. FUZES, IGNITING: UN Nos. 0316, 0317, 0368 Articles with primary explosive components designed to produce a deflagration in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to start the deflagration. They generally incorporate protective features. GRENADES, hand or rifle, with bursting charge: UN Nos. 0284, 0285 Articles which are designed to be thrown by hand or to be projected by a rifle. They are without means of initiation or with means of initiation containing two or more effective protective features. GRENADES, hand or rifle, with bursting charge: UN Nos. 0292, 0293 Articles which are designed to be thrown by hand or to be projected by a rifle. They are with means of initiation not containing two or more effective protective features. GRENADES, PRACTICE, hand or rifle: UN Nos. 0110, 0372, 0318, 0452 Articles without a main bursting charge which are designed to be thrown by hand or to be projected by a rifle. They contain the priming device and may contain a spotting charge. HEXOTONAL: UN No. 0393 Substance consisting of an intimate mixture of cyclotrimethylene-trinitramine (RDX), trinitrotoluene (TNT) and aluminium. HEXOLITE (HEXOTOL), dry or wetted with less than 15% water, by mass: UN No. 0118 Substance consisting of an intimate mixture of cyclotrimethylene-trinitramine (RDX) and trinitrotoluene (TNT). The term includes "Composition B". - 132 - Copyright © United Nations, 2010. All rights reserved IGNITERS: UN Nos. 0121, 0314, 0315, 0325, 0454 Articles containing one or more explosive substances designed to produce a deflagration in an explosive train. They may be actuated chemically, electrically or mechanically. NOTE: The following articles: CORD, IGNITER; FUSE, IGNITER; FUSE, NON-DETONATING; FUZES, IGNITING; LIGHTERS, FUSE; PRIMERS, CAP TYPE; PRIMERS, TUBULAR are not included in this definition. They are listed separately. JET PERFORATING GUNS, CHARGED, oil well, without detonator: UN Nos. 0124, 0494 Articles consisting of a steel tube or metallic strip, into which are inserted shaped charges connected by detonating cord, without means of initiation. LIGHTERS, FUSE: UN No. 0131 Articles of various design actuated by friction, percussion or electricity and used to ignite safety fuse. MINES with bursting charge: UN Nos. 0137, 0138 Articles consisting normally of metal or composition receptacles filled with a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be operated by the passage of ships, vehicles or personnel. The term includes "Bangalore torpedoes". MINES with bursting charge: UN Nos. 0136, 0294 Articles consisting normally of metal or composition receptacles filled with a detonating explosive, with means of initiation not containing two or more effective protective features. They are designed to be operated by the passage of ships, vehicles or personnel. The term includes "Bangalore torpedoes". OCTOLITE (OCTOL), dry or wetted with less than 15% water, by mass: UN No. 0266 Substance consisting of an intimate mixture of cyclotetramethylene-tetranitramine (HMX) and trinitrotoluene (TNT). OCTONAL: UN No. 0496 Substance consisting of an intimate mixture of cyclotetramethylenetetranitramine (HMX), trinitrotoluene (TNT) and aluminium. PENTOLITE, dry or wetted with less than 15% water, by mass: UN No. 0151 Substance consisting of an intimate mixture of pentaerythrite tetranitrate (PETN) and trinitrotoluene (TNT). POWDER CAKE (POWDER PASTE), WETTED with not less than 17% alcohol, by mass; POWDER CAKE (POWDER PASTE), WETTED with not less than 25% water, by mass: UN Nos. 0433, 0159 Substance consisting of nitrocellulose impregnated with not more than 60% of nitroglycerine or other liquid organic nitrates or a mixture of these. - 133 - Copyright © United Nations, 2010. All rights reserved POWDER, SMOKELESS: UN Nos. 0160, 0161, 0509 Substance based on nitrocellulose used as propellant. The term includes propellants with a single base (nitrocellulose (NC) alone), those with a double base (such as NC and nitroglycerine/(NG)) and those with a triple base (such as NC/NG/nitroguanidine). NOTE: Cast, pressed or bag-charges of smokeless powder are listed under CHARGES, PROPELLING or CHARGES, PROPELLING, FOR CANON. PRIMERS, CAP TYPE: UN Nos. 0044, 0377, 0378 Articles consisting of a metal or plastics cap containing a small amount of primary explosive mixture that is readily ignited by impact. They serve as igniting elements in small arms cartridges and in percussion primers for propelling charges. PRIMERS, TUBULAR: UN Nos. 0319, 0320, 0376 Articles consisting of a primer for ignition and an auxiliary charge of deflagrating explosive such as black powder used to ignite the propelling charge in a cartridge case for cannon, etc. PROJECTILES, inert with tracer: UN Nos. 0345, 0424, 0425 Articles such as a shell or bullet, which are projected from a cannon or other gun, rifle or other small arm. PROJECTILES with burster or expelling charge: UN Nos. 0346, 0347 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are without means of initiation or with means of initiation containing two or more effective protective features. They are used to scatter dyes for spotting or other inert materials. PROJECTILES with burster or expelling charge: UN Nos. 0426, 0427 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are with means of initiation not containing two or more effective protective features. They are used to scatter dyes for spotting or other inert materials. PROJECTILES with burster or expelling charge: UN Nos. 0434, 0435 Articles such as a shell or bullet, which are projected from a cannon or other gun, rifle or other small arm. They are used to scatter dyes for spotting or other inert materials. PROJECTILES with bursting charge: UN Nos. 0168, 0169, 0344 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are without means of initiation or with means of initiation containing two or more effective protective features. PROJECTILES with bursting charge: UN Nos. 0167, 0324 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are with means of initiation not containing two or more effective protective features. PROPELLANT, LIQUID: UN Nos. 0495, 0497 Substance consisting of a deflagrating liquid explosive, used for propulsion. - 134 - Copyright © United Nations, 2010. All rights reserved PROPELLANT, SOLID: UN Nos. 0498, 0499, 0501 Substance consisting of a deflagrating solid explosive, used for propulsion. RELEASE DEVICES, EXPLOSIVE: UN No. 0173 Articles consisting of a small charge of explosive with means of initiation and rods or links. They sever the rods or links to release equipment quickly. RIVETS, EXPLOSIVE: UN No. 0174 Articles consisting of a small charge of explosive inside a metallic rivet. ROCKET MOTORS: UN Nos. 0186, 0280, 0281 Articles consisting of a charge of explosive, generally a solid propellant, contained in a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile. ROCKET MOTORS, LIQUID FUELLED: UN Nos. 0395, 0396 Articles consisting of a liquid fuel within a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile. ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge: UN Nos. 0322, 0250 Articles consisting of a hypergolic fuel contained in a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile. ROCKETS, LINE THROWING: UN Nos. 0238, 0240, 0453 Articles consisting of a rocket motor which is designed to extend a line. ROCKETS, LIQUID FUELLED with bursting charge: UN Nos. 0397, 0398 Articles consisting of a liquid fuel within a cylinder fitted with one or more nozzles and fitted with a warhead. The term includes guided missiles. ROCKETS with bursting charge: UN Nos. 0181, 0182 Articles consisting of a rocket motor and a warhead without means of initiation or with means of initiation containing two or more effective protective features. The term includes guided missiles. ROCKETS with bursting charge: UN Nos. 0180, 0295 Articles consisting of a rocket motor and a warhead with means of initiation not containing two or more effective protective features. The term includes guided missiles. ROCKETS with expelling charge: UN Nos. 0436, 0437, 0438 Articles consisting of a rocket motor and a charge to expel the payload from a rocket head. The term includes guided missiles. - 135 - Copyright © United Nations, 2010. All rights reserved ROCKETS with inert head: UN Nos. 0183, 0502 Articles consisting of a rocket motor and an inert head. The term includes guided missiles. SAMPLES, EXPLOSIVE, other than initiating explosive UN No. 0190 New or existing explosive substances or articles, not yet assigned to a name in Table A of Chapter 3.2 and carried in conformity with the instructions of the competent authority and generally in small quantities, inter alia, for the purposes of testing, classification, research and development, or quality control, or as commercial samples. NOTE: Explosive substances or articles already assigned to another name in Table A of Chapter 3.2 are not included in this definition. SIGNAL DEVICES, HAND: UN Nos. 0191, 0373 Portable articles containing pyrotechnic substances which produce visual signals or warnings. The term includes small surface flares such as highway or railway flares and small distress flares. SIGNALS, DISTRESS, ship: UN Nos. 0194, 0195, 0505, 0506 Articles containing pyrotechnic substances designed to produce signals by means of sound, flame or smoke or any combination thereof. SIGNALS, RAILWAY TRACK, EXPLOSIVE: UN Nos. 0192, 0193, 0492, 0493 Articles containing a pyrotechnic substance which explodes with a loud report when the article is crushed. They are designed to be placed on a rail. SIGNALS, SMOKE: UN Nos. 0196, 0197, 0313, 0487, 0507 Articles containing pyrotechnic substances which emit smoke. In addition they may contain devices for emitting audible signals. SOUNDING DEVICES, EXPLOSIVE: UN Nos. 0374, 0375 Articles consisting of a charge of detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are dropped from ships and function when they reach a predetermined depth or the sea bed. SOUNDING DEVICES, EXPLOSIVE: UN Nos. 0204, 0296 Articles consisting of a charge of detonating explosive with means of initiation not containing two or more effective protective features. They are dropped from ships and function when they reach a predetermined depth or the sea bed. SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (Substances, EVI), N.O.S.: UN No. 0482 Substances presenting a mass explosion hazard but which are so insensitive that there is very little probability of initiation or of transition from burning to detonation under normal conditions of transport, and which have passed Test Series 5. - 136 - Copyright © United Nations, 2010. All rights reserved TORPEDOES, LIQUID FUELLED with inert head: UN No. 0450 Articles consisting of a liquid explosive system to propel the torpedo through the water, with an inert head. TORPEDOES, LIQUID FUELLED with or without bursting charge: UN No. 0449 Articles consisting of either a liquid explosive system to propel the torpedo through the water, with or without a warhead; or a liquid non-explosive system to propel the torpedo through the water, with a warhead. TORPEDOES with bursting charge: UN No. 0451 Articles consisting of a non-explosive system to propel the torpedo through the water, and a warhead without means of initiation or with means of initiation containing two or more effective protective features. TORPEDOES with bursting charge: UN No. 0329 Articles consisting of an explosive system to propel the torpedo through the water, and a warhead without means of initiation or with means of initiation containing two or more effective protective features. TORPEDOES with bursting charge: UN No. 0330 Articles consisting of an explosive or non-explosive system to propel the torpedo through the water, and a warhead with means of initiation not containing two or more effective protective features. TRACERS FOR AMMUNITION: UN Nos. 0212, 0306 Sealed articles containing pyrotechnic substances, designed to reveal the trajectory of a projectile. TRITONAL: UN No. 0390 Substance consisting of trinitrotoluene (TNT) mixed with aluminium. WARHEADS, ROCKET with burster or expelling charge: UN No. 0370 Articles consisting of an inert payload and a small charge of detonating or deflagrating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a rocket motor to scatter inert material. The term includes warheads for guided missiles. WARHEADS, ROCKET with burster or expelling charge: UN No. 0371 Articles consisting of an inert payload and a small charge of detonating or deflagrating explosive, with means of initiation not containing two or more effective protective features. They are designed to be fitted to a rocket motor to scatter inert material. The term includes warheads for guided missiles. - 137 - Copyright © United Nations, 2010. All rights reserved WARHEADS, ROCKET with bursting charge: UN Nos. 0286, 0287 Articles consisting of a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a rocket. The term includes warheads for guided missiles. WARHEADS, ROCKET with bursting charge: UN No. 0369 Articles consisting of a detonating explosive, with means of initiation not containing two or more effective protective features. They are designed to be fitted to a rocket. The term includes warheads for guided missiles. WARHEADS, TORPEDO with bursting charge: UN No. 0221 Articles consisting of a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a torpedo. 2.2.1.2 Substances and articles not accepted for carriage 2.2.1.2.1 Explosive substances which are unduly sensitive according to the criteria of the Manual of Tests and Criteria, Part I, or are liable to spontaneous reaction, as well as explosive substances and articles which cannot be assigned to a name or n.o.s. entry listed in Table A of Chapter 3.2, shall not be accepted for carriage. 2.2.1.2.2 Articles of compatibility group K shall not be accepted for carriage (1.2K, UN No. 0020 and 1.3K, UN No. 0021). - 138 - Copyright © United Nations, 2010. All rights reserved 2.2.1.3 List of collective entries UN Name of the substance or article Classification code (see 2.2.1.1.4) No. 1.1A 0473 SUBSTANCES, EXPLOSIVE, N.O.S. 1.1B 0461 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1.1C 0474 SUBSTANCES, EXPLOSIVE, N.O.S. 0497 PROPELLANT, LIQUID 0498 PROPELLANT, SOLID 0462 ARTICLES, EXPLOSIVE, N.O.S. 0475 SUBSTANCES, EXPLOSIVE, N.O.S. 0463 ARTICLES, EXPLOSIVE, N.O.S. 1.1E 0464 ARTICLES, EXPLOSIVE, N.O.S. 1.1F 0465 ARTICLES, EXPLOSIVE, N.O.S. 1.1G 0476 SUBSTANCES, EXPLOSIVE, N.O.S. 1.1L 0357 SUBSTANCES, EXPLOSIVE, N.O.S. 0354 ARTICLES, EXPLOSIVE, N.O.S. 1.2B 0382 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1.2C 0466 ARTICLES, EXPLOSIVE, N.O.S. 1.2D 0467 ARTICLES, EXPLOSIVE, N.O.S. 1.2E 0468 ARTICLES, EXPLOSIVE, N.O.S. 1.2F 0469 ARTICLES, EXPLOSIVE, N.O.S. 1.2L 0358 SUBSTANCES, EXPLOSIVE, N.O.S. 0248 CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge 0355 ARTICLES, EXPLOSIVE, N.O.S. 0132 DEFLAGRATING METAL SALTS OF AROMATIC NITRODERIVATIVES, N.O.S. 0477 SUBSTANCES, EXPLOSIVE, N.O.S. 0495 PROPELLANT, LIQUID 0499 PROPELLANT, SOLID 0470 ARTICLES, EXPLOSIVE, N.O.S. 1.3G 0478 SUBSTANCES, EXPLOSIVE, N.O.S. 1.3L 0359 SUBSTANCES, EXPLOSIVE, N.O.S. 0249 CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge 0356 ARTICLES, EXPLOSIVE, N.O.S. 0350 ARTICLES, EXPLOSIVE, N.O.S. 0383 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 0479 SUBSTANCES, EXPLOSIVE, N.O.S. 0501 PROPELLANT, SOLID 0351 ARTICLES, EXPLOSIVE, N.O.S. 1.1D 1.3C 1.4B 1.4C - 139 - Copyright © United Nations, 2010. All rights reserved UN Name of the substance or article Classification code (see 2.2.1.1.4) No. 1.4D 0480 SUBSTANCES, EXPLOSIVE, N.O.S. 0352 ARTICLES, EXPLOSIVE, N.O.S. 1.4E 0471 ARTICLES, EXPLOSIVE, N.O.S. 1.4F 0472 ARTICLES, EXPLOSIVE, N.O.S. 1.4G 0485 SUBSTANCES, EXPLOSIVE, N.O.S. 0353 ARTICLES, EXPLOSIVE, N.O.S. 0481 SUBSTANCES, EXPLOSIVE, N.O.S. 0349 ARTICLES, EXPLOSIVE, N.O.S. 0384 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 0482 SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (SUBSTANCES, EVI) N.O.S. 0486 ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES, EEI) 0190 SAMPLES, EXPLOSIVE other than initiating explosive 1.4S 1.5D 1.6N NOTE: Division and Compatibility Group shall be defined as directed by the competent authority and according to the principles in 2.2.1.1.4. - 140 - Copyright © United Nations, 2010. All rights reserved 2.2.2 Class 2 Gases 2.2.2.1 Criteria 2.2.2.1.1 The heading of Class 2 covers pure gases, mixtures of gases, mixtures of one or more gases with one or more other substances and articles containing such substances. A gas is a substance which: (a) at 50 °C has a vapour pressure greater than 300 kPa (3 bar); or (b) is completely gaseous at 20 °C at the standard pressure of 101.3 kPa. NOTE 1: UN No. 1052 HYDROGEN FLUORIDE, ANHYDROUS is nevertheless classified in Class 8. NOTE 2: A pure gas may contain other components deriving from its production process or added to preserve the stability of the product, provided that the level of these components does not change its classification or its conditions of carriage, such as filling ratio, filling pressure, test pressure. NOTE 3: N.O.S. entries in 2.2.2.3 may cover pure gases as well as mixtures. 2.2.2.1.2 The substances and articles of Class 2 are subdivided as follows: 1. Compressed gas: a gas which when packaged under pressure for carriage is entirely gaseous at -50 °C; this category includes all gases with a critical temperature less than or equal to -50 °C; 2. Liquefied gas: a gas which when packaged under pressure for carriage is partially liquid at temperatures above -50 °C. A distinction is made between: High pressure liquefied gas: a gas with a critical temperature above -50 °C and equal to or below +65 °C; and Low pressure liquefied gas: a gas with a critical temperature above +65 °C; 2.2.2.1.3 3. Refrigerated liquefied gas: a gas which when packaged for carriage is made partially liquid because of its low temperature; 4. Dissolved gas: a gas which when packaged under pressure for carriage is dissolved in a liquid phase solvent; 5. Aerosol dispensers and receptacles, small, containing gas (gas cartridges); 6. Other articles containing gas under pressure; 7. Non-pressurized gases subject to special requirements (gas samples). Substances and articles (except aerosols) of Class 2 are assigned to one of the following groups according to their hazardous properties, as follows: A asphyxiant; O oxidizing; - 141 - Copyright © United Nations, 2010. All rights reserved F flammable; T toxic; TF toxic, flammable; TC toxic, corrosive; TO toxic, oxidizing; TFC toxic, flammable, corrosive; TOC toxic, oxidizing, corrosive. For gases and gas mixtures presenting hazardous properties associated with more than one group according to the criteria, the groups designated by letter T take precedence over all other groups. The groups designated by letter F take precedence over the groups designated by letters A or O. NOTE 1: In the UN Model Regulations, the IMDG Code and the ICAO Technical Instructions, gases are assigned to one of the following three divisions, based on the primary hazard: Division 2.1: Division 2.2: Division 2.3: flammable gases (corresponding to the groups designated by the capital letter F); non-flammable, non-toxic gases (corresponding to the groups designated by the capital letters A or O); toxic gases (corresponding to the groups designated by the capital letter T i.e. T, TF, TC, TO, TFC and TOC). NOTE 2: Receptacles, small containing gas (UN No. 2037) shall be assigned to the groups A to TOC according to the hazard of the contents. For aerosols (UN No. 1950), see 2.2.2.1.6. NOTE 3: Corrosive gases are considered to be toxic, and are therefore assigned to the group TC, TFC or TOC. 2.2.2.1.4 If a mixture of Class 2 mentioned by name in Table A of Chapter 3.2 meets different criteria as mentioned in 2.2.2.1.2 and 2.2.2.1.5, this mixture shall be classified according to the criteria and assigned to an appropriate N.O.S. entry. 2.2.2.1.5 Substances and articles (except aerosols) of Class 2 which are not mentioned by name in Table A of Chapter 3.2 shall be classified under a collective entry listed in 2.2.2.3 in accordance with 2.2.2.1.2 and 2.2.2.1.3. The following criteria shall apply: Asphyxiant gases Gases which are non-oxidizing, non-flammable and non-toxic and which dilute or replace oxygen normally in the atmosphere. Flammable gases Gases which at 20 °C and a standard pressure of 101.3 kPa: (a) are ignitable when in a mixture of 13% or less by volume with air; or - 142 - Copyright © United Nations, 2010. All rights reserved (b) have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit. Flammability shall be determined by tests or by calculation, in accordance with methods adopted by ISO (see ISO 10156:1996). Where insufficient data are available to use these methods, tests by a comparable method recognized by the competent authority of the country of origin may be used. If the country of origin is not a Contracting Party to ADR these methods shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. Oxidizing gases Gases, which may, generally by providing oxygen, cause or contribute to the combustion of other material more than air does. These are pure gases or gas mixtures with an oxidizing power greater than 23.5% as determined by a method specified in ISO 10156:1996 or ISO 10156-2:2005. Toxic gases NOTE: Gases meeting the criteria for toxicity in part or completely owing to their corrosivity are to be classified as toxic. See also the criteria under the heading "Corrosive gases" for a possible subsidiary corrosivity risk. Gases which: (a) are known to be so toxic or corrosive to humans as to pose a hazard to health; or (b) are presumed to be toxic or corrosive to humans because they have a LC50 value for acute toxicity equal to or less than 5 000 ml/m³ (ppm) when tested in accordance with 2.2.61.1. In the case of gas mixtures (including vapours of substances from other classes) the following formula may be used: LC50 Toxic (mixture) = 1 n ∑ Tf i =1 where i i fi = mole fraction of the ith component substance of the mixture; Ti = toxicity index of the ith component substance of the mixture. The Ti equals the LC50 value as found in packing instruction P200 of 4.1.4.1. When no LC50 value is listed in packing instruction P200 of 4.1.4.1, a LC50 value available in scientific literature shall be used. When the LC50 value is unknown, the toxicity index is determined by using the lowest LC50 value of substances of similar physiological and chemical effects, or through testing if this is the only practical possibility. - 143 - Copyright © United Nations, 2010. All rights reserved Corrosive gases Gases or gas mixtures meeting the criteria for toxicity completely owing to their corrosivity are to be classified as toxic with a subsidiary corrosivity risk. A gas mixture that is considered to be toxic due to the combined effects of corrosivity and toxicity has a subsidiary risk of corrosivity when the mixture is known by human experience to be destructive to the skin, eyes or mucous membranes or when the LC50 value of the corrosive components of the mixture is equal to or less than 5 000 ml/m3 (ppm) when the LC50 is calculated by the formula: LC50 Corrosive (mixture) = 1 n ∑ Tfcici i =1 where fci = mole fraction of the ith corrosive component substance of the mixture; Tci = toxicity index of the ith corrosive component substance of the mixture. The Tci equals the LC50 value as found in packing instruction P200 of 4.1.4.1. When no LC50 value is listed in packing instruction P200 of 4.1.4.1, a LC50 value available in scientific literature shall be used. When the LC50 value is unknown the toxicity index is determined by using the lowest LC50 value of substances of similar physiological and chemical effects, or through testing if this is the only practical possibility. 2.2.2.1.6 Aerosols Aerosols (UN No. 1950) are assigned to one of the following groups according to their hazardous properties, as follows: A asphyxiant; O oxidizing; F flammable; T toxic; C corrosive; CO corrosive, oxidizing; FC flammable, corrosive; TF toxic, flammable; TC toxic, corrosive; TO toxic, oxidizing; TFC toxic, flammable, corrosive; - 144 - Copyright © United Nations, 2010. All rights reserved TOC toxic, oxidizing, corrosive. The classification depends on the nature of the contents of the aerosol dispenser. NOTE: Gases, which meet the definition of toxic gases according to 2.2.2.1.5 or of pyrophoric gases according to packing instruction P200 in 4.1.4.1, shall not be used as a propellant in an aerosol dispenser. Aerosols with contents meeting the criteria for packing group I for toxicity or corrosivity shall not be accepted for carriage (see also 2.2.2.2.2). The following criteria shall apply: (a) Assignment to group A shall apply when the contents do not meet the criteria for any other group according to sub-paragraphs (b) to (f) below; (b) Assignment to group O shall apply when the aerosol contains an oxidizing gas according to 2.2.2.1.5; (c) Assignment to group F shall apply if the contents include 85% by mass or more flammable components and the chemical heat of combustion is 30 kJ/g or more. It shall not apply if the contents contain 1% by mass or less flammable components and the heat of combustion is less than 20 kJ/g. Otherwise the aerosol shall be tested for flammability in accordance with the tests described in the Manual of Tests and Criteria, Part III, section 31. Extremely flammable and flammable aerosols shall be assigned to group F; NOTE: Flammable components are flammable liquids, flammable solids or flammable gases and gas mixtures as defined in Notes 1 to 3 of sub-section 31.1.3 of Part III of the Manual of Tests and Criteria. This designation does not cover pyrophoric, self-heating or water-reactive substances. The chemical heat of combustion shall be determined by one of the following methods ASTM D 240, ISO/FDIS 13943:1999 (E/F) 86.1 to 86.3 or NFPA 30B. (d) Assignment to group T shall apply when the contents, other than the propellant of aerosol dispensers to be ejected, are classified as Class 6.1, packing groups II or III; (e) Assignment to group C shall apply when the contents, other than the propellant of aerosol dispensers to be ejected, meet the criteria for Class 8, packing groups II or III; (f) When the criteria for more than one group amongst groups O, F, T, and C are met, assignment to groups CO, FC, TF, TC TO, TFC or TOC shall apply, as relevant. 2.2.2.2 Gases not accepted for carriage 2.2.2.2.1 Chemically unstable substances of Class 2 shall not be accepted for carriage, unless the necessary steps have been taken to prevent all possibility of a dangerous reaction e.g. decomposition, dismutation or polymerisation under normal conditions during transport. To this end particular care shall be taken to ensure that receptacles and tanks do not contain any substances liable to promote these reactions. 2.2.2.2.2 The following substances and mixtures shall not be accepted for carriage: - UN No. 2186 HYDROGEN CHLORIDE, REFRIGERATED LIQUID; - 145 - Copyright © United Nations, 2010. All rights reserved - UN No. 2421 NITROGEN TRIOXIDE; - UN No. 2455 METHYL NITRITE; - Refrigerated liquefied gases which cannot be assigned to classification codes 3A, 3O or 3F; - Dissolved gases which cannot be classified under UN Nos. 1001, 2073 or 3318; - Aerosols where gases which are toxic according to 2.2.2.1.5 or pyrophoric according to packing instruction P200 in 4.1.4.1 are used as propellants; - Aerosols with contents meeting the criteria for packing group I for toxicity or corrosivity (see 2.2.61 and 2.2.8); - Receptacles, small, containing gases which are very toxic (LC50 lower than 200 ppm) or pyrophoric according to packing instruction P200 in 4.1.4.1. - 146 - Copyright © United Nations, 2010. All rights reserved 2.2.2.3 List of collective entries Compressed gases Classification UN code No. 1956 1A 3156 1O 1964 1F 1954 1955 1T 1953 1 TF 3304 1 TC 3303 1 TO 3305 1 TFC 3306 1 TOC Liquefied gases Classification code 2A UN No. 1058 1078 2O 1968 3163 3157 2F 1010 1060 Name of the substance or article COMPRESSED GAS, N.O.S. COMPRESSED GAS, OXIDIZING, N.O.S. HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. COMPRESSED GAS, FLAMMABLE, N.O.S. COMPRESSED GAS, TOXIC, N.O.S. COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. Name of the substance or article LIQUEFIED GASES, non-flammable, charged with nitrogen, carbon dioxide or air REFRIGERANT GAS, N.O.S. such as mixtures of gases, indicated by the letter R..., which as: Mixture F1, have a vapour pressure at 70 °C not exceeding 1.3 MPa (13 bar) and a density at 50 °C not lower than that of dichlorofluoromethane (1.30 kg/l); Mixture F2, have a vapour pressure at 70 °C not exceeding 1.9 MPa (19 bar) and a density at 50 °C not lower than that of dichlorodifluoromethane (1.21 kg/l); Mixture F3, have a vapour pressure at 70 °C not exceeding 3 MPa (30 bar) and a density at 50 °C not lower than that of chlorodifluoromethane (1.09 kg/l). NOTE: Trichlorofluoromethane (Refrigerant R 11), 1,1,2-trichloro-1,2,2trifluoroethane (Refrigerant R 113), 1,1,1-trichloro-2,2,2-trifluoroethane (Refrigerant R 113a), 1-chloro-1,2,2-trifluoroethane (Refrigerant R 133) and 1-chloro-1,1,2trifluoroethane (Refrigerant R 133b) are not substances of Class 2. They may, however, enter into the composition of mixtures F1 to F3. INSECTICIDE GAS, N.O.S. LIQUEFIED GAS, N.O.S. LIQUEFIED GAS, OXIDIZING, N.O.S. BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED, having a vapour pressure at 70 °C not exceeding 1.1 MPa (11 bar) and a density at 50 °C not lower than 0.525 kg/l. NOTE: Butadienes, stabilized are also classified under UN No. 1010, see Table A of Chapter 3.2. METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED such as mixtures of methylacetylene and propadiene with hydrocarbons, which as: Mixture P1, contain not more than 63% methylacetylene and propadiene by volume and not more than 24% propane and propylene by volume, the percentage of C4- saturated hydrocarbons being not less than 14% by volume; and as Mixture P2, contain not more than 48% methylacetylene and propadiene by volume and not more than 50% propane and propylene by volume, the percentage of C4- saturated hydrocarbons being not less than 5% by volume, as well as mixtures of propadiene with 1 to 4% methylacetylene. - 147 - Copyright © United Nations, 2010. All rights reserved Liquefied gases (cont'd) Classification UN code No. 1965 2F (cont'd) 2T 2 TF 2 TC 2 TO 2 TFC 2 TOC 3354 3161 1967 3162 3355 3160 3308 3307 3309 3310 Name of the substance or article HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S such as mixtures, which as: Mixture A, have a vapour pressure at 70 °C not exceeding 1.1 MPa (11 bar) and a density at 50 °C not lower than 0.525 kg/l; Mixture A01, have a vapour pressure at 70 °C not exceeding 1.6 MPa (16 bar) and a relative density at 50 °C not lower than 0.516 kg/l; Mixture A02, have a vapour pressure at 70 °C not exceeding 1.6 MPa (16 bar) and a relative density at 50 °C not lower than 0.505 kg/l; Mixture A0, have a vapour pressure at 70 °C not exceeding 1.6 MPa (16 bar) and a density at 50 °C not lower than 0.495 kg/l; Mixture A1, have a vapour pressure at 70 °C not exceeding 2.1 MPa (21 bar) and a density at 50 °C not lower than 0.485 kg/l; Mixture B1 have a vapour pressure at 70 °C not exceeding 2.6 MPa (26 bar) and a relative density at 50 °C not lower than 0.474 kg/l; Mixture B2 have a vapour pressure at 70 °C not exceeding 2.6 MPa (26 bar) and a relative density at 50 °C not lower than 0.463 kg/l; Mixture B, have a vapour pressure at 70 °C not exceeding 2.6 MPa (26 bar) and a density at 50 °C not lower than 0.450 kg/l; Mixture C, have a vapour pressure at 70 °C not exceeding 3.1 MPa (31 bar) and a relative density at 50 °C not lower than 0.440 kg/l; NOTE 1: In the case of the foregoing mixtures, the use of the following names customary in the trade is permitted for describing these substances: for mixtures A, A01, A02 and A0: BUTANE; for mixture C: PROPANE. NOTE 2: UN No. 1075 PETROLEUM GASES, LIQUEFIED may be used as an alternative entry for UN No. 1965 HYDROCARBON GAS MIXTURE LIQUEFIED, N.O.S. for carriage prior to or following maritime or air carriage. INSECTICIDE GAS, FLAMMABLE, N.O.S. LIQUEFIED GAS, FLAMMABLE, N.O.S. INSECTICIDE GAS, TOXIC, N.O.S. LIQUEFIED GAS, TOXIC, N.O.S. INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S. LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. Refrigerated liquefied gases Name of the substance or article Classification UN code No. 3158 GAS, REFRIGERATED LIQUID, N.O.S. 3A 3311 GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S. 3O 3312 GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S. 3F Dissolved gases Classification code 4 UN No. Name of the substance or article Only substances listed in Table A of Chapter 3.2 are to be accepted for carriage. - 148 - Copyright © United Nations, 2010. All rights reserved Aerosols and receptacles, small, containing gas Name of the substance or article Classification UN code No. 1950 AEROSOLS 5 2037 RECEPTACLES, SMALL CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable Other articles containing gas under pressure Name of the substance or article Classification UN code No. 2857 REFRIGERATING MACHINES containing non-flammable, non-toxic gases or 6A ammonia solutions (UN 2672) 3164 ARTICLES, PRESSURIZED, PNEUMATIC (containing non-flammable gas) or 3164 ARTICLES, PRESSURIZED, HYDRAULIC (containing non-flammable gas) 3150 DEVICES, SMALL, HYDROCARBON GAS POWERED or 6F 3150 HYDROCARBON GAS REFILLS FOR SMALL DEVICES, with release device 3478 FUEL CELL CARTRIDGES, containing liquefied flammable gas or 3478 FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT, containing liquefied flammable gas or 3478 FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing liquefied flammable gas 3479 FUEL CELL CARTRIDGES, containing hydrogen in metal hydride or 3479 FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT, containing hydrogen in metal hydride or 3479 FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing hydrogen in metal hydride Gas samples Classification code 7F 7T 7 TF UN No. 3167 3169 3168 Name of the substance or article GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, N.O.S., not refrigerated liquid GAS SAMPLE, NON-PRESSURIZED, TOXIC, N.O.S., not refrigerated liquid GAS SAMPLE, NON-PRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not refrigerated liquid - 149 - Copyright © United Nations, 2010. All rights reserved 2.2.3 Class 3 Flammable liquids 2.2.3.1 Criteria 2.2.3.1.1 The heading of Class 3 covers substances and articles containing substances of this Class which: - are liquids according to subparagraph (a) of the definition for "liquid" in 1.2.1; - have at 50 °C a vapour pressure of not more than 300 kPa (3 bar) and are not completely gaseous at 20 °C and at standard pressure of 101.3 kPa; and - have a flash-point of not more than 60 °C (see 2.3.3.1 for the relevant test). The heading of Class 3 also covers liquid substances and molten solid substances with a flash-point of more than 60°C and which are carried or handed over for carriage whilst heated at temperatures equal to or higher than their flash-point. These substances are assigned to UN No. 3256. The heading of Class 3 also covers liquid desensitized explosives. Liquid desensitized explosives are explosive substances which are dissolved or suspended in water or other liquid substances, to form an homogeneous liquid mixture to suppress their explosive properties. Such entries in Table A of Chapter 3.2 are UN Nos. 1204, 2059, 3064, 3343, 3357 and 3379. NOTE 1: Substances having a flash-point above 35 °C, non-toxic and non-corrosive, which do not sustain combustion according to the criteria of sub-section 32.2.5 of Part III of the Manual of Tests and Criteria, are not substances of Class 3; if, however, these substances are handed over for carriage and carried whilst heated at temperatures equal to or higher than their flash-point, they are substances of Class 3. NOTE 2: By derogation from paragraph 2.2.3.1.1 above, diesel fuel, gasoil, heating oil (light) having a flash-point above 60 °C and not more than 100 °C shall be deemed substances of Class 3, UN No. 1202. NOTE 3: Liquids which are highly toxic on inhalation, having a flash-point below 23 °C and toxic substances, having a flash-point of 23 °C or above are substances of Class 6.1 (see 2.2.61.1). NOTE 4: Flammable liquid substances and preparations used as pesticides, which are highly toxic, toxic or slightly toxic and have a flash-point of 23 °C or above are substances of Class 6.1 (see 2.2.61.1). 2.2.3.1.2 The substances and articles of Class 3 are subdivided as follows: F Flammable liquids, without subsidiary risk: F1 F2 FT Flammable liquids having a flash-point of or below 60 °C; Flammable liquids having a flash-point above 60 °C which are carried or handed over for carriage at or above their flash-point (elevated temperature substances); Flammable liquids, toxic: FT1 Flammable liquids, toxic; FT2 Pesticides; - 150 - Copyright © United Nations, 2010. All rights reserved FC Flammable liquids, corrosive; FTC Flammable liquids, toxic, corrosive; D 2.2.3.1.3 Liquid desensitized explosives. Substances and articles classified in Class 3 are listed in Table A of Chapter 3.2. Substances not mentioned by name in Table A of Chapter 3.2 shall be assigned to the relevant entry of 2.2.3.3 and the relevant packing group in accordance with the provisions of this section. Flammable liquids shall be assigned to one of the following packing groups according to the degree of danger they present for carriage: Packing group Flash point (closed cup) -- ≤ 35°C < 23°C > 35°C ≥ 23°C ≤ 60°C > 35°C I II a III a a Initial boiling point See also 2.2.3.1.4. For a liquid with (a) subsidiary risk(s), the packing group determined in accordance with the table above and the packing group based on the severity of the subsidiary risk(s) shall be considered; the classification and packing group shall then be determined in accordance with the table of precedence of hazards in 2.1.3.10. 2.2.3.1.4 Liquid or viscous mixtures and preparations, including those containing no more than 20% nitrocellulose with a nitrogen content not exceeding 12.6% (by dry mass), shall be assigned to packing group III only if the following requirements are met: (a) the height of the separated layer of solvent is less than 3% of the total height of the sample in the solvent-separation test (see Manual of Tests and Criteria, Part III, sub-section 32.5.1); and (b) the viscosity 2 and flash-point are in accordance with the following table: Kinematic viscosity (extrapolated) ν (at nearzero shear rate) mm2/s at 23 °C Flow time t in accordance with ISO 2431:1993 in s Jet diameter in mm Flash-point in °C 20 < ν ≤ 80 20 < t ≤ 60 4 above 17 80 < ν ≤ 135 60 < t ≤ 100 4 above 10 135 < ν ≤ 220 20 < t ≤ 32 6 above 5 220 < ν ≤ 300 32 < t ≤ 44 6 above -1 300 < ν ≤ 700 44 < t ≤ 100 6 above -5 700 < ν 100 < t 6 -5 and below Viscosity determination: Where the substance concerned is non-Newtonian, or where a flow cup method of viscosity determination is otherwise unsuitable, a variable shear-rate viscometer shall be used to determine the dynamic viscosity coefficient of the substance, at 23 °C, at a number of shear rates. The values obtained are plotted against shear rate and then extrapolated to zero shear rate. The dynamic viscosity thus obtained, divided by the density, gives the apparent kinematic viscosity at near-zero shear rate. 2 - 151 - Copyright © United Nations, 2010. All rights reserved NOTE: Mixtures containing more than 20% but not more than 55% nitrocellulose with a nitrogen content not exceeding 12.6% by dry mass are substances assigned to UN No. 2059. Mixtures having a flash-point below 23 °C and containing: - more than 55% nitrocellulose, whatever their nitrogen content; or - not more than 55% nitrocellulose with a nitrogen content above 12.6% by dry mass, are substances of Class 1 (UN Nos. 0340 or 0342) or of Class 4.1 (UN Nos. 2555, 2556 or 2557). 2.2.3.1.5 2.2.3.1.6 Non-toxic, non-corrosive and non-environmentally hazardous solutions and homogeneous mixtures having a flash-point of 23 °C or above (viscous substances, such as paints or varnishes, excluding substances containing more than 20% nitrocellulose) packed in receptacles of less than 450 litres capacity, are not subject to ADR if, in the solvent-separation test (see Manual of Tests and Criteria, Part III, sub-section 32.5.1), the height of the separated layer of solvent is less than 3% of the total height, and if the substances at 23 °C have, in the flow cup conforming to ISO 2431:1993 having a jet 6 mm in diameter, a flow time of: (a) not less than 60 seconds; or (b) not less than 40 seconds and contain not more than 60% of substances of Class 3. If substances of Class 3, as a result of admixtures, come into categories of risk different from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes) see also 2.1.3. 2.2.3.1.7 On the basis of the test procedures in accordance with 2.3.3.1 and 2.3.4, and the criteria set out in 2.2.3.1.1, it may also be determined whether the nature of a solution or a mixture mentioned by name or containing a substance mentioned by name is such that the solution or mixture is not subject to the provisions for this Class (see also 2.1.3). 2.2.3.2 Substances not accepted for carriage 2.2.3.2.1 Substances of Class 3 which are liable to form peroxides easily (as happens with ethers or with certain heterocyclic oxygenated substances) shall not be accepted for carriage if their peroxide content, calculated as hydrogen peroxide (H2O2), exceeds 0.3%. The peroxide content shall be determined as indicated in 2.3.3.3. 2.2.3.2.2 The chemically unstable substances of Class 3 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end, it shall be ensured in particular that receptacles and tanks do not contain any substance liable to promote these reactions. 2.2.3.2.3 Liquid desensitized explosives other than those listed in Table A of Chapter 3.2 shall not be accepted for carriage as substances of Class 3. - 152 - Copyright © United Nations, 2010. All rights reserved 2.2.3.3 List of collective entries Flammable liquids F1 Without subsidiary risk F 1133 ADHESIVES containing flammable liquid 1136 COAL TAR DISTILLATES, FLAMMABLE 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle undercoating, drum or barrel lining) 1169 EXTRACTS, AROMATIC, LIQUID 1197 EXTRACTS, FLAVOURING, LIQUID 1210 PRINTING INK, flammable or 1210 PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or 1263 PAINT RELATED MATERIAL (including paint thinning or reducing compound) 1266 PERFUMERY PRODUCTS with flammable solvents 1293 TINCTURES, MEDICINAL 1306 WOOD PRESERVATIVES, LIQUID 1866 RESIN SOLUTION, flammable 1999 TARS, LIQUID, including road oils, and cutback bitumens 3065 ALCOHOLIC BEVERAGES 3269 POLYESTER RESIN KITS 1224 KETONES, LIQUID, N.O.S. 1268 PETROLEUM DISTILLATES, N.O.S. or 1268 PETROLEUM PRODUCTS, N.O.S. 1987 ALCOHOLS, N.O.S. 1989 ALDEHYDES, N.O.S. 2319 TERPENE HYDROCARBONS, N.O.S. 3271 ETHERS, N.O.S. 3272 ESTERS, N.O.S. 3295 HYDROCARBONS, LIQUID, N.O.S. 3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or 3336 MERCAPTANS MIXTURE, LIQUID, FLAMMABLE, N.O.S. 1993 FLAMMABLE LIQUID, N.O.S. F2 3256 ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S., with flash-point above 60 °C, elevated at or above its flash-point temperature (cont'd on next page) - 153 - Copyright © United Nations, 2010. All rights reserved 2.2.3.3 List of collective entries (cont'd) FT1 Toxic FT FT2 pesticide (f.p<23 °C) Liquid desensitised explosive 2758 CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2760 ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2762 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2764 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2772 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2776 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2778 MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2780 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2782 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2784 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2787 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3024 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3346 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3350 PYRETHROID PESTICIDE, LIQUID, FLAMMABLE TOXIC 3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S. NOTE: The classification of a pesticide under an entry shall be effected on the basis of the active ingredient, of the physical state of the pesticide and any subsidiary risks it may exhibit. FC 3469 PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or 3469 PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound) 2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or 2733 POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 2985 CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S. 3274 ALCOHOLATES SOLUTION, N.O.S., in alcohol 2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. FTC 3286 FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. Corrosive Toxic, corrosive 1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or 1228 MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 2478 ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or 2478 ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. 3248 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3273 NITRILES, FLAMMABLE, TOXIC, N.O.S. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. D 3343 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin by mass 3357 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, N.O.S. with not more than 30% nitroglycerin by mass 3379 DESENSITIZED EXPLOSIVE, LIQUID, N.O.S. - 154 - Copyright © United Nations, 2010. All rights reserved 2.2.41 Class 4.1 Flammable solids, self-reactive substances and solid desensitized explosives 2.2.41.1 Criteria 2.2.41.1.1 The heading of Class 4.1 covers flammable substances and articles, desensitized explosives which are solids according to subparagraph (a) of the definition "solid" in 1.2.1 and self-reactive liquids or solids. The following are assigned to Class 4.1: 2.2.41.1.2 - readily flammable solid substances and articles (see paragraphs 2.2.41.1.3 to 2.2.41.1.8); - self-reactive solids or liquids (see paragraphs 2.2.41.1.9 to 2.2.41.1.17); - solid desensitized explosives (see 2.2.41.1.18); - substances related to self-reactive substances (see 2.2.41.1.19). The substances and articles of Class 4.1 are subdivided as follows: F Flammable solids, without subsidiary risk: F1 F2 F3 Organic; Organic, molten; Inorganic; FO Flammable solids, oxidizing; FT Flammable solids, toxic: FT1 Organic, toxic; FT2 Inorganic, toxic; FC Flammable solids, corrosive: FC1 Organic, corrosive; FC2 Inorganic, corrosive; D Solid desensitized explosives without subsidiary risk; DT Solid desensitized explosives, toxic; SR Self-reactive substances: SR1 Not requiring temperature control; SR2 Requiring temperature control. - 155 - Copyright © United Nations, 2010. All rights reserved Flammable solids Definition and properties 2.2.41.1.3 Flammable solids are readily combustible solids and solids which may cause fire through friction. Readily combustible solids are powdered, granular, or pasty substances which are dangerous if they can be easily ignited by brief contact with an ignition source, such as a burning match, and if the flame spreads rapidly. The danger may come not only from the fire but also from toxic combustion products. Metal powders are especially dangerous because of the difficulty of extinguishing a fire since normal extinguishing agents such as carbon dioxide or water can increase the hazard. Classification 2.2.41.1.4 Substances and articles classified as flammable solids of Class 4.1 are listed in Table A of Chapter 3.2. The assignment of organic substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant entry of sub-section 2.2.41.3 in accordance with the provisions of Chapter 2.1 can be based on experience or on the results of the test procedures in accordance with Part III, sub-section 33.2.1 of the Manual of Tests and Criteria. The assignment of inorganic substances not mentioned by name shall be based on the results of the test procedures in accordance with Part III, sub-section 33.2.1 of the Manual of Tests and Criteria; experience shall also be taken into account when it leads to a more stringent assignment. 2.2.41.1.5 When substances not mentioned by name are assigned to one of the entries listed in 2.2.41.3 on the basis of the test procedures in accordance with the Manual of Tests and Criteria, Part III, sub-section 33.2.1, the following criteria apply: (a) With the exception of metal powders or powders of metal alloys, powdery, granular or pasty substances shall be classified as readily flammable substances of Class 4.1 if they can be easily ignited by brief contact with an ignition source (e.g. a burning match), or if, in the event of ignition, the flame spreads rapidly, the burning time is less than 45 seconds for a measured distance of 100 mm or the rate of burning is greater than 2.2 mm/s; (b) Metal powders or powders of metal alloys shall be assigned to Class 4.1 if they can be ignited by a flame and the reaction spreads over the whole length of the sample in 10 minutes or less. Solids which may cause fire through friction shall be classified in Class 4.1 by analogy with existing entries (e.g. matches) or in accordance with any appropriate special provision. 2.2.41.1.6 On the basis of the test procedure in accordance with the Manual of Tests and Criteria, Part III, Section 33.2.1 and the criteria set out in 2.2.41.1.4 and 2.2.41.1.5, it may also be determined whether the nature of a substance mentioned by name is such that the substance is not subject to the provisions for this Class. 2.2.41.1.7 If substances of Class 4.1, as a result of admixtures, come into different categories of risk from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also 2.1.3. - 156 - Copyright © United Nations, 2010. All rights reserved Assignment of packing groups 2.2.41.1.8 Flammable solids classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups II or III on the basis of test procedures of the Manual of Tests and Criteria, Part III, sub-section 33.2.1, in accordance with the following criteria: (a) Readily flammable solids which, when tested, have a burning time of less than 45 seconds over a measured distance of 100 mm shall be assigned to: Packing group II: if the flame passes the wetted zone; Packing group III: if the wetted zone stops the flame for at least four minutes; (b) Metal powders or powders of metal alloys shall be assigned to: Packing group II: if, when tested, the reaction spreads over the whole length of the sample in five minutes or less; Packing group III: if, when tested, the reaction spreads over the whole length of the sample in more than five minutes. For solids which may cause fire through friction, the packing group shall be assigned by analogy with existing entries or in accordance with any special provision. Self-reactive substances Definitions 2.2.41.1.9 For the purposes of ADR, self-reactive substances are thermally unstable substances liable to undergo a strongly exothermic decomposition even without participation of oxygen (air). Substances are not considered to be self-reactive substances of Class 4.1, if: (a) they are explosives according to the criteria of Class 1; (b) they are oxidizing substances according to the classification procedure for Class 5.1 (see 2.2.51.1) except that mixtures of oxidizing substances which contain 5% or more of combustible organic substances shall be subjected to the classification procedure defined in Note 2; (c) they are organic peroxides according to the criteria of Class 5.2 (see 2.2.52.1); (d) their heat of decomposition is less than 300 J/g; or (e) their self-accelerating decomposition temperature (SADT) (see Note 3 below) is greater than 75 °C for a 50 kg package. NOTE 1: The heat of decomposition can be determined using any internationally recognised method e.g. differential scanning calorimetry and adiabatic calorimetry. NOTE 2: Mixtures of oxidizing substances meeting the criteria of Class 5.1 which contain 5% or more of combustible organic substances, which do not meet the criteria mentioned in (a), (c), (d) or (e) above, shall be subjected to the self-reactive substance classification procedure. A mixture showing the properties of a self-reactive substance, type B to F, shall be classified as a self-reactive substance of Class 4.1. - 157 - Copyright © United Nations, 2010. All rights reserved A mixture showing the properties of a self-reactive substance, type G, according to the principle given in sub-section 20.4.3 (g) of Part II of the Manual of Tests and Criteria shall be considered for classification as a substance of Class 5.1 (see 2.2.51.1). NOTE 3: The self-accelerating decomposition temperature (SADT) is the lowest temperature at which self-accelerating decomposition may occur with a substance in the packaging as used during carriage. Requirements for the determination of the SADT are given in the Manual of Tests and Criteria, Part II, Chapter 20 and section 28.4. NOTE 4: Any substance which shows the properties of a self-reactive substance shall be classified as such, even if this substance gives a positive test result according to 2.2.42.1.5 for inclusion in Class 4.2. Properties 2.2.41.1.10 The decomposition of self-reactive substances can be initiated by heat, contact with catalytic impurities (e.g. acids, heavy-metal compounds, bases), friction or impact. The rate of decomposition increases with temperature and varies with the substance. Decomposition, particularly if no ignition occurs, may result in the evolution of toxic gases or vapours. For certain self-reactive substances, the temperature shall be controlled. Some self-reactive substances may decompose explosively, particularly if confined. This characteristic may be modified by the addition of diluents or by the use of appropriate packagings. Certain selfreactive substances burn vigorously. Self-reactive substances are, for example, some compounds of the types listed below: aliphatic azo compounds (-C-N=N-C-); organic azides (-C-N3); diazonium salts (-CN2+ Z-); N-nitroso compounds (-N-N=O); and aromatic sulphohydrazides (-SO2-NH-NH2). This list is not exhaustive and substances with other reactive groups and some mixtures of substances may have similar properties. Classification 2.2.41.1.11 Self-reactive substances are classified into seven types according to the degree of danger they present. The types of self-reactive substances range from type A, which is not accepted for carriage in the packaging in which it is tested, to type G, which is not subject to the provisions for self-reactive substances of Class 4.1. The classification of types B to F is directly related to the maximum quantity allowed in one packaging. The principles to be applied for classification as well as the applicable classification procedures, test methods and criteria and an example of a suitable test report are given in Part II of the Manual of Tests and Criteria. 2.2.41.1.12 Self-reactive substances which have already been classified and are already permitted for carriage in packagings are listed in 2.2.41.4, those already permitted for carriage in IBCs are listed in 4.1.4.2, packing instruction IBC520 and those already permitted for carriage in tanks according to Chapter 4.2 are listed in 4.2.5.2, portable tank instruction T23. Each permitted substance listed is assigned to a generic entry of Table A of Chapter 3.2 (UN Nos. 3221 to 3240), and appropriate subsidiary risks and remarks providing relevant transport information are given. The collective entries specify: - self-reactive substances types B to F, see 2.2.41.1.11 above; - 158 - Copyright © United Nations, 2010. All rights reserved - physical state (liquid/solid); and - temperature control (when required), see 2.2.41.1.17 below. The classification of the self-reactive substances listed in 2.2.41.4 is based on the technically pure substance (except where a concentration of less than 100% is specified). 2.2.41.1.13 Classification of self-reactive substances not listed in 2.2.41.4, 4.1.4.2, packing instruction IBC520 or 4.2.5.2, portable tank instruction T23 and assignment to a collective entry shall be made by the competent authority of the country of origin on the basis of a test report. The statement of approval shall contain the classification and the relevant conditions of carriage. If the country of origin is not a Contracting Party to ADR, the classification and the conditions of carriage shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. 2.2.41.1.14 Activators, such as zinc compounds, may be added to some self-reactive substances to change their reactivity. Depending on both the type and the concentration of the activator, this may result in a decrease in thermal stability and a change in explosive properties. If either of these properties is altered, the new formulation shall be assessed in accordance with the classification procedure. 2.2.41.1.15 Samples of self-reactive substances or formulations of self-reactive substances not listed in 2.2.41.4, for which a complete set of test results is not available and which are to be carried for further testing or evaluation, shall be assigned to one of the appropriate entries for selfreactive substances type C provided the following conditions are met: - the available data indicate that the sample would be no more dangerous than selfreactive substances type B; - the sample is packaged in accordance with packing method OP2 and the quantity per transport unit is limited to 10 kg; - the available data indicate that the control temperature, if any, is sufficiently low to prevent any dangerous decomposition and sufficiently high to prevent any dangerous phase separation. Desensitization 2.2.41.1.16 In order to ensure safety during carriage, self-reactive substances are in many cases desensitized by use of a diluent. Where a percentage of a substance is stipulated, this refers to the percentage by mass, rounded to the nearest whole number. If a diluent is used, the selfreactive substance shall be tested with the diluent present in the concentration and form used in carriage. Diluents which may allow a self-reactive substance to concentrate to a dangerous extent in the event of leakage from a packaging shall not be used. Any diluent shall be compatible with the self-reactive substance. In this regard, compatible diluents are those solids or liquids which have no detrimental influence on the thermal stability and hazard type of the self-reactive substance. Liquid diluents in formulations requiring temperature control (see 2.2.41.1.14) shall have a boiling point of at least 60 °C and a flash-point not less than 5 °C. The boiling point of the liquid shall be at least 50 °C higher than the control temperature of the self-reactive substance. Temperature control requirements 2.2.41.1.17 Certain self-reactive substances may only be carried under temperature controlled conditions. The control temperature is the maximum temperature at which the self-reactive substance can be safely carried. It is assumed that the temperature of the immediate - 159 - Copyright © United Nations, 2010. All rights reserved surroundings of a package only exceeds 55 °C during carriage for a relatively short time in a 24 hour period. In the event of loss of temperature control, it may be necessary to implement emergency procedures. The emergency temperature is the temperature at which such procedures shall be implemented. The control and emergency temperatures are derived from the SADT (see table 1). The SADT shall be determined in order to decide whether a substance shall be subjected to temperature control during carriage. Provisions for the determination of the SADT are given in the Manual of Tests and Criteria, Part II, Chapter 20 and Section 28.4. Table 1: Derivation of control and emergency temperatures SADT a Type of receptacle Single packagings and IBCs Tanks a 20 °C or less Control temperature 20 °C below SADT Emergency temperature 10 °C below SADT over 20 °C to 35 °C over 35 °C not greater than 50 °C 15 °C below SADT 10 °C below SADT 10 °C below SADT 10 °C below SADT 5 °C below SADT 5 °C below SADT SADT of the substance as packaged for carriage. Self-reactive substances with an SADT not greater than 55 °C shall be subject to temperature control during carriage. Where applicable, control and emergency temperatures are listed in 2.2.41.4. The actual temperature during carriage may be lower than the control temperature but shall be selected so as to avoid dangerous separation of phases. Solid desensitized explosives 2.2.41.1.18 Solid desensitized explosives are substances which are wetted with water or alcohols or are diluted with other substances to suppress their explosive properties. Such entries in Table A of Chapter 3.2 are: UN Nos. 1310, 1320, 1321, 1322, 1336, 1337, 1344, 1347, 1348, 1349, 1354, 1355, 1356, 1357, 1517, 1571, 2555, 2556, 2557, 2852, 2907, 3317, 3319, 3344, 3364, 3365, 3366, 3367, 3368, 3369, 3370, 3376, 3380 and 3474. Substances related to self-reactive substances 2.2.41.1.19 Substances that: (a) have been provisionally accepted into Class 1 according to Test Series 1 and 2 but exempted from Class 1 by Test Series 6; (b) are not self-reactive substances of Class 4.1; and (c) are not substances of Classes 5.1 or 5.2; are also assigned to Class 4.1. UN Nos. 2956, 3241, 3242 and 3251 are such entries. 2.2.41.2 Substances not accepted for carriage 2.2.41.2.1 The chemically unstable substances of Class 4.1 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end, it shall in particular be ensured that receptacles and tanks do not contain any substance liable to promote these reactions. - 160 - Copyright © United Nations, 2010. All rights reserved 2.2.41.2.2 Flammable solids, oxidizing, assigned to UN No. 3097 shall not be accepted for carriage unless they meet the requirements for Class 1 (see also 2.1.3.7). 2.2.41.2.3 The following substances shall not be accepted for carriage: - Self-reactive substances of type A (see Manual of Tests and Criteria, Part II, paragraph 20.4.2 (a)); - Phosphorus sulphides which are not free from yellow and white phosphorus; - Solid densitized explosives other than those listed in Table A of Chapter 3.2; - Inorganic flammable substances in the molten form other than UN No. 2448 SULPHUR, MOLTEN. - 161 - Copyright © United Nations, 2010. All rights reserved 2.2.41.3 List of collective entries without subsidiary risk 3175 SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. 1353 FIBRES IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. or 1353 FABRICS IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. 1325 FLAMMABLE SOLID, ORGANIC, N.O.S. organic F1 organic molten F2 3176 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. F3 3089 METAL POWDER, FLAMMABLE, N.O.S. 3181 METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. a b inorganic c 3182 METAL HYDRIDES, FLAMMABLE,N.O.S. 3178 FLAMMABLE SOLID, INORGANIC, N.O.S. Flammable solids FO 3097 FLAMMABLE SOLID, OXIDIZING, N.O.S. (not allowed, see para. 2.2.41.2.2) organic FT1 2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. inorganic FT2 3179 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. organic FC1 2925 FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. inorganic FC2 3180 FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. D 3319 NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin by mass 3344 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE, PETN) MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 10% but not more than 20% PETN by mass 3380 DESENSITIZED EXPLOSIVE, SOLID, N.O.S. oxidizing toxic FT corrosive FC without subsidiary risk Solid desensitized explosives toxic not requiring temperature control DT SR1 Self-reactive substances SR requiring temperature control SR2 Only substances listed in Table A of Chapter 3.2 are to be accepted for carriage as substances of Class 4.1 3221 3222 3223 3224 3225 3226 3227 3228 3229 3230 3231 3232 3233 3234 3235 3236 3237 3238 3239 3240 SELF-REACTIVE LIQUID TYPE A SELF-REACTIVE SOLID TYPE A SELF-REACTIVE LIQUID TYPE B SELF-REACTIVE SOLID TYPE B SELF-REACTIVE LIQUID TYPE C SELF-REACTIVE SOLID TYPE C SELF-REACTIVE LIQUID TYPE D SELF-REACTIVE SOLID TYPE D SELF-REACTIVE LIQUID TYPE E SELF-REACTIVE SOLID TYPE E SELF-REACTIVE LIQUID TYPE F SELF-REACTIVE SOLID TYPE F SELF-REACTIVE LIQUID TYPE G SELF-REACTIVE SOLID TYPE G } Not accepted for carriage, see 2.2.41.2.3 } Not subject to the provisions applicable to Class 4.1, see 2.2.41.1.11 SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE B, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE C, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE E, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE F, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED Metals and metal alloys in powdered or other flammable form, liable to spontaneous combustion, are substances of Class 4.2. b Metals and metal alloys in powdered or other flammable form, which in contact with water, emit flammable gases, are substances of Class 4.3. c Metals hydrides which, in contact with water, emit flammable gases, are substances of Class 4.3. Aluminium borohydride or aluminium borohydride in devices are substances of Class 4.2, UN No. 2870. a - 162 - Copyright © United Nations, 2010. All rights reserved 2.2.41.4 List of currently assigned self-reactive substances in packagings In the column "Packing Method" codes "OP1" to "OP8" refer to packing methods in 4.1.4.1, packing instruction P520 (see also 4.1.7.1). Self-reactive substances to be carried shall fulfil the classification and the control and emergency temperatures (derived from the SADT) as listed. For substances permitted in IBCs, see 4.1.4.2, packing instruction IBC520 and, for those permitted in tanks according to Chapter 4.2, see 4.2.5.2, portable tank instruction T23. NOTE: The classification given in this table is based on the technically pure substance (except where a concentration of less than 100% is specified). For other concentrations, the substance may be classified differently following the procedures given in Part II of the Manual of Tests and Criteria and in 2.2.41.1.17. SELF-REACTIVE SUBSTANCE Concentration (%) Packing method ACETONE-PYROGALLOL COPOLYMER 2-DIAZO-1-NAPHTHOL-5-SULPHONATE AZODICARBONAMIDE FORMULATION TYPE B, TEMPERATURE CONTROLLED AZODICARBONAMIDE FORMULATION TYPE C AZODICARBONAMIDE FORMULATION TYPE C, TEMPERATURE CONTROLLED AZODICARBONAMIDE FORMULATION TYPE D AZODICARBONAMIDE FORMULATION TYPE D, TEMPERATURE CONTROLLED 2,2' -AZODI(2,4-DIMETHYL- 4-METHOXYVALERONITRILE) 2,2' -AZODI(2,4-DIMETHYL- VALERONITRILE) 2,2' -AZODI(ETHYL- 2-METHYL-PROPIONATE) 1,1-AZODI(HEXAHYDROBENZONITRILE) 2,2' -AZODI(ISOBUTYRONITRILE 2,2' -AZODI(ISOBUTYRONITRILE) as a water based paste 2,2' -AZODI(2-METHYLBUTYRONITRILE) BENZENE-1,3-DISULPHONYL HYDRAZIDE, as a paste BENZENE SULPHONYL HYDRAZIDE 4-(BENZYL(ETHYL)AMINO)-3-ETHOXYBENZENEDIAZONIUM ZINC CHLORIDE 4-(BENZYL(METHYL)AMINO)-3-ETHOXYBENZENEDIAZONIUM ZINC CHLORIDE 3-CHLORO-4-DIETHYLAMINOBENZENEDIAZONIUM ZINC CHLORIDE 2-DIAZO-1-NAPHTHOL-4-SULPHONYL CHLORIDE 2-DIAZO-1-NAPHTHOL-5-SULPHONYL CHLORIDE 2-DIAZO-1-NAPHTHOL SULPHONIC ACID ESTER MIXTURE, TYPE D 2,5-DIBUTOXY-4-(4-MORPHOLINYL)BENZENEDIAZONIUM, TETRACHLOROZINCATE (2:1) 2,5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM ZINC CHLORIDE 2,5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM ZINC CHLORIDE 2,5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM TETRAFLUOROBORATE 100 OP8 < 100 OP5 3232 (1) (2) < 100 < 100 OP6 OP6 3224 3234 (3) (4) < 100 < 100 OP7 OP7 3226 3236 (5) (6) 100 OP7 -5 +5 3236 100 100 100 100 +10 +20 +15 +25 +40 +45 ≤ 50% OP7 OP7 OP7 OP6 OP6 3236 3235 3226 3234 3224 100 52 OP7 OP7 +35 +40 100 100 OP7 OP7 100 OP7 100 OP7 3226 100 100 < 100 OP5 OP5 OP7 3222 3222 3226 100 OP8 3228 67-100 OP7 +35 +40 3236 66 OP7 +40 +45 3236 100 OP7 +30 +35 3236 - 163 - Control Emergency UN Remarks tempera- tempera- generic ture ture entry (°C) (°C) 3228 3236 3226 3226 3226 +40 +45 3236 (2) (2) (9) Copyright © United Nations, 2010. All rights reserved SELF-REACTIVE SUBSTANCE Concentration (%) Packing method 2,5-DIETHOXY-4-(4-MORPHOLINYL)BENZENEDIAZONIUM SULPHATE 2,5-DIETHOXY-4-(PHENYLSULPHONYL)BENZENEDIAZONIUM ZINC CHLORIDE DIETHYLENEGLYCOL BIS (ALLYL CARBONATE) + DI- ISOPROPYL-PEROXYDICARBONATE 2,5-DIMETHOXY-4-(4-METHYLPHENYLSULPHONYL)BENZENE- DIAZONIUM ZINC CHLORIDE 4-(DIMETHYLAMINO)-BENZENE-DIAZONIUM TRICHLOROZINCATE (-1) 4-DIMETHYLAMINO-6-(2-DIMETHYLAMINOETHOXY) TOLUENE- 2-DIAZONIUM ZINC CHLORIDE N,N'-DINITROSO-N,N'- DIMETHYL TEREPHTHALAMIDE, as a paste N,N'-DINITROSOPENTAMETHYLENETETRAMINE DIPHENYLOXIDE-4,4'-DISULPHONYL HYDRAZIDE 4-DIPROPYLAMINOBENZENE- DIAZONIUM ZINC CHLORIDE 2-(N,N-ETHOXYCARBONYLPHENYLAMINO)-3-METHOXY-4(N-METHYL-N-CYCLOHEXYLAMINO) BENZENEDIAZONIUM ZINC CHLORIDE 2-(N,N-ETHOXYCARBONYLPHENYLAMINO)-3-METHOXY-4(N-METHYL-N-CYCLOHEXYLAMINO) BENZENEDIAZONIUM ZINC CHLORIDE N-FORMYL-2-(NITROMETHYLENE) -1,3-PERHYDROTHIAZINE 2-(2-HYDROXYETHOXY)-1(PYRROLIDIN-1-YL)BENZENE-4- DIAZONIUM ZINC CHLORIDE 3-(2-HYDROXYETHOXY)-4- (PYRROLIDIN-1-YL) BENZENE DIAZONIUM ZINC CHLORIDE 2-(N,N-METHYLAMINOETHYLCARBONYL)4-(3,4-DIMETHYLPHENYLSULPHONYL) BENZENEDIAZONIUM HYDROGEN SULPHATE 4-METHYLBENZENESULPHONYLHYDRAZIDE 3-METHYL-4-(PYRROLIDIN-1-YL) BENZENEDIAZONIUM TETRAFLUOROBORATE 4-NITROSOPHENOL SELF-REACTIVE LIQUID, SAMPLE SELF-REACTIVE LIQUID, SAMPLE, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID, SAMPLE SELF-REACTIVE SOLID, SAMPLE, TEMPERATURE CONTROLLED SODIUM 2-DIAZO-1-NAPHTHOL- 4-SULPHONATE SODIUM 2-DIAZO-1-NAPHTHOL- 5-SULPHONATE TETRAMINE PALLADIUM (II) NITRATE 100 OP7 67 OP7 +40 +45 3236 ≥ 88+≤ 12 OP8 -10 0 3237 79 OP7 +40 +45 3236 100 OP8 100 OP7 72 OP6 3224 82 OP6 3224 100 OP7 3226 100 OP7 3226 63-92 OP7 + 40 + 45 3236 62 OP7 + 35 + 40 3236 100 OP7 +45 +50 3236 100 OP7 + 45 + 50 3236 100 OP7 +40 +45 3236 96 OP7 +45 +50 3236 100 95 OP7 OP6 +45 +50 3226 3234 100 OP7 OP2 OP2 +35 +40 100 100 100 - 164 - Control Emergency UN Remarks tempera- tempera- generic ture ture entry (°C) (°C) 3226 3228 +40 +45 3236 (7) 3236 3223 3233 (8) (8) OP2 OP2 3224 3234 (8) (8) OP7 OP7 OP6 3226 3226 3234 +30 +35 Copyright © United Nations, 2010. All rights reserved Remarks (1) Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (b) of the Manual of Tests and Criteria. The control and emergency temperatures shall be determined by the procedure given in 2.2.41.1.17. (2) "EXPLOSIVE" subsidiary risk label required (Model No. 1, see 5.2.2.2.2). (3) Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (c) of the Manual of Tests and Criteria. (4) Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (c) of the Manual of Tests and Criteria. The control and emergency temperatures shall be determined by the procedure given in 2.2.41.1.17. (5) Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (d) of the Manual of Tests and Criteria. (6) Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (d) of the Manual of Tests and Criteria. The control and emergency temperatures shall be determined by the procedure given in 2.2.41.1.17. (7) With a compatible diluent having a boiling point of not less than 150 °C. (8) See 2.2.41.1.15. (9) This entry applies to mixtures of esters of 2-diazo-1-naphthol-4-sulphonic acid and 2-diazo-1-naphthol-5-sulphonic acid which fulfil the criteria of paragraph 20.4.2 (d) of the Manual of Test and Criteria. - 165 - Copyright © United Nations, 2010. All rights reserved 2.2.42 Class 4.2 2.2.42.1 Criteria 2.2.42.1.1 The heading of Class 4.2 covers: 2.2.42.1.2 Substances liable to spontaneous combustion - Pyrophoric substances which are substances, including mixtures and solutions (liquid or solid), which even in small quantities ignite on contact with air within five minutes. These are the Class 4.2 substances the most liable to spontaneous combustion; and - Self-heating substances and articles which are substances and articles, including mixtures and solutions, which, on contact with air, without energy supply, are liable to self-heating. These substances will ignite only in large amounts (kilograms) and after long periods of time (hours or days). The substances and articles of Class 4.2 are subdivided as follows: S Substances liable to spontaneous combustion, without subsidiary risk: S1 S2 S3 S4 S5 Organic, liquid; Organic, solid; Inorganic, liquid; Inorganic, solid; Organometallic; SW Substances liable to spontaneous combustion, which, in contact with water, emit flammable gases; SO Substances liable to spontaneous combustion, oxidizing; ST Substances liable to spontaneous combustion, toxic: ST1 ST2 ST3 ST4 SC Organic, toxic, liquid; Organic, toxic, solid; Inorganic, toxic, liquid; Inorganic, toxic, solid; Substances liable to spontaneous combustion, corrosive: SC1 SC2 SC3 SC4 Organic, corrosive, liquid; Organic, corrosive, solid; Inorganic, corrosive, liquid; Inorganic, corrosive, solid. Properties 2.2.42.1.3 Self-heating of a substance is a process where the gradual reaction of that substance with oxygen (in air) generates heat. If the rate of heat production exceeds the rate of heat loss, then the temperature of the substance will rise which, after an induction time, may lead to self-ignition and combustion. - 166 - Copyright © United Nations, 2010. All rights reserved Classification 2.2.42.1.4 Substances and articles classified in Class 4.2 are listed in Table A of Chapter 3.2. The assignment of substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant specific N.O.S. entry of 2.2.42.3 in accordance with the provisions of Chapter 2.1 can be based on experience or the results of the test procedures in accordance with the Manual of Tests and Criteria, Part III, Section 33.3. Assignment to general N.O.S. entries of Class 4.2 shall be based on the results of the test procedures in accordance with the Manual of Tests and Criteria, Part III, section 33.3; experience shall also be taken into account when it leads to a more stringent assignment. 2.2.42.1.5 When substances or articles not mentioned by name are assigned to one of the entries listed in 2.2.42.3 on the basis of the test procedures in accordance with the Manual of Tests and Criteria, Part III, section 33.3, the following criteria shall apply: (a) Solids liable to spontaneous combustion (pyrophoric) shall be assigned to Class 4.2 when they ignite on falling from a height of 1 m or within five minutes; (b) Liquids liable to spontaneous combustion (pyrophoric) shall be assigned to Class 4.2 when: (c) (i) on being poured on an inert carrier, they ignite within five minutes, or (ii) in the event of a negative result of the test according to (i), when poured on a dry, indented filter paper (Whatman No. 3 filter), they ignite or carbonize it within five minutes; Substances in which, in a 10 cm sample cube, at 140 °C test temperature, spontaneous combustion or a rise in temperature to over 200 °C is observed within 24 hours shall be assigned to Class 4.2. This criterion is based on the temperature of the spontaneous combustion of charcoal, which is at 50 °C for a sample cube of 27 m3. Substances with a temperature of spontaneous combustion higher than 50 °C for a volume of 27 m3 are not to be assigned to Class 4.2. NOTE 1: Substances carried in packages with a volume of not more than 3 m3 are exempted from Class 4.2 if, tested with a 10 cm sample cube at 120 °C, no spontaneous combustion nor a rise in temperature to over 180 °C is observed within 24 hours. NOTE 2: Substances carried in packages with a volume of not more than 450 litres are exempted from Class 4.2 if, tested with a 10 cm sample cube at 100 °C, no spontaneous combustion nor a rise in temperature to over 160 °C is observed within 24 hours. NOTE 3: Since organometallic substances can be classified in Class 4.2 or 4.3 with additional subsidiary risks, depending on their properties, a specific classification flow chart for these substances is given in 2.3.5. 2.2.42.1.6 If substances of Class 4.2, as a result of admixtures, come into different categories of risk from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also 2.1.3. - 167 - Copyright © United Nations, 2010. All rights reserved 2.2.42.1.7 On the basis of the test procedure in the Manual of Tests and Criteria, Part III, section 33.3 and the criteria set out in 2.2.42.1.5, it may also be determined whether the nature of a substance mentioned by name is such that the substance is not subject to the provisions for this Class. Assignment of packing groups 2.2.42.1.8 Substances and articles classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups I, II or III on the basis of test procedures of the Manual of Tests and Criteria, Part III, section 33.3, in accordance with the following criteria: (a) Substances liable to spontaneous combustion (pyrophoric) shall be assigned to packing group I; (b) Self-heating substances and articles in which, in a 2.5 cm sample cube, at 140 °C test temperature, spontaneous combustion or a rise in temperature to over 200 °C is observed within 24 hours, shall be assigned to packing group II; Substances with a temperature of spontaneous combustion higher than 50 °C for a volume of 450 litres are not to be assigned to packing group II; (c) 2.2.42.2 Slightly self-heating substances in which, in a 2.5 cm sample cube, the phenomena referred to under (b) are not observed, in the given conditions, but in which in a 10 cm sample cube at 140 °C test temperature spontaneous combustion or a rise in temperature to over 200 °C is observed within 24 hours, shall be assigned to packing group III. Substances not accepted for carriage The following substances shall not be accepted for carriage: - UN No. 3255 tert-BUTYL HYPOCHLORITE; and - Self-heating solids, oxidizing, assigned to UN No. 3127 unless they meet the requirements for Class 1 (see 2.1.3.7). - 168 - Copyright © United Nations, 2010. All rights reserved 2.2.42.3 List of collective entries Substances liable to spontaneous combustion liquid S1 2845 3183 PYROPHORIC LIQUID, ORGANIC, N.O.S. SELF-HEATING LIQUID, ORGANIC, N.O.S. 1373 organic solid S2 2006 3313 2846 3088 FIBRES or FABRICS, ANIMAL or VEGETABLE or SYNTHETIC, N.O.S. with oil PLASTICS, NITROCELLULOSE-BASED, SELF-HEATING, N.O.S. ORGANIC PIGMENTS, SELF HEATING PYROPHORIC SOLID, ORGANIC, N.O.S. SELF-HEATING SOLID, ORGANIC, N.O.S. liquid S3 3194 3186 PYROPHORIC LIQUID, INORGANIC, N.O.S. SELF-HEATING LIQUID, INORGANIC, N.O.S. 1383 1383 1378 2881 3189a 3205 3200 3190 PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. METAL CATALYST, WETTED with a visible excess of liquid METAL CATALYST, DRY METAL POWDER, SELF-HEATING, N.O.S. ALKALINE EARTH METAL ALCOHOLATES, N.O.S. PYROPHORIC SOLID, INORGANIC, N.O.S. SELF-HEATING SOLID, INORGANIC, N.O.S. 3392 3391 3400 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC ORGANOMETALLIC SUBSTANCE, SOLID, SELF-HEATING Without subsidiary risk S inorganic solid organometallic Water-reactive S4 S5 SW 3394 3393 Oxidizing SO ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC, WATER-REACTIVE 3127 SELF-HEATING SOLID, OXIDIZING, N.O.S. (not allowed, see 2.2.42.2) liquid ST1 3184 SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. solid ST2 3128 SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. liquid ST3 3187 SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. solid ST4 3191 SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. liquid SC1 3185 SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. solid SC2 3126 SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. liquid SC3 3188 SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. 3206 solid SC4 ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S. SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S. organic Toxic ST inorganic organic Corrosive SC inorganic 3192 Dust and powder of metals, non toxic in a non-spontaneous combustible form which nevertheless, in contact with water, emit flammable gases, are substances of Class 4.3. a - 169 - Copyright © United Nations, 2010. All rights reserved 2.2.43 Class 4.3 2.2.43.1 Criteria 2.2.43.1.1 The heading of Class 4.3 covers substances which react with water to emit flammable gases liable to form explosive mixtures with air, and articles containing such substances. 2.2.43.1.2 Substances and articles of Class 4.3 are subdivided as follows: W Substances which, in contact with water, emit flammable gases Substances which, in contact with water, emit flammable gases, without subsidiary risk, and articles containing such substances: W1 W2 W3 Liquid; Solid; Articles; WF1 Substances which, in contact with water, emit flammable gases, liquid, flammable; WF2 Substances which, in contact with water, emit flammable gases, solid, flammable; WS Substances which, in contact with water, emit flammable gases, solid, self-heating; WO Substances which, in contact with water, emit flammable gases, oxidizing, solid; WT Substances which, in contact with water, emit flammable gases, toxic: WT1 Liquid; WT2 Solid; WC Substances which, in contact with water, emit flammable gases, corrosive: WC1 Liquid; WC2 Solid; WFC Substances which, in contact with water, emit flammable gases, flammable, corrosive. Properties 2.2.43.1.3 Certain substances in contact with water may emit flammable gases that can form explosive mixtures with air. Such mixtures are easily ignited by all ordinary sources of ignition, for example naked lights, sparking handtools or unprotected light bulbs. The resulting blast wave and flames may endanger people and the environment. The test method referred to in 2.2.43.1.4 below is used to determine whether the reaction of a substance with water leads to the development of a dangerous amount of gases which may be flammable. This test method shall not be applied to pyrophoric substances. Classification 2.2.43.1.4 Substances and articles classified in Class 4.3 are listed in Table A of Chapter 3.2. The assignment of substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant entry of 2.2.43.3 in accordance with the provisions of Chapter 2.1 shall be based on the results of the test procedure in accordance with the Manual of Tests and Criteria, Part III, Section 33.4; experience shall also be taken into account when it leads to a more stringent assignment. - 170 - Copyright © United Nations, 2010. All rights reserved 2.2.43.1.5 When substances not mentioned by name are assigned to one of the entries listed in 2.2.43.3 on the basis of the test procedure in accordance with the Manual of Tests and Criteria, Part III, Section 33.4, the following criteria shall apply: A substance shall be assigned to Class 4.3 if: (a) spontaneous ignition of the gas emitted takes place in any step of the test procedure; or (b) there is an evolution of flammable gas at a rate greater than 1 litre per kilogram of the substance to be tested per hour. NOTE: Since organometallic substances can be classified in Class 4.2 or 4.3 with additional subsidiary risks, depending on their properties, a specific classification flow chart for these substances is given in 2.3.5. 2.2.43.1.6 If substances of Class 4.3, as a result of admixtures, come into different categories of risk from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes) see also 2.1.3. 2.2.43.1.7 On the basis of the test procedures in accordance with the Manual of Tests and Criteria, Part III, Section 33.4, and the criteria set out in paragraph 2.2.43.1.5, it may also be determined whether the nature of a substance mentioned by name is such that the substance is not subject to the provisions for this Class. Assignment of packing groups 2.2.43.1.8 2.2.43.2 Substances and articles classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups I, II or III on the basis of test procedures of the Manual of Tests and Criteria, Part III, section 33.4, in accordance with the following criteria: (a) Packing group I shall be assigned to any substance which reacts vigorously with water at ambient temperature and generally demonstrates a tendency for the gas produced to ignite spontaneously, or one which reacts readily with water at ambient temperatures such that the rate of evolution of flammable gas is equal to or greater than 10 litres per kilogram of substance over any one minute period; (b) Packing group II shall be assigned to any substance which reacts readily with water at ambient temperature such that the maximum rate of evolution of flammable gas is equal to or greater than 20 litres per kilogram of substance per hour, and which does not meet the criteria of packing group I; (c) Packing group III shall be assigned to any substance which reacts slowly with water at ambient temperature such that the maximum rate of evolution of flammable gas is greater than 1 litre per kilogram of substance per hour, and which does not meet the criteria of packing groups I or II. Substances not accepted for carriage Water-reactive solids, oxidizing, assigned to UN No. 3133 shall not be accepted for carriage unless they meet the requirements for Class 1 (see also 2.1.3.7). - 171 - Copyright © United Nations, 2010. All rights reserved 2.2.43.3 List of collective entries Substances which, in contact with water, emit flammable gases liquid Without subsidiary risk W W1 solid W2 a articles W3 1389 1391 1391 1392 1420 1421 1422 3398 3148 ALKALI METAL AMALGAM, LIQUID ALKALI METAL DISPERSION or ALKALINE EARTH METAL DISPERSION ALKALINE EARTH METAL AMALGAM, LIQUID POTASSIUM METAL ALLOYS, LIQUID ALKALI METAL ALLOY, LIQUID, N.O.S. POTASSIUM SODIUM ALLOYS, LIQUID ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE WATER-REACTIVE LIQUID, N.O.S. 1390 3401 3402 3170 3170 3403 3404 1393 1409 3208 3395 2813 ALKALI METAL AMIDES ALKALI METAL AMALGAM, SOLID ALKALINE EARTH METAL AMALGAM, SOLID ALUMINIUM SMELTING BY-PRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS POTASSIUM METAL ALLOYS, SOLID POTASSIUM SODIUM ALLOYS, SOLID ALKALINE EARTH METAL ALLOY, N.O.S. METAL HYDRIDES, WATER-REACTIVE, N.O.S. METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE WATER-REACTIVE SOLID, N.O.S. 3292 BATTERIES, CONTAINING SODIUM or 3292 CELLS, CONTAINING SODIUM Liquid, flammable WF1 3399 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE 3482 ALKALI METAL DISPERSION, FLAMMABLE or 3482 ALKALINE EARTH METAL DISPERSION, FLAMMABLE Solid, flammable WF2 3396 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, FLAMMABLE 3132 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. WS b Solid, self-heating 3397 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, SELF-HEATING 3209 METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S. 3135 WATER-REACTIVE SOLID, SELF-HEATING, N.O.S. WO 3133 WATER-REACTIVE SOLID, OXIDIZING, N.O.S. (not allowed, see 2.2.43.2) liquid WT1 3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. solid WT2 3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. liquid WC1 3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. solid WC2 3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. WFC c 2988 CHLOROSILANES, WATER-REACTIVE, FLAMMABLE, CORROSIVE, NO.S. Solid, oxidizing Toxic WT Corrosive WC Flammable, corrosive (No other collective entry with this classification code available, if need be, classification under a collective entry with a classification code to be determined according to the table of precedence of hazard in 2.1.3.10.) Metals and metal alloys which, in contact with water, do not emit flammable gases and are not pyrophoric or self-heating, but which are readily flammable, are substances of Class 4.1. Alkaline-earth metals and alkaline-earth metal alloys in pyrophoric form are substances of Class 4.2 Dust and powders of metals in pyrophoric form are substances of Class 4.2. Metals and metal alloys in pyrophoric form are substances of Class 4.2. Compounds of phosphorus with heavy metals such as iron, copper, etc. are not subject to the provisions of ADR. a b Metals and metal alloys in pyrophoric form are substances of Class 4.2. Chlorosilanes, having a flash-point of less than 23 °C and which, in contact with water, do not emit flammable gases, are substances of Class 3. Chlorosilanes, having a flash-point equal to or greater than 23 °C and which, in contact with water, do not emit flammable gases, are substances of Class 8. c - 172 - Copyright © United Nations, 2010. All rights reserved 2.2.51 Class 5.1 2.2.51.1 Criteria 2.2.51.1.1 The heading of Class 5.1 covers substances which, while in themselves not necessarily combustible, may, generally by yielding oxygen, cause or contribute to the combustion of other material, and articles containing such substances. 2.2.51.1.2 The substances of Class 5.1 and articles containing such substances are subdivided as follows: O Oxidizing substances Oxidizing substances without subsidiary risk or articles containing such substances: O1 O2 O3 Liquid; Solid; Articles; OF Oxidizing substances, solid, flammable; OS Oxidizing substances, solid, self-heating; OW Oxidizing substances, solid which, in contact with water, emit flammable gases; OT Oxidizing substances, toxic: OT1 Liquid; OT2 Solid; OC Oxidizing substances, corrosive: OC1 Liquid; OC2 Solid; OTC Oxidizing substances, toxic, corrosive. 2.2.51.1.3 Substances and articles classified in Class 5.1 are listed in Table A of Chapter 3.2. The assignment of substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant entry of 2.2.51.3 in accordance with the provisions of Chapter 2.1 can be based on the tests, methods and criteria in paragraphs 2.2.51.1.6-2.2.51.1.9 below and the Manual of Tests and Criteria, Part III, Section 34.4. In the event of divergence between test results and known experience, judgement based on known experience shall take precedence over test results. 2.2.51.1.4 If substances of Class 5.1, as a result of admixtures, come into different categories of risk from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also Section 2.1.3. 2.2.51.1.5 On the basis of the test procedures in the Manual of Tests and Criteria, Part III, Section 34.4 and the criteria set out in 2.2.51.1.6 to 2.2.51.1.9 it may also be determined whether the nature of a substance mentioned by name in Table A of Chapter 3.2 is such that the substance is not subject to the provisions for this class. - 173 - Copyright © United Nations, 2010. All rights reserved Oxidizing solids Classification 2.2.51.1.6 When oxidizing solid substances not mentioned by name in Table A of Chapter 3.2 are assigned to one of the entries listed in 2.2.51.3 on the basis of the test procedure in accordance with the Manual of Tests and Criteria, Part III, sub-section 34.4.1, the following criteria shall apply: A solid substance shall be assigned to Class 5.1 if, in the 4:1 or the 1:1 sample-to-cellulose ratio (by mass) tested, it ignites or burns or exhibits mean burning times equal to or less than that of a 3:7 mixture (by mass) of potassium bromate and cellulose. Assignment of packing groups 2.2.51.1.7 Oxidizing solids classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups I, II or III on the basis of test procedures of the Manual of Tests and Criteria, Part III, sub-section 34.4.1, in accordance with the following criteria: (a) Packing group I: any substance which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time less than the mean burning time of a 3:2 mixture, by mass, of potassium bromate and cellulose; (b) Packing group II: any substance which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time equal to or less than the mean burning time of a 2:3 mixture (by mass) of potassium bromate and cellulose and the criteria for packing group I are not met; (c) Packing group III: any substance which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time equal to or less than the mean burning time of a 3:7 mixture (by mass) of potassium bromate and cellulose and the criteria for packing groups I and II are not met. Oxidizing liquids Classification 2.2.51.1.8 When oxidizing liquid substances not mentioned by name in Table A of Chapter 3.2 are assigned to one of the entries listed in sub-section 2.2.51.3 on the basis of the test procedure in accordance with the Manual of Tests and Criteria, Part III, sub-section 34.4.2, the following criteria shall apply: A liquid substance shall be assigned to Class 5.1 if, in the 1:1 mixture, by mass, of substance and cellulose tested, it exhibits a pressure rise of 2070 kPa gauge or more and a mean pressure rise time equal to or less than the mean pressure rise time of a 1:1 mixture, by mass, of 65% aqueous nitric acid and cellulose. Assignment of packing groups 2.2.51.1.9 Oxidizing liquids classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups I, II or III on the basis of test procedures of the Manual of Tests and Criteria, Part III, section 34.4.2, in accordance with the following criteria: - 174 - Copyright © United Nations, 2010. All rights reserved (a) Packing group I: any substance which, in the 1:1 mixture, by mass, of substance and cellulose tested, spontaneously ignites; or the mean pressure rise time of a 1:1 mixture, by mass, of substance and cellulose is less than that of a 1:1 mixture, by mass, of 50% perchloric acid and cellulose; (b) Packing group II: any substance which, in the 1:1 mixture, by mass, of substance and cellulose tested, exhibits a mean pressure rise time less than or equal to the mean pressure rise time of a 1:1 mixture, by mass, of 40% aqueous sodium chlorate solution and cellulose; and the criteria for packing group I are not met; (c) Packing group III: any substance which, in the 1:1 mixture, by mass, of substance and cellulose tested, exhibits a mean pressure rise time less than or equal to the mean pressure rise time of a 1:1 mixture, by mass, of 65% aqueous nitric acid and cellulose; and the criteria for packing groups I and II are not met. 2.2.51.2 Substances not accepted for carriage 2.2.51.2.1 The chemically unstable substances of Class 5.1 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end it shall in particular be ensured that receptacles and tanks do not contain any material liable to promote these reactions. 2.2.51.2.2 The following substances and mixtures shall not be accepted for carriage: - oxidizing solids, self-heating, assigned to UN No. 3100, oxidizing solids, water-reactive, assigned to UN No. 3121 and oxidizing solids, flammable, assigned to UN No. 3137, unless they meet the requirements for Class 1 (see also 2.1.3.7); - hydrogen peroxide, not stabilized or hydrogen peroxide, aqueous solutions, not stabilized containing more than 60% hydrogen peroxide; - tetranitromethane not free from combustible impurities; - perchloric acid solutions containing more than 72% (mass) acid, or mixtures of perchloric acid with any liquid other than water; - chloric acid solution containing more than 10% chloric acid or mixtures of chloric acid with any liquid other than water; - halogenated fluor compounds other than UN Nos. 1745 BROMINE PENTAFLUORIDE; 1746 BROMINE TRIFLUORIDE and 2495 IODINE PENTAFLUORIDE of Class 5.1 as well as UN Nos. 1749 CHLORINE TRIFLUORIDE and 2548 CHLORINE PENTAFLUORIDE of Class 2; - ammonium chlorate and its aqueous solutions and mixtures of a chlorate with an ammonium salt; - ammonium chlorite and its aqueous solutions and mixtures of a chlorite with an ammonium salt; - mixtures of a hypochlorite with an ammonium salt; - ammonium bromate and its aqueous solutions and mixtures of a bromate with an ammonium salt; - 175 - Copyright © United Nations, 2010. All rights reserved - ammonium permanganate and its aqueous solutions and mixtures of a permanganate with an ammonium salt; - ammonium nitrate containing more than 0.2% combustible substances (including any organic substance calculated as carbon) unless it is a constituent of a substance or article of Class 1; - fertilizers having an ammonium nitrate content (in determining the ammonium nitrate content, all nitrate ions for which a molecular equivalent of ammonium ions is present in the mixture shall be calculated as ammonium nitrate) or a content in combustible substances exceeding the values specified in special provision 307 except under the conditions applicable to Class 1; - ammonium nitrite and its aqueous solutions and mixtures of an inorganic nitrite with an ammonium salt; - mixtures of potassium nitrate, sodium nitrite and an ammonium salt. - 176 - Copyright © United Nations, 2010. All rights reserved 2.2.51.3 List of collective entries Oxidizing substances liquid O1 3210 3211 3213 3214 3216 3218 3219 3139 CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. OXIDIZING LIQUID, N.O.S. BROMATES, INORGANIC, N.O.S CHLORATES, INORGANIC, N.O.S. CHLORITES, INORGANIC, N.O.S. NITRATES, INORGANIC, N.O.S PERCHLORATES, INORGANIC, N.O.S. PERMANGANATES, INORGANIC, N.O.S. PEROXIDES, INORGANIC, N.O.S NITRITES, INORGANIC, N.O.S. HYPOCHLORITES, INORGANIC, N.O.S. PERSULPHATES, INORGANIC, N.O.S. OXIDIZING SOLID, N.O.S. solid O2 1450 1461 1462 1477 1481 1482 1483 2627 3212 3215 1479 articles O3 3356 OXYGEN GENERATOR, CHEMICAL Solid, flammable OF 3137 OXIDIZING SOLID, FLAMMABLE, N.O.S. (not allowed, see 2.2.51.2) Solid, self-heating OS 3100 OXIDIZING SOLID, SELF-HEATING, N.O.S. (not allowed, see 2.2.51.2) OW 3121 OXIDIZING SOLID, WATER REACTIVE, N.O.S. (not allowed, see 2.2.51.2) liquid OT1 3099 OXIDIZING LIQUID, TOXIC, N.O.S. solid OT2 3087 OXIDIZING SOLID, TOXIC, N.O.S. liquid OC1 3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. solid OC2 3085 OXIDIZING SOLID, CORROSIVE, N.O.S. Without subsidiary risk O Solid, water reactive Toxic OT Corrosive OC Toxic, corrosive OTC (No collective entry with this classification code available; if need be, classification under a collective entry with a classification code to be determined according to the table of precedence of hazard in 2.1.3.10.) - 177 - Copyright © United Nations, 2010. All rights reserved 2.2.52 Class 5.2 2.2.52.1 Criteria 2.2.52.1.1 The heading of Class 5.2 covers organic peroxides and formulations of organic peroxides. 2.2.52.1.2 The substances of Class 5.2 are subdivided as follows: P1 P2 Organic peroxides Organic peroxides, not requiring temperature control; Organic peroxides, requiring temperature control. Definition 2.2.52.1.3 Organic peroxides are organic substances which contain the bivalent -O-O- structure and may be considered derivatives of hydrogen peroxide, where one or both of the hydrogen atoms have been replaced by organic radicals. Properties 2.2.52.1.4 Organic peroxides are liable to exothermic decomposition at normal or elevated temperatures. The decomposition can be initiated by heat, contact with impurities (e.g. acids, heavy-metal compounds, amines), friction or impact. The rate of decomposition increases with temperature and varies with the organic peroxide formulation. Decomposition may result in the evolution of harmful, or flammable, gases or vapours. For certain organic peroxides the temperature shall be controlled during carriage. Some organic peroxides may decompose explosively, particularly if confined. This characteristic may be modified by the addition of diluents or by the use of appropriate packagings. Many organic peroxides burn vigorously. Contact of organic peroxides with the eyes is to be avoided. Some organic peroxides will cause serious injury to the cornea, even after brief contact, or will be corrosive to the skin. NOTE: Test methods for determining the flammability of organic peroxides are set out in the Manual of Tests and Criteria, Part III, sub-section 32.4. Because organic peroxides may react vigorously when heated, it is recommended to determine their flash-point using small sample sizes such as described in ISO 3679:1983. Classification 2.2.52.1.5 Any organic peroxide shall be considered for classification in Class 5.2 unless the organic peroxide formulation contains: (a) Not more than 1.0% available oxygen from the organic peroxides when containing not more than 1.0% hydrogen peroxide; (b) Not more than 0.5% available oxygen from the organic peroxides when containing more than 1.0% but not more than 7.0% hydrogen peroxide. NOTE: The available oxygen content (%) of an organic peroxide formulation is given by the formula 16 × ∑ (ni × ci /mi) where: ni = ci = mi = number of peroxygen groups per molecule of organic peroxide i; concentration (mass %) of organic peroxide i; and molecular mass of organic peroxide i. - 178 - Copyright © United Nations, 2010. All rights reserved 2.2.52.1.6 Organic peroxides are classified into seven types according to the degree of danger they present. The types of organic peroxide range from type A, which is not accepted for carriage in the packaging in which it is tested, to type G, which is not subject to the provisions of Class 5.2. The classification of types B to F is directly related to the maximum quantity allowed in one packaging. The principles to be applied to the classification of substances not listed in 2.2.52.4 are set out in the Manual of Tests and Criteria, Part II. 2.2.52.1.7 Organic peroxides which have already been classified and are already permitted for carriage in packagings are listed in 2.2.52.4, those already permitted for carriage in IBCs are listed in 4.1.4.2, packing instruction IBC520 and those already permitted for carriage in tanks in accordance with Chapters 4.2 and 4.3 are listed in 4.2.5.2, portable tank instruction T23. Each permitted substance listed is assigned to a generic entry of Table A of Chapter 3.2 (UN Nos. 3101 to 3120) and appropriate subsidiary risks and remarks providing relevant transport information are given. These generic entries specify: - the type (B to F) of organic peroxide (see 2.2.52.1.6 above); - physical state (liquid/solid); and - temperature control (when required), see 2.2.52.1.15 to 2.2.52.1.18. Mixtures of these formulations may be classified as the same type of organic peroxide as that of the most dangerous component and be carried under the conditions of carriage given for this type. However, as two stable components can form a thermally less stable mixture, the self-accelerating decomposition temperature (SADT) of the mixture shall be determined and, if necessary, the control and emergency temperatures derived from the SADT in accordance with 2.2.52.1.16. 2.2.52.1.8 Classification of organic peroxides, formulations or mixtures of organic peroxides not listed in 2.2.52.4, 4.1.4.2 packing instruction IBC520 or 4.2.5.2, portable tank instruction T23, and assignment to a collective entry shall be made by the competent authority of the country of origin. The statement of approval shall contain the classification and the relevant conditions of carriage. If the country of origin is not a Contracting Party to ADR, the classification and conditions of carriage shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. 2.2.52.1.9 Samples of organic peroxides or formulations of organic peroxides not listed in 2.2.52.4, for which a complete set of test results is not available and which are to be carried for further testing or evaluation, shall be assigned to one of the appropriate entries for organic peroxides type C provided the following conditions are met: - the available data indicate that the sample would be no more dangerous than organic peroxides type B; - the sample is packaged in accordance with packing method OP2 and the quantity per transport unit is limited to 10 kg; - the available data indicate that the control temperature, if any, is sufficiently low to prevent any dangerous decomposition and sufficiently high to prevent any dangerous phase separation. - 179 - Copyright © United Nations, 2010. All rights reserved Desensitization of organic peroxides 2.2.52.1.10 In order to ensure safety during carriage, organic peroxides are in many cases desensitized by organic liquids or solids, inorganic solids or water. Where a percentage of a substance is stipulated, this refers to the percentage by mass, rounded to the nearest whole number. In general, desensitization shall be such that, in case of spillage, the organic peroxide will not concentrate to a dangerous extent. 2.2.52.1.11 Unless otherwise stated for the individual organic peroxide formulation, the following definition(s) shall apply to diluents used for desensitization: - diluents type A are organic liquids which are compatible with the organic peroxide and which have a boiling point of not less than 150 °C. Type A diluents may be used for desensitizing all organic peroxides; - diluents type B are organic liquids which are compatible with the organic peroxide and which have a boiling point of less than 150 °C but not less than 60 °C and a flash-point of not less than 5 °C. Type B diluents may be used for desensitization of all organic peroxides provided that the boiling point of the liquid is at least 60 °C higher than the SADT in a 50 kg package. 2.2.52.1.12 Diluents, other than type A or type B, may be added to organic peroxide formulations as listed in 2.2.52.4 provided that they are compatible. However, replacement of all or part of a type A or type B diluent by another diluent with differing properties requires that the organic peroxide formulation be re-assessed in accordance with the normal acceptance procedure for Class 5.2. 2.2.52.1.13 Water may only be used for the desensitization of organic peroxides which are listed in 2.2.52.4 or in the competent authority decision according to 2.2.52.1.8 as being "with water" or "as a stable dispersion in water". Samples of organic peroxides or formulations of organic peroxides not listed in 2.2.52.4 may also be desensitized with water provided the requirements of 2.2.52.1.9 are met. 2.2.52.1.14 Organic and inorganic solids may be used for desensitization of organic peroxides provided that they are compatible. Compatible liquids and solids are those which have no detrimental influence on the thermal stability and hazard type of the organic peroxide formulation. Temperature control requirements 2.2.52.1.15 Certain organic peroxides may only be carried under temperature-controlled conditions. The control temperature is the maximum temperature at which the organic peroxide can be safely carried. It is assumed that the temperature of the immediate surroundings of a package only exceeds 55 °C during carriage for a relatively short time in a 24 hour period. In the event of loss of temperature control, it may be necessary to implement emergency procedures. The emergency temperature is the temperature at which such procedures shall be implemented. 2.2.52.1.16 The control and emergency temperatures are derived from the SADT which is defined as the lowest temperature at which self-accelerating decomposition may occur with a substance in the packaging as used during carriage (see Table 1). The SADT shall be determined in order to decide whether a substance shall be subjected to temperature control during carriage. Provisions for the determination of the SADT are given in the Manual of Tests and Criteria, Part II, Sections 20 and 28.4. - 180 - Copyright © United Nations, 2010. All rights reserved Table 1: Derivation of control and emergency temperatures Type of receptacle Single packagings and IBCs Tanks a SADT a Control temperature Emergency temperature 20 °C or less 20 °C below SADT 10 °C below SADT over 20 °C to 35 °C 15 °C below SADT 10 °C below SADT over 35 °C 10 °C below SADT 5 °C below SADT not greater than 50 °C 10 °C below SADT 5 °C below SADT SADT of the substance as packaged for carriage 2.2.52.1.17 The following organic peroxides shall be subject to temperature control during carriage: - organic peroxides types B and C with an SADT ≤ 50 °C; - organic peroxides type D showing a medium effect when heated under confinement with an SADT ≤ 50 °C or showing a low or no effect when heated under confinement with an SADT ≤ 45 °C; and - organic peroxides types E and F with an SADT ≤ 45 °C. NOTE: Provisions for the determination of the effects of heating under confinement are given in the Manual of Tests and Criteria, Part II, Section 20 and Sub-section 28.4. 2.2.52.1.18 Where applicable, control and emergency temperatures are listed in 2.2.52.4. The actual temperature during carriage may be lower than the control temperature but shall be selected so as to avoid dangerous separation of phases. 2.2.52.2 Substances not accepted for carriage Organic peroxides, type A, shall not be accepted for carriage under the provisions of Class 5.2 (see Manual of Tests and Criteria, Part II, paragraph 20.4.3 (a)). - 181 - Copyright © United Nations, 2010. All rights reserved 2.2.52.3 List of collective entries Organic peroxides Not requiring temperature control Requiring temperature control 2.2.52.4 P1 P2 3101 3102 3103 3104 3105 3106 3107 3108 3109 3110 3111 3112 3113 3114 3115 3116 3117 3118 3119 3120 ORGANIC PEROXIDE TYPE A, LIQUID ORGANIC PEROXIDE TYPE A, SOLID ORGANIC PEROXIDE TYPE B, LIQUID ORGANIC PEROXIDE TYPE B, SOLID ORGANIC PEROXIDE TYPE C, LIQUID ORGANIC PEROXIDE TYPE C, SOLID ORGANIC PEROXIDE TYPE D, LIQUID ORGANIC PEROXIDE TYPE D, SOLID ORGANIC PEROXIDE TYPE E, LIQUID ORGANIC PEROXIDE TYPE E, SOLID ORGANIC PEROXIDE TYPE F, LIQUID ORGANIC PEROXIDE TYPE F, SOLID ORGANIC PEROXIDE TYPE G, LIQUID ORGANIC PEROXIDE TYPE G, SOLID accepted for carriage, }Not see 2.2.52.2 } Not subject to the provisions applicable to Class 5.2, see 2.2.52.1.6 ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE C, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE E, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED List of currently assigned organic peroxides in packagings In the column "Packing Method", codes "OP1" to "OP8" refer to packing methods in 4.1.4.1, packing instruction P520 (see also 4.1.7.1). Organic peroxides to be carried shall fulfil the classification and the control and emergency temperatures (derived from the SADT) as listed. For substances permitted in IBCs, see 4.1.4.2, packing instruction IBC520 and, for those permitted in tanks according to Chapters 4.2 and 4.3, see 4.2.5.2, portable tank instruction T23. - 182 - Copyright © United Nations, 2010. All rights reserved ORGANIC PEROXIDE ACETYL ACETONE PEROXIDE " ACETYL CYCLOHEXANESULPHONYL PEROXIDE " Concentration (%) Diluent type A (%) ≤ 42 ≥ 48 Diluent type B (%) 1) Inert solid (%) Water Packing Method ≥8 OP7 3105 2) OP7 3106 20) 3) ≤ 32 as a paste ≤ 82 ≥ 12 ≤ 32 ≥ 68 tert-AMYL HYDROPEROXIDE ≤ 88 ≥6 tert-AMYL PEROXYACETATE ≤ 62 ≥ 38 tert-AMYL PEROXYBENZOATE Emergency temperature (°C) Number (Generic entry) OP4 -10 0 3112 OP7 -10 0 3115 OP8 3107 OP7 3105 ≤ 100 OP5 3103 tert-AMYL PEROXY-2-ETHYLHEXANOATE ≤ 100 OP7 tert-AMYL PEROXY-2-ETHYLHEXYL CARBONATE ≤ 100 OP7 3105 tert-AMYL PEROXY ISOPROPYL CARBONATE ≤ 77 OP5 3103 tert-AMYL PEROXYNEODECANOATE ≤ 77 " ≤ 47 ≥6 Control temperature (°C) ≥ 23 ≥ 23 ≥ 53 +25 3115 - 183 - OP7 0 +10 3115 OP8 0 + 10 3119 OP5 +10 +15 3113 tert-AMYL PEROXYPIVALATE ≤ 77 tert-AMYLPEROXY-3,5,5-TRIMETHYLHEXANOATE ≤ 100 OP7 3105 > 42 - 100 OP8 3107 OP8 3108 OP5 3103 OP8 3108 OP5 3103 13) OP7 3105 4) 13) tert-BUTYL CUMYL PEROXIDE " n-BUTYL-4,4-DI-(tert-BUTYLPEROXY)VALERATE " tert-BUTYL HYDROPEROXIDE ≥ 23 +20 Subsidiary risks and remarks ≤ 52 ≥ 48 > 52 - 100 ≤ 52 ≥ 48 >79 - 90 ≥ 10 " ≤ 80 " ≤ 79 > 14 OP8 3107 13) 23) " ≤ 72 ≥ 28 OP8 3109 13) < 82 + >9 ≥7 OP5 3103 13) tert-BUTYL HYDROPEROXIDE + DI-tert-BUTYLPEROXIDE ≥ 20 Copyright © United Nations, 2010. All rights reserved ORGANIC PEROXIDE tert-BUTYL MONOPEROXYMALEATE Concentration (%) Diluent type B (%) 1) Inert solid (%) > 52 - 100 " ≤ 52 " ≤ 52 " ≤ 52 as a paste tert-BUTYL PEROXYACETATE Diluent type A (%) ≥ 48 ≥ 48 Water Packing Method Control temperature (°C) Emergency temperature (°C) Number (Generic entry) OP5 3102 OP6 3103 OP8 3108 OP8 3108 > 52 - 77 ≥ 23 OP5 3101 " > 32 - 52 ≥ 48 OP6 3103 " ≤ 32 OP8 3109 OP5 3103 OP7 3105 OP7 3106 tert-BUTYL PEROXYBENZOATE ≥ 68 > 77 - 100 " > 52 - 77 " ≤ 52 ≥23 ≥ 48 - 184 - tert-BUTYL PEROXYBUTYL FUMARATE ≤ 52 ≥ 48 OP7 3105 tert-BUTYL PEROXYCROTONATE ≤ 77 ≥ 23 OP7 3105 tert-BUTYL PEROXYDIETHYLACETATE ≤ 100 OP5 +20 +25 3113 > 52 – 100 OP6 +20 +25 3113 OP8 +30 +35 3117 OP8 +20 +25 3118 OP8 +40 +45 3119 tert-BUTYL PEROXY-2-ETHYLHEXANOATE " > 32 - 52 " ≤ 52 " ≤ 32 tert-BUTYL PEROXY-2-ETHYLHEXANOATE + 2,2-DI-(tert-BUTYLPEROXY)BUTANE " tert-BUTYL PEROXY-2-ETHYLHEXYLCARBONATE tert-BUTYL PEROXYISOBUTYRATE " tert-BUTYLPEROXY ISOPROPYLCARBONATE ≤ 12 +≤ 14 ≥ 48 ≥ 48 ≥ 68 ≥ 14 ≤ 31 + ≤ 36 ≥ 60 ≥ 33 ≤ 100 OP7 OP7 +35 +40 OP7 3105 OP5 +15 +20 3111 ≤ 52 ≥ 48 OP7 +15 +20 3115 OP5 3) 3115 ≥ 23 ≥ 23 3) 3106 > 52 - 77 ≤ 77 Subsidiary risks and remarks 3103 3) Copyright © United Nations, 2010. All rights reserved ORGANIC PEROXIDE 1-(2-tert-BUTYLPEROXY ISOPROPYL)-3- Concentration (%) Diluent type A (%) ≤ 77 ≥ 23 Diluent type B (%) 1) Inert solid (%) Water Packing Method Control temperature (°C) Emergency temperature (°C) Number (Generic entry) OP7 3105 OP8 3108 ≤ 100 OP5 3103 > 77 - 100 OP7 -5 +5 3115 OP7 0 +10 3115 Subsidiary risks and remarks ISOPROPENYLBENZENE " tert-BUTYL PEROXY-2-METHYLBENZOATE tert-BUTYL PEROXYNEODECANOATE ≤ 42 ≥ 58 " ≤ 77 " ≤ 52 as a stable dispersion in water OP8 0 +10 3119 " ≤ 42 as a stable dispersion in water (frozen) OP8 0 +10 3118 " ≤ 32 ≥ 68 OP8 0 +10 3119 ≤ 77 ≥ 23 OP7 0 +10 3115 OP8 0 +10 3117 OP5 0 +10 3113 tert-BUTYL PEROXYNEOHEPTANOATE ≥ 23 - 185 - ≤ 42 as a stable dispersion in water " tert-BUTYL PEROXYPIVALATE > 67 - 77 ≥ 23 " > 27 - 67 ≥ 33 OP7 0 +10 3115 " ≤ 27 ≥ 73 OP8 +30 +35 3119 tert-BUTYLPEROXY STEARYLCARBONATE tert-BUTYL PEROXY-3,5,5-TRIMETHYLHEXANOATE ≤ 100 OP7 3106 > 32 - 100 OP7 3105 OP7 3106 OP8 3109 OP1 3102 " ≤ 42 " ≤ 32 3-CHLOROPEROXYBENZOIC ACID ≥ 58 ≥ 68 > 57 - 86 ≥ 14 " ≤ 57 ≥3 ≥ 40 OP7 3106 " ≤ 77 ≥6 ≥ 17 OP7 3106 CUMYL HYDROPEROXIDE " 3) > 90 - 98 ≤10 OP8 3107 13) ≤ 90 ≥ 10 OP8 3109 13) 18) Copyright © United Nations, 2010. All rights reserved ORGANIC PEROXIDE CUMYL PEROXYNEODECANOATE Concentration (%) Diluent type A (%) ≤ 87 ≥ 13 " ≤ 77 " ≤ 52 as a stable dispersion in water CUMYL PEROXYNEOHEPTANOATE ≤ 77 CUMYL PEROXYPIVALATE ≤ 77 CYCLOHEXANONE PEROXIDE(S) ≤ 91 " ≤ 72 " ≤ 72 as a paste " ≤ 32 Diluent type B (%) 1) Water ≥ 23 ≥ 23 ≥ 23 ≥9 ≥ 28 Packing Method Control temperature (°C) Emergency temperature (°C) Number (Generic entry) OP7 - 10 0 3115 OP7 -10 0 3115 OP8 -10 0 3119 OP7 -10 0 3115 OP7 -5 +5 3115 - 186 - ≤ 57 ≥ 26 DIACETYL PEROXIDE ≤ 27 ≥ 73 DI-tert-AMYL PEROXIDE ≤ 100 2,2-DI-(tert-AMYLPEROXY)BUTANE ≤ 57 1,1-DI-(tert-AMYLPEROXY)CYCLOHEXANE ≤ 82 ≥8 Subsidiary risks and remarks OP6 3104 13) OP7 3105 5) OP7 3106 5) 20) ≥ 68 DIACETONE ALCOHOL PEROXIDES DIBENZOYL PEROXIDE Inert solid (%) Exempt 29) OP7 +40 +45 3115 6) OP7 +20 +25 3115 7) 13) OP8 3107 ≥ 43 OP7 3105 ≥ 18 OP6 3103 OP2 3102 3) 3) > 51 - 100 ≤ 48 " > 77 - 94 ≥6 OP4 3102 " ≤ 77 ≥ 23 OP6 3104 " ≤ 62 ≥ 10 OP7 3106 " > 52 – 62 as a paste OP7 3106 " > 35 - 52 OP7 3106 " > 36 - 42 ≤ 40 OP8 3107 " ≤ 56.5 as a paste ≥ 15 OP8 3108 ≥ 28 ≥ 48 ≥ 18 " ≤ 52 as a paste OP8 3108 " ≤ 42 as a stable dispersion in water OP8 3109 " ≤ 35 ≥ 65 Exempt 20) 20) 29) Copyright © United Nations, 2010. All rights reserved ORGANIC PEROXIDE DI-(4-tert-BUTYLCYCLOHEXYL) PEROXYDICARBONATE " DI-tert-BUTYL PEROXIDE " Packing Method Control temperature (°C) Emergency temperature (°C) Number (Generic entry) ≤ 100 OP6 +30 +35 3114 ≤ 42 as a stable dispersion in water OP8 +30 +35 3119 > 52 - 100 OP8 3107 OP8 3109 Concentration (%) Diluent type A (%) ≤ 52 Diluent type B (%) 1) Inert solid (%) ≥ 48 Water Subsidiary risks and remarks 25) DI-tert-BUTYL PEROXYAZELATE ≤ 52 ≥ 48 OP7 3105 2,2-DI-(tert-BUTYLPEROXY)BUTANE ≤ 52 ≥ 48 OP6 3103 1,6-Di-(tert-BUTYLPEROXYCARBONYLOXY) HEXANE ≤ 72 ≥ 28 OP5 3103 1,1-DI-(tert-BUTYLPEROXY) CYCLOHEXANE > 80 - 100 OP5 3101 3) OP5 3103 30) - 187 - " ≤ 72 " > 52 - 80 ≥ 20 OP5 3103 " > 42 - 52 ≥ 48 OP7 3105 " ≤ 42 ≥ 13 OP7 3106 " ≤ 42 ≥ 58 OP8 3109 " ≤ 27 ≥ 25 OP8 3107 " ≤ 13 ≥ 13 OP8 3109 ≤ 43 + ≤ 16 ≥ 41 OP 7 3105 1,1-DI-(tert-BUTYLPEROXY) CYCLOHEXANE + tert-BUTYL PEROXY-2-ETHYLHEXANOATE DI-n-BUTYL PEROXYDICARBONATE ≥ 28 ≥ 45 ≥ 74 > 27 - 52 ≥ 48 OP7 -15 -5 3115 " ≤ 27 ≥ 73 OP8 -10 0 3117 " ≤ 42 as a stable dispersion in water (frozen) OP8 -15 -5 3118 > 52 - 100 OP4 -20 -10 3113 OP7 -15 -5 3115 DI-sec-BUTYL PEROXYDICARBONATE " ≤ 52 ≥ 48 21) Copyright © United Nations, 2010. All rights reserved ORGANIC PEROXIDE DI-(tert-BUTYLPEROXYISOPROPYL)BENZENE(S) " DI-(tert-BUTYLPEROXY) PHTHALATE Concentration (%) Diluent type A (%) Diluent type B (%) 1) Inert solid (%) > 42 - 100 ≤ 57 ≤ 42 ≥ 58 > 42 - 52 Water Packing Method Control temperature (°C) Emergency temperature (°C) OP7 Number (Generic entry) 3106 Exempt ≥ 48 Subsidiary risks and remarks OP7 3105 OP7 3106 29) " ≤ 52 as a paste " ≤ 42 ≥ 58 OP8 3107 ≤ 52 ≥ 48 OP7 3105 ≤ 42 ≥ 13 OP7 3106 OP5 3101 3) OP5 3103 30) OP5 3103 OP5 3103 OP8 3110 OP8 3107 OP8 3107 2,2-DI-(tert-BUTYLPEROXY)PROPANE " 1,1-DI-(tert-BUTYLPEROXY)-3,3,5TRIMETHYLCYCLOHEXANE > 90 - 100 - 188 - " ≤ 90 " > 57 - 90 " ≤ 77 " ≤ 57 " ≤ 57 ≥ 43 " ≤ 32 ≥ 26 DICETYL PEROXYDICARBONATE " DI-4-CHLOROBENZOYL PEROXIDE ≥ 23 ≥ 43 ≥ 42 +30 +35 3116 ≤ 42 as a stable dispersion in water OP8 +30 +35 3119 ≤ 77 " ≤ 32 DICYCLOHEXYL PEROXYDICARBONATE ≥ 10 OP7 ≤ 52 as a paste " ≥ 10 ≤ 100 " DICUMYL PEROXIDE ≥ 45 ≥ 23 ≤ 52 ≤ 91 " ≤ 42 as a stable dispersion in water 3102 3) OP7 3106 20) Exempt 29) 3110 12) Exempt 29) 3) OP8 ≥ 48 > 91 - 100 " OP5 ≥ 68 > 52 - 100 ≥9 20) OP3 +10 +15 3112 OP5 +10 +15 3114 OP8 +15 +20 3119 Copyright © United Nations, 2010. All rights reserved ORGANIC PEROXIDE Concentration (%) DIDECANOYL PEROXIDE ≤ 100 2,2-DI-(4,4-DI (tert-BUTYLPEROXY) CYCLOHEXYL) PROPANE ≤ 42 " DI-2,4-DICHLOROBENZOYL PEROXIDE Diluent type A (%) Diluent type B (%) 1) Inert solid (%) Water ≥ 58 ≤ 22 ≥ 78 ≤ 77 ≥ 23 Packing Method Control temperature (°C) Emergency temperature (°C) Number (Generic entry) OP6 +30 +35 3114 OP7 3106 OP8 3107 OP5 3102 " ≤ 52 as a paste OP8 " ≤ 52 as a paste with silicon oil OP7 DI-(2-ETHOXYETHYL) PEROXYDICARBONATE DI-(2-ETHYLHEXYL) PEROXYDICARBONATE ≤ 52 ≥ 48 > 77 – 100 + 25 3106 OP7 -10 0 3115 OP5 -20 -10 3113 OP7 -15 -5 3115 - 189 - ≤ 77 " ≤ 62 as a stable dispersion in water OP8 -15 -5 3119 " ≤ 52 as a stable dispersion in water (frozen) OP8 -15 -5 3120 ≤ 27 DI-(1-HYDROXYCYCLOHEXYL) PEROXIDE ≤ 100 DIISOBUTYRYL PEROXIDE " DIISOPROPYLBENZENE DIHYDROPEROXIDE DIISOPROPYL PEROXYDICARBONATE OP7 3106 OP5 -20 -10 3111 ≤ 32 ≥ 68 OP7 -20 -10 3115 ≤ 82 ≥5 ≥5 > 52-100 " ≤ 28 DI-(3-METHOXYBUTYL) PEROXYDICARBONATE 3102 ≥ 48 ≤ 52 " OP5 > 32 – 52 " DILAUROYL PEROXIDE ≥ 73 ≥ 48 ≥ 72 OP7 3) OP2 -15 -5 3112 OP7 -20 -10 3115 OP7 -15 -5 3115 3106 ≤ 42 as a stable dispersion in water OP8 3109 OP7 -5 +5 3) 24) OP7 ≥ 48 3) 3106 ≤ 100 ≤ 52 3) 3118 " 2,2-DIHYDROPEROXYPROPANE ≥ 23 + 20 Subsidiary risks and remarks 3115 Copyright © United Nations, 2010. All rights reserved ORGANIC PEROXIDE DI-(2-METHYLBENZOYL) PEROXIDE DI-(3-METHYLBENZOYL) PEROXIDE + BENZOYL (3-METHYLBENZOYL) PEROXIDE + DIBENZOYL PEROXIDE DI-(4-METHYLBENZOYL) PEROXIDE 2,5-DIMETHYL-2,5-DI(BENZOYLPEROXY)HEXANE Concentration (%) Diluent type B (%) 1) Inert solid (%) ≤ 87 ≤ 20 + ≤ 18 + ≤ 4 Water Packing Method Control temperature (°C) Emergency temperature (°C) Number (Generic entry) ≥ 13 OP5 +30 +35 3112 OP7 +35 +40 3115 ≥ 58 - 190 - ≤ 52 as a paste with silicon oil OP7 3106 > 82-100 OP5 3102 OP7 3106 OP5 3104 OP5 3103 OP7 3105 OP8 3108 OP8 3109 " ≤ 82 " ≤ 82 2,5-DIMETHYL-2,5-DI(tert-BUTYLPEROXY)HEXANE Diluent type A (%) ≥ 18 ≥ 18 > 90 - 100 3) 3) " > 52 - 90 " ≤ 77 " ≤ 52 " ≤ 47 as a paste OP8 3108 > 86-100 OP5 3101 3) OP5 3103 26) OP7 3106 2,5-DIMETHYL-2,5-DI(tert-BUTYLPEROXY)HEXYNE-3 " >52-86 " ≤ 52 2,5-DIMETHYL-2,5-DI(2-ETHYLHEXANOYLPEROXY)HEXANE ≤ 100 2,5-DIMETHYL-2,5-DIHYDROPEROXYHEXANE ≤ 82 2,5-DIMETHYL-2,5-DI-(3,5,5TRIMETHYLHEXANOYLPEROXY)HEXANE ≤ 77 1,1-DIMETHYL-3-HYDROXYBUTYL PEROXYNEOHEPTANOATE ≤ 52 DIMYRISTYL PEROXYDICARBONATE " ≥ 10 Subsidiary risks and remarks ≥ 23 ≥ 48 ≥ 14 ≥ 48 OP5 ≥ 18 +20 +25 3113 OP6 3104 ≥ 23 OP7 3105 ≥ 48 OP8 0 +10 3117 ≤ 100 OP7 +20 +25 3116 ≤ 42 as a stable dispersion in water OP8 +20 +25 3119 Copyright © United Nations, 2010. All rights reserved ORGANIC PEROXIDE Packing Method Control temperature (°C) Emergency temperature (°C) Number (Generic entry) OP7 -10 0 3115 ≤ 100 OP7 0 +10 3116 ≤ 100 OP5 +10 +15 3114 >85-100 OP5 3102 OP7 3106 Concentration (%) Diluent type A (%) DI-(2-NEODECANOYLPEROXYISOPROPYL) BENZENE ≤ 52 ≥ 48 DI-n-NONANOYL PEROXIDE DI-n-OCTANOYL PEROXIDE DI-(2-PHENOXYETHYL) PEROXYDICARBONATE " ≤ 27 DI-n-PROPYL PEROXYDICARBONATE ≤ 100 DISUCCINIC ACID PEROXIDE " DI-(3,5,5-TRIMETHYLHEXANOYL) PEROXIDE Inert solid (%) ≤ 85 DIPROPIONYL PEROXIDE " Diluent type B (%) 1) Water ≥ 15 ≥ 73 ≤ 77 ≥ 23 > 72-100 +15 +20 3117 OP3 -25 -15 3113 OP5 -20 -10 3113 OP4 ≤ 72 > 38-82 OP8 ≥ 28 ≥ 18 3102 - 191 - OP7 +10 +15 3116 OP7 0 +10 3115 OP8 +10 +15 3119 +20 +25 3119 " ≤ 52 as a stable dispersion in water " ≤ 38 ≥ 62 OP8 ETHYL 3,3-DI-(tert-AMYLPEROXY)BUTYRATE ≤ 67 ≥ 33 OP7 3105 ETHYL 3,3-DI-(tert-BUTYLPEROXY)BUTYRATE > 77 - 100 OP5 3103 OP7 3105 OP7 3106 " ≤ 77 " ≤ 52 ≥ 23 ≥ 48 1-(2-ETHYLHEXANOYLPEROXY)-1,3DIMETHYLBUTYL PEROXYPIVALATE ≤ 52 ≥ 45 tert-HEXYL PEROXYNEODECANOATE ≤ 71 ≥ 29 tert-HEXYL PEROXYPIVALATE ≤ 72 3-HYDROXY-1,1-DIMETHYLBUTYL PEROXYNEODECANOATE ≤ 77 " ≤ 52 " ≤ 52 as a stable dispersion in water ≥ 10 OP7 -20 -10 3115 OP7 0 +10 3115 OP7 +10 +15 3115 ≥ 23 OP 7 -5 +5 3115 ≥ 48 OP 8 -5 +5 3117 OP 8 -5 +5 3119 ≥ 28 Subsidiary risks and remarks 3) 3) 17) Copyright © United Nations, 2010. All rights reserved ORGANIC PEROXIDE ISOPROPYL sec-BUTYL PEROXYDICARBONATE +DI-sec-BUTYL PEROXYDICARBONATE +DI-ISOPROPYL PEROXYDICARBONATE " ISOPROPYLCUMYL HYDROPEROXIDE p-MENTHYL HYDROPEROXIDE " METHYLCYCLOHEXANONE PEROXIDE(S) METHYL ETHYL KETONE PEROXIDE(S) Concentration (%) ≤ 32 + ≤ 15 – 18 ≤ 12 – 15 Diluent type A (%) Diluent type B (%) 1) ≥ 38 ≤ 52 + ≤ 28 + ≤ 22 ≤ 72 ≥ 28 > 72 - 100 ≤ 72 ≥ 28 ≤ 67 ≥ 33 Inert solid (%) Water Packing Method Control temperature (°C) Emergency temperature (°C) Number (Generic entry) OP7 -20 -10 3115 OP5 -20 -10 3111 3) OP8 3109 13) OP7 3105 13) OP8 3109 27) OP7 +35 +40 Subsidiary risks and remarks 3115 - 192 - see remark 8) ≥ 48 OP5 3101 3) 8) 13) " see remark 9) ≥ 55 OP7 3105 9) " see remark 10) ≥ 60 OP8 3107 10) METHYL ISOBUTYL KETONE PEROXIDE(S) ≤ 62 ≥ 19 OP7 3105 22) METHYL ISOPROPYL KETONE PEROXIDE(S) see remark 31) ≥ 70 OP8 3109 31) ORGANIC PEROXIDE, LIQUID, SAMPLE OP2 3103 11) ORGANIC PEROXIDE, LIQUID, SAMPLE, TEMPERATURE CONTROLLED OP2 3113 11) ORGANIC PEROXIDE, SOLID, SAMPLE OP2 3104 11) ORGANIC PEROXIDE, SOLID, SAMPLE, TEMPERATURE CONTROLLED OP2 3114 11) 3,3,5,7,7-PENTAMETHYL-1,2,4-TRIOXEPANE ≤ 100 OP8 3107 PEROXYACETIC ACID, TYPE D, stabilized ≤ 43 OP7 3105 13) 14) 19) PEROXYACETIC ACID, TYPE E, stabilized ≤ 43 OP8 3107 13) 15) 19) PEROXYACETIC ACID, TYPE F, stabilized ≤ 43 OP8 3109 13) 16) 19) PEROXYLAURIC ACID ≤ 100 OP8 > 56 – 100 OP7 3105 OP8 3109 OP8 3107 PINANYL HYDROPEROXIDE " POLYETHER POLY-tert-BUTYLPEROXYCARBONATE ≤ 56 ≤ 52 ≥ 44 ≥ 48 +35 +40 3118 13) Copyright © United Nations, 2010. All rights reserved ORGANIC PEROXIDE Concentration (%) Diluent type A (%) Diluent type B (%) 1) Inert solid (%) Water Packing Method Control temperature (°C) Emergency temperature (°C) Number (Generic entry) 1,1,3,3-TETRAMETHYLBUTYL HYDROPEROXIDE ≤ 100 OP7 1,1,3,3-TETRAMETHYLBUTYL PEROXY-2ETHYLHEXANOATE ≤ 100 OP7 +15 +20 3115 1,1,3,3- TETRAMETHYLBUTYL PEROXYNEODECANOATE ≤ 72 OP7 -5 +5 3115 OP8 -5 +5 3119 0 +10 3115 " ≥ 28 ≤ 52 as a stable dispersion in water 1,1,3,3-TETRAMETHYLBUTYL PEROXYPIVALATE ≤ 77 ≥ 23 OP7 3,6,9-TRIETHYL-3,6,9-TRIMETHYL -1,4,7 TRIPEROXONANE ≤ 42 ≥ 58 OP7 Subsidiary risks and remarks 3105 3105 28) - 193 - Copyright © United Nations, 2010. All rights reserved Remarks (refer to the last column of the Table in 2.2.52.4): 1) Diluent type B may always be replaced by diluent type A. The boiling point of diluent type B shall be at least 60°C higher than the SADT of the organic peroxide. 2) Available oxygen ≤ 4.7%. 3) "EXPLOSIVE" subsidiary risk label required (Model No.1, see 5.2.2.2.2). 4) Diluent may be replaced by di-tert-butyl peroxide. 5) Available oxygen ≤ 9%. 6) With ≤ 9% hydrogen peroxide; available oxygen ≤ 10%. 7) Only non-metallic packagings allowed. 8) Available oxygen > 10% and ≤ 10.7%, with or without water. 9) Available oxygen ≤ 10% , with or without water. 10) Available oxygen ≤ 8.2% , with or without water. 11) See 2.2.52.1.9. 12) Up to 2000 kg per receptacle assigned to ORGANIC PEROXIDE TYPE F on the basis of large scale trials. 13) "CORROSIVE" subsidiary risk label required (Model No.8, see 5.2.2.2.2). 14) Peroxyacetic acid formulations which fulfil the criteria of the Manual of Tests and Criteria, paragraph 20.4.3 (d). 15) Peroxyacetic acid formulations which fulfil the criteria of the Manual of Tests and Criteria, paragraph 20.4.3 (e). 16) Peroxyacetic acid formulations which fulfil the criteria of the Manual of Tests and Criteria, paragraph 20.4.3 (f). 17) Addition of water to this organic peroxide will decrease its thermal stability. 18) No "CORROSIVE" subsidiary risk label (Model No.8, see 5.2.2.2.2) required for concentrations below 80%. 19) Mixtures with hydrogen peroxide, water and acid(s). 20) With diluent type A, with or without water. 21) With ≥ 25% diluent type A by mass, and in addition ethylbenzene. 22) With ≥ 19%, diluent type A by mass, and in addition methyl isobutyl ketone. 23) With < 6% di-tert-butyl peroxide. 24) With ≤ 8% 1-isopropylhydroperoxy-4-isopropylhydroxybenzene. 25) Diluent type B with boiling point > 110 °C. 26) With < 0.5% hydroperoxides content. 27) For concentrations more than 56%, "CORROSIVE" subsidiary risk label required (Model No.8, see 5.2.2.2.2). 28) Available active oxygen ≤ 7.6% in diluent type A having a 95% boil-off point in the range of 200 - 260 °C. 29) Not subject to the requirements of ADR for Class 5.2. 30) Diluent type B with boiling point > 130 °C. 31) Active oxygen ≤ 6.7%. - 194 - Copyright © United Nations, 2010. All rights reserved 2.2.61 Class 6.1 Toxic substances 2.2.61.1 Criteria 2.2.61.1.1 The heading of Class 6.1 covers substances of which it is known by experience or regarding which it is presumed from experiments on animals that in relatively small quantities they are able by a single action or by action of short duration to cause damage to human health, or death, by inhalation, by cutaneous absorption or by ingestion. NOTE: Genetically modified microorganisms and organisms shall be assigned to this Class if they meet the conditions for this Class. 2.2.61.1.2 Substances of Class 6.1 are subdivided as follows: T Toxic substances without subsidiary risk: T1 T2 T3 T4 T5 T6 T7 T8 T9 TF Organic, liquid; Organic, solid; Organometallic substances; Inorganic, liquid; Inorganic, solid; Liquid, used as pesticides; Solid, used as pesticides; Samples; Other toxic substances; Toxic substances, flammable: TF1 Liquid; TF2 Liquid, used as pesticides; TF3 Solid; TS Toxic substances, self-heating, solid; TW Toxic substances, which, in contact with water, emit flammable gases: TW1 Liquid; TW2 Solid; TO Toxic substances, oxidizing: TO1 Liquid; TO2 Solid; TC Toxic substances, corrosive: TC1 TC2 TC3 TC4 Organic, liquid; Organic, solid; Inorganic, liquid; Inorganic, solid; TFC Toxic substances, flammable, corrosive; TFW Toxic substances, flammable, which, in contact with water, emit flammable gases. - 195 - Copyright © United Nations, 2010. All rights reserved Definitions 2.2.61.1.3 For the purposes of ADR: LD50 (median lethal dose) for acute oral toxicity is the statistically derived single dose of a substance that can be expected to cause death within 14 days in 50 per cent of young adult albino rats when administered by the oral route. The LD50 value is expressed in terms of mass of test substance per mass of test animal (mg/kg); LD50 for acute dermal toxicity is that dose of the substance which, administered by continuous contact for 24 hours with the bare skin of albino rabbits, is most likely to cause death within 14 days in one half of the animals tested. The number of animals tested shall be sufficient to give a statistically significant result and be in conformity with good pharmacological practice. The result is expressed in milligrams per kg body mass; LC50 for acute toxicity on inhalation is that concentration of vapour, mist or dust which, administered by continuous inhalation to both male and female young adult albino rats for one hour, is most likely to cause death within 14 days in one half of the animals tested. A solid substance shall be tested if at least 10% (by mass) of its total mass is likely to be dust in a respirable range, e.g. the aerodynamic diameter of that particle-fraction is 10 µm or less. A liquid substance shall be tested if a mist is likely to be generated in a leakage of the transport containment. Both for solid and liquid substances more than 90% (by mass) of a specimen prepared for inhalation toxicity shall be in the respirable range as defined above. The result is expressed in milligrams per litre of air for dusts and mists or in millilitres per cubic metre of air (parts per million) for vapours. Classification and assignment of packing groups 2.2.61.1.4 Substances of Class 6.1 shall be classified in three packing groups according to the degree of danger they present for carriage, as follows: Packing group I: Packing group II: Packing group III: highly toxic substances toxic substances slightly toxic substances. 2.2.61.1.5 Substances, mixtures, solutions and articles classified in Class 6.1 are listed in Table A of Chapter 3.2. The assignment of substances, mixtures and solutions not mentioned by name in Table A of Chapter 3.2 to the relevant entry of sub-section 2.2.61.3 and to the relevant packing group in accordance with the provisions of Chapter 2.1, shall be made according to the following criteria in 2.2.61.1.6 to 2.2.61.1.11. 2.2.61.1.6 To assess the degree of toxicity, account shall be taken of human experience of instances of accidental poisoning, as well as special properties possessed by any individual substances: liquid state, high volatility, any special likelihood of cutaneous absorption, and special biological effects. - 196 - Copyright © United Nations, 2010. All rights reserved 2.2.61.1.7 In the absence of observations on humans, the degree of toxicity shall be assessed using the available data from animal experiments in accordance with the table below: I Oral toxicity LD50 (mg/kg) ≤5 Dermal toxicity LD50 (mg/kg) ≤ 50 Inhalation toxicity by dusts and mists LC50 (mg/l) ≤ 0.2 II III a > 5 and ≤ 50 > 50 and ≤ 300 > 50 and ≤ 200 > 200 and ≤ 1 000 > 0.2 and ≤ 2 > 2 and ≤ 4 Packing group Highly toxic Toxic Slightly toxic a Tear gas substances shall be included in packing group II even if data concerning their toxicity correspond to packing group III criteria. 2.2.61.1.7.1 Where a substance exhibits different degrees of toxicity for two or more kinds of exposure, it shall be classified under the highest such degree of toxicity. 2.2.61.1.7.2 Substances meeting the criteria of Class 8 and with an inhalation toxicity of dusts and mists (LC50) leading to packing group I shall only be accepted for an allocation to Class 6.1 if the toxicity through oral ingestion or dermal contact is at least in the range of packing groups I or II. Otherwise an assignment to Class 8 shall be made if appropriate (see 2.2.8.1.5). 2.2.61.1.7.3 The criteria for inhalation toxicity of dusts and mists are based on LC50 data relating to 1-hour exposure, and where such information is available it shall be used. However, where only LC50 data relating to 4-hour exposure are available, such figures can be multiplied by four and the product substituted in the above criteria, i.e. LC50 value multiplied by four (4 hour) is considered the equivalent of LC50 (1 hour). Inhalation toxicity of vapours 2.2.61.1.8 Liquids giving off toxic vapours shall be classified into the following groups where "V" is the saturated vapour concentration (in ml/m3 of air) (volatility) at 20 °C and standard atmospheric pressure: Highly toxic Toxic Slightly toxic a Packing group I Where V ≥ 10 LC50 and LC50 ≤ 1 000 ml/m3 II Where V ≥ LC50 and LC50 ≤ 3 000 ml/m3 and the criteria for packing group I are not met IIIa Where V ≥ 1/5 LC50 and LC50 ≤ 5 000 ml/m3 and the criteria for packing groups I and II are not met Tear gas substances shall be included in packing group II even if data concerning their toxicity correspond to packing group III criteria. These criteria for inhalation toxicity of vapours are based on LC50 data relating to 1-hour exposure, and where such information is available, it shall be used. However, where only LC50 data relating to 4-hour exposure to the vapours are available, such figures can be multiplied by two and the product substituted in the above criteria, i.e. LC50 (4 hour) × 2 is considered the equivalent of LC50 (1 hour). - 197 - Copyright © United Nations, 2010. All rights reserved In this figure, the criteria are expressed in graphical form, as an aid to easy classification. However, due to approximations inherent in the use of graphs, substances falling on or near group borderlines shall be checked using numerical criteria. GROUP BORDERLINES INHALATION TOXICITY OF VAPOURS 10.000 NOT DANGEROUS FOR TRANSPORT PACKING GROUP III PACKING GROUP II LC50 ml/m3 1.000 PACKING GROUP I 100 10 10 100 1.000 3 Volatility ml/m - 198 - 10.000 100.000 Copyright © United Nations, 2010. All rights reserved Mixtures of liquids 2.2.61.1.9 Mixtures of liquids which are toxic on inhalation shall be assigned to packing groups according to the following criteria: 2.2.61.1.9.1 If LC50 is known for each of the toxic substances constituting the mixture, the packing group may be determined as follows: (a) calculation of the LC50 of the mixture: LC 50 (mixture) = where fi = LC50i = (b) molar fraction of constituent i of the mixture; average lethal concentration of constituent i in ml/m3. calculation of volatility of each mixture constituent: Vi = Pi × where (c) 1 f ∑ i i =1 LC 50 i 1 Pi = 10 6 (ml/m 3 ) 101.3 partial pressure of constituent i in kPa at 20 °C and at standard atmospheric pressure. calculation of the ratio of volatility to LC50: Vi i = 1 LC 50i n R= ∑ (d) 2.2.61.1.9.2 the values calculated for LC50 (mixture) and R are then used to determine the packing group of the mixture: Packing group I R ≥ 10 and LC50 (mixture) ≤ 1 000 ml/m3; Packing group II R ≥ 1 and LC50 (mixture) ≤ 3 000 ml/m3, if the mixture does not meet the criteria for packing group I; Packing group III R ≥ 1/5 and LC50 (mixture) ≤ 5 000 ml/m3, if the mixture does not meet the criteria of packing groups I or II. In the absence of LC50 data on the toxic constituent substances, the mixture may be assigned to a group based on the following simplified threshold toxicity tests. When these threshold tests are used, the most restrictive group shall be determined and used for carrying the mixture. - 199 - Copyright © United Nations, 2010. All rights reserved 2.2.61.1.9.3 2.2.61.1.9.4 2.2.61.1.9.5 A mixture is assigned to packing group I only if it meets both of the following criteria: (a) A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 1 000 ml/m3 vaporized mixture in air. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have an LC50 equal to or less than 1 000 ml/m3; (b) A sample of vapour in equilibrium with the liquid mixture is diluted with 9 equal volumes of air to form a test atmosphere. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have a volatility equal to or greater than 10 times the mixture LC50. A mixture is assigned to packing group II only if it meets both of the following criteria, and does not meet the criteria for packing group I: (a) A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 3 000 ml/m3 vaporized mixture in air. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have an LC50 equal to or less than 3 000 ml/m3; (b) A sample of the vapour in equilibrium with the liquid mixture is used to form a test atmosphere. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have a volatility equal to or greater than the mixture LC50. A mixture is assigned to packing group III only if it meets both of the following criteria, and does not meet the criteria for packing groups I or II: (a) A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 5 000 ml/m3 vaporized mixture in air. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have an LC50 equal to or less than 5 000 ml/m3; (b) The vapour concentration (volatility) of the liquid mixture is measured and if the vapour concentration is equal to or greater than 1 000 ml/m3, the mixture is presumed to have a volatility equal to or greater than 1/5 the mixture LC50. Methods for determining oral and dermal toxicity of mixtures 2.2.61.1.10 When classifying and assigning the appropriate packing group to mixtures in Class 6.1 in accordance with the oral and dermal toxicity criteria (see 2.2.61.1.3), it is necessary to determine the acute LD50 of the mixture. 2.2.61.1.10.1 If a mixture contains only one active substance, and the LD50 of that constituent is known, in the absence of reliable acute oral and dermal toxicity data on the actual mixture to be carried, the oral or dermal LD50 may be obtained by the following method: LD 50 value of preparation = LD 50 value of active substance × 100 percentage of active substance by mass - 200 - Copyright © United Nations, 2010. All rights reserved 2.2.61.1.10.2 If a mixture contains more than one active constituent, there are three possible approaches that may be used to determine the oral or dermal LD50 of the mixture. The preferred method is to obtain reliable acute oral and dermal toxicity data on the actual mixture to be carried. If reliable, accurate data are not available, then either of the following methods may be performed: (a) Classify the formulation according to the most hazardous constituent of the mixture as if that constituent were present in the same concentration as the total concentration of all active constituents; or (b) Apply the formula: CA CB C 100 + + ... + Z = TA TB TZ TM where: C = the percentage concentration of constituent A, B, ..., Z in the mixture; T = the oral LD50 values of constituent A, B, ... Z; TM = the oral LD50 value of the mixture. NOTE: This formula can also be used for dermal toxicities provided that this information is available on the same species for all constituents. The use of this formula does not take into account any potentiation or protective phenomena. Classification of pesticides 2.2.61.1.11 All active pesticide substances and their preparations for which the LC50 and/or LD50 values are known and which are classified in Class 6.1 shall be classified under appropriate packing groups in accordance with the criteria given in 2.2.61.1.6 to 2.2.61.1.9. Substances and preparations which are characterized by subsidiary risks shall be classified according to the precedence of hazard Table in 2.1.3.10 with the assignment of appropriate packing groups. 2.2.61.1.11.1 If the oral or dermal LD50 value for a pesticide preparation is not known, but the LD50 value of its active substance(s) is known, the LD50 value for the preparation may be obtained by applying the procedures in 2.2.61.1.10. NOTE: LD50 toxicity data for a number of common pesticides may be obtained from the most current edition of the document "The WHO Recommended Classification of Pesticides by Hazard and Guidelines to Classification" available from the International Programme on Chemical Safety, World Health Organisation (WHO), 1211 Geneva 27, Switzerland. While that document may be used as a source of LD50 data for pesticides, its classification system shall not be used for purposes of transport classification of, or assignment of packing groups to, pesticides, which shall be in accordance with the requirements of ADR. 2.2.61.1.11.2 The proper shipping name used in the carriage of the pesticide shall be selected on the basis of the active ingredient, of the physical state of the pesticide and any subsidiary risks it may exhibit (see 3.1.2). - 201 - Copyright © United Nations, 2010. All rights reserved 2.2.61.1.12 If substances of Class 6.1, as a result of admixtures, come into categories of risk different from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also 2.1.3. 2.2.61.1.13 On the basis of the criteria of 2.2.61.1.6 to 2.2.61.1.11, it may also be determined whether the nature of a solution or mixture mentioned by name or containing a substance mentioned by name is such that the solution or mixture is not subject to the requirements for this Class. 2.2.61.1.14 Substances, solutions and mixtures, with the exception of substances and preparations used as pesticides, which do not meet the criteria of Directives 67/548/EEC 3 or 1999/45/EC 4 as amended and which are not therefore classified as highly toxic, toxic or harmful according to these directives, as amended, may be considered as substances not belonging to Class 6.1. 2.2.61.2 Substances not accepted for carriage 2.2.61.2.1 Chemically unstable substances of Class 6.1 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end, it shall in particular be ensured that receptacles and tanks do not contain any substance(s) likely to cause such a reaction. 2.2.61.2.2 The following substances and mixtures shall not be accepted for carriage: - Hydrogen cyanide, anhydrous or in solution, which do not meet the descriptions of UN Nos. 1051, 1613, 1614 and 3294; - metal carbonyls, having a flash-point below 23 °C, other than UN Nos. 1259 NICKEL CARBONYL and 1994 IRON PENTACARBONYL; - 2,3,7,8-TETRACHLORODIBENZO-P-DIOXINE (TCDD) in considered highly toxic in accordance with the criteria in 2.2.61.1.7; - UN No. 2249 DICHLORODIMETHYL ETHER, SYMMETRICAL; - preparations of phosphides without additives inhibiting the emission of toxic flammable gases. concentrations Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances (Official Journal of the European Communities No. L 196 of 16.08.1967). 4 Directive 1999/45/EC of the European Parliament and of the Council of 31 May 1999 on the approximation of laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations (Official Journal of the European Communities No. L 200 of 30 July 1999). - 202 3 Copyright © United Nations, 2010. All rights reserved 2.2.61.3 List of collective entries Toxic substances without subsidiary risk(s) liquid a T1 Organic solid a, b Organometallic c, d T2 T3 1583 1602 1602 1693 1851 2206 2206 3140 3140 3142 3144 3144 3172 3276 3278 3381 CHLOROPICRIN MIXTURE, N.O.S. DYE, LIQUID, TOXIC, N.O.S., or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. TEAR GAS SUBSTANCE, LIQUID, N.O.S. MEDICINE, LIQUID, TOXIC, N.O.S. ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S. DISINFECTANT, LIQUID, TOXIC, N.O.S. NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. NITRILES, TOXIC, LIQUID, N.O.S ORGANOPHOSPHORUS COMPOUND, TOXIC, LIQUID, N.O.S. TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3382 TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 2810 TOXIC LIQUID, ORGANIC, N.O.S. 1544 1544 1601 1655 1655 3448 3143 3143 3462 3249 3464 3439 2811 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. DISINFECTANT, SOLID, TOXIC, N.O.S. NICOTINE COMPOUND, SOLID, N.O.S., or NICOTINE PREPARATION, SOLID, N.O.S. TEAR GAS SUBSTANCE, SOLID, N.O.S. DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. MEDICINE, SOLID, TOXIC, N.O.S. ORGANOPHOSPHORUS COMPOUND, TOXIC, SOLID, N.O.S. NITRILES, TOXIC, SOLID, N.O.S. TOXIC SOLID, ORGANIC, N.O.S. 2026 2788 3146 3280 3465 3281 3466 3282 3467 PHENYLMERCURIC COMPOUND, N.O.S. ORGANOTIN COMPOUND, LIQUID, N.O.S. ORGANOTIN COMPOUND, SOLID, N.O.S. ORGANOARSENIC COMPOUND, LIQUID, N.O.S. ORGANOARSENIC COMPOUND, SOLID, N.O.S. METAL CARBONYLS, LIQUID, N.O.S. METAL CARBONYLS, SOLID, N.O.S. ORGANOMETALLIC COMPOUND, TOXIC, LIQUID, N.O.S. ORGANOMETALLIC COMPOUND, TOXIC, SOLID, N.O.S. (cont'd on next page) Substances and preparations containing alkaloids or nicotine used as pesticides shall be classified under UN No. 2588 PESTICIDES, SOLID, TOXIC, N.O.S., UN No. 2902 PESTICIDES, LIQUID, TOXIC, N.O.S. or UN No. 2903 PESTICIDES, LIQUID, TOXIC, FLAMMABLE, N.O.S. a Active substances and triturations or mixtures of substances intended for laboratories and experiments and for the manufacture of pharmaceutical products with other substances shall be classified according to their toxicity (see 2.2.61.1.7 to 2.2.61.1.11). b Self-heating substances, slightly toxic and spontaneously combustible organometallic compounds, are substances of Class 4.2. c Water-reactive substances, slightly toxic, and water-reactive organometallic compounds, are substances of Class 4.3. d - 203 - Copyright © United Nations, 2010. All rights reserved 2.2.61.3 List of collective entries (cont'd) Toxic substances without subsidiary risk(s) (cont'd) liquid e T4 Inorganic solids f, g T5 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1935 CYANIDE SOLUTION, N.O.S. 2024 MERCURY COMPOUND, LIQUID, N.O.S. 3141 ANTIMONY COMPOUND, INORGANIC, LIQUID, N.O.S. 3440 SELENIUM COMPOUND, LIQUID, N.O.S. 3381 TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3382 TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 3287 TOXIC LIQUID, INORGANIC, N.O.S. 1549 ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S 1557 ARSENIC COMPOUND, SOLID, N.O.S., including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1564 BARIUM COMPOUND, N.O.S. 1566 BERYLLIUM COMPOUND, N.O.S. 1588 CYANIDES, INORGANIC, SOLID, N.O.S. 1707 THALLIUM COMPOUND, N.O.S. 2025 MERCURY COMPOUND, SOLID, N.O.S. 2291 LEAD COMPOUND, SOLUBLE, N.O.S. 2570 CADMIUM COMPOUND 2630 SELENATES or 2630 SELENITES 2856 FLUOROSILICATES, N.O.S. 3283 SELENIUM COMPOUND, SOLID, N.O.S. 3284 TELLURIUM COMPOUND, N.O.S. 3285 VANADIUM COMPOUND, N.O.S. 3288 TOXIC SOLID, INORGANIC, N.O.S. 2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 3010 COPPER BASED PESTICIDE, LIQUID, TOXIC 3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC liquidh T6 3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC 3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC 3348 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC 3352 PYRETHROID PESTICIDE, LIQUID, TOXIC Pesticides 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. (cont'd on next page) Mercury fulminate, wetted with not less than 20% water, or mixture of alcohol and water by mass is a substance of Class 1, UN No. 0135. e Ferricyanides, ferrocyanides, alkaline thiocyanates and ammonium thiocyanates are not subject to the provisions of ADR. f Lead salts and lead pigments which, when mixed in a ratio of 1:1,000 with 0.07M hydrochloric acid and stirred for one hour at a temperature of 23 °C ± 2 °C, exhibit a solubility of 5% or less, are not subject to the provisions of ADR. g Articles impregnated with this pesticide, such as fibreboard plates, paper strips, cotton-wool balls, sheets of plastics material, in hermetically closed wrappings, are not subject to the provisions of ADR. - 204 - h Copyright © United Nations, 2010. All rights reserved 2.2.61.3 List of collective entries (cont'd) Toxic substances without subsidiary risk(s) (cont'd) Pesticides (cont'd) Solidh Samples Other toxic substances i T7 2757 2759 2761 2763 2771 2775 2777 2779 2781 2783 2786 3027 3048 3345 3349 2588 CARBAMATE PESTICIDE, SOLID, TOXIC ARSENICAL PESTICIDE, SOLID, TOXIC ORGANOCHLORINE PESTICIDE, SOLID, TOXIC TRIAZINE PESTICIDE, SOLID, TOXIC THIOCARBAMATE PESTICIDE, SOLID, TOXIC COPPER BASED PESTICIDE, SOLID, TOXIC MERCURY BASED PESTICIDE, SOLID, TOXIC SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC BIPYRIDILIUM PESTICIDE, SOLID, TOXIC ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC ORGANOTIN PESTICIDE, SOLID, TOXIC COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC ALUMINIUM PHOSPHIDE PESTICIDE PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC PYRETHROID PESTICIDE, SOLID, TOXIC PESTICIDE, SOLID, TOXIC, N.O.S. T8 3315 CHEMICAL SAMPLE, TOXIC T9 3243 SOLIDS CONTAINING TOXIC LIQUID, N.O.S. Toxic substances with subsidiary risk(s) Liquid j, k Flammable TF TF1 3071 3071 3080 3080 3275 3279 3383 MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. ISOCYANATES, TOXIC, FLAMMABLE, N.O.S. or ISOCYANATE SOLUTION, TOXIC, FLAMMABLE, N.O.S. NITRILES, TOXIC, FLAMMABLE, N.O.S. ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3384 TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. (cont'd on next page) Articles impregnated with this pesticide, such as fibreboard plates, paper strips, cotton-wool balls, sheets of plastics material, in hermetically closed wrappings, are not subject to the provisions of ADR. h Mixtures of solids which are not subject to the provisions of ADR and of toxic liquids may be carried under UN No. 3243 without first applying the classification criteria of Class 6.1, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, container or transport unit is closed. Each packaging shall correspond to a design type that has passed a leakproofness test at the packing group II level. This entry shall not be used for solids containing a packing group I liquid. i Highly toxic or toxic, flammable liquids having a flash-point below 23 °C excluding substances which are highly toxic on inhalation, i.e. UN Nos. 1051, 1092, 1098, 1143, 1163, 1182, 1185, 1238, 1239, 1244, 1251, 1259, 1613, 1614, 1695, 1994, 2334, 2382, 2407, 2438, 2480, 2482, 2484, 2485, 2606, 2929, 3279 and 3294 are substances of Class 3. j Flammable liquids, slightly toxic, with the exception of substances and preparations used as pesticides, having a flash-point between 23 °C and 60 °C inclusive, are substances of Class 3. k - 205 - Copyright © United Nations, 2010. All rights reserved 2.2.61.3 List of collective entries (cont'd) Toxic substances with subsidiary risk(s) (cont'd) Flammable TF (cont'd) pesticides, liquid TF2 (flashpoint not less than 23 °C) solid TF3 Solid, self-heating c TS Water-reactive d TW Oxidizing l TO 2991 2993 2995 2997 3005 3009 3011 3013 3015 3017 3019 3025 3347 3351 2903 1700 2930 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S. TEAR GAS CANDLES TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 3124 TOXIC SOLID, SELF-HEATING, N.O.S. liquid TW1 3385 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3386 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 3123 TOXIC LIQUID, WATER-REACTIVE, N.O.S. solid n TW2 3125 TOXIC SOLID, WATER-REACTIVE, N.O.S. liquid TO1 3387 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3388 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 3122 TOXIC LIQUID, OXIDIZING, N.O.S. solid TO2 3086 TOXIC SOLID, OXIDIZING, N.O.S. liquid TC1 3277 CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. 3361 CHLOROSILANES, TOXIC, CORROSIVE, N.O.S. 3389 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3390 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 2927 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. solid TC2 2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. organic Corron sive m TC (cont'd on next page) Self-heating substances, slightly toxic and spontaneously combustible organometallic compounds, are substances of Class 4.2. c Water-reactive substances, slightly toxic, and water-reactive organometallic compounds, are substances of Class 4.3. d l Oxidizing substances, slightly toxic, are substances of Class 5.1. m Substances slightly toxic and slightly corrosive, are substances of Class 8. Metal phosphides assigned to UN Nos. 1360, 1397, 1432, 1714, 2011 and 2013 are substances of Class 4.3. - 206 n Copyright © United Nations, 2010. All rights reserved 2.2.61.3 List of collective entries (cont'd) Toxic substances with subsidiary risk(s) (cont'd) Corrosive m TC (cont'd) liquid TC3 solid TC4 inorganic Flammable, corrosive TFC Flammable, water-reactive TFW m 3389 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3390 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 3289 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. 3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. 2742 CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 3362 CHLOROSILANES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 3488 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 3489 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 3492 TOXIC BY INHALATION LIQUID, CORROSIVE, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 3493 TOXIC BY INHALATION LIQUID, CORROSIVE, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 3490 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 3491 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 Substances slightly toxic and slightly corrosive, are substances of Class 8. - 207 - Copyright © United Nations, 2010. All rights reserved 2.2.62 Class 6.2 Infectious substances 2.2.62.1 Criteria 2.2.62.1.1 The heading of Class 6.2 covers infectious substances. For the purposes of ADR, infectious substances are substances which are known or are reasonably expected to contain pathogens. Pathogens are defined as microorganisms (including bacteria, viruses, rickettsiae, parasites, fungi) and other agents such as prions, which can cause disease in humans or animals. NOTE 1: Genetically modified microorganisms and organisms, biological products, diagnostic specimens and infected live animals shall be assigned to this Class if they meet the conditions for this class. NOTE 2: Toxins from plant, animal or bacterial sources which do not contain any infectious substances or organisms or which are not contained in them are substances of Class 6.1, UN Nos. 3172 or 3462. 2.2.62.1.2 Substances of Class 6.2 are subdivided as follows: I1 Infectious substances affecting humans; I2 Infectious substances affecting animals only; I3 Clinical waste; I4 Biological substances. Definitions 2.2.62.1.3 For the purposes of ADR, "Biological products" are those products derived from living organisms which are manufactured and distributed in accordance with the requirements of appropriate national authorities, which may have special licensing requirements, and are used either for prevention, treatment, or diagnosis of disease in humans or animals, or for development, experimental or investigational purposes related thereto. They include, but are not limited to, finished or unfinished products such as vaccines; "Cultures" are the result of a process by which pathogens are intentionally propagated. This definition does not include human or animal patient specimens as defined in this paragraph; "Medical or clinical wastes" are wastes derived from the medical treatment of animals or humans or from bio-research; "Patient specimens" are human or animal materials, collected directly from humans or animals, including, but not limited to, excreta, secreta, blood and its components, tissue and tissue fluid swabs, and body parts being carried for purposes such as research, diagnosis, investigational activities, disease treatment and prevention. Classification 2.2.62.1.4 Infectious substances shall be classified in Class 6.2 and assigned to UN Nos. 2814, 2900, 3291 or 3373, as appropriate. Infectious substances are divided into the following categories: - 208 - Copyright © United Nations, 2010. All rights reserved 2.2.62.1.4.1 Category A: An infectious substance which is carried in a form that, when exposure to it occurs, is capable of causing permanent disability, life-threatening or fatal disease in otherwise healthy humans or animals. Indicative examples of substances that meet these criteria are given in the table in this paragraph. NOTE: An exposure occurs when an infectious substance is released outside of the protective packaging, resulting in physical contact with humans or animals. (a) Infectious substances meeting these criteria which cause disease in humans or both in humans and animals shall be assigned to UN No. 2814. Infectious substances which cause disease only in animals shall be assigned to UN No. 2900; (b) Assignment to UN No. 2814 or UN No. 2900 shall be based on the known medical history and symptoms of the source human or animal, endemic local conditions, or professional judgement concerning individual circumstances of the source human or animal. NOTE 1: The proper shipping name for UN No. 2814 is "INFECTIOUS SUBSTANCE, AFFECTING HUMANS". The proper shipping name for UN No. 2900 is "INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only". NOTE 2: The following table is not exhaustive. Infectious substances, including new or emerging pathogens, which do not appear in the table but which meet the same criteria shall be assigned to Category A. In addition, if there is doubt as to whether or not a substance meets the criteria it shall be included in Category A. NOTE 3: In the following table, the microorganisms written in italics are bacteria, mycoplasmas, rickettsia or fungi. - 209 - Copyright © United Nations, 2010. All rights reserved INDICATIVE EXAMPLES OF INFECTIOUS SUBSTANCES INCLUDED IN CATEGORY A IN ANY FORM UNLESS OTHERWISE INDICATED (2.2.62.1.4.1) UN Number and Microorganism name UN No. 2814 Bacillus anthracis (cultures only) Infectious Brucella abortus (cultures only) substances Brucella melitensis (cultures only) affecting humans Brucella suis (cultures only) Burkholderia mallei - Pseudomonas mallei – Glanders (cultures only) Burkholderia pseudomallei – Pseudomonas pseudomallei (cultures only) Chlamydia psittaci - avian strains (cultures only) Clostridium botulinum (cultures only) Coccidioides immitis (cultures only) Coxiella burnetii (cultures only) Crimean-Congo haemorrhagic fever virus Dengue virus (cultures only) Eastern equine encephalitis virus (cultures only) Escherichia coli, verotoxigenic (cultures only) a Ebola virus Flexal virus Francisella tularensis (cultures only) Guanarito virus Hantaan virus Hantavirus causing haemorrhagic fever with renal syndrome Hendra virus Hepatitis B virus (cultures only) Herpes B virus (cultures only) Human immunodeficiency virus (cultures only) Highly pathogenic avian influenza virus (cultures only) Japanese Encephalitis virus (cultures only) Junin virus Kyasanur Forest disease virus Lassa virus Machupo virus Marburg virus Monkeypox virus Mycobacterium tuberculosis (cultures only) a Nipah virus Omsk haemorrhagic fever virus Poliovirus (cultures only) Rabies virus (cultures only) Rickettsia prowazekii (cultures only) Rickettsia rickettsii (cultures only) Rift Valley fever virus (cultures only) Russian spring-summer encephalitis virus (cultures only) Sabia virus Shigella dysenteriae type 1 (cultures only) a Tick-borne encephalitis virus (cultures only) Variola virus Venezuelan equine encephalitis virus (cultures only) West Nile virus (cultures only) Yellow fever virus (cultures only) Yersinia pestis (cultures only) Nevertheless, when the cultures are intended for diagnostic or clinical purposes, they may be classified as infectious substances of Category B. - 210 - a Copyright © United Nations, 2010. All rights reserved INDICATIVE EXAMPLES OF INFECTIOUS SUBSTANCES INCLUDED IN CATEGORY A IN ANY FORM UNLESS OTHERWISE INDICATED (2.2.62.1.4.1) UN Number Microorganism and name African swine fever virus (cultures only) UN No. 2900 Infectious Avian paramyxovirus Type 1 - Velogenic Newcastle disease virus (cultures only) substances Classical swine fever virus (cultures only) affecting animals Foot and mouth disease virus (cultures only) only Lumpy skin disease virus (cultures only) Mycoplasma mycoides - Contagious bovine pleuropneumonia (cultures only) Peste des petits ruminants virus (cultures only) Rinderpest virus (cultures only) Sheep-pox virus (cultures only) Goatpox virus (cultures only) Swine vesicular disease virus (cultures only) Vesicular stomatitis virus (cultures only) 2.2.62.1.4.2 Category B: An infectious substance which does not meet the criteria for inclusion in Category A. Infectious substances in Category B shall be assigned to UN No. 3373. NOTE: The proper shipping name of UN No. 3373 is "BIOLOGICAL SUBSTANCE, CATEGORY B ". 2.2.62.1.5 Exemptions 2.2.62.1.5.1 Substances which do not contain infectious substances or substances which are unlikely to cause disease in humans or animals are not subject to the provisions of ADR unless they meet the criteria for inclusion in another class. 2.2.62.1.5.2 Substances containing microorganisms which are non-pathogenic to humans or animals are not subject to ADR unless they meet the criteria for inclusion in another class. 2.2.62.1.5.3 Substances in a form that any present pathogens have been neutralized or inactivated such that they no longer pose a health risk are not subject to ADR unless they meet the criteria for inclusion in another class. 2.2.62.1.5.4 Substances where the concentration of pathogens is at a level naturally encountered (including foodstuff and water samples) and which are not considered to pose a significant risk of infection are not subject to ADR unless they meet the criteria for inclusion in another class. 2.2.62.1.5.5 Dried blood spots, collected by applying a drop of blood onto absorbent material, or faecal occult blood screening tests and blood or blood components which have been collected for the purposes of transfusion or for the preparation of blood products to be used for transfusion or transplantation and any tissues or organs intended for use in transplantation are not subject to the provisions of ADR. 2.2.62.1.5.6 Human or animal specimens for which there is minimal likelihood that pathogens are present are not subject to ADR if the specimen is carried in a packaging which will prevent any leakage and which is marked with the words "Exempt human specimen" or "Exempt animal specimen", as appropriate. - 211 - Copyright © United Nations, 2010. All rights reserved The packaging is deemed to comply with the above requirements if it meets the following conditions: (a) The packaging consists of three components: (i) a leak-proof primary receptacle(s); (ii) a leak-proof secondary packaging; and (iii) an outer packaging of adequate strength for its capacity, mass and intended use, and with at least one surface having minimum dimensions of 100 mm × 100 mm; (b) For liquids, absorbent material in sufficient quantity to absorb the entire contents is placed between the primary receptacle(s) and the secondary packaging so that, during carriage, any release or leak of a liquid substance will not reach the outer packaging and will not compromise the integrity of the cushioning material; (c) When multiple fragile primary receptacles are placed in a single secondary packaging, they are either individually wrapped or separated to prevent contact between them. NOTE 1: An element of professional judgment is required to determine if a substance is exempt under this paragraph. That judgment should be based on the known medical history, symptoms and individual circumstances of the source, human or animal, and endemic local conditions. Examples of specimens which may be carried under this paragraph include the blood or urine tests to monitor cholesterol levels, blood glucose levels, hormone levels, or prostate specific antibodies (PSA); those required to monitor organ function such as heart, liver or kidney function for humans or animals with non-infectious diseases, or for therapeutic drug monitoring; those conducted for insurance or employment purposes and are intended to determine the presence of drugs or alcohol; pregnancy test; biopsies to detect cancer; and antibody detection in humans or animals in the absence of any concern for infection (e.g. evaluation of vaccine induced immunity, diagnosis of autoimmune disease, etc.). NOTE 2: For air transport, packagings for specimens exempted under this paragraph shall meet the conditions in (a) to (c). 2.2.62.1.6 to 2.2.62.1.8 2.2.62.1.9 (Reserved) Biological products For the purposes of ADR, biological products are divided into the following groups: (a) those which are manufactured and packaged in accordance with the requirements of appropriate national authorities and carried for the purposes of final packaging or distribution, and use for personal health care by medical professionals or individuals. Substances in this group are not subject to the provisions of ADR; (b) those which do not fall under paragraph (a) and are known or reasonably believed to contain infectious substances and which meet the criteria for inclusion in Category A or Category B. Substances in this group shall be assigned to UN Nos. 2814, 2900 or 3373, as appropriate. NOTE: Some licensed biological products may present a biohazard only in certain parts of the world. In that case, competent authorities may require these biological products to be in compliance with local requirements for infectious substances or may impose other restrictions. - 212 - Copyright © United Nations, 2010. All rights reserved 2.2.62.1.10 Genetically modified microorganisms and organisms Genetically modified microorganisms not meeting the definition of infectious substance shall be classified according to section 2.2.9. 2.2.62.1.11 Medical or clinical wastes 2.2.62.1.11.1 Medical or clinical wastes containing Category A infectious substances shall be assigned to UN No. 2814 or UN No. 2900 as appropriate. Medical or clinical wastes containing infectious substances in Category B shall be assigned to UN No. 3291. NOTE: Medical or clinical wastes assigned to number 18 01 03 (Wastes from human or animal health care and/or related research – wastes from natal care, diagnosis, treatment or prevention of disease in humans – wastes whose collection and disposal is subject to special requirements in order to prevent infection) or 18 02 02 (Wastes from human or animal health care and/or related research – wastes from research, diagnosis, treatment or prevention of disease involving animals – wastes whose collection and disposal is subject to special requirements in order to prevent infection) according to the list of wastes annexed to the Commission Decision 2000/532/EC 5 as amended, shall be classified according to the provisions set out in this paragraph, based on the medical or veterinary diagnosis concerning the patient or the animal. 2.2.62.1.11.2 Medical or clinical wastes which are reasonably believed to have a low probability of containing infectious substances shall be assigned to UN No. 3291. For the assignment, international, regional or national waste catalogues may be taken into account. NOTE 1: The proper shipping name for UN No. 3291 is "CLINICAL WASTE, UNSPECIFIED, N.O.S." or "(BIO) MEDICAL WASTE, N.O.S". or "REGULATED MEDICAL WASTE, N.O.S.". NOTE 2: Notwithstanding the classification criteria set out above, medical or clinical wastes assigned to number 18 01 04 (Wastes from human or animal health care and/or related research – wastes from natal care, diagnosis, treatment or prevention of disease in humans – wastes whose collection and disposal is not subject to special requirements in order to prevent infection) or 18 02 03 (Wastes from human or animal health care and/or related research – wastes from research, diagnosis, treatment or prevention of disease involving animals – wastes whose collection and disposal is not subject to special requirements in order to prevent infection) according to the list of wastes annexed to the Commission Decision 2000/532/EC 5 as amended, are not subject to the provisions of ADR. 2.2.62.1.11.3 Decontaminated medical or clinical wastes which previously contained infectious substances are not subject to the provisions of ADR unless they meet the criteria for inclusion in another class. 2.2.62.1.11.4 Medical or clinical wastes assigned to UN No. 3291 are assigned to packing group II. Commission Decision 2000/532/EC of 3 May 2000 replacing Decision 94/3/EC establishing a list of wastes pursuant to Article 1(a) of Council Directive 75/442/EEC on waste (replaced by the Directive 2006/12/EC of the European Parliament and of the Council (Official Journal of the European Union No. L 114 of 27 April 2006, page 9)) and Council Decision 94/904/EC establishing a list of hazardous waste pursuant to Article 1(4) of Council Directive 91/689/EEC on hazardous waste (Official Journal of the European Communities No. L 226 of 6 September 2000, page 3). - 213 - 5 Copyright © United Nations, 2010. All rights reserved 2.2.62.1.12 Infected animals 2.2.62.1.12.1 Unless an infectious substance cannot be consigned by any other means, live animals shall not be used to consign such a substance. A live animal which has been intentionally infected and is known or suspected to contain an infectious substance shall only be carried under terms and conditions approved by the competent authority 6. 2.2.62.1.12.2 Animal material affected by pathogens of Category A or by pathogens which would be assigned to Category A in cultures only, shall be assigned to UN 2814 or UN 2900 as appropriate. Animal material affected by pathogens of Category B, other than those which would be assigned to Category A if they were in cultures, shall be assigned to UN 3373. 2.2.62.2 Substances not accepted for carriage Live vertebrate or invertebrate animals shall not be used to carry an infectious agent unless the agent cannot be carried by other means or unless this carriage has been approved by the competent authority (see 2.2.62.1.12.1). 2.2.62.3 List of collective entries Effects on humans I1 2814 INFECTIOUS SUBSTANCE, AFFECTING HUMANS Effects on animals only I2 2900 INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only Clinical waste I3 3291 3291 3291 CLINICAL WASTE, UNSPECIFIED, N.O.S. or (BIO) MEDICAL WASTE, N.O.S. or REGULATED MEDICAL WASTE, N.O.S. Biological substances I4 3373 BIOLOGICAL SUBSTANCE, CATEGORY B Regulations governing the carriage of live animals are contained in, e.g. Directive 91/628/EEC of 19 November 1991 on the protection of animals during transport (Official Journal of the European Communities No. L 340 of 11.12.1991, p.17) and in the Recommendations of the Council of Europe (Ministerial Committee) on the carriage of certain animal species. - 214 - 6 Copyright © United Nations, 2010. All rights reserved 2.2.7 Class 7 Radioactive material 2.2.7.1 Definitions 2.2.7.1.1 Radioactive material means any material containing radionuclides where both the activity concentration and the total activity in the consignment exceed the values specified in 2.2.7.2.2.1 to 2.2.7.2.2.6. 2.2.7.1.2 Contamination Contamination means the presence of a radioactive substance on a surface in quantities in excess of 0.4 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 0.04 Bq/cm2 for all other alpha emitters. Non-fixed contamination means contamination that can be removed from a surface during routine conditions of carriage. Fixed contamination means contamination other than non-fixed contamination. 2.2.7.1.3 Definitions of specific terms A1 and A2 A1 means the activity value of special form radioactive material which is listed in the Table in 2.2.7.2.2.1 or derived in 2.2.7.2.2.2 and is used to determine the activity limits for the requirements of ADR. A2 means the activity value of radioactive material, other than special form radioactive material, which is listed in the Table in 2.2.7.2.2.1 or derived in 2.2.7.2.2.2 and is used to determine the activity limits for the requirements of ADR. Fissile nuclides means uranium-233, uranium-235, plutonium-239 and plutonium-241. Fissile material means a material containing any of the fissile nuclides. Excluded from the definition of fissile material are: (a) Natural uranium or depleted uranium which is unirradiated; and (b) Natural uranium or depleted uranium which has been irradiated in thermal reactors only. Low dispersible radioactive material means either a solid radioactive material or a solid radioactive material in a sealed capsule, that has limited dispersibility and is not in powder form. Low specific activity (LSA) material means radioactive material which by its nature has a limited specific activity, or radioactive material for which limits of estimated average specific activity apply. External shielding materials surrounding the LSA material shall not be considered in determining the estimated average specific activity. Low toxicity alpha emitters are: natural uranium; depleted uranium; natural thorium; uranium-235 or uranium-238; thorium-232; thorium-228 and thorium-230 when contained in ores or physical and chemical concentrates; or alpha emitters with a half-life of less than 10 days. - 215 - Copyright © United Nations, 2010. All rights reserved Special form radioactive material means either: (a) An indispersible solid radioactive material; or (b) A sealed capsule containing radioactive material. Specific activity of a radionuclide means the activity per unit mass of that nuclide. The specific activity of a material shall mean the activity per unit mass of the material in which the radionuclides are essentially uniformly distributed. Surface contaminated object (SCO) means a solid object which is not itself radioactive but which has radioactive material distributed on its surfaces. Unirradiated thorium means thorium containing not more than 10-7 g of uranium-233 per gram of thorium-232. Unirradiated uranium means uranium containing not more than 2 × 103 Bq of plutonium per gram of uranium-235, not more than 9 × 106 Bq of fission products per gram of uranium-235 and not more than 5 × 10-3 g of uranium-236 per gram of uranium-235. Uranium - natural, depleted, enriched means the following: Natural uranium means uranium (which may be chemically separated) containing the naturally occurring distribution of uranium isotopes (approximately 99.28% uranium-238, and 0.72% uranium-235 by mass). Depleted uranium means uranium containing a lesser mass percentage of uranium-235 than in natural uranium. Enriched uranium means uranium containing a greater mass percentage of uranium-235 than 0.72%. In all cases, a very small mass percentage of uranium-234 is present. 2.2.7.2 Classification 2.2.7.2.1 General provisions 2.2.7.2.1.1 Radioactive material shall be assigned to one of the UN number specified in Table 2.2.7.2.1.1 depending on the activity level of the radionuclides contained in a package, the fissile or non fissile properties of these radionuclides, the type of package to be presented for carriage, and the nature or form of the contents of the package, or special arrangements governing the carriage operation, in accordance with the provisions laid down in 2.2.7.2.2 to 2.2.7.2.5. - 216 - Copyright © United Nations, 2010. All rights reserved Table 2.2.7.2.1.1 Assignment of UN numbers (1.7.1.5) Excepted packages UN 2908 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - EMPTY PACKAGING UN 2909 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - ARTICLES MANUFACTURED FROM NATURAL URANIUM or DEPLETED URANIUM or NATURAL THORIUM UN 2910 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL UN 2911 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - INSTRUMENTS or ARTICLES Low specific activity radioactive material (2.2.7.2.3.1) UN 2912 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-I), non fissile or fissile-excepted UN 3321 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), non fissile or fissile-excepted UN 3322 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-III), non fissile or fissile-excepted UN 3324 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), FISSILE UN 3325 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY, (LSA-III), FISSILE Surface contaminated objects (2.2.7.2.3.2) UN 2913 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), non fissile or fissile-excepted UN 3326 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), FISSILE Type A packages (2.2.7.2.4.4) UN 2915 RADIOACTIVE MATERIAL, TYPE A PACKAGE, non-special form, non fissile or fissile-excepted UN 3327 RADIOACTIVE MATERIAL, TYPE A PACKAGE, FISSILE, non-special form UN 3332 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, non fissile or fissile-excepted UN 3333 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, FISSILE Type B(U) packages (2.2.7.2.4.6) UN 2916 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, non fissile or fissile-excepted UN 3328 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, FISSILE Type B(M) packages (2.2.7.2.4.6) UN 2917 RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, non fissile or fissile-excepted UN 3329 RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, FISSILE Type C packages (2.2.7.2.4.6) UN 3323 RADIOACTIVE MATERIAL, TYPE C PACKAGE, non fissile or fissile-excepted UN 3330 RADIOACTIVE MATERIAL, TYPE C PACKAGE, FISSILE Special arrangement (2.2.7.2.5) UN 2919 RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, non fissile or fissile-excepted UN 3331 RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, FISSILE Uranium hexafluoride (2.2.7.2.4.5) UN 2977 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE UN 2978 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, non fissile or fissileexcepted - 217 - Copyright © United Nations, 2010. All rights reserved 2.2.7.2.2 Determination of activity level 2.2.7.2.2.1 The following basic values for individual radionuclides are given in Table 2.2.7.2.2.1: (a) A1 and A2 in TBq; (b) Activity concentration for exempt material in Bq/g; and (c) Activity limits for exempt consignments in Bq. Table 2.2.7.2.2.1: Basic radionuclides values for individual radionuclides Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 6 × 10-3 1 × 101 1 × 104 9 × 10-1 9 × 10-5 1 × 10-1 1 × 103 6 × 10-1 5 × 10-1 1 × 101 1 × 106 Ag-105 2 × 100 2 × 100 1 × 102 1 × 106 Ag-108m (a) 7 × 10-1 7 ×10-1 1 ×101 (b) 1 × 106 (b) Ag-110m (a) 4 × 10-1 4 × 10-1 1 × 101 1 × 106 Ag-111 2 × 100 6 × 10-1 1 × 103 1 × 106 1 × 10-1 1 × 10-1 1 × 101 1 × 105 Am-241 1 × 101 1 × 10-3 1 × 100 1 × 104 Am-242m (a) 1 × 101 1 × 10-3 1 × 100 (b) 1 × 104 (b) Am-243 (a) 5 × 100 1 × 10-3 1 × 100 (b) 1 × 103 (b) Ar-37 4 × 101 4 × 101 1 × 106 1 × 108 Ar-39 4 × 101 2 × 101 1 × 107 1 × 104 Ar-41 3 × 10-1 3 × 10-1 1 × 102 1 × 109 As-72 3 × 10-1 3 × 10-1 1 × 101 1 × 105 As-73 4 × 101 4 × 101 1 × 103 1 × 107 As-74 1 × 100 9 × 10-1 1 × 101 1 × 106 Radionuclide (atomic number) A1 A2 (TBq) (TBq) Ac-225 (a) 8 × 10-1 Ac-227 (a) Ac-228 Actinium (89) Silver (47) Aluminium (13) Al-26 Americium (95) Argon (18) Arsenic (33) - 218 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 3 × 10-1 1 × 102 1 × 105 2 × 101 7 × 10-1 1 × 103 1 × 106 2 × 101 5 × 10-1 1 × 103 1 × 107 Au-193 7 × 100 2 × 100 1 × 102 1 × 107 Au-194 1 × 100 1 × 100 1 × 101 1 × 106 Au-195 1 × 101 6 × 100 1 × 102 1 × 107 Au-198 1 × 100 6 × 10-1 1 × 102 1 × 106 Au-199 1 × 101 6 × 10-1 1 × 102 1 × 106 Ba-131 (a) 2 × 100 2 × 100 1 × 102 1 × 106 Ba-133 3 × 100 3 × 100 1 × 102 1 × 106 Ba-133m 2 × 101 6 × 10-1 1 × 102 1 × 106 Ba-140 (a) 5 × 10-1 3 × 10-1 1 × 101 (b) 1 × 105 (b) Be-7 2 × 101 2 × 101 1 × 103 1 × 107 Be-10 4 × 101 6 × 10-1 1 × 104 1 × 106 Bi-205 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Bi-206 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Bi-207 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Bi-210 1 × 100 6 × 10-1 1 × 103 1 × 106 Bi-210m (a) 6 × 10-1 2 × 10-2 1 × 101 1 × 105 Bi-212 (a) 7 × 10-1 6 × 10-1 1 × 101 (b) 1 × 105 (b) Bk-247 8 × 100 8 × 10-4 1 × 100 1 × 104 Bk-249 (a) 4 × 101 3 × 10-1 1 × 103 1 × 106 Br-76 4 × 10-1 4 × 10-1 1 × 101 1 × 105 Br-77 3 × 100 3 × 100 1 × 102 1 × 106 Radionuclide (atomic number) A1 A2 (TBq) (TBq) As-76 3 × 10-1 As-77 Astatine (85) At-211 (a) Gold (79) Barium (56) Beryllium (4) Bismuth (83) Berkelium (97) Bromine (35) - 219 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 4 × 10-1 1 × 101 1 × 106 1 × 100 6 × 10-1 1 × 101 1 × 106 4 × 101 3 × 100 1 × 104 1 × 107 Ca-41 Unlimited Unlimited 1 × 105 1 × 107 Ca-45 4 × 101 1 × 100 1 × 104 1 × 107 Ca-47 (a) 3 × 100 3 × 10-1 1 × 101 1 × 106 Cd-109 3 × 101 2 × 100 1 × 104 1 × 106 Cd-113m 4 × 101 5 × 10-1 1 × 103 1 × 106 Cd-115 (a) 3 × 100 4 × 10-1 1 × 102 1 × 106 Cd-115m 5 × 10-1 5 × 10-1 1 × 103 1 × 106 Ce-139 7 × 100 2 × 100 1 × 102 1 × 106 Ce-141 2 × 101 6 × 10-1 1 × 102 1 × 107 Ce-143 9 × 10-1 6 × 10-1 1 × 102 1 × 106 Ce-144 (a) 2 × 10-1 2 × 10-1 1 × 102 (b) 1 × 105 (b) Cf-248 4 × 101 6 × 10-3 1 × 101 1 × 104 Cf-249 3 × 100 8 × 10-4 1 × 100 1 × 103 Cf-250 2 × 101 2 × 10-3 1 × 101 1 × 104 Cf-251 7 × 100 7 × 10-4 1 × 100 1 × 103 Cf-252 1 × 10-1 3 × 10-3 1 × 101 1 × 104 Cf-253 (a) 4 × 101 4 × 10-2 1 × 102 1 × 105 Cf-254 1 × 10-3 1 × 10-3 1 × 100 1 × 103 Cl-36 1 × 101 6 × 10-1 1 × 104 1 × 106 Cl-38 2 × 10-1 2 × 10-1 1 × 101 1 × 105 Radionuclide (atomic number) A1 A2 (TBq) (TBq) 4 × 10-1 C-11 C-14 Br-82 Carbon (6) Calcium (20) Cadmium (48) Cerium (58) Californium (98) Chlorine (17) - 220 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 2 × 10-2 1 × 102 1 × 105 2 × 100 1 × 100 1 × 102 1 × 106 Cm-242 4 × 101 1 × 10-2 1 × 102 1 × 105 Cm-243 9 × 100 1 × 10-3 1 × 100 1 × 104 Cm-244 2 × 101 2 × 10-3 1 × 101 1 × 104 Cm-245 9 × 100 9 × 10-4 1 × 100 1 × 103 Cm-246 9 × 100 9 × 10-4 1 × 100 1 × 103 Cm-247 (a) 3 × 100 1 × 10-3 1 × 100 1 × 104 Cm-248 2 × 10-2 3 × 10-4 1 × 100 1 × 103 Co-55 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Co-56 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Co-57 1 × 101 1 × 101 1 × 102 1 × 106 Co-58 1 × 100 1 × 100 1 × 101 1 × 106 Co-58m 4 × 101 4 × 101 1 × 104 1 × 107 Co-60 4 × 10-1 4 × 10-1 1 × 101 1 × 105 3 × 101 3 × 101 1 × 103 1 × 107 Cs-129 4 × 100 4 × 100 1 × 102 1 × 105 Cs-131 3 × 101 3 × 101 1 × 103 1 × 106 Cs-132 1 × 100 1 × 100 1 × 101 1 × 105 Cs-134 7 × 10-1 7 × 10-1 1 × 101 1 × 104 Cs-134m 4 × 101 6 × 10-1 1 × 103 1 × 105 Cs-135 4 × 101 1 × 100 1 × 104 1 × 107 Cs-136 5 × 10-1 5 × 10-1 1 × 101 1 × 105 Cs-137 (a) 2 × 100 6 × 10-1 1 × 101 (b) 1 × 104 (b) Radionuclide (atomic number) A1 A2 (TBq) (TBq) Cm-240 4 × 101 Cm-241 Curium (96) Cobalt (27) Chromium (24) Cr-51 Caesium (55) - 221 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 1 × 100 1 × 102 1 × 106 1 × 101 7 × 10-1 1 × 102 1 × 106 Dy-159 2 × 101 2 × 101 1 × 103 1 × 107 Dy-165 9 × 10-1 6 × 10-1 1 × 103 1 × 106 Dy-166 (a) 9 × 10-1 3 × 10-1 1 × 103 1 × 106 Er-169 4 × 101 1 × 100 1 × 104 1 × 107 Er-171 8 × 10-1 5 × 10-1 1 × 102 1 × 106 Eu-147 2 × 100 2 × 100 1 × 102 1 × 106 Eu-148 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Eu-149 2 × 101 2 × 101 1 × 102 1 × 107 Eu-150(short lived) 2 × 100 7 × 10-1 1 × 103 1 × 106 Eu-150(long lived) 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Eu-152 1 × 100 1 × 100 1 × 101 1 × 106 Eu-152m 8 × 10-1 8 × 10-1 1 × 102 1 × 106 Eu-154 9 × 10-1 6 × 10-1 1 × 101 1 × 106 Eu-155 2 × 101 3 × 100 1 × 102 1 × 107 Eu-156 7 × 10-1 7 × 10-1 1 × 101 1 × 106 1 × 100 6 × 10-1 1 × 101 1 × 106 Fe-52 (a) 3 × 10-1 3 × 10-1 1 × 101 1 × 106 Fe-55 4 × 101 4 × 101 1 × 104 1 × 106 Fe-59 9 × 10-1 9 × 10-1 1 × 101 1 × 106 Fe-60 (a) 4 × 101 2 × 10-1 1 × 102 1 × 105 Ga-67 7 × 100 3 × 100 1 × 102 1 × 106 Ga-68 5 × 10-1 5 × 10-1 1 × 101 1 × 105 Radionuclide (atomic number) A1 A2 (TBq) (TBq) Cu-64 6 × 100 Cu-67 Copper (29) Dysprosium (66) Erbium (68) Europium (63) Fluorine (9) F-18 Iron (26) Gallium (31) - 222 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 4 × 10-1 1 × 101 1 × 105 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Gd-148 2 × 101 2 × 10-3 1 × 101 1 × 104 Gd-153 1 × 101 9 × 100 1 × 102 1 × 107 Gd-159 3 × 100 6 × 10-1 1 × 103 1 × 106 Ge-68 (a) 5 × 10-1 5 × 10-1 1 × 101 1 × 105 Ge-71 4 × 101 4 × 101 1 × 104 1 × 108 Ge-77 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Hf-172 (a) 6 × 10-1 6 × 10-1 1 × 101 1 × 106 Hf-175 3 × 100 3 × 100 1 × 102 1 × 106 Hf-181 2 × 100 5 × 10-1 1 × 101 1 × 106 Hf-182 Unlimited Unlimited 1 × 102 1 × 106 Hg-194 (a) 1 × 100 1 × 100 1 × 101 1 × 106 Hg-195m (a) 3 × 100 7 × 10-1 1 × 102 1 × 106 Hg-197 2 × 101 1 × 101 1 × 102 1 × 107 Hg-197m 1 × 101 4 × 10-1 1 × 102 1 × 106 Hg-203 5 × 100 1 × 100 1 × 102 1 × 105 Ho-166 4 × 10-1 4 × 10-1 1 × 103 1 × 105 Ho-166m 6 × 10-1 5 × 10-1 1 × 101 1 × 106 I-123 6 × 100 3 × 100 1 × 102 1 × 107 I-124 1 × 100 1 × 100 1 × 101 1 × 106 I-125 2 × 101 3 × 100 1 × 103 1 × 106 I-126 2 × 100 1 × 100 1 × 102 1 × 106 I-129 Unlimited Unlimited 1 ×102 1 × 105 I-131 3 × 100 7 × 10-1 1 × 102 1 × 106 Radionuclide (atomic number) A1 A2 (TBq) (TBq) 4 × 10-1 Gd-146 (a) Ga-72 Gadolinium (64) Germanium (32) Hafnium (72) Mercury (80) Holmium (67) Iodine (53) - 223 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 4 × 10-1 1 × 101 1 × 105 7 × 10-1 6 × 10-1 1 × 101 1 × 106 I-134 3 × 10-1 3 × 10-1 1 × 101 1 × 105 I-135 (a) 6 × 10-1 6 × 10-1 1 × 101 1 × 106 In-111 3 × 100 3 × 100 1 × 102 1 × 106 In-113m 4 × 100 2 × 100 1 × 102 1 × 106 In-114m (a) 1 × 101 5 × 10-1 1 × 102 1 × 106 In-115m 7 × 100 1 × 100 1 × 102 1 × 106 Ir-189 (a) 1 × 101 1 × 101 1 × 102 1 × 107 Ir-190 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Ir-192 1 × 100(c) 6 × 10-1 1 × 101 1 × 104 Ir-194 3 × 10-1 3 × 10-1 1 × 102 1 × 105 K-40 9 × 10-1 9 × 10-1 1 × 102 1 × 106 K-42 2 × 10-1 2 × 10-1 1 × 102 1 × 106 K-43 7 × 10-1 6 × 10-1 1 × 101 1 × 106 Kr-79 4 × 100 2 × 100 1 × 103 1 × 105 Kr-81 4 × 101 4 × 101 1 × 104 1 × 107 Kr-85 1 × 101 1 × 101 1 × 105 1 × 104 Kr-85m 8 × 100 3 × 100 1 × 103 1 × 1010 Kr-87 2 × 10-1 2 × 10-1 1 × 102 1 × 109 La-137 3 × 101 6 × 100 1 × 103 1 × 107 La-140 4 × 10-1 4 × 10-1 1 × 101 1 × 105 Lu-172 6 × 10-1 6 × 10-1 1 × 101 1 × 106 Lu-173 8 × 100 8 × 100 1 × 102 1 × 107 Lu-174 9 × 100 9 × 100 1 × 102 1 × 107 Radionuclide (atomic number) A1 A2 (TBq) (TBq) I-132 4 × 10-1 I-133 Indium (49) Iridium (77) Potassium (19) Krypton (36) Lanthanum (57) Lutetium (71) - 224 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 1 × 101 1 × 102 1 × 107 3 × 101 7 × 10-1 1 × 103 1 × 107 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Mn-52 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Mn-53 Unlimited Unlimited 1 × 104 1 × 109 Mn-54 1 × 100 1 × 100 1 × 101 1 × 106 Mn-56 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Mo-93 4 × 101 2 × 101 1 × 103 1 × 108 Mo-99 (a) 1 × 100 6 × 10-1 1 × 102 1 × 106 9 × 10-1 6 × 10-1 1 × 102 1 × 109 Na-22 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Na-24 2 × 10-1 2 × 10-1 1 × 101 1 × 105 Nb-93m 4 × 101 3 × 101 1 × 104 1 × 107 Nb-94 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Nb-95 1 × 100 1 × 100 1 × 101 1 × 106 Nb-97 9 × 10-1 6 × 10-1 1 × 101 1 × 106 Nd-147 6 × 100 6 × 10-1 1 × 102 1 × 106 Nd-149 6 × 10-1 5 × 10-1 1 × 102 1 × 106 Ni-59 Unlimited Unlimited 1 × 104 1 × 108 Ni-63 4 × 101 3 × 101 1 × 105 1 × 108 Ni-65 4 × 10-1 4 × 10-1 1 × 101 1 × 106 4 × 101 4 × 101 1 × 103 1 × 107 Radionuclide (atomic number) A1 A2 (TBq) (TBq) Lu-174m 2 × 101 Lu-177 Magnesium (12) Mg-28 (a) Manganese (25) Molybdenum (42) Nitrogen (7) N-13 Sodium (11) Niobium (41) Neodymium (60) Nickel (28) Neptunium (93) Np-235 - 225 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 2 × 100 1 × 103 1 × 107 9 × 100 2 × 10-2 1 × 102 1 × 105 Np-237 2 × 101 2 × 10-3 1 × 100 (b) 1 × 103 (b) Np-239 7 × 100 4 × 10-1 1 × 102 1 × 107 Os-185 1 × 100 1 × 100 1 × 101 1 × 106 Os-191 1 × 101 2 × 100 1 × 102 1 × 107 Os-191m 4 × 101 3 × 101 1 × 103 1 × 107 Os-193 2 × 100 6 × 10-1 1 × 102 1 × 106 Os-194 (a) 3 × 10-1 3 × 10-1 1 × 102 1 × 105 P-32 5 × 10-1 5 × 10-1 1 × 103 1 × 105 P-33 4 × 101 1 × 100 1 × 105 1 × 108 Pa-230 (a) 2 × 100 7 × 10-2 1 × 101 1 × 106 Pa-231 4 × 100 4 × 10-4 1 × 100 1 × 103 Pa-233 5 × 100 7 × 10-1 1 × 102 1 × 107 Pb-201 1 × 100 1 × 100 1 × 101 1 × 106 Pb-202 4 × 101 2 × 101 1 × 103 1 × 106 Pb-203 4 × 100 3 × 100 1 × 102 1 × 106 Pb-205 Unlimited Unlimited 1 × 104 1 × 107 Pb-210 (a) 1 × 100 5 × 10-2 1 × 101 (b) 1 × 104 (b) Pb-212 (a) 7 × 10-1 2 × 10-1 1 × 101 (b) 1 × 105 (b) 4 × 101 4 × 101 1 × 103 1 × 108 Pd-107 Unlimited Unlimited 1 × 105 1 × 108 Pd-109 2 × 100 5 × 10-1 1 × 103 1 × 106 Pm-143 3 × 100 3 × 100 1 × 102 1 × 106 Pm-144 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Radionuclide (atomic number) A1 A2 (TBq) (TBq) Np-236(short-lived) 2 × 101 Np-236(long-lived) Osmium (76) Phosphorus (15) Protactinium (91) Lead (82) Palladium (46) Pd-103 (a) Promethium (61) - 226 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 1 × 101 1 × 103 1 × 107 4 × 101 2 × 100 1 × 104 1 × 107 Pm-148m (a) 8 × 10-1 7 × 10-1 1 × 101 1 × 106 Pm-149 2 × 100 6 × 10-1 1 × 103 1 × 106 Pm-151 2 × 100 6 × 10-1 1 × 102 1 × 106 4 × 101 2 × 10-2 1 × 101 1 × 104 Pr-142 4 × 10-1 4 × 10-1 1 × 102 1 × 105 Pr-143 3 × 100 6 × 10-1 1 × 104 1 × 106 Pt-188 (a) 1 × 100 8 × 10-1 1 × 101 1 × 106 Pt-191 4 × 100 3 × 100 1 × 102 1 × 106 Pt-193 4 × 101 4 × 101 1 × 104 1 × 107 Pt-193m 4 × 101 5 × 10-1 1 × 103 1 × 107 Pt-195m 1 × 101 5 × 10-1 1 × 102 1 × 106 Pt-197 2 × 101 6 × 10-1 1 × 103 1 × 106 Pt-197m 1 × 101 6 × 10-1 1 × 102 1 × 106 Pu-236 3 × 101 3 × 10-3 1 × 101 1 × 104 Pu-237 2 × 101 2 × 101 1 × 103 1 × 107 Pu-238 1 × 101 1 × 10-3 1 × 100 1 × 104 Pu-239 1 × 101 1 × 10-3 1 × 100 1 × 104 Pu-240 1 × 101 1 × 10-3 1 × 100 1 × 103 Pu-241 (a) 4 × 101 6 × 10-2 1 × 102 1 × 105 Pu-242 1 × 101 1 × 10-3 1 × 100 1 × 104 Pu-244 (a) 4 × 10-1 1 × 10-3 1 × 100 1 × 104 Ra-223 (a) 4 × 10-1 7 × 10-3 1 × 102 (b) 1 × 105 (b) Ra-224 (a) 4 × 10-1 2 × 10-2 1 × 101 (b) 1 × 105 (b) Ra-225 (a) 2 × 10-1 4 × 10-3 1 × 102 1 × 105 Radionuclide (atomic number) A1 A2 (TBq) (TBq) Pm-145 3 × 101 Pm-147 Polonium (84) Po-210 Praseodymium (59) Platinum (78) Plutonium (94) Radium (88) - 227 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 3 × 10-3 1 × 101 (b) 1 × 104 (b) 6 × 10-1 2 × 10-2 1 × 101 (b) 1 × 105 (b) Rb-81 2 × 100 8 × 10-1 1 × 101 1 × 106 Rb-83 (a) 2 × 100 2 × 100 1 × 102 1 × 106 Rb-84 1 × 100 1 × 100 1 × 101 1 × 106 Rb-86 5 × 10-1 5 × 10-1 1 × 102 1 × 105 Rb-87 Unlimited Unlimited 1 × 104 1 × 107 Rb(nat) Unlimited Unlimited 1 × 104 1 × 107 Re-184 1 × 100 1 × 100 1 × 101 1 × 106 Re-184m 3 × 100 1 × 100 1 × 102 1 × 106 Re-186 2 × 100 6 × 10-1 1 × 103 1 × 106 Re-187 Unlimited Unlimited 1 × 106 1 × 109 Re-188 4 × 10-1 4 × 10-1 1 × 102 1 × 105 Re-189 (a) 3 × 100 6 × 10-1 1 × 102 1 × 106 Unlimited Unlimited 1 × 106 1 × 109 Rh-99 2 × 100 2 × 100 1 × 101 1 × 106 Rh-101 4 × 100 3 × 100 1 × 102 1 × 107 Rh-102 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Rh-102m 2 × 100 2 × 100 1 × 102 1 × 106 Rh-103m 4 × 101 4 × 101 1 × 104 1 × 108 Rh-105 1 × 101 8 × 10-1 1 × 102 1 × 107 3 × 10-1 4 × 10-3 1 × 101 (b) 1 × 108 (b) Ru-97 5 × 100 5 × 100 1 × 102 1 × 107 Ru-103 (a) 2 × 100 2 × 100 1 × 102 1 × 106 Ru-105 1 × 100 6 × 10-1 1 × 101 1 × 106 Ru-106 (a) 2 × 10-1 2 × 10-1 1 × 102 (b) 1 × 105 (b) Radionuclide (atomic number) A1 A2 (TBq) (TBq) Ra-226 (a) 2 × 10-1 Ra-228 (a) Rubidium (37) Rhenium (75) Re(nat) Rhodium (45) Radon (86) Rn-222 (a) Ruthenium (44) - 228 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 3 × 100 1 × 105 1 × 108 4 × 10-1 4 × 10-1 1 × 102 1 × 104 Sb-124 6 × 10-1 6 × 10-1 1 × 101 1 × 106 Sb-125 2 × 100 1 × 100 1 × 102 1 × 106 Sb-126 4 × 10-1 4 × 10-1 1 × 101 1 × 105 Sc-44 5 × 10-1 5 × 10-1 1 × 101 1 × 105 Sc-46 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Sc-47 1 × 101 7 × 10-1 1 × 102 1 × 106 Sc-48 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Se-75 3 × 100 3 × 100 1 × 102 1 × 106 Se-79 4 × 101 2 × 100 1 × 104 1 × 107 Si-31 6 × 10-1 6 × 10-1 1 × 103 1 × 106 Si-32 4 × 101 5 × 10-1 1 × 103 1 × 106 Sm-145 1 × 101 1 × 101 1 × 102 1 × 107 Sm-147 Unlimited Unlimited 1 × 101 1 × 104 Sm-151 4 × 101 1 × 101 1 × 104 1 × 108 Sm-153 9 × 100 6 × 10-1 1 × 102 1 × 106 Sn-113 (a) 4 × 100 2 × 100 1 × 103 1 × 107 Sn-117m 7 × 100 4 × 10-1 1 × 102 1 × 106 Sn-119m 4 × 101 3 × 101 1 × 103 1 × 107 Sn-121m (a) 4 × 101 9 × 10-1 1 × 103 1 × 107 Sn-123 8 × 10-1 6 × 10-1 1 × 103 1 × 106 Sn-125 4 × 10-1 4 × 10-1 1 × 102 1 × 105 Sn-126 (a) 6 × 10-1 4 × 10-1 1 × 101 1 × 105 Radionuclide (atomic number) A1 A2 (TBq) (TBq) 4 × 101 Sb-122 Sulphur (16) S-35 Antimony (51) Scandium (21) Selenium (34) Silicon (14) Samarium (62) Tin (50) - 229 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 2 × 10-1 1 × 101 1 × 105 2 × 100 2 × 100 1 × 102 1 × 106 Sr-85m 5 × 100 5 × 100 1 × 102 1 × 107 Sr-87m 3 × 100 3 × 100 1 × 102 1 × 106 Sr-89 6 × 10-1 6 × 10-1 1 × 103 1 × 106 Sr-90 (a) 3 × 10-1 3 × 10-1 1 × 102 (b) 1 × 104 (b) Sr-91 (a) 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Sr-92 (a) 1 × 100 3 × 10-1 1 × 101 1 × 106 4 × 101 4 × 101 1 × 106 1 × 109 Ta-178(long-lived) 1 × 100 8 × 10-1 1 × 101 1 × 106 Ta-179 3 × 101 3 × 101 1 × 103 1 × 107 Ta-182 9 × 10-1 5 × 10-1 1 × 101 1 × 104 Tb-157 4 × 101 4 × 101 1 × 104 1 × 107 Tb-158 1 × 100 1 × 100 1 × 101 1 × 106 Tb-160 1 × 100 6 × 10-1 1 × 101 1 × 106 Tc-95m (a) 2 × 100 2 × 100 1 × 101 1 × 106 Tc-96 4 × 10-1 4 × 10-1 1 × 101 1 × 106 Tc-96m (a) 4 × 10-1 4 × 10-1 1 × 103 1 × 107 Unlimited Unlimited 1 × 103 1 × 108 Tc-97m 4 × 101 1 × 100 1 × 103 1 × 107 Tc-98 8 × 10-1 7 × 10-1 1 × 101 1 × 106 Tc-99 4 × 101 9 × 10-1 1 × 104 1 × 107 Tc-99m 1 × 101 4 × 100 1 × 102 1 × 107 Te-121 2 × 100 2 × 100 1 × 101 1 × 106 Te-121m 5 × 100 3 × 100 1 × 102 1 × 106 Radionuclide (atomic number) A1 A2 (TBq) (TBq) Sr-82 (a) 2 × 10-1 Sr-85 Strontium (38) Tritium (1) T(H-3) Tantalum (73) Terbium (65) Technetium (43) Tc-97 Tellurium (52) - 230 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 1 × 100 1 × 102 1 × 107 2 × 101 9 × 10-1 1 × 103 1 × 107 Te-127 2 × 101 7 × 10-1 1 × 103 1 × 106 Te-127m (a) 2 × 101 5 × 10-1 1 × 103 1 × 107 Te-129 7 × 10-1 6 × 10-1 1 × 102 1 × 106 Te-129m (a) 8 × 10-1 4 × 10-1 1 × 103 1 × 106 Te-131m (a) 7 × 10-1 5 × 10-1 1 × 101 1 × 106 Te-132 (a) 5 × 10-1 4 × 10-1 1 × 102 1 × 107 Th-227 1 × 101 5 × 10-3 1 × 101 1 × 104 Th-228 (a) 5 × 10-1 1 × 10-3 1 × 100 (b) 1 × 104 (b) Th-229 5 × 100 5 × 10-4 1 × 100 (b) 1 × 103 (b) Th-230 1 × 101 1 × 10-3 1 × 100 1 × 104 Th-231 4 × 101 2 × 10-2 1 × 103 1 × 107 Th-232 Unlimited Unlimited 1 × 101 1 × 104 3 × 10-1 3 × 10-1 1 × 103 (b) 1 × 105 (b) Unlimited Unlimited 1 × 100 (b) 1 × 103 (b) 5 × 10-1 4 × 10-1 1 × 101 1 × 105 Tl-200 9 × 10-1 9 × 10-1 1 × 101 1 × 106 Tl-201 1 × 101 4 × 100 1 × 102 1 × 106 Tl-202 2 × 100 2 × 100 1 × 102 1 × 106 Tl-204 1 × 101 7 × 10-1 1 × 104 1 × 104 Tm-167 7 × 100 8 × 10-1 1 × 102 1 × 106 Tm-170 3 × 100 6 × 10-1 1 × 103 1 × 106 Tm-171 4 × 101 4 × 101 1 × 104 1 × 108 U-230 (fast lung absorption) (a)(d) 4 × 101 1 × 10-1 1 × 101 (b) 1 × 105 (b) U-230 (medium lung absorption) (a)(e) 4 × 101 4 × 10-3 1 × 101 1 × 104 Radionuclide (atomic number) A1 A2 (TBq) (TBq) Te-123m 8 × 100 Te-125m Thorium (90) Th-234 (a) Th(nat) Titanium (22) Ti-44 (a) Thallium (81) Thulium (69) Uranium (92) - 231 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 3 × 10-3 1 × 101 1 × 104 4 × 101 1 × 10-2 1 × 100 (b) 1 × 103 (b) U-232 (medium lung absorption) (e) 4 × 101 7 × 10-3 1 × 101 1 × 104 U-232 (slow lung absorption) (f) 1 × 101 1 × 10-3 1 × 101 1 × 104 U-233 (fast lung absorption) (d) 4 × 101 9 × 10-2 1 × 101 1 × 104 U-233 (medium lung absorption) (e) 4 × 101 2 × 10-2 1 × 102 1 × 105 U-233 (slow lung absorption) (f) 4 × 101 6 × 10-3 1 × 101 1 × 105 U-234 (fast lung absorption) (d) 4 × 101 9 × 10-2 1 × 101 1 × 104 U-234 (medium lung absorption) (e) 4 × 101 2 × 10-2 1 × 102 1 × 105 U-234 (slow lung absorption) (f) 4 × 101 6 × 10-3 1 × 101 1 × 105 U-235 (all lung absorption types) (a)(d)(e)(f) Unlimited Unlimited 1 × 101 (b) 1 × 104 (b) U-236 (fast lung absorption) (d) Unlimited Unlimited 1 × 101 1 × 104 U-236 (medium lung absorption) (e) 4 × 101 2 × 10-2 1 × 102 1 × 105 U-236 (slow lung absorption) (f) 4 × 101 6 × 10-3 1 × 101 1 × 104 U-238 (all lung absorption types) (d)(e)(f) Unlimited Unlimited 1 × 101 (b) 1 × 104 (b) U (nat) Unlimited Unlimited 1 × 100 (b) 1 × 103 (b) U (enriched to 20% or less) (g) Unlimited Unlimited 1 × 100 1 × 103 U (dep) Unlimited Unlimited 1 × 100 1 × 103 V-48 4 × 10-1 4 × 10-1 1 × 101 1 × 105 V-49 4 × 101 4 × 101 1 × 104 1 × 107 W-178 (a) 9 × 100 5 × 100 1 × 101 1 × 106 W-181 3 × 101 3 × 101 1 × 103 1 × 107 W-185 4 × 101 8 × 10-1 1 × 104 1 × 107 W-187 2 × 100 6 × 10-1 1 × 102 1 × 106 W-188 (a) 4 × 10-1 3 × 10-1 1 × 102 1 × 105 Radionuclide (atomic number) A1 A2 (TBq) (TBq) U-230 (slow lung absorption) (a)(f) 3 × 101 U-232 (fast lung absorption) (d) Vanadium (23) Tungsten (74) - 232 - Copyright © United Nations, 2010. All rights reserved Activity concentration for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 4 × 10-1 1 × 102 1 × 109 2 × 100 7 × 10-1 1 × 102 1 × 109 Xe-127 4 × 100 2 × 100 1 × 103 1 × 105 Xe-131m 4 × 101 4 × 101 1 × 104 1 × 104 Xe-133 2 × 101 1 × 101 1 × 103 1 × 104 Xe-135 3 × 100 2 × 100 1 × 103 1 × 1010 Y-87 (a) 1 × 100 1 × 100 1 × 101 1 × 106 Y-88 4 × 10-1 4 × 10-1 1 × 101 1 × 106 Y-90 3 × 10-1 3 × 10-1 1 × 103 1 × 105 Y-91 6 × 10-1 6 × 10-1 1 × 103 1 × 106 Y-91m 2 × 100 2 × 100 1 × 102 1 × 106 Y-92 2 × 10-1 2 × 10-1 1 × 102 1 × 105 Y-93 3 × 10-1 3 × 10-1 1 × 102 1 × 105 Yb-169 4 × 100 1 × 100 1 × 102 1 × 107 Yb-175 3 × 101 9 × 10-1 1 × 103 1 × 107 Zn-65 2 × 100 2 × 100 1 × 101 1 × 106 Zn-69 3 × 100 6 × 10-1 1 × 104 1 × 106 Zn-69m (a) 3 × 100 6 × 10-1 1 × 102 1 × 106 Zr-88 3 × 100 3 × 100 1 × 102 1 × 106 Zr-93 Unlimited Unlimited 1 × 103 (b) 1 × 107 (b) Zr-95 (a) 2 × 100 8 × 10-1 1 × 101 1 × 106 Zr-97 (a) 4 × 10-1 4 × 10-1 1 × 101 (b) 1 × 105 (b) Radionuclide (atomic number) A1 A2 (TBq) (TBq) Xe-122 (a) 4 × 10-1 Xe-123 Xenon (54) Yttrium (39) Ytterbium (70) Zinc (30) Zirconium (40) - 233 - Copyright © United Nations, 2010. All rights reserved (a) A1 and/or A2 values for these parent radionuclides include contributions from daughter radionuclides with half-lives less than 10 days, as listed in the following: Mg-28 Ar-42 Ca-47 Ti-44 Fe-52 Fe-60 Zn-69m Ge-68 Rb-83 Sr-82 Sr-90 Sr-91 Sr-92 Y-87 Zr-95 Zr-97 Mo-99 Tc-95m Tc-96m Ru-103 Ru-106 Pd-103 Ag-108m Ag-110m Cd-115 In-114m Sn-113 Sn-121m Sn-126 Te-118 Te-127m Te-129m Te-131m Te-132 I-135 Xe-122 Cs-137 Ba-131 Ba-140 Ce-144 Pm-148m Gd-146 Dy-166 Hf-172 W-178 W-188 Re-189 Os-194 Ir-189 Pt-188 Hg-194 Hg-195m Pb-210 Pb-212 Bi-210m Al-28 K-42 Sc-47 Sc-44 Mn-52m Co-60m Zn-69 Ga-68 Kr-83m Rb-82 Y-90 Y-91m Y-92 Sr-87m Nb-95m Nb-97m, Nb-97 Tc-99m Tc-95 Tc-96 Rh-103m Rh-106 Rh-103m Ag-108 Ag-110 In-115m In-114 In-113m Sn-121 Sb-126m Sb-118 Te-127 Te-129 Te-131 I-132 Xe-135m I-122 Ba-137m Cs-131 La-140 Pr-144m, Pr-144 Pm-148 Eu-146 Ho-166 Lu-172 Ta-178 Re-188 Os-189m Ir-194 Os-189m Ir-188 Au-194 Hg-195 Bi-210 Bi-212, Tl-208, Po-212 Tl-206 - 234 - Copyright © United Nations, 2010. All rights reserved Bi-212 At-211 Rn-222 Ra-223 Ra-224 Ra-225 Ra-226 Ra-228 Ac-225 Ac-227 Th-228 Th-234 Pa-230 U-230 U-235 Pu-241 Pu-244 Am-242m Am-243 Cm-247 Bk-249 Cf-253 (b) Tl-208, Po-212 Po-211 Po-218, Pb-214, At-218, Bi-214, Po-214 Rn-219, Po-215, Pb-211, Bi-211, Po-211, Tl-207 Rn-220, Po-216, Pb-212, Bi-212, Tl-208, Po-212 Ac-225, Fr-221, At-217, Bi-213, Tl-209, Po-213, Pb-209 Rn-222, Po-218, Pb-214, At-218, Bi-214, Po-214 Ac-228 Fr-221, At-217, Bi-213, Tl-209, Po-213, Pb-209 Fr-223 Ra-224, Rn-220, Po-216, Pb-212, Bi-212, Tl-208, Po-212 Pa-234m, Pa-234 Ac-226, Th-226, Fr-222, Ra-222, Rn-218, Po-214 Th-226, Ra-222, Rn-218, Po-214 Th-231 U-237 U-240, Np-240m Am-242, Np-238 Np-239 Pu-243 Am-245 Cm-249 Parent nuclides and their progeny included in secular equilibrium are listed in the following: Sr-90 Zr-93 Zr-97 Ru-106 Ag-108m Cs-137 Ce-144 Ba-140 Bi-212 Pb-210 Pb-212 Rn-222 Ra-223 Ra-224 Ra-226 Ra-228 Th-228 Th-229 Th-nat Th-234 U-230 U-232 U-235 U-238 U-nat Np-237 Am-242m Am-243 Y-90 Nb-93m Nb-97 Rh-106 Ag-108 Ba-137m Pr-144 La-140 Tl-208 (0.36), Po-212 (0.64) Bi-210, Po-210 Bi-212, Tl-208 (0.36), Po-212 (0.64) Po-218, Pb-214, Bi-214, Po-214 Rn-219, Po-215, Pb-211, Bi-211, Tl-207 Rn-220, Po-216, Pb-212, Bi-212, Tl-208 (0.36), Po-212 (0.64) Rn-222, Po-218, Pb-214, Bi-214, Po-214, Pb-210, Bi-210, Po-210 Ac-228 Ra-224, Rn-220, Po-216, Pb212, Bi-212, Tl208 (0.36), Po-212 (0.64) Ra-225, Ac-225, Fr-221, At-217, Bi-213, Po-213, Pb-209 Ra-228, Ac-228, Th-228, Ra-224, Rn-220, Po-216, Pb-212, Bi-212, l208 (0.36), Po-212 (0.64) Pa-234m Th-226, Ra-222, Rn-218, Po-214 Th-228, Ra-224, Rn-220, Po-216, Pb-212, Bi-212, Tl-208 (0.36), Po-212 (0.64) Th-231 Th-234, Pa-234m Th-234, Pa-234m, U-234, Th-230, Ra-226, Rn-222, Po-218, Pb-214, Bi-214, Po-214, Pb-210, Bi-210, Po-210 Pa-233 Am-242 Np-239 - 235 - Copyright © United Nations, 2010. All rights reserved 2.2.7.2.2.2 (c) The quantity may be determined from a measurement of the rate of decay or a measurement of the radiation level at a prescribed distance from the source. (d) These values apply only to compounds of uranium that take the chemical form of UF6, UO2F2 and UO2(NO3)2 in both normal and accident conditions of carriage. (e) These values apply only to compounds of uranium that take the chemical form of UO3, UF4, UCl4 and hexavalent compounds in both normal and accident conditions of carriage. (f) These values apply to all compounds of uranium other than those specified in (d) and (e) above. (g) These values apply to unirradiated uranium only. For individual radionuclides which are not listed in Table 2.2.7.2.2.1 the determination of the basic radionuclide values referred to in 2.2.7.2.2.1 shall require multilateral approval. It is permissible to use an A2 value calculated using a dose coefficient for the appropriate lung absorption type as recommended by the International Commission on Radiological Protection, if the chemical forms of each radionuclide under both normal and accident conditions of carriage are taken into consideration. Alternatively, the radionuclide values in Table 2.2.7.2.2.2 may be used without obtaining competent authority approval. Table 2.2.7.2.2.2: Basic radionuclide values for unknown radionuclides or mixtures A1 (TBq) A2 (TBq) Activity concentration for exempt material (Bq/g) Only beta or gamma emitting nuclides are known to be present 0.1 0.02 1 × 101 1 × 104 Alpha emitting nuclides but no neutron emitters are known to be present 0.2 9 × 10-5 1 × 10-1 1 × 103 Neutron emitting nuclides are known to be present or no relevant data are available 0.001 9 × 10-5 1 × 10-1 1 × 103 Radioactive contents 2.2.7.2.2.3 Activity limit for exempt consignments (Bq) In the calculations of A1 and A2 for a radionuclide not in Table 2.2.7.2.2.1, a single radioactive decay chain in which the radionuclides are present in their naturally occurring proportions, and in which no daughter nuclide has a half-life either longer than 10 days or longer than that of the parent nuclide, shall be considered as a single radionuclide; and the activity to be taken into account and the A1 or A2 value to be applied shall be those corresponding to the parent nuclide of that chain. In the case of radioactive decay chains in which any daughter nuclide has a half-life either longer than 10 days or greater than that of the parent nuclide, the parent and such daughter nuclides shall be considered as mixtures of different nuclides. - 236 - Copyright © United Nations, 2010. All rights reserved 2.2.7.2.2.4 For mixtures of radionuclides, the determination of the basic radionuclide values referred to in 2.2.7.2.2.1 may be determined as follows: Χm = 1 f(i) Σi X(i) where, f(i) is the fraction of activity or activity concentration of radionuclide i in the mixture; X(i) is the appropriate value of A1 or A2, or the activity concentration for exempt material or the activity limit for an exempt consignment as appropriate for the radionuclide i; and Xm is the derived value of A1 or A2, or the activity concentration for exempt material or the activity limit for an exempt consignment in the case of a mixture. 2.2.7.2.2.5 When the identity of each radionuclide is known but the individual activities of some of the radionuclides are not known, the radionuclides may be grouped and the lowest radionuclide value, as appropriate, for the radionuclides in each group may be used in applying the formulas in 2.2.7.2.2.4 and 2.2.7.2.4.4. Groups may be based on the total alpha activity and the total beta/gamma activity when these are known, using the lowest radionuclide values for the alpha emitters or beta/gamma emitters, respectively. 2.2.7.2.2.6 For individual radionuclides or for mixtures of radionuclides for which relevant data are not available, the values shown in Table 2.2.7.2.2.2 shall be used. 2.2.7.2.3 Determination of other material characteristics 2.2.7.2.3.1 Low specific activity (LSA) material 2.2.7.2.3.1.1 (Reserved) 2.2.7.2.3.1.2 LSA material shall be in one of three groups: (a) LSA-I (i) uranium and thorium ores and concentrates of such ores, and other ores containing naturally occurring radionuclides which are intended to be processed for the use of these radionuclides; (ii) natural uranium, depleted uranium, natural thorium or their compounds or mixtures, that are unirradiated and in solid or liquid form; (iii) radioactive material for which the A2 value is unlimited, excluding fissile material not excepted under 2.2.7.2.3.5; or (iv) other radioactive material in which the activity is distributed throughout and the estimated average specific activity does not exceed 30 times the values for activity concentration specified in 2.2.7.2.2.1 to 2.2.7.2.2.6, excluding fissile material not excepted under 2.2.7.2.3.5; - 237 - Copyright © United Nations, 2010. All rights reserved (b) (c) LSA-II (i) water with tritium concentration up to 0.8 TBq/l; or (ii) other material in which the activity is distributed throughout and the estimated average specific activity does not exceed 10-4 A2/g for solids and gases, and 10-5 A2/g for liquids; LSA-III - Solids (e.g. consolidated wastes, activated materials), excluding powders, meeting the requirements of 2.2.7.2.3.1.3, in which: (i) the radioactive material is distributed throughout a solid or a collection of solid objects, or is essentially uniformly distributed in a solid compact binding agent (such as concrete, bitumen, ceramic, etc.); (ii) the radioactive material is relatively insoluble, or it is intrinsically contained in a relatively insoluble matrix, so that, even under loss of packaging, the loss of radioactive material per package by leaching when placed in water for seven days would not exceed 0.1 A2; and (iii) the estimated average specific activity of the solid, excluding any shielding material, does not exceed 2 × 10-3 A2/g. 2.2.7.2.3.1.3 LSA-III material shall be a solid of such a nature that if the entire contents of a package were subjected to the test specified in 2.2.7.2.3.1.4 the activity in the water would not exceed 0.1 A2. 2.2.7.2.3.1.4 LSA-III material shall be tested as follows: A solid material sample representing the entire contents of the package shall be immersed for 7 days in water at ambient temperature. The volume of water to be used in the test shall be sufficient to ensure that at the end of the 7 day test period the free volume of the unabsorbed and unreacted water remaining shall be at least 10% of the volume of the solid test sample itself. The water shall have an initial pH of 6-8 and a maximum conductivity of 1 mS/m at 20 °C. The total activity of the free volume of water shall be measured following the 7 day immersion of the test sample. 2.2.7.2.3.1.5 Demonstration of compliance with the performance standards in 2.2.7.2.3.1.4 shall be in accordance with 6.4.12.1 and 6.4.12.2. 2.2.7.2.3.2 Surface contaminated object (SCO) SCO is classified in one of two groups: (a) SCO-I: A solid object on which: (i) the non-fixed contamination on the accessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 4 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 0.4 Bq/cm2 for all other alpha emitters; and (ii) the fixed contamination on the accessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 4 × 104 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 4 × 103 Bq/cm2 for all other alpha emitters; and - 238 - Copyright © United Nations, 2010. All rights reserved (iii) (b) the non-fixed contamination plus the fixed contamination on the inaccessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 4 × 104 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 4 × 103 Bq/cm2 for all other alpha emitters; SCO-II: A solid object on which either the fixed or non-fixed contamination on the surface exceeds the applicable limits specified for SCO-I in (a) above and on which: (i) the non-fixed contamination on the accessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 400 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 40 Bq/cm2 for all other alpha emitters; and (ii) the fixed contamination on the accessible surface, averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 8 × 105 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 8 × 104 Bq/cm2 for all other alpha emitters; and (iii) the non-fixed contamination plus the fixed contamination on the inaccessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 8 × 105 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 8 × 104 Bq/cm2 for all other alpha emitters. 2.2.7.2.3.3 Special form radioactive material 2.2.7.2.3.3.1 Special form radioactive material shall have at least one dimension not less than 5 mm. When a sealed capsule constitutes part of the special form radioactive material, the capsule shall be so manufactured that it can be opened only by destroying it. The design for special form radioactive material requires unilateral approval. 2.2.7.2.3.3.2 Special form radioactive material shall be of such a nature or shall be so designed that if it is subjected to the tests specified in 2.2.7.2.3.3.4 to 2.2.7.2.3.3.8, it shall meet the following requirements: (a) It would not break or shatter under the impact, percussion and bending tests 2.2.7.2.3.3.5 (a), (b), (c) and 2.2.7.2.3.3.6 (a) as applicable; (b) It would not melt or disperse in the applicable heat test 2.2.7.2.3.3.5 (d) or 2.2.7.2.3.3.6 (b) as applicable; and (c) The activity in the water from the leaching tests specified in 2.2.7.2.3.3.7 and 2.2.7.2.3.3.8 would not exceed 2 kBq; or alternatively for sealed sources, the leakage rate for the volumetric leakage assessment test specified in ISO 9978:1992 "Radiation Protection - Sealed Radioactive Sources - Leakage Test Methods", would not exceed the applicable acceptance threshold acceptable to the competent authority. 2.2.7.2.3.3.3 Demonstration of compliance with the performance standards in 2.2.7.2.3.3.2 shall be in accordance with 6.4.12.1 and 6.4.12.2. 2.2.7.2.3.3.4 Specimens that comprise or simulate special form radioactive material shall be subjected to the impact test, the percussion test, the bending test, and the heat test specified in 2.2.7.2.3.3.5 or alternative tests as authorized in 2.2.7.2.3.3.6. A different specimen may be used for each of the tests. Following each test, a leaching assessment or volumetric leakage test shall be performed on the specimen by a method no less sensitive than the methods given in 2.2.7.2.3.3.7 for indispersible solid material or 2.2.7.2.3.3.8 for encapsulated material. - 239 - Copyright © United Nations, 2010. All rights reserved 2.2.7.2.3.3.5 2.2.7.2.3.3.6 The relevant test methods are: (a) Impact test: The specimen shall drop onto the target from a height of 9 m. The target shall be as defined in 6.4.14; (b) Percussion test: The specimen shall be placed on a sheet of lead which is supported by a smooth solid surface and struck by the flat face of a mild steel bar so as to cause an impact equivalent to that resulting from a free drop of 1.4 kg through 1 m. The lower part of the bar shall be 25 mm in diameter with the edges rounded off to a radius of (3.0 ± 0.3) mm. The lead, of hardness number 3.5 to 4.5 on the Vickers scale and not more than 25 mm thick, shall cover an area greater than that covered by the specimen. A fresh surface of lead shall be used for each impact. The bar shall strike the specimen so as to cause maximum damage; (c) Bending test: The test shall apply only to long, slender sources with both a minimum length of 10 cm and a length to minimum width ratio of not less than 10. The specimen shall be rigidly clamped in a horizontal position so that one half of its length protrudes from the face of the clamp. The orientation of the specimen shall be such that the specimen will suffer maximum damage when its free end is struck by the flat face of a steel bar. The bar shall strike the specimen so as to cause an impact equivalent to that resulting from a free vertical drop of 1.4 kg through 1 m. The lower part of the bar shall be 25 mm in diameter with the edges rounded off to a radius of (3.0 ± 0.3) mm; (d) Heat test: The specimen shall be heated in air to a temperature of 800 °C and held at that temperature for a period of 10 minutes and shall then be allowed to cool. Specimens that comprise or simulate radioactive material enclosed in a sealed capsule may be excepted from: (a) (b) 2.2.7.2.3.3.7 The tests prescribed in 2.2.7.2.3.3.5 (a) and (b) provided the mass of the special form radioactive material: (i) is less than 200 g and they are alternatively subjected to the Class 4 impact test prescribed in ISO 2919:1999 "Radiation protection - Sealed radioactive sources - General requirements and classification"; or (ii) is less than 500 g and they are alternatively subjected to the Class 5 impact test prescribed in ISO 2919:1999 "Radiation protection - Sealed radioactive sources - General requirements and classification"; and The test prescribed in 2.2.7.2.3.3.5 (d) provided they are alternatively subjected to the Class 6 temperature test specified in ISO 2919:1999 "Radiation protection - Sealed radioactive sources - General requirements and classification". For specimens which comprise or simulate indispersible solid material, a leaching assessment shall be performed as follows: (a) The specimen shall be immersed for 7 days in water at ambient temperature. The volume of water to be used in the test shall be sufficient to ensure that at the end of the 7 day test period the free volume of the unabsorbed and unreacted water remaining shall be at least 10% of the volume of the solid test sample itself. The water shall have an initial pH of 6-8 and a maximum conductivity of 1 mS/m at 20 °C; (b) The water with specimen shall then be heated to a temperature of (50 ± 5) °C and maintained at this temperature for 4 hours; - 240 - Copyright © United Nations, 2010. All rights reserved 2.2.7.2.3.3.8 (c) The activity of the water shall then be determined; (d) The specimen shall then be kept for at least 7 days in still air at not less than 30 °C and relative humidity not less than 90%; (e) The specimen shall then be immersed in water of the same specification as in (a) above and the water with the specimen heated to (50 ± 5) °C and maintained at this temperature for 4 hours; (f) The activity of the water shall then be determined. For specimens which comprise or simulate radioactive material enclosed in a sealed capsule, either a leaching assessment or a volumetric leakage assessment shall be performed as follows: (a) (b) The leaching assessment shall consist of the following steps: (i) the specimen shall be immersed in water at ambient temperature. The water shall have an initial pH of 6-8 with a maximum conductivity of 1 mS/m at 20 °C; (ii) the water and specimen shall be heated to a temperature of (50 ± 5) °C and maintained at this temperature for 4 hours; (iii) the activity of the water shall then be determined; (iv) the specimen shall then be kept for at least 7 days in still air at not less than 30 °C and relative humidity of not less than 90%; (v) the process in (i), (ii) and (iii) shall be repeated; The alternative volumetric leakage assessment shall comprise any of the tests prescribed in ISO 9978:1992 "Radiation Protection - Sealed radioactive sources Leakage test methods", which are acceptable to the competent authority. 2.2.7.2.3.4 Low dispersible radioactive material 2.2.7.2.3.4.1 The design for low dispersible radioactive material shall require multilateral approval. Low dispersible radioactive material shall be such that the total amount of this radioactive material in a package, taking into account the provisions of 6.4.8.14, shall meet the following requirements: (a) The radiation level at 3 m from the unshielded radioactive material does not exceed 10 mSv/h; (b) If subjected to the tests specified in 6.4.20.3 and 6.4.20.4, the airborne release in gaseous and particulate forms of up to 100 μm aerodynamic equivalent diameter would not exceed 100 A2. A separate specimen may be used for each test; and (c) If subjected to the test specified in 2.2.7.2.3.1.4 the activity in the water would not exceed 100 A2. In the application of this test, the damaging effects of the tests specified in (b) above shall be taken into account. - 241 - Copyright © United Nations, 2010. All rights reserved 2.2.7.2.3.4.2 Low dispersible radioactive material shall be tested as follows: A specimen that comprises or simulates low dispersible radioactive material shall be subjected to the enhanced thermal test specified in 6.4.20.3 and the impact test specified in 6.4.20.4. A different specimen may be used for each of the tests. Following each test, the specimen shall be subjected to the leach test specified in 2.2.7.2.3.1.4. After each test it shall be determined if the applicable requirements of 2.2.7.2.3.4.1 have been met. 2.2.7.2.3.4.3 Demonstration of compliance with the performance standards and 2.2.7.2.3.4.2 shall be in accordance with 6.4.12.1 and 6.4.12.2. 2.2.7.2.3.5 Fissile material in 2.2.7.2.3.4.1 Packages containing fissile material shall be classified under the relevant entry of Table 2.2.7.2.1.1, the description of which includes the words "FISSILE" or "fissile-excepted". Classification as "fissile-excepted" is allowed only if one of the conditions (a) to (d) of this paragraph is met. Only one type of exception is allowed per consignment (see also 6.4.7.2). (a) A mass limit per consignment, provided that the smallest external dimension of each package is not less than 10 cm, such that: mass of uranium − 235 (g) mass of other fissile material (g) + <1 X Y where X and Y are the mass limits defined in Table 2.2.7.2.3.5, provided that either: (i) each individual package contains not more than 15 g of fissile nuclides; for unpackaged material, this quantity limitation shall apply to the consignment being carried in or on the vehicle; or (ii) the fissile material is a homogeneous hydrogenous solution or mixture where the ratio of fissile nuclides to hydrogen is less than 5% by mass; or (iii) there are not more than 5 g of fissile nuclides in any 10 litre volume of material. Beryllium shall not be present in quantities exceeding 1% of the applicable consignment mass limits provided in Table 2.2.7.2.3.5 except where the concentration of beryllium in the material does not exceed 1 gram beryllium in any 1 000 grams. Deuterium shall also not be present in quantities exceeding 1% of the applicable consignment mass limits provided in Table 2.2.7.2.3.5 except where deuterium occurs up to natural concentration in hydrogen. (b) Uranium enriched in uranium-235 to a maximum of 1% by mass, and with a total plutonium and uranium-233 content not exceeding 1% of the mass of uranium-235, provided that the fissile nuclides are distributed essentially homogeneously throughout the material. In addition, if uranium-235 is present in metallic, oxide or carbide forms, it shall not form a lattice arrangement; (c) Liquid solutions of uranyl nitrate enriched in uranium-235 to a maximum of 2% by mass, with a total plutonium and uranium-233 content not exceeding 0.002% of the mass of uranium, and with a minimum nitrogen to uranium atomic ratio (N/U) of 2; (d) Plutonium containing not more than 20% of fissile nuclides by mass up to a maximum of 1 kg of plutonium per consignment. Shipments under this exception shall be under exclusive use. - 242 - Copyright © United Nations, 2010. All rights reserved Table 2.2.7.2.3.5: Consignment mass limits for exceptions from the requirements for packages containing fissile material Fissile material Fissile material mass (g) mixed Fissile material mass (g) mixed with substances having an average with substances having an average hydrogen density less than hydrogen density greater than or equal to water water 400 290 Uranium-235 (X) Other fissile material (Y) 2.2.7.2.4 250 180 Classification of packages or unpacked material The quantity of radioactive material in a package shall not exceed the relevant limits for the package type as specified below. 2.2.7.2.4.1 Classification as excepted package 2.2.7.2.4.1.1 Packages may be classified as excepted packages if: 2.2.7.2.4.1.2 (a) They are empty packagings having contained radioactive material; (b) They contain instruments or articles in limited quantities as specified in Table 2.2.7.2.4.1.2; (c) They contain articles manufactured of natural uranium, depleted uranium or natural thorium; or (d) They contain radioactive material in limited quantities as specified in Table 2.2.7.2.4.1.2. A package containing radioactive material may be classified as an excepted package provided that the radiation level at any point on its external surface does not exceed 5 μSv/h. Table 2.2.7.2.4.1.2: Activity limits for excepted packages Physical state of contents (1) Solids special form other form Liquids Instruments or articles Package limits a Item limits a (2) (3) 10-2 A1 10-2 A2 A1 A2 10-3 A1 10-3 A2 10-3 A2 10-1 A2 10-4 A2 Gases tritium 2 × 10-2 A2 2 × 10-1 A2 -3 special form 10 A1 10-2 A1 -3 other forms 10 A2 10-2 A2 a For mixtures of radionuclides, see 2.2.7.2.2.4 to 2.2.7.2.2.6. 2.2.7.2.4.1.3 Materials Package limits a (4) 2 × 10-2 A2 10-3 A1 10-3 A2 Radioactive material which is enclosed in or is included as a component part of an instrument or other manufactured article may be classified under UN No. 2911 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - INSTRUMENTS or ARTICLES only if: - 243 - Copyright © United Nations, 2010. All rights reserved 2.2.7.2.4.1.4 2.2.7.2.4.1.5 (a) The radiation level at 10 cm from any point on the external surface of any unpackaged instrument or article is not greater than 0.1 mSv/h; and (b) Each instrument or manufactured article bears the marking "RADIOACTIVE" except: radioluminescent time-pieces or devices; (ii) consumer products that either have received regulatory approval according to 1.7.1.4 (d) or do not individually exceed the activity limit for an exempt consignment in Table 2.2.7.2.2.1 (column 5), provided such products are carried in a package that bears the marking "RADIOACTIVE" on an internal surface in such a manner that warning of the presence of radioactive material is visible on opening the package; and (c) The active material is completely enclosed by non-active components (a device performing the sole function of containing radioactive material shall not be considered to be an instrument or manufactured article); and (d) The limits specified in columns 2 and 3 of Table 2.2.7.2.4.1.2 are met for each individual item and each package, respectively. Radioactive material in forms other than as specified in 2.2.7.2.4.1.3 and with an activity not exceeding the limits specified in column 4 of Table 2.2.7.2.4.1.2, may be classified under UN No. 2910 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL provided that: (a) The package retains its radioactive contents under routine conditions of carriage; and (b) The package bears the marking "RADIOACTIVE" on an internal surface in such a manner that a warning of the presence of radioactive material is visible on opening the package. An empty packaging which had previously contained radioactive material may be classified under UN No. 2908 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - EMPTY PACKAGING, only if: (a) It is in a well-maintained condition and securely closed; (b) The outer surface of any uranium or thorium in its structure is covered with an inactive sheath made of metal or some other substantial material; (c) The level of internal non-fixed contamination, when averaged over any 300 cm2, does not exceed: (d) 2.2.7.2.4.1.6 (i) (i) 400 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters; and (ii) 40 Bq/cm2 for all other alpha emitters; and Any labels which may have been displayed on it in conformity with 5.2.2.1.11.1 are no longer visible. Articles manufactured of natural uranium, depleted uranium or natural thorium and articles in which the sole radioactive material is unirradiated natural uranium, unirradiated depleted uranium or unirradiated natural thorium may be classified under UN No. 2909 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - ARTICLES MANUFACTURED FROM NATURAL URANIUM or DEPLETED URANIUM or NATURAL THORIUM, - 244 - Copyright © United Nations, 2010. All rights reserved only if the outer surface of the uranium or thorium is enclosed in an inactive sheath made of metal or some other substantial material. 2.2.7.2.4.2 Classification as Low specific activity (LSA) material Radioactive material may only be classified as LSA material if the definition of LSA in 2.2.7.1.3 and the conditions of 2.2.7.2.3.1, 4.1.9.2 and 7.5.11 CV33 (2) are met. 2.2.7.2.4.3 Classification as Surface contaminated object (SCO) Radioactive material may be classified as SCO if the definition of SCO in 2.2.7.1.3 and the conditions of 2.2.7.2.3.2, 4.1.9.2 and 7.5.11 CV33 (2) are met. 2.2.7.2.4.4 Classification as Type A package Packages containing radioactive material may be classified as Type A packages provided that the following conditions are met: Type A packages shall not contain activities greater than the following: (a) For special form radioactive material - A1; or (b) For all other radioactive material - A2. For mixtures of radionuclides whose identities and respective activities are known, the following condition shall apply to the radioactive contents of a Type A package: Σi where C(j) B(i) + Σj ≤1 A2 (j) A1 (i) B(i) is the activity of radionuclide i as special form radioactive material; A1(i) is the A1 value for radionuclide i; C(j) is the activity of radionuclide j as other than special form radioactive material; and A2(j) is the A2 value for radionuclide j. 2.2.7.2.4.5 Classification of Uranium hexafluoride Uranium hexafluoride shall only be assigned to UN Nos. 2977 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE, or 2978 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, non fissile or fissile-excepted. 2.2.7.2.4.5.1 Packages containing uranium hexafluoride shall not contain: (a) A mass of uranium hexafluoride different from that authorized for the package design; (b) A mass of uranium hexafluoride greater than a value that would lead to an ullage smaller than 5% at the maximum temperature of the package as specified for the plant systems where the package shall be used; or (c) Uranium hexafluoride other than in solid form or at an internal pressure above atmospheric pressure when presented for carriage. - 245 - Copyright © United Nations, 2010. All rights reserved 2.2.7.2.4.6 Classification as Type B(U), Type B(M) or Type C packages 2.2.7.2.4.6.1 Packages not otherwise classified in 2.2.7.2.4 (2.2.7.2.4.1 to 2.2.7.2.4.5) shall be classified in accordance with the competent authority approval certificate for the package issued by the country of origin of design. 2.2.7.2.4.6.2 A package may only be classified as a Type B(U) if it does not contain: (a) Activities greater than those authorized for the package design; (b) Radionuclides different from those authorized for the package design; or (c) Contents in a form, or a physical or chemical state different from those authorized for the package design; as specified in the certificate of approval. 2.2.7.2.4.6.3 A package may only be classified as a Type B(M) if it does not contain: (a) Activities greater than those authorized for the package design; (b) Radionuclides different from those authorized for the package design; or (c) Contents in a form, or a physical or chemical state different from those authorized for the package design; as specified in the certificate of approval. 2.2.7.2.4.6.4 A package may only be classified as a Type C if it does not contain: (a) Activities greater than those authorized for the package design; (b) Radionuclides different from those authorized for the package design; or (c) Contents in a form, or physical or chemical state different from those authorized for the package design; as specified in the certificate of approval. 2.2.7.2.5 Special arrangements Radioactive material shall be classified as transported under special arrangement when it is intended to be carried in accordance with 1.7.4. - 246 - Copyright © United Nations, 2010. All rights reserved 2.2.8 Class 8 2.2.8.1 Criteria 2.2.8.1.1 The heading of Class 8 covers substances and articles containing substances of this class which by chemical action attack epithelial tissue - of skin or mucous membranes - with which they are in contact, or which in the event of leakage are capable of damaging or destroying other goods, or means of transport. The heading of this class also covers other substances which form a corrosive liquid only in the presence of water, or which produce corrosive vapour or mist in the presence of natural moisture of the air. 2.2.8.1.2 Substances and articles of Class 8 are subdivided as follows: C1-C10 Corrosive substances Corrosive substances without subsidiary risk: C1-C4 Acid substances: C1 Inorganic, liquid; C2 Inorganic, solid; C3 Organic, liquid; C4 Organic, solid; C5-C8 Basic substances: C5 Inorganic, liquid; C6 Inorganic, solid; C7 Organic, liquid; C8 Organic, solid; C9-C10 Other corrosive substances: C9 Liquid; C10 Solid; C11 Articles; CF Corrosive substances, flammable: CF1 Liquid; CF2 Solid; CS Corrosive substances, self-heating: CS1 Liquid; CS2 Solid; CW Corrosive substances which, in contact with water, emit flammable gases: CW1 Liquid; CW2 Solid; CO Corrosive substances, oxidizing: CO1 Liquid; CO2 Solid; CT Corrosive substances, toxic: CT1 Liquid; CT2 Solid; CFT Corrosive substances, flammable, liquid, toxic; COT Corrosive substances, oxidizing, toxic. - 247 - Copyright © United Nations, 2010. All rights reserved Classification and assignment of packing groups 2.2.8.1.3 Substances of Class 8 shall be classified in three packing groups according to the degree of danger they present for carriage, as follows: Packing group I: Packing group II: Packing group III: highly corrosive substances corrosive substances slightly corrosive substances. 2.2.8.1.4 Substances and articles classified in Class 8 are listed in Table A of Chapter 3.2. Allocation of substances to packing groups I, II and III has been made on the basis of experience taking into account such additional factors as inhalation risk (see 2.2.8.1.5) and reactivity with water (including the formation of dangerous decomposition products). 2.2.8.1.5 A substance or preparation meeting the criteria of Class 8 having an inhalation toxicity of dusts and mists (LC50) in the range of packing group I, but toxicity through oral ingestion or dermal contact only in the range of packing group III or less, shall be allocated to Class 8. 2.2.8.1.6 Substances, including mixtures, not mentioned by name in Table A of Chapter 3.2 can be assigned to the relevant entry of sub-section 2.2.8.3, and to the relevant packing group on the basis of the length of time of contact necessary to produce full thickness destruction of human skin in accordance with the criteria of (a) to (c) below. Liquids, and solids which may become liquid during carriage, which are judged not to cause full thickness destruction of human skin shall still be considered for their potential to cause corrosion to certain metal surfaces. In assigning the packing group, account shall be taken of human experience in instances of accidental exposure. In the absence of human experience, the grouping shall be based on data obtained from experiments in accordance with OECD Test Guideline 4047 or 4358. A substance which is determined not to be corrosive in accordance with OECD Test Guideline 4309 or 43110 may be considered not to be corrosive to skin for the purposes of ADR without further testing.. 7 8 9 10 (a) Packing group I is assigned to substances that cause full thickness destruction of intact skin tissue within an observation period up to 60 minutes starting after the exposure time of 3 minutes or less; (b) Packing group II is assigned to substances that cause full thickness destruction of intact skin tissue within an observation period up to 14 days starting after the exposure time of more than 3 minutes but not more than 60 minutes; (c) Packing group III is assigned to substances that: - cause full thickness destruction of intact skin tissue within an observation period up to 14 days starting after the exposure time of more than 60 minutes but not more than 4 hours; or - are judged not to cause full thickness destruction of intact skin tissue, but which exhibit a corrosion rate on either steel or aluminium surfaces exceeding 6.25 mm a year at a test temperature of 55 °C when tested on both materials. For the purposes of testing steel, type S235JR+CR (1.0037 resp. St 37-2), OECD Guideline for the testing of chemicals No. 404 "Acute Dermal Irritation/Corrosion" 2002. OECD Guideline for the testing of chemicals No. 435 "In Vitro Membrane Barrier Test Method for Skin Corrosion" 2006. OECD Guideline for the testing of chemicals No. 430 "In Vitro Skin Corrosion: Transcutaneous Electrical Resistance Test (TER)" 2004. OECD Guideline for the testing of chemicals No. 431 "In Vitro Skin Corrosion: Human Skin Model Test" 2004. - 248 - Copyright © United Nations, 2010. All rights reserved S275J2G3+CR (1.0144 resp. St 44-3), ISO 3574, Unified Numbering System (UNS) G10200 or SAE 1020, and for testing aluminium, non-clad, types 7075T6 or AZ5GU-T6 shall be used. An acceptable test is prescribed in the Manual of Tests and Criteria, Part III, Section 37. NOTE: Where an initial test on either steel or aluminium indicates the substance being tested is corrosive the follow up test on the other metal is not required. 2.2.8.1.7 If substances of Class 8, as a result of admixtures, come into categories of risk different from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong, on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also 2.1.3. 2.2.8.1.8 On the basis of the criteria set out in paragraph 2.2.8.1.6, it may also be determined whether the nature of a solution or mixture mentioned by name or containing a substance mentioned by name is such that the solution or mixture is not subject to the provisions for this class. 2.2.8.1.9 Substances, solutions and mixtures, which - do not meet the criteria of Directives 67/548/EEC 3 or 1999/45/EC 4 as amended and therefore are not classified as corrosive according to these directives, as amended; and - do not exhibit a corrosive effect on steel or aluminium; may be considered as substances not belonging to Class 8. NOTE: UN No. 1910 calcium oxide and UN No. 2812 sodium aluminate, listed in the UN Model Regulations, are not subject to the provisions of ADR. 2.2.8.2 Substances not accepted for carriage 2.2.8.2.1 The chemically unstable substances of Class 8 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end it shall in particular be ensured that receptacles and tanks do not contain any substance liable to promote these reactions. 2.2.8.2.2 The following substances shall not be accepted for carriage: - UN No. 1798 NITROHYDROCHLORIC ACID; - chemically unstable mixtures of spent sulphuric acid; - chemically unstable mixtures of nitrating acid or mixtures of residual sulphuric and nitric acids, not denitrated; - perchloric acid aqueous solution with more than 72% pure acid, by mass, or mixtures of perchloric acid with any liquid other than water. 3 Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances (Official Journal of the European Communities No. L 196 of 16.08.1967). 4 Directive 1999/45/EC of the European Parliament and of the Council of 31 May 1999 on the approximation of laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations (Official Journal of the European Communities No. L 200 of 30 July 1999). - 249 - Copyright © United Nations, 2010. All rights reserved 2.2.8.3 List of collective entries Corrosive substances without subsidiary risk liquid C1 2584 2584 2693 2837 3264 ALKYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid or ARYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid BISULPHITES, AQUEOUS SOLUTION, N.O.S. BISULPHATES, AQUEOUS SOLUTION CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 1740 2583 2583 3260 HYDROGENDIFLUORIDES, SOLID, N.O.S. ALKYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid or ARYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 2586 2586 2987 3145 3265 ALKYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid or ARYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid CHLOROSILANES, CORROSIVE, N.O.S. ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S 2430 2585 2585 3261 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) ALKYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid or ARYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. inorganic solid C2 Acid C1-C4 liquid C3 organic solid C4 liquid C5 1719 CAUSTIC ALKALI LIQUID, N.O.S. 2797 BATTERY FLUID, ALKALI 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. solid 3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. inorganic C6 Basic C5-C8 liquid C7 organic solid C8 liquid C9 Other corrosive substances C9-C10 2735 AMINES, LIQUID, CORROSIVE, N.O.S. or 2735 POLYAMINES, LIQUID, CORROSIVE, N.O.S. 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 3259 AMINES, SOLID, CORROSIVE, N.O.S., or 3259 POLYAMINES, SOLID, CORROSIVE, N.O.S. 3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 1903 2801 2801 3066 DISINFECTANT, LIQUID, CORROSIVE, N.O.S DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. PAINT (including paint, enamel, stain, shellac, varnish, polish, liquid filler and lacquer base) or 3066 PAINT RELATED MATERIAL (including paint thinning or reducing compound) 1760 CORROSIVE LIQUID, N.O.S. 3147 DYE, SOLID, CORROSIVE, N.O.S. or 3147 DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. 3244 SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S. solida Articles C10 C11 1759 CORROSIVE SOLID, N.O.S. 2794 2795 2800 3028 BATTERIES, WET, FILLED WITH ACID, electric storage BATTERIES, WET, FILLED WITH ALKALI, electric storage BATTERIES, WET, NON-SPILLABLE, electric storage BATTERIES, DRY, CONTAINING POTASSIUM HYDROXIDE SOLID, electric storage (cont'd on next page) a Mixtures of solids which are not subject to the provisions of ADR and of corrosive liquids may be carried under UN No. 3244 without being subject to the classification criteria of Class 8, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, container or transport unit is closed. Each packaging shall correspond to a design type which has passed the leakproofness test for Packing group II level. - 250 - Copyright © United Nations, 2010. All rights reserved Corrosive substances with subsidiary risk(s) (cont'd) 3470 PAINT, CORROSIVE, FLAMMABLE (including paint, enamel, stain, shellac, varnish, polish, liquid filler and lacquer base) or 3470 PAINT RELATED MATERIAL, CORROSIVE, FLAMMABLE (including paint thinning or reducing compound) 2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or 2734 POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. 2986 CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S. 2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S. liquid CF1 solid CF2 2921 CORROSIVE SOLID, FLAMMABLE, N.O.S. liquid CS1 3301 CORROSIVE LIQUID, SELF-HEATING, N.O.S. solid CS2 3095 CORROSIVE SOLID, SELF-HEATING, N.O.S. liquid b CW1 3094 CORROSIVE LIQUID, WATER-REACTIVE, N.O.S. solid CW2 3096 CORROSIVE SOLID, WATER-REACTIVE, N.O.S. liquid CO1 3093 CORROSIVE LIQUID, OXIDIZING, N.O.S. solid CO2 3084 CORROSIVE SOLID, OXIDIZING, N.O.S. liquid c CT1 3471 2922 HYDROGENDIFLUORIDES SOLUTION, N.O.S. CORROSIVE LIQUID, TOXIC, N.O.S. solid e CT2 2923 CORROSIVE SOLID, TOXIC, N.O.S. Flammable, liquid, toxic d CFT No collective entry with this classification code available; if need be, classification under a collective entry with a classification code to be determined according to table of precedence of hazard in 2.1.3.10. Oxidizing, toxic d, e COT No collective entry with this classification code available; if need be, classification under a collective entry with a classification code to be determined according to table of precedence of hazard in 2.1.3.10. Flammable CF b Self-heating CS Water-reactive CW Oxidizing CO c Toxic d CT b Chlorosilanes which, in contact with water or moist air, emit flammable gases, are substances of Class 4.3. c Chloroformates having predominantly toxic properties are substances of Class 6.1. d Corrosive substances which are highly toxic by inhalation, as defined in 2.2.61.1.4 to 2.2.61.1.9 are substances of Class 6.1. e UN No. 2505 AMMONIUM FLUORIDE, UN No. 1812 POTASSIUM FLUORIDE, SOLID, UN No. 1690 SODIUM FLUORIDE, SOLID, UN No. 2674 SODIUM FLUOROSILICATE, UN No. 2856 FLUOROSILICATES, N.O.S., UN No. 3415 SODIUM FLUORIDE SOLUTION and UN No. 3422 POTASSIUM FLUORIDE SOLUTION are substances of Class 6.1. - 251 - Copyright © United Nations, 2010. All rights reserved 2.2.9 Class 9 Miscellaneous dangerous substances and articles 2.2.9.1 Criteria 2.2.9.1.1 The heading of Class 9 covers substances and articles which, during carriage, present a danger not covered by the heading of other classes. 2.2.9.1.2 The substances and articles of Class 9 are subdivided as follows: M1 Substances which, on inhalation as fine dust, may endanger health; M2 Substances and apparatus which, in the event of fire, may form dioxins; M3 Substances evolving flammable vapour; M4 Lithium batteries; M5 Life-saving appliances; M6-M8 Environmentally hazardous substances: M6 M7 M8 M9-M10 Pollutant to the aquatic environment, liquid; Pollutant to the aquatic environment, solid; Genetically modified microorganisms and organisms; Elevated temperature substances: M9 Liquid; M10 Solid; M11 Other substances presenting a danger during carriage, but not meeting the definitions of another class. Definitions and classification 2.2.9.1.3 Substances and articles classified in Class 9 are listed in Table A of Chapter 3.2. The assignment of substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant entry of that Table or of sub-section 2.2.9.3 shall be done in accordance with 2.2.9.1.4 to 2.2.9.1.14 below. Substances which, on inhalation as fine dust, may endanger health 2.2.9.1.4 Substances which, on inhalation as fine dust, may endanger health include asbestos and mixtures containing asbestos. Substances and apparatus which, in the event of fire, may form dioxins 2.2.9.1.5 Substances and apparatus which, in the event of fire, may form dioxins include polychlorinated biphenyls (PCBs) and terphenyls (PCTs) and polyhalogenated biphenyls and terphenyls and mixtures containing these substances, as well as apparatus such as transformers, condensers and apparatus containing those substances or mixtures. NOTE: Mixtures with a PCB or PCT content of not more than 50 mg/kg are not subject to the provisions of ADR. - 252 - Copyright © United Nations, 2010. All rights reserved Substances evolving flammable vapour 2.2.9.1.6 Substances evolving flammable vapour include polymers containing flammable liquids with a flash-point not exceeding 55 °C. Lithium batteries 2.2.9.1.7 The term "lithium battery" covers all cells and batteries containing lithium in any form. They may be assigned to Class 9 if they meet the requirements of special provision 230 of Chapter 3.3. They are not subject to the provisions of ADR if they meet the requirements of special provision 188 of Chapter 3.3. They shall be classified in accordance with the procedures of Section 38.3 of the Manual of Tests and Criteria. Life-saving appliances 2.2.9.1.8 Life-saving appliances include life-saving appliances and motor vehicle components which meet the descriptions of special provisions 235 or 296 of Chapter 3.3. Environmentally hazardous substances 2.2.9.1.9 (Deleted) Pollutants to the aquatic environment 2.2.9.1.10 Environmentally hazardous substances (aquatic environment) 2.2.9.1.10.1 General definitions 2.2.9.1.10.1.1 Environmentally hazardous substances include, inter alia, liquid or solid substances pollutant to the aquatic environment and solutions and mixtures of such substances (such as preparations and wastes). For the purposes of 2.2.9.1.10, "substance" means chemical elements and their compounds in the natural state or obtained by any production process, including any additive necessary to preserve the stability of the product and any impurities deriving from the process used, but excluding any solvent which may be separated without affecting the stability of the substance or changing its composition. 2.2.9.1.10.1.2 The aquatic environment may be considered in terms of the aquatic organisms that live in the water, and the aquatic ecosystem of which they are part 11. The basis, therefore, of the identification of hazard is the aquatic toxicity of the substance or mixture, although this may be modified by further information on the degradation and bioaccumulation behaviour. 2.2.9.1.10.1.3 While the following classification procedure is intended to apply to all substances and mixtures, it is recognised that in some cases, e.g. metals or poorly soluble inorganic compounds, special guidance will be necessary 12. 2.2.9.1.10.1.4 The following definitions apply for acronyms or terms used in this section: - BCF: Bioconcentration Factor; BOD: Biochemical Oxygen Demand; COD: Chemical Oxygen Demand; 11 This does not address aquatic pollutants for which there may be a need to consider effects beyond the aquatic environment such as the impacts on human health etc. 12 This can be found in Annex 10 of the GHS. - 253 - Copyright © United Nations, 2010. All rights reserved 2.2.9.1.10.2 GLP: Good Laboratory Practices; ECx: the concentration associated with x% response; EC50: the effective concentration of substance that causes 50% of the maximum response; ErC50: EC50 in terms of reduction of growth; Kow: octanol/water partition coefficient; LC50 (50% lethal concentration): the concentration of a substance in water which causes the death of 50% (one half) in a group of test animals; L(E)C50: LC50 or EC50; NOEC (No Observed Effect Concentration): the test concentration immediately below the lowest tested concentration with statistically significant adverse effect. The NOEC has no statistically significant adverse effect compared to the control; OECD Test Guidelines: Test guidelines published by the Organization for Economic Cooperation and Development (OECD). Definitions and data requirements 2.2.9.1.10.2.1 The basic elements for classification of environmentally hazardous substances (aquatic environment) are: (a) (b) (c) (d) Acute aquatic toxicity; Chronic aquatic toxicity; Potential for or actual bioaccumulation; and Degradation (biotic or abiotic) for organic chemicals. 2.2.9.1.10.2.2 While data from internationally harmonised test methods are preferred, in practice, data from national methods may also be used where they are considered as equivalent. In general, it has been agreed that freshwater and marine species toxicity data can be considered as equivalent data and are preferably to be derived using OECD Test Guidelines or equivalent according to the principles of Good Laboratory Practices (GLP). Where such data are not available, classification shall be based on the best available data. 2.2.9.1.10.2.3 Acute aquatic toxicity means the intrinsic property of a substance to be injurious to an organism in a short-term aquatic exposure to that substance. Acute (short-term) hazard, for classification purposes, means the hazard of a chemical caused by its acute toxicity to an organism during short-term aquatic exposure to that chemical. Acute aquatic toxicity shall normally be determined using a fish 96 hour LC50 (OECD Test Guideline 203 or equivalent), a crustacea species 48 hour EC50 (OECD Test Guideline 202 or equivalent) and/or an algal species 72 or 96 hour EC50 (OECD Test Guideline 201 or equivalent). These species are considered as surrogate for all aquatic organisms and data on other species such as Lemna may also be considered if the test methodology is suitable. 2.2.9.1.10.2.4 Chronic aquatic toxicity means the intrinsic property of a substance to cause adverse effects to aquatic organisms during aquatic exposures which are determined in relation to the lifecycle of the organism. Long-term hazard, for classification purposes, means the hazard of a chemical caused by its chronic toxicity following long-term exposure in the aquatic environment. Chronic toxicity data are less available than acute data and the range of testing procedures less standardised. Data generated according to the OECD Test Guidelines 210 (Fish Early Life Stage) or 211 (Daphnia Reproduction) and 201 (Algal Growth Inhibition) may be accepted. Other validated and internationally accepted tests may also be used. The NOECs or other equivalent ECx shall be used. - 254 - Copyright © United Nations, 2010. All rights reserved 2.2.9.1.10.2.5 Bioaccumulation means net result of uptake, transformation and elimination of a substance in an organism due to all routes of exposure (i.e. air, water, sediment/soil and food). The potential for bioaccumulation shall normally be determined by using the octanol/water partition coefficient, usually reported as a log Kow determined according to OECD Test Guideline 107 or 117. While this represents a potential to bioaccumulate, an experimentally determined Bioconcentration Factor (BCF) provides a better measure and shall be used in preference when available. A BCF shall be determined according to OECD Test Guideline 305. 2.2.9.1.10.2.6 Degradation means the decomposition of organic molecules to smaller molecules and eventually to carbon dioxide, water and salts. Environmental degradation may be biotic or abiotic (e.g. hydrolysis) and the criteria used reflect this fact. Ready biodegradation is most easily defined using the biodegradability tests (A-F) of OECD Test Guideline 301. A pass level in these tests may be considered as indicative of rapid degradation in most environments. These are freshwater tests and thus the use of the results from OECD Test Guideline 306, which is more suitable for marine environments, has also been included. Where such data are not available, a BOD(5 days)/COD ratio ≥ 0.5 is considered as indicative of rapid degradation. Abiotic degradation such as hydrolysis, primary degradation, both abiotic and biotic, degradation in non-aquatic media and proven rapid degradation in the environment may all be considered in defining rapid degradability 13. Substances are considered rapidly degradable in the environment if the following criteria are met: (a) In 28-day ready biodegradation studies, the following levels of degradation are achieved: (i) Tests based on dissolved organic carbon: 70%; (ii) Tests based on oxygen depletion or carbon dioxide generation: 60% of theoretical maxima; These levels of biodegradation shall be achieved within 10 days of the start of degradation which point is taken as the time when 10% of the substance has been degraded ", unless the substance is identified as a complex, multi-component substance with structurally similar constituents. In this case, and where there is sufficient justification, the 10-day window condition may be waived and the pass level applied at 28 days 14; or 13 14 (b) In those cases where only BOD and COD data are available, when the ratio of BOD5/COD is ≥ 0.5; or (c) If other convincing scientific evidence is available to demonstrate that the substance or mixture can be degraded (biotically and/or abiotically) in the aquatic environment to a level above 70% within a 28 day period. Special guidance on data interpretation is provided in Chapter 4.1 and Annex 9 of the GHS. See Chapter 4.1 and Annex 9, paragraph A9.4.2.2.3 of the GHS. - 255 - Copyright © United Nations, 2010. All rights reserved 2.2.9.1.10.3 Substance classification categories and criteria 2.2.9.1.10.3.1 Substances shall be classified as "environmentally hazardous substances (aquatic environment)", if they satisfy the criteria for Acute 1, Chronic 1 or Chronic 2, according to Table 2.2.9.1.10.3.1. These criteria describe in detail the classification categories. They are diagrammatically summarized in Table 2.2.9.1.10.3.2. Table 2.2.9.1.10.3.1: Categories for substances hazardous to the aquatic environment (see Note 1) (a) Acute (short-term) aquatic hazard Category Acute 1: (see Note 2) 96 hr LC50 (for fish) ≤ 1 mg/l and/or 48 hr EC50 (for crustacea) ≤ 1 mg/l and/or 72 or 96hr ErC50 (for algae or other aquatic plants) ≤ 1 mg/l (see Note 3) (b) Long-term aquatic hazard (see also Figure 2.2.9.1.10.3.1) (i) Non-rapidly degradable substances (see Note 4) for which there are adequate chronic toxicity data available Category Chronic 1: (see Note 2) Chronic NOEC or ECx (for fish) ≤ 0.1 mg/l and/or Chronic NOEC or ECx (for crustacea) ≤ 0.1 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants) ≤ 0.1 mg/l Category Chronic 2: Chronic NOEC or ECx (for fish) ≤ 1 mg/l and/or ≤ 1 mg/l and/or Chronic NOEC or ECx (for crustacea) ≤ 1 mg/l Rapidly degradable substances for which there are adequate chronic toxicity data available Chronic NOEC or ECx (for algae or other aquatic plants) (ii) Category Chronic 1: (see Note 2) Chronic NOEC or ECx (for fish) ≤ 0.01 mg/l and/or Chronic NOEC or ECx (for crustacea) ≤ 0.01 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants) ≤ 0.01 mg/l Category Chronic 2: Chronic NOEC or ECx (for fish) (iii) ≤ 0.1 mg/l and/or Chronic NOEC or ECx (for crustacea) ≤ 0.1 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants) ≤ 0.1 mg/l Substances for which adequate chronic toxicity data are not available Category Chronic 1: (see Note 2) 96 hr LC50 (for fish) ≤ 1 mg/l and/or 48 hr EC50 (for crustacea) ≤ 1 mg/l and/or 72 or 96hr ErC50 (for algae or other aquatic plants) ≤ 1 mg/l (see Note 3) and the substance is not rapidly degradable and/or the experimentally determined BCF is ≥ 500 (or, if absent the log Kow ≥ 4) (see Notes 4 and 5). Category Chronic 2: 96 hr LC50 (for fish) >1 but ≤ 10 mg/l and/or 48 hr EC50 (for crustacea) >1 but ≤ 10 mg/l and/or 72 or 96hr ErC50 (for algae or other aquatic plants) >1 but ≤ 10 mg/l (see Note 3) and the substance is not rapidly degradable and/or the experimentally determined BCF is ≥ 500 (or, if absent the log Kow ≥ 4 (see Notes 4 and 5). - 256 - Copyright © United Nations, 2010. All rights reserved NOTE 1: The organisms fish, crustacea and algae are tested as surrogate species covering a range of trophic levels and taxa, and the test methods are highly standardized. Data on other organisms may also be considered, however, provided they represent equivalent species and test endpoints. NOTE 2: When classifying substances as Acute 1 and/or Chronic 1 it is necessary at the same time to indicate an appropriate M factor (see 2.2.9.1.10.4.6.4 ) to apply the summation method. NOTE 3: Where the algal toxicity ErC50 (= EC50 (growth rate)) falls more than 100 times below the next most sensitive species and results in a classification based solely on this effect, consideration shall be given to whether this toxicity is representative of the toxicity to aquatic plants. Where it can be shown that this is not the case, professional judgment shall be used in deciding if classification shall be applied. Classification shall be based on the ErC50. In circumstances where the basis of the EC50 is not specified and no ErC50 is recorded, classification shall be based on the lowest EC50 available. NOTE 4: Lack of rapid degradability is based on either a lack of ready biodegradability or other evidence of lack of rapid degradation. When no useful data on degradability are available, either experimentally determined or estimated data, the substance shall be regarded as not rapidly degradable. NOTE 5: Potential to bioaccumulate, based on an experimentally derived BCF ≥ 500 or, if absent, a log Kow ≥ 4 provided log Kow is an appropriate descriptor for the bioaccumulation potential of the substance. Measured log Kow values take precedence over estimated values and measured BCF values take precedence over log Kow values. Figure 2.2.9.1.10.3.1: Categories for substances long-term hazardous to the aquatic environment Are there adequate chronic toxicity data available for all three trophic levels? See Note 2 to Table 2.2.9.1.10.3.1 Yes Classify according to the criteria given in Table 2.2.9.1.10.3.1 (b) (i) or 2.2.9.1.10.3.1 (b)(ii) depending on information on rapid degradation No Are there adequate chronic toxicity data available for one or two trophic levels? Yes Assess both: (a) according to the criteria given in Table2.2.9.1.10.3.1 (b)(i) or 2.2.9.1.10.3.1(b)(ii) (depending on information on rapid degradation), and (b) (if for the other trophic level(s) adequate acute toxicity data are available) according to the criteria given in Table 2.2.9.1.10.3.1(b) (iii), and classify according to the most stringent outcome No Are there adequate acute toxicity data available? Yes Classify according to the criteria given in Table 2.2.9.1.10.3.1(b) (iii) - 257 - Copyright © United Nations, 2010. All rights reserved 2.2.9.1.10.3.2 The classification scheme in Table 2.2.9.1.10.3.2 below summarizes the classification criteria for substances. Table 2.2.9.1.10.3.2: Classification scheme for substances hazardous to the aquatic environment Acute hazard (see Note 1) Category: Acute 1 L(E)C50 ≤ 1.00 Classification categories Long-term hazard (see Note 2) Adequate chronic toxicity data available Adequate chronic toxicity data not Non-rapidly Rapidly available (see Note 1) degradable substances degradable substances (see Note 3) (see Note 3) Category: Chronic 1 Category: Chronic 1 Category: Chronic 1 L(E)C50 ≤ 1.00 and lack of rapid NOEC or ECx ≤ 0.1 NOEC or ECx ≤ 0.01 degradability and/or BCF ≥ 500 or, if absent log Kow ≥ 4 Category: Chronic 2 Category: Chronic 2 Category: Chronic 2 1.00 < L(E)C50 ≤ 10.0 and lack of rapid degradability and/or 0.1 < NOEC or ECx ≤ 1 0.01 < NOEC or ECx ≤ 0.1 BCF ≥ 500 or, if absent log Kow ≥ 4 NOTE 1: Acute toxicity band based on L(E)C50 values in mg/l for fish, crustacea and/or algae or other aquatic plants (or Quantitative Structure Activity Relationships (QSAR) estimation if no experimental data15). NOTE 2: Substances are classified in the various chronic categories unless there are adequate chronic toxicity data available for all three trophic levels above the water solubility or above 1 mg/l. ("Adequate" means that the data sufficiently cover the endpoint of concern. Generally this would mean measured test data, but in order to avoid unnecessary testing it can on a case by case basis also be estimated data, e.g. (Q)SAR, or for obvious cases expert judgment). NOTE 3: Chronic toxicity band based on NOEC or equivalent ECx values in mg/l for fish or crustacea or other recognized measures for chronic toxicity. 2.2.9.1.10.4 Mixtures classification categories and criteria 2.2.9.1.10.4.1 The classification system for mixtures covers the classification categories which are used for substances, meaning categories Acute 1 and Chronic 1 and 2. In order to make use of all available data for purposes of classifying the aquatic environmental hazards of the mixture, the following assumption is made and is applied where appropriate: The "relevant ingredients" of a mixture are those which are present in a concentration equal to or greater than 0.1% (by mass) for ingredients classified as Acute and/or Chronic 1 and equal to or greater than 1% for other ingredients, unless there is a presumption (e.g. in the case of highly toxic ingredients) that an ingredient present at less than 0.1% can still be relevant for classifying the mixture for aquatic environmental hazards. 2.2.9.1.10.4.2 The approach for classification of aquatic environmental hazards is tiered, and is dependent upon the type of information available for the mixture itself and for its ingredients. Elements of the tiered approach include: 15 Special guidance is provided in Chapter 4.1, paragraph 4.1.2.13 and Annex 9, Section A9.6 of the GHS. - 258 - Copyright © United Nations, 2010. All rights reserved (a) Classification based on tested mixtures; (b) Classification based on bridging principles; (c) The use of "summation of classified ingredients" and/or an "additivity formula". Figure 2.2.9.1.10.4.2 below outlines the process to be followed. Figure 2.2.9.1.10.4.2: Tiered approach to classification of mixtures for acute and long-term aquatic environmental hazards Aquatic toxicity test data available on the mixture as a whole No Sufficient data available on similar mixtures to estimate hazards Yes Yes Apply bridging principles (2.2.9.1.10.4.4) CLASSIFY for acute/ long-term hazard (2.2.9.1.10.4.3) CLASSIFY For acute/long-term hazard No Either aquatic toxicity or classification data available for all relevant ingredients Yes Apply Summation Method (2.2.9.1.10.4.6.1 to 2.2.9.1.10.4.6.4) using: (a) Percentage of all ingredients classified as "Chronic" (b) Percentage of ingredients classified as "Acute" (c) Percentage of ingredients with acute toxicity data: apply additivity formulas (2.2.9.1.10.4.5.2) and convert the derived L(E)C50 or EqNOECm to the appropriate "Acute" or "Chronic" Category CLASSIFY For acute/long-term hazard Apply Summation Method and additivity formula (2.2.9.1.10.4.6.1 to 2.2.9.1.10.4.6.4) and apply 2.2.9.1.10.4.6.5 CLASSIFY For acute/long-term hazard No Use available hazard data of known ingredients 2.2.9.1.10.4.3 Classification of mixtures when toxicity data are available for the complete mixture 2.2.9.1.10.4.3.1 When the mixture as a whole has been tested to determine its aquatic toxicity, this information shall be used for classifying the mixture according to the criteria that have been agreed for substances. The classification is normally based on the data for fish, crustacea and algae/plants (see 2.2.9.1.10.2.3 and 2.2.9.1.10.2.4). When adequate acute or chronic data for the mixture as a whole are lacking, "bridging principles" or "summation method" shall be applied (see 2.2.9.1.10.4.4 to 2.2.9.1.10.4.6). 2.2.9.1.10.4.3.2 The long-term hazard classification of mixtures requires additional information on degradability and in certain cases bioaccumulation. There are no degradability and bioaccumulation data for mixtures as a whole. Degradability and bioaccumulation tests for mixtures are not used as they are usually difficult to interpret, and such tests may be meaningful only for single substances. - 259 - Copyright © United Nations, 2010. All rights reserved 2.2.9.1.10.4.3.3 Classification for category Acute 1 (a) When there are adequate acute toxicity test data (LC50 or EC50) available for the mixture as a whole showing L(E)C50 ≤ 1 mg/l: Classify the mixture as Acute 1 in accordance with Table 2.2.9.1.10.3.1 (a); (b) When there are acute toxicity test data (LC50(s) or EC50(s) available for the mixture as a whole showing L(E)C50(s) > 1 mg/l, or above the water solubility: No need to classify for acute hazard under ADR. 2.2.9.1.10.4.3.4 Classification for categories Chronic 1 and 2 (a) (b) When there are adequate chronic toxicity data (ECx or NOEC) available for the mixture as a whole showing ECx or NOEC of the tested mixture ≤ 1mg/l: (i) classify the mixture as Chronic 1 or 2 in accordance with Table 2.2.9.1.10.3.1 (b) (ii) (rapidly degradable) if the available information allows the conclusion that all relevant ingredients of the mixture are rapidly degradable; (ii) classify the mixture as Chronic 1 or 2 in all other cases in accordance with Table 2.2.9.1.10.3.1 (b) (i) (non-rapidly degradable); When there are adequate chronic toxicity data (ECx or NOEC) available for the mixture as a whole showing ECx(s) or NOEC(s) of the tested mixture > 1mg/l or above the water solubility: No need to classify for long-term hazard under ADR. 2.2.9.1.10.4.4 Classification of mixtures when toxicity data are not available for the complete mixture: bridging principles 2.2.9.1.10.4.4.1 Where the mixture itself has not been tested to determine its aquatic environmental hazard, but there are sufficient data on the individual ingredients and similar tested mixtures to adequately characterise the hazards of the mixture, these data shall be used in accordance with the following agreed bridging rules. This ensures that the classification process uses the available data to the greatest extent possible in characterising the hazards of the mixture without the necessity for additional testing in animals. 2.2.9.1.10.4.4.2 Dilution Where a new mixture is formed by diluting a tested mixture or a substance with a diluent which has an equivalent or lower aquatic hazard classification than the least toxic original ingredient and which is not expected to affect the aquatic hazards of other ingredients, then the resulting mixture shall be classified as equivalent to the original tested mixture or substance. Alternatively, the method explained in 2.2.9.1.10.4.5 may be applied. 2.2.9.1.10.4.4.3 Batching The aquatic hazard classification of a tested production batch of a mixture shall be assumed to be substantially equivalent to that of another untested production batch of the same commercial product when produced by or under the control of the same manufacturer, unless there is reason to believe there is significant variation such that the aquatic hazard classification of the untested batch has changed. If the latter occurs, new classification is necessary. - 260 - Copyright © United Nations, 2010. All rights reserved 2.2.9.1.10.4.4.4 Concentration of mixtures which are classified with the most severe classification categories (Chronic 1 and Acute 1) If a tested mixture is classified as Chronic 1 and/or Acute 1, and the ingredients of the mixture which are classified as Chronic 1 and/or Acute 1 are further concentrated, the more concentrated untested mixture shall be classified with the same classification category as the original tested mixture without additional testing. 2.2.9.1.10.4.4.5 Interpolation within one toxicity category For three mixtures (A, B and C) with identical ingredients, where mixtures A and B have been tested and are in the same toxicity category, and where untested mixture C has the same toxicologically active ingredients as mixtures A and B but has concentrations of toxicologically active ingredients intermediate to the concentrations in mixtures A and B, then mixture C is assumed to be in the same category as A and B. 2.2.9.1.10.4.4.6 Substantially similar mixtures Given the following: (a) Two mixtures: (i) A + B; (ii) C + B; (b) The concentration of ingredient B is essentially the same in both mixtures; (c) The concentration of ingredient A in mixture (i) equals that of ingredient C in mixture (ii); (d) Data on aquatic hazards for A and C are available and are substantially equivalent, i.e. they are in the same hazard category and are not expected to affect the aquatic toxicity of B. If mixture (i) or (ii) is already classified based on test data, then the other mixture can be assigned the same hazard category. 2.2.9.1.10.4.5 Classification of mixtures when toxicity data are available for all ingredients or only for some ingredients of the mixture 2.2.9.1.10.4.5.1 The classification of a mixture shall be based on summation of the concentrations of its classified ingredients. The percentage of ingredients classified as "Acute" or "Chronic" will feed straight into the summation method. Details of the summation method are described in 2.2.9.1.10.4.6.1 to 2.2.9.1.10.4.6.4. 2.2.9.1.10.4.5.2 Mixtures may be made of a combination of both ingredients that are classified (as Acute 1 and/or Chronic 1, 2) and those for which adequate toxicity test data are available. When adequate toxicity data are available for more than one ingredient in the mixture, the combined toxicity of those ingredients shall be calculated using the following additivity formulas (a) or (b), depending on the nature of the toxicity data: (a) Based on acute aquatic toxicity: ∑C i L(E)C50 m =∑ n - 261 - Ci L(E)C50 i Copyright © United Nations, 2010. All rights reserved where: = Ci L(E)C50i = n = L(E)C50m = concentration of ingredient i (mass percentage); LC50 or EC50 for ingredient i (mg/l); number of ingredients, and i is running from 1 to n; L(E)C50 of the part of the mixture with test data; The calculated toxicity shall be used to assign that portion of the mixture an acute hazard category which is then subsequently used in applying the summation method; (b) Based on chronic aquatic toxicity: ∑C + ∑C i EqNOECm j =∑ n Cj Ci +∑ NOECi n 0.1 ⋅ NOEC j where: Ci = concentration of ingredient i (mass percentage) covering the rapidly degradable ingredients; Cj = concentration of ingredient j (mass percentage) covering the non rapidly degradable ingredients; NOECi = NOEC (or other recognized measures for chronic toxicity) for ingredient i covering the rapidly degradable ingredients, in mg/l; NOECj = NOEC (or other recognized measures for chronic toxicity) for ingredient j covering the non-rapidly degradable ingredients, in mg/l; n = number of ingredients, and i and j are running from 1 to n; EqNOECm = equivalent NOEC of the part of the mixture with test data; The equivalent toxicity thus reflects the fact that non-rapidly degrading are classified one hazard category level more "severe" than rapidly substances. substances degrading The calculated equivalent toxicity shall be used to assign that portion of the mixture a long-term hazard category, in accordance with the criteria for rapidly degradable substances (Table 2.2.9.1.10.3.1 (b) (ii)), which is then subsequently used in applying the summation method. 2.2.9.1.10.4.5.3 When applying the additivity formula for part of the mixture, it is preferable to calculate the toxicity of this part of the mixture using for each ingredient toxicity values that relate to the same taxonomic group (i.e. fish, crustacea or algae) and then to use the highest toxicity (lowest value) obtained (i.e. use the most sensitive of the three groups). However, when toxicity data for each ingredient are not available in the same taxonomic group, the toxicity value of each ingredient shall be selected in the same manner that toxicity values are selected for the classification of substances, i.e. the higher toxicity (from the most sensitive test organism) is used. The calculated acute and chronic toxicity shall then be used to classify this part of the mixture as Acute 1 and/or Chronic 1 or 2 using the same criteria described for substances. 2.2.9.1.10.4.5.4 If a mixture is classified in more than one way, the method yielding the more conservative result shall be used. - 262 - Copyright © United Nations, 2010. All rights reserved 2.2.9.1.10.4.6 Summation method 2.2.9.1.10.4.6.1 Classification procedure In general a more severe classification for mixtures overrides a less severe classification, e.g. a classification with Chronic 1 overrides a classification with Chronic 2. As a consequence the classification procedure is already completed if the results of the classification is Chronic 1. A more severe classification than Chronic 1 is not possible; therefore, it is not necessary to pursue the classification procedure further. 2.2.9.1.10.4.6.2 Classification for category Acute 1 2.2.9.1.10.4.6.2.1 First, all ingredients classified as Acute 1 are considered. If the sum of the concentrations (in %) of these ingredients is greater than or equal to 25% the whole mixture shall be classified as Acute 1. If the result of the calculation is a classification of the mixture as Acute 1, the classification process is completed. 2.2.9.1.10.4.6.2.2 The classification of mixtures for acute hazards based on this summation of the concentrations of classified ingredients is summarized in Table 2.2.9.1.10.4.6.2.2 below. Table 2.2.9.1.10.4.6.2.2: Classification of a mixture for acute hazards based on summation of the concentrations of classified ingredients a Sum of the concentrations (in %) of Mixture classified as: ingredients classified as: Acute 1 Acute 1 × M a ≥ 25% For explanation of the M factor, see 2.2.9.1.10.4.6.4. 2.2.9.1.10.4.6.3 Classification for categories Chronic 1 and 2 2.2.9.1.10.4.6.3.1 First, all ingredients classified as Chronic 1 are considered. If the sum of the concentrations (in %) of these ingredients is greater than or equal to 25% the mixture shall be classified as Chronic 1. If the result of the calculation is a classification of the mixture as Chronic 1 the classification procedure is completed. 2.2.9.1.10.4.6.3.2 In cases where the mixture is not classified as Chronic 1, classification of the mixture as Chronic 2 is considered. A mixture shall be classified as Chronic 2 if 10 times the sum of the concentrations (in %) of all ingredients classified as Chronic 1 plus the sum of the concentrations (in %) of all ingredients classified as Chronic 2 is greater than or equal to 25%. If the result of the calculation is classification of the mixture as Chronic 2, the classification process is completed. 2.2.9.1.10.4.6.3.3 The classification of mixtures for long-term hazards based on this summation of the concentrations of classified ingredients is summarized in Table 2.2.9.1.10.4.6.3.3 below. Table 2.2.9.1.10.4.6.3.3: Classification of a mixture for long-term hazards based on summation of the concentrations of classified ingredients Sum of the concentrations (in %) of ingredients classified as: Chronic 1 × M a ≥ 25% (M × 10 × Chronic 1) + Chronic 2 ≥ 25% For explanation of the M factor, see 2.2.9.1.10.4.6.4. a - 263 - Mixture classified as: Chronic 1 Chronic 2 Copyright © United Nations, 2010. All rights reserved 2.2.9.1.10.4.6.4 Mixtures with highly toxic ingredients Acute 1 or Chronic 1 ingredients with acute toxicities well below 1 mg/l and/or chronic toxicities well below 0.1 mg/l (if non-rapidly degradable) and 0.01 mg/l (if rapidly degradable) may influence the toxicity of the mixture and are given increased weight in applying the summation method. When a mixture contains ingredients classified as acute or Chronic 1, the tiered approach described in 2.2.9.1.10.4.6.2 and 2.2.9.1.10.4.6.3 shall be applied using a weighted sum by multiplying the concentrations of Acute 1 and Chronic 1 ingredients by a factor, instead of merely adding up the percentages. This means that the concentration of "Acute 1" in the left column of Table 2.2.9.1.10.4.6.2.2 and the concentration of "Chronic 1" in the left column of Table 2.2.9.1.10.4.6.3.3 are multiplied by the appropriate multiplying factor. The multiplying factors to be applied to these ingredients are defined using the toxicity value, as summarised in Table 2.2.9.1.10.4.6.4 below. Therefore, in order to classify a mixture containing Acute 1 and/or Chronic 1 ingredients, the classifier needs to be informed of the value of the M factor in order to apply the summation method. Alternatively, the additivity formula (see 2.2.9.1.10.4.5.2) may be used when toxicity data are available for all highly toxic ingredients in the mixture and there is convincing evidence that all other ingredients, including those for which specific acute and/or chronic toxicity data are not available, are of low or no toxicity and do not significantly contribute to the environmental hazard of the mixture. Table 2.2.9.1.10.4.6.4: Multiplying factors for highly toxic ingredients of mixtures Acute toxicity M factor L(E)C50 value Chronic toxicity NOEC value M factor a NRD ingredients RD b ingredients 0.1 < L(E)C50 ≤ 1 1 0.01 < NOEC ≤ 0.1 1 − 0.01 < L(E)C50 ≤ 0.1 10 0.001 < NOEC ≤ 0.01 10 1 0.001 < L(E)C50 ≤ 0.01 100 0.0001 < NOEC ≤ 0.001 100 10 0.0001 < L(E)C50 ≤ 0.001 1 000 0.00001 < NOEC ≤ 0.0001 1 000 100 10 000 1 000 0.00001 < L(E)C50 ≤ 0.0001 10 000 0.000001 < NOEC ≤ 0.00001 (continue in factor 10 intervals) Non-rapidly degradable. b Rapidly degradable. (continue in factor 10 intervals) a 2.2.9.1.10.4.6.5 Classification of mixtures with ingredients without any useable information In the event that no useable information on acute and/or chronic aquatic toxicity is available for one or more relevant ingredients, it is concluded that the mixture cannot be attributed (a) definitive hazard category(ies). In this situation the mixture shall be classified based on the known ingredients only with the additional statement that: "x percent of the mixture consists of ingredient(s) of unknown hazard to the aquatic environment. - 264 - Copyright © United Nations, 2010. All rights reserved 2.2.9.1.10.5 Substances or mixtures classified as environmentally hazardous substances (aquatic environment) on the basis of Regulation 1272/2008/EC16 If data for classification according to the criteria of 2.2.9.1.10.3 and 2.2.9.1.10.4 are not available, a substance or mixture: 2.2.9.1.10.6 (a) Shall be classified as an environmentally hazardous substance (aquatic environment) if it has to be assigned category(ies) Aquatic Acute 1, Aquatic Chronic 1 or Aquatic Chronic 2 according to Regulation 1272/2008/EC16 or, if still relevant according to the said Regulation, risk phrase(s) R50, R50/53 or R51/53 according to the Directives 67/548/EEC3 or 1999/45/EC4; (b) May be regarded as not being an environmentally hazardous substance (aquatic environment) if it does not have to be assigned such a risk phrase or category according to the said Directives or Regulation. Assignment of substances or mixtures classified as environmentally hazardous substances (aquatic environment) according to the provisions in 2.2.9.1.10.3, 2.2.9.1.10.4 or 2.2.9.1.10.5 Substances or mixtures classified as environmentally hazardous substances (aquatic environment), not otherwise classified under ADR shall be designated: UN No. 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.; or UN No. 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. They shall be assigned to packing group III. Genetically modified microorganisms or organisms 2.2.9.1.11 Genetically modified microorganisms (GMMOs) and genetically modified organisms (GMOs) are microorganisms and organisms in which genetic material has been purposely altered through genetic engineering in a way that does not occur naturally. They are assigned to Class 9 (UN No. 3245) if they do not meet the definition of toxic substances or of infectious substances, but are capable of altering animals, plants or microbiological substances in a way not normally the result of natural reproduction. NOTE 1: GMMOs and GMOs which are infectious are substances of Class 6.2, UN Nos. 2814, 2900 or 3373. 16 Regulation 1272/2008/EC of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (Official Journal of the European Union No. L 353 of 30 December 2008). 3 Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances (Official Journal of the European Communities No. L 196 of 16 August 1967). 4 Directive 1999/45/EC of the European Parliament and of the Council of 31 May 1999 concerning the approximation of the laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations (Official Journal of the European Communities No. L 200 of 30 July 1999). - 265 - Copyright © United Nations, 2010. All rights reserved NOTE 2: GMMOs or GMOs are not subject to the provisions of ADR when authorized for use by the competent authorities of the countries of origin, transit and destination 17. NOTE 3: Live animals shall not be used to carry genetically modified microorganisms classified in Class 9 unless the substance can be carried no other way. Genetically modified live animals shall be carried under terms and conditions of the competent authorities of the countries of origin and destination. 2.2.9.1.12 (Deleted) Elevated temperature substances 2.2.9.1.13 Elevated temperature substances include substances which are carried or handed over for carriage in the liquid state at or above 100 °C and, in the case of those with a flash-point, below their flash-point. They also include solids which are carried or handed over for carriage at or above 240 °C. NOTE: Elevated temperature substances may be assigned to Class 9 only if they do not meet the criteria of any other class. Other substances presenting a danger during carriage but not meeting the definitions of another class. 2.2.9.1.14 The following other miscellaneous substances not meeting the definitions of another class are assigned to Class 9: Solid ammonia compounds having a flash-point below 60 °C; Low hazard dithionites; Highly volatile liquids; Substances emitting noxious fumes; Substances containing allergens; Chemical kits and first aid kits; NOTE: UN No. 1845 carbon dioxide, solid (dry ice), UN No. 2071 ammonium nitrate fertilizers, UN No. 2216 fish meal (fish scrap), stabilized, UN No. 2807 magnetized material, UN No. 3166 engine, internal combustion or 3166 vehicle, flammable gas powered or 3166 vehicle, flammable liquid powered or 3166 engine, fuel cell, flammable gas powered or 3166 engine, fuel cell, flammable liquid powered or 3166 vehicle, fuel cell, flammable gas powered or 3166 vehicle, fuel cell, flammable liquid powered, UN No. 3171 battery-powered vehicle or 3171 battery-powered equipment (wet battery), UN No. 3334 aviation regulated liquid, n.o.s., UN No. 3335 aviation regulated solid, n.o.s. and UN No. 3363 dangerous goods in machinery or dangerous goods in apparatus listed in the UN Model Regulations, are not subject to the provisions of ADR. Assignment of the packing groups 2.2.9.1.15 When indicated in column (4) of Table A of Chapter 3.2, substances and articles of Class 9 are assigned to one of the following packing groups according to their degree of danger: Packing group II: Packing group III: substances presenting medium danger; substances presenting low danger. 17 See in particular Part C of Directive 2001/18/EC of the European Parliament and of the Council on the deliberate release into the environment of genetically modified organisms and repealing Council Directive 90/220/EEC (Official Journal of the European Communities, No. L 106, of 17 April 2001, pp. 8-14), which sets out the authorization procedures for the European Community. - 266 - Copyright © United Nations, 2010. All rights reserved 2.2.9.2 Substances and articles not accepted for carriage The following substances and articles shall not be accepted for carriage: - Lithium batteries which do not meet the relevant conditions of special provisions 188, 230 or 636 of Chapter 3.3; - Uncleaned empty containment vessels for apparatus such as transformers, condensers and hydraulic apparatus containing substances assigned to UN Nos. 2315, 3151, 3152 or 3432. - 267 - Copyright © United Nations, 2010. All rights reserved 2.2.9.3 List of entries Substances which, on inhalation as fine dust, may endanger health Substances and apparatus which, in the event of fire, may form dioxins Substances evolving flammable vapour 2315 3432 3151 M2 3151 3152 3152 POLYCHLORINATED BIPHENYLS, LIQUID POLYCHLORINATED BIPHENYLS, SOLID POLYHALOGENATED BIPHENYLS, LIQUID or POLYHALOGENATED TERPHENYLS, LIQUID POLYHALOGENATED BIPHENYLS, SOLID or POLYHALOGENATED TERPHENYLS, SOLID 2211 POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour M3 3314 PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form evolving flammable vapour 3090 LITHIUM METAL BATTERIES (including lithium alloy batteries) 3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT (including lithium alloy batteries) or 3091 LITHIUM METAL BATTERIES PACKED WITH EQUIPMENT (including lithium alloy batteries) M4 3480 LITHIUM ION BATTERIES (including lithium ion polymer batteries) 3481 LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT (including lithium ion polymer batteries) or 3481 LITHIUM ION BATTERIES PACKED WITH EQUIPMENT (including lithium ion polymer batteries) Lithium batteries 2990 LIFE-SAVING APPLIANCES, SELF-INFLATING 3072 LIFE-SAVING APPLIANCES NOT SELF-INFLATING containing dangerous goods as equipment M5 3268 AIR BAG INFLATORS or 3268 AIR BAG MODULES or 3268 SEAT-BELT PRETENSIONERS Live-saving appliances pollutant to the aquatic environment, liquid Environmentally hazardous substances 2212 BLUE ASBESTOS (crocidolite) or M1 2212 BROWN ASBESTOS (amosite, mysorite) 2590 WHITE ASBESTOS (chrysotile, actinolite, anthophyllite, tremolite) M6 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. pollutant to the aquatic environment, solid M7 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. genetically modified microorganisms and organisms 3245 GENETICALLY MODIFIED MICROORGANISMS or M8 3245 GENETICALLY MODIFIED ORGANISMS liquid M9 3257 ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 °C and below its flash-point (including molten metal, molten salts, etc.) Elevated temperature substances solid Other substances or articles presenting a danger during carriage, but not meeting the definitions of another class M10 3258 ELEVATED TEMPERATURE SOLID, N.O.S., at or above 240 °C No collective entry available. Only substances listed in Table A of Chapter 3.2 are subject to the provisions for Class 9 under this classification code, as follows: 1841 ACETALDEHYDE AMMONIA 1931 ZINC DITHIONITE (ZINC HYDROSULPHITE) 1941 DIBROMODIFLUOROMETHANE 1990 BENZALDEHYDE 2969 CASTOR BEANS, or M11 2969 CASTOR MEAL, or 2969 CASTOR POMACE, or 2969 CASTOR FLAKE 3316 CHEMICAL KIT, or 3316 FIRST AID KIT 3359 FUMIGATED UNIT - 268 - Copyright © United Nations, 2010. All rights reserved CHAPTER 2.3 TEST METHODS 2.3.0 General Unless otherwise provided for in Chapter 2.2 or in this Chapter, the test methods to be used for the classification of dangerous goods are those described in the Manual of Tests and Criteria. 2.3.1 Exudation test for blasting explosives of Type A 2.3.1.1 Blasting explosives of type A (UN No. 0081) shall, if they contain more than 40% liquid nitric ester, in addition to the testing specified in the Manual of Tests and Criteria, satisfy the following exudation test. 2.3.1.2 The apparatus for testing blasting explosive for exudation (figs. 1 to 3) consists of a hollow bronze cylinder. This cylinder, which is closed at one end by a plate of the same metal, has an internal diameter of 15.7 mm and a depth of 40 mm. It is pierced by 20 holes 0.5 mm in diameter (four sets of five holes) on the circumference. A bronze piston, cylindrically fashioned over a length of 48 mm and having a total length of 52 mm, slides into the vertically placed cylinder. The piston, whose diameter is 15.6 mm, is loaded with a mass of 2 220 g so that a pressure of 120 kPa (1.20 bar) is exerted on the base of the cylinder. 2.3.1.3 A small plug of blasting explosive weighing 5 to 8 g, 30 mm long and 15 mm in diameter, is wrapped in very fine gauze and placed in the cylinder; the piston and its loading mass are then placed on it so that the blasting explosive is subjected to a pressure of 120 kPa (1.20 bar). The time taken for the appearance of the first signs of oily droplets (nitroglycerine) at the outer orifices of the cylinder holes is noted. 2.3.1.4 The blasting explosive is considered satisfactory if the time elapsing before the appearance of the liquid exudations is more than five minutes, the test having been carried out at a temperature of 15 °C to 25 °C. - 269 - Copyright © United Nations, 2010. All rights reserved Test of blasting explosive for exudation 24 4 14 3 88 120º 4 8 56 2 Fig.1: Bell-form charge, mass 2220 g, capable of being suspended from a bronze piston 100 106 Fig.2: Cylindrical bronze piston, dimensions in mm 52 48 120º 9 15,6 5 40 20 15.7 Fig.3: Hollow bronze cylinder, closed at one end; Plan and cut dimensions in mm 15 5 5 55 5 1 1 72º 72º 1 Fig. 1 to 3 (1) 4 series of 5 holes at 0.5 Ν (2) copper (3) iron plate with centre cone at the inferior face (4) 4 openings, approximately 46x56, set at even intervals on the periphery 97 - 270 - Copyright © United Nations, 2010. All rights reserved 2.3.2 Tests relating to nitrated cellulose mixtures of Class 4.1 2.3.2.1 Nitrocellulose heated for half an hour at 132 °C shall not give off visible yellowish-brown nitrous fumes (nitrous gases). The ignition temperature shall be above 180 °C. See 2.3.2.3 to 2.3.2.8, 2.3.2.9 (a) and 2.3.2.10 below. 2.3.2.2 3 g of plasticized nitrocellulose, heated for one hour at 132 °C, shall not give off visible yellowish-brown nitrous fumes (nitrous gases). The ignition temperature shall be above 170 °C. See 2.3.2.3 to 2.3.2.8, 2.3.2.9 (b) and 2.3.2.10 below. 2.3.2.3 The test procedures set out below are to be applied when differences of opinion arise as to the acceptability of substances for carriage by road. 2.3.2.4 If other methods or test procedures are used to verify the conditions of stability prescribed above in this section, those methods shall lead to the same findings as could be reached by the methods specified below. 2.3.2.5 In carrying out the stability tests by heating described below, the temperature of the oven containing the sample under test shall not deviate by more than 2 °C from the prescribed temperature; the prescribed duration of a 30-minute or 60-minute test shall be observed to within two minutes. The oven shall be such that the required temperature is restored not more than five minutes after insertion of the sample. 2.3.2.6 Before undergoing the tests in 2.3.2.9 and 2.3.2.10, the samples shall be dried for not less than 15 hours at the ambient temperature in a vacuum desiccator containing fused and granulated calcium chloride, the sample substance being spread in a thin layer; for this purpose, substances which are neither in powder form nor fibrous shall be ground, or grated, or cut into small pieces. The pressure in the desiccator shall be brought below 6.5 kPa (0.065 bar). 2.3.2.7 Before being dried as prescribed in 2.3.2.6 above, substances conforming to 2.3.2.2 shall undergo preliminary drying in a well-ventilated oven, with its temperature set at 70 °C, until the loss of mass per quarter-hour is less than 0.3% of the original mass. 2.3.2.8 Weakly nitrated nitrocellulose conforming to 2.3.2.1 shall first undergo preliminary drying as prescribed in 2.3.2.7 above; drying shall then be completed by keeping the nitrocellulose for at least 15 hours over concentrated sulphuric acid in a desiccator. 2.3.2.9 Test of chemical stability under heat (a) Test of the substance listed in paragraph 2.3.2.1 above. (i) In each of two glass test tubes having the following dimensions: length internal diameter thickness of wall 350 mm 16 mm 1.5 mm is placed 1 g of substance dried over calcium chloride (if necessary the drying shall be carried out after reducing the substance to pieces weighing not more than 0.05 g each). Both test tubes, completely covered with loose-fitting closures, are then so placed in an oven that at least four-fifths of their length is visible, and are kept at a constant temperature of 132 °C for 30 minutes. It is observed whether nitrous gases in the form of yellowish-brown fumes clearly visible against a white background are given off during this time; (ii) In the absence of such fumes the substance is deemed to be stable; - 271 - Copyright © United Nations, 2010. All rights reserved (b) 2.3.2.10 Test of plasticized nitrocellulose (see 2.3.2.2) (i) 3 g of plasticized nitrocellulose are placed in glass test tubes, similar to those referred to in (a), which are then placed in an oven kept at a constant temperature of 132 °C; (ii) The test tubes containing the plasticized nitrocellulose are kept in the oven for one hour. During this time no yellowish-brown nitrous fumes (nitrous gases) shall be visible. Observation and appraisal as in (a). Ignition temperature (see 2.3.2.1 and 2.3.2.2) (a) The ignition temperature is determined by heating 0.2 g of substance enclosed in a glass test tube immersed in a Wood's alloy bath. The test tube is placed in the bath when the latter has reached 100 °C. The temperature of the bath is then progressively increased by 5 °C per minute; (b) The test tubes must have the following dimensions: length internal diameter thickness of wall 125 mm 15 mm 0.5 mm and shall be immersed to a depth of 20 mm; (c) The test shall be repeated three times, the temperature at which ignition of the substance occurs, i.e., slow or rapid combustion, deflagration or detonation, being noted each time; (d) The lowest temperature recorded in the three tests is the ignition temperature. 2.3.3 Tests relating to flammable liquids of Classes 3, 6.1 and 8 2.3.3.1 Determination of flash-point 2.3.3.1.1 The following methods for determining the flash-point of flammable liquids may be used: International standards: ISO 1516 (Determination of flash/no flash – Closed cup equilibrium method) ISO 1523 (Determination of flash point – Closed cup equilibrium method) ISO 2719 (Determination of flash point – Pensky-Martens closed cup method) ISO 13736 (Determination of flash point – Abel closed-cup method) ISO 3679 (Determination of flash point – Rapid equilibrium closed cup method) ISO 3680 (Determination of flash/no flash – Rapid equilibrium closed cup method) National standards: American Society for Testing Materials International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, Pennsylvania, USA 19428-2959: ASTM D3828-07a, Standard Test Methods for Flash Point by Small Scale Closed-Cup Tester ASTM D56-05, Standard Test Method for Flash Point by Tag Closed-Cup Tester ASTM D3278-96(2004)e1, Standard Test Methods for Flash Point of Liquids by Small Scale Closed-Cup Apparatus ASTM D93-08, Standard Test Methods for Flash Point by Pensky-Martens Closed-Cup Tester - 272 - Copyright © United Nations, 2010. All rights reserved Association française de normalisation, AFNOR, 11, rue de Pressensé, F-93571 La Plaine Saint-Denis Cedex: French standard NF M 07 - 019 French standards NF M 07 - 011 / NF T 30 - 050 / NF T 66 - 009 French standard NF M 07 - 036 Deutsches Institut für Normung, Burggrafenstr. 6, D-10787 Berlin: Standard DIN 51755 (flash-points below 65 °C) State Committee of the Council of Ministers for Standardization, RUS-113813, GSP, Moscow, M-49 Leninsky Prospect, 9: GOST 12.1.044-84 2.3.3.1.2 To determine the flash-point of paints, gums and similar viscous products containing solvents, only apparatus and test methods suitable for determining the flash-point for viscous liquids shall be used, in accordance with the following standards: (a) (b) (c) (d) International Standard ISO 3679: 1983; International Standard ISO 3680: 1983; International Standard ISO 1523: 1983; International standards EN ISO 13736 and EN ISO 2719, Method B. 2.3.3.1.3 The standards listed in 2.3.3.1.1 shall only be used for flash-point ranges which are specified therein. The possibility of chemical reactions between the substance and the sample holder shall be considered when selecting the standard to be used. The apparatus shall, as far as is consistent with safety, be placed in a draught-free position. For safety, a method utilizing a small sample size, around 2 ml, shall be used for organic peroxides and self-reactive substances (also known as "energetic" substances), or for toxic substances. 2.3.3.1.4 When the flash-point, determined by a non-equilibrium method is found to be 23 ± 2 °C or 60 ± 2 °C, it shall be confirmed for each temperature range by an equilibrium method. 2.3.3.1.5 In the event of a dispute as to the classification of a flammable liquid, the classification proposed by the consignor shall be accepted if a check-test of the flash-point, yields a result not differing by more than 2 °C from the limits (23 °C and 60 °C respectively) stated in 2.2.3.1. If the difference is more than 2 °C, a second check-test shall be carried out, and the lowest figure of the flash-points obtained in either check-test shall be adopted. 2.3.3.2 Determination of initial boiling point The following methods for determining the initial boiling point of flammable liquids may be used: International standards: ISO 3924 (Petroleum products – Determination of boiling range distribution – Gas chromatography method) ISO 4626 (Volatile organic liquids – Determination of boiling range of organic solvents used as raw materials) ISO 3405 (Petroleum products – Determination of distillation characteristics at atmospheric pressure) - 273 - Copyright © United Nations, 2010. All rights reserved National standards: American Society for Testing Materials International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, Pennsylvania, USA 19428-2959: ASTM D86-07a, Standard Test Method for Distillation of Petroleum Products at Atmospheric Pressure ASTM D1078-05, Standard Test Method for Distillation Range of Volatile Organic Liquids Further acceptable methods: Method A.2 as described in Part A of the Annex to Commission Regulation (EC) No 440/20081. 2.3.3.3 Test for determining peroxide content To determine the peroxide content of a liquid, the procedure is as follows: A quantity p (about 5 g, weighed to the nearest 0.01 g) of the liquid to be titrated is placed in an Erlenmeyer flask; 20 cm3 of acetic anhydride and about 1 g of powdered solid potassium iodide are added; the flask is shaken and, after 10 minutes, heated for 3 minutes to about 60 °C. When it has been left to cool for 5 minutes, 25 cm3 of water are added. After this, it is left standing for half an hour, then the liberated iodine is titrated with a decinormal solution of sodium thiosulphate, no indicator being added; complete discoloration indicates the end of the reaction. If n is the number of cm3 of thiosulphate solution required, the percentage of peroxide (calculated as H2O2) present in the sample is obtained by the formula: 17 n 100p 2.3.4 Test for determining fluidity To determine the fluidity of liquid, viscous or pasty substances and mixtures, the following test method shall be used. 2.3.4.1 Test apparatus Commercial penetrometer conforming to ISO 2137:1985, with a guide rod of 47.5 g ± 0.05 g; sieve disc of duralumin with conical bores and a mass of 102.5 g ± 0.05 g (see Figure 1); penetration vessel with an inside diameter of 72 mm to 80 mm for reception of the sample. 2.3.4.2 Test procedure The sample is poured into the penetration vessel not less than half an hour before the measurement. The vessel is then hermetically closed and left standing until the measurement. The sample in the hermetically closed penetration vessel is heated to 35 °C ± 0.5 °C and is placed on the penetrometer table immediately prior to measurement (not more than two minutes). The point S of the sieve disc is then brought into contact with the surface of the liquid and the rate of penetration is measured. 1 Commission Regulation (EC) No 440/2008 of 30 May 2008 laying down test methods pursuant to Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (Official Journal of the European Union, No. L 142 of 31.05.2008, p.1-739 and No. L 143 of 03.06.2008, p.55). - 274 - Copyright © United Nations, 2010. All rights reserved 2.3.4.3 Evaluation of test results A substance is pasty if, after the centre S has been brought into contact with the surface of the sample, the penetration indicated by the dial gauge: (a) after a loading time of 5 s ± 0.1 s, is less than 15.0 mm ± 0.3 mm; or (b) after a loading time of 5 s ± 0.1 s, is greater than 15.0 mm ± 0.3 mm, but the additional penetration after another 55 s ± 0.5 s is less than 5.0 mm ± 0.5 mm. NOTE: In the case of samples having a flow point, it is often impossible to produce a steady level surface in the penetration vessel and, hence, to establish satisfactory initial measuring conditions for the contact of the point S. Furthermore, with some samples, the impact of the sieve disc can cause an elastic deformation of the surface and, in the first few seconds, simulate a deeper penetration. In all these cases, it may be appropriate to make the evaluation in paragraph (b) above. - 275 - Copyright © United Nations, 2010. All rights reserved Figure 1 – Penetrometer 3.2 0.02 12.7 3 82.6 Adjust mass to 102.5g 0.05g 9 0.5 12.7 7.4 0.02 3.2 10.3 16 052' S Press fit S 69.9 50.8 19.05 40 ° 120 ° Tolerances not specified are ± 0.1 mm. - 276 - Copyright © United Nations, 2010. All rights reserved 2.3.5 Classification of organometallic substances in Classes 4.2 and 4.3 Depending on their properties as determined in accordance with tests N.1 to N.5 of the Manual of Tests end Criteria, Part III, section 33, organometallic substances may be classified in Class 4.2 or 4.3, as appropriate, in accordance with the flowchart scheme given in Figure 2.3.5. NOTE 1: Depending on their other properties and on the precedence of hazard table (see 2.1.3.10), organometallic substances may have to be classified in other classes as appropriate. NOTE 2: Flammable solutions with organometallic compounds in concentrations which are not liable to spontaneous combustion or, in contact with water, do not emit flammable gases in dangerous quantities, are substances of Class 3. - 277 - Copyright © United Nations, 2010. All rights reserved Figure 2.3.5: Flowchart scheme for the classification of organometallic substances in Classes 4.2 and 4.3ab Organometallic substance/formulation/solutiona Organometallic substance, solid, pyrophoric UN 3391 Solid No Is the substance pyrophoric? Test N.2 (solid) Test N.3 (liquid) Yes Is the substance water-reactive? Test N.5 Liquid Organometallic substance, liquid, pyrophoric UN 3392 Solid Organometallic substance, solid, pyrophoric, water-reactive UN 3393 Yes No Organometallic substance, liquid, pyrophoric, water-reactive UN 3394 Liquid No Is the substance a flammable solid? Test N.1 Yes Organometallic substance, solid, water-reactive UN 3395 Organometallic substance, solid, water-reactive, flammable UN 3396 No Yes Yes Is the substance water-reactive? Test N.5 Class 4.3, PG I, II or III. Is the substance a solid? No No Is the substance a self-heating solid? Test N.4 Yes Is the substance self-heating? Test N.4 Yes No Does the substance contain a diluent with a flash point ≤ 60ºC? Yes Organometallic substance, solid, water reactive, self-heating UN 3397 Organometallic substance, liquid, water-reactive UN 3398 Organometallic substance, liquid, water-reactive, flammable UN 3399 Organometallic substance, solid, self-heating UN 3400 No Substance does not have to be classified in Class 4.2 or in Class 4.3 a If applicable and testing is relevant, taking into account reactivity properties, class 6.1 and 8 properties should be considered according to the precedence of hazard table of 2.1.3.10. b Test methods N.1 to N.5 can be found in the Manual of Tests and Criteria, Part III, Section 33. - 278 - Copyright © United Nations, 2010. All rights reserved PART 3 Dangerous goods list, special provisions and exemptions related to limited and excepted quantities - 279 - Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved CHAPTER 3.1 GENERAL 3.1.1 Introduction In addition to the provisions referred to or given in the tables of this Part, the general requirements of each Part, Chapter and/or Section are to be observed. These general requirements are not given in the tables. When a general requirement is contradictory to a special provision, the special provision prevails. 3.1.2 Proper shipping name NOTE: For proper shipping names used for the carriage of samples, see 2.1.4.1. 3.1.2.1 The proper shipping name is that portion of the entry most accurately describing the goods in Table A in Chapter 3.2, which is shown in upper case characters (plus any numbers, Greek letters, "sec", "tert", and the letters "m", "n", "o", "p", which form an integral part of the name). An alternative proper shipping name may be shown in brackets following the main proper shipping name [e.g., ETHANOL (ETHYL ALCOHOL)]. Portions of an entry appearing in lower case need not be considered as part of the proper shipping name. 3.1.2.2 When conjuncti ons such as "and" or "or" are in lower case or when segments of the name are punctuated by commas, the entire name of the entry need not necessarily be shown in the transport document or package markings. This is the case particularly when a combination of several distinct entries are listed under a single UN Number. Examples illustrating the selection of the proper shipping name for such entries are: (a) UN 1057 LIGHTERS or LIGHTER REFILLS - The proper shipping name is the most appropriate of the following possible combinations: LIGHTERS LIGHTER REFILLS; (b) UN 2793 FERROUS METAL BORINGS, SHAVINGS, TURNINGS or CUTTINGS in a form liable to self-heating. The proper shipping name is the most appropriate of the following combinations: FERROUS METAL BORINGS FERROUS METAL SHAVINGS FERROUS METAL TURNINGS FERROUS METAL CUTTINGS. 3.1.2.3 Proper shipping names may be used in the singular or plural as appropriate. In addition, when qualifying words are used as part of the proper shipping name, their sequence on documentation or package markings is optional. For instance, "DIMETHYLAMINE AQUEOUS SOLUTION" may alternatively be shown "AQUEOUS SOLUTION OF DIMETHYLAMINE". Commercial or military names for goods of Class 1 which contain the proper shipping name supplemented by additional descriptive text may be used. - 281 - Copyright © United Nations, 2010. All rights reserved 3.1.2.4 Many substances have an entry for both the liquid and solid state (see definitions for liquid and solid in 1.2.1), or for the solid and solution. These are allocated separate UN numbers which are not necessarily adjacent to each other 1. 3.1.2.5 Unless it is already included in capital letters in the name indicated in Table A in Chapter 3.2, the qualifying word "MOLTEN" shall be added as part of the proper shipping name when a substance, which is a solid in accordance with the definition in 1.2.1, is offered for carriage in the molten state (e.g. ALKYLPHENOL, SOLID, N.O.S., MOLTEN). 3.1.2.6 Except for self-reactive substances and organic peroxides and unless it is already included in capital letters in the name indicated in Column (2) of Table A of Chapter 3.2, the word "STABILIZED" shall be added as part of the proper shipping name of a substance which without stabilization would be forbidden from carriage in accordance with paragraphs 2.2.X.2 due to it being liable to dangerously react under conditions normally encountered in carriage (e.g.: "TOXIC LIQUID, ORGANIC, N.O.S., STABILIZED"). When temperature control is used to stabilize such substances to prevent the development of any dangerous excess pressure, then: (a) For liquids: where the SADT is less than or equal to 50 °C, the provisions of 2.2.41.1.17, the special provision V8 of Chapter 7.2, the special provision S4 of Chapter 8.5 and the requirements of Chapter 9.6 shall apply; for carriage in IBCs and tanks, all the provisions applicable to UN No. 3239 apply (see in particular 4.1.7.2, packing instruction IBC520 et 4.2.1.13); (b) For gases: the conditions of carriage shall be approved by the competent authority. 3.1.2.7 Hydrates may be carried under the proper shipping name for the anhydrous substance. 3.1.2.8 Generic or "not otherwise specified" (N.O.S.) names 3.1.2.8.1 Generic and "not otherwise specified" proper shipping names that are assigned to special provision 274 or 318 in Column (6) of Table A in Chapter 3.2 shall be supplemented with the technical name of the goods unless a national law or international convention prohibits its disclosure if it is a controlled substance. For explosives of Class 1, the dangerous goods description may be supplemented by additional descriptive text to indicate commercial or military names. Technical names shall be entered in brackets immediately following the proper shipping name. An appropriate modifier, such as "contains" or "containing" or other qualifying words such as "mixture", "solution", etc. and the percentage of the technical constituent may also be used. For example: "UN 1993 FLAMMABLE LIQUID, N.O.S. (CONTAINS XYLENE AND BENZENE), 3, II". 3.1.2.8.1.1 The technical name shall be a recognized chemical name or biological name, or other name currently used in scientific and technical handbooks, journals and texts. Trade names shall not be used for this purpose. In the case of pesticides, only ISO common name(s), other name(s) in the World Health Organization (WHO) Recommended Classification of Pesticides by Hazard and Guidelines to Classification, or the name(s) of the active substance(s) may be used. 3.1.2.8.1.2 When a mixture of dangerous goods is described by one of the "N.O.S." or "generic" entries to which special provision 274 has been allocated in Column (6) of Table A in Chapter 3.2, not more than the two constituents which most predominantly contribute to the hazard or 1 Details are provided in the alphabetical index (Table B of Chapter 3.2), e.g.: NITROXYLENES, LIQUID 6.1 1665; NITROXYLENES, SOLID 6.1 3447. - 282 - Copyright © United Nations, 2010. All rights reserved hazards of a mixture need to be shown, excluding controlled substances when their disclosure is prohibited by national law or international convention. If a package containing a mixture is labelled with any subsidiary risk label, one of the two technical names shown in parentheses shall be the name of the constituent which compels the use of the subsidiary risk label. NOTE: See 5.4.1.2.2. 3.1.2.8.1.3 Examples illustrating the selection of the proper shipping name supplemented with the technical name of goods for such N.O.S. entries are: UN 2902 UN 3394 3.1.3 PESTICIDE, LIQUID, TOXIC, N.O.S. (drazoxolon); ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATERREACTIVE (trimethylgallium). Solutions or mixtures NOTE: Where a substance is specifically mentioned by name in Table A of Chapter 3.2, it shall be identified in carriage by the proper shipping name in Column (2) of Table A of Chapter 3.2. Such substances may contain technical impurities (for example those deriving from the production process) or additives for stability or other purposes that do not affect its classification. However, a substance mentioned by name containing technical impurities or additives for stability or other purposes affecting its classification shall be considered a solution or mixture (see 2.1.3.3). 3.1.3.1 A solution or mixture is not subject to ADR if the characteristics, properties, form or physical state of the solution or mixture are such that it does not meet the criteria, including human experience criteria, for inclusion in any class. 3.1.3.2 A solution or mixture composed of a single predominant substance mentioned by name in Table A of Chapter 3.2 and one or more substances not subject to ADR or traces of one or more substances mentioned by name in Table A of Chapter 3.2, shall be assigned the UN number and proper shipping name of the predominant substance mentioned by name in Table A of Chapter 3.2 unless: (a) The solution or mixture is mentioned by name in Table A of Chapter 3.2; (b) The name and description of the substance mentioned by name in Table A of Chapter 3.2 specifically indicate that they apply only to the pure substance; (c) The class, classification code, packing group, or physical state of the solution or mixture is different from that of the substance mentioned by name in Table A of Chapter 3.2; or (d) The hazard characteristics and properties of the solution or mixture necessitate emergency response measures that are different from those required for the substance mentioned by name in Table A of Chapter 3.2. Qualifying words such as "SOLUTION" or "MIXTURE", as appropriate, shall be added as part of the proper shipping name, for example, "ACETONE SOLUTION". In addition, the concentration of the mixture or solution may also be indicated after the basic description of the mixture or solution, for example, "ACETONE 75% SOLUTION". 3.1.3.3 A solution or mixture that is not mentioned by name in Table A of Chapter 3.2 and that is composed of two or more dangerous goods shall be assigned to an entry that has the proper shipping name, description, class, classification code and packing group that most precisely describe the solution or mixture. - 283 - Copyright © United Nations, 2010. All rights reserved Copyright © United Nations, 2010. All rights reserved CHAPTER 3.2 DANGEROUS GOODS LIST 3.2.1 Table A: Dangerous Goods List Explanations As a rule, each row of Table A of this Chapter deals with the substance(s) or article(s) covered by a specific UN number. However, when substances or articles belonging to the same UN number have different chemical properties, physical properties and/or carriage conditions, several consecutive rows may be used for that UN number. Each column of Table A is dedicated to a specific subject as indicated in the explanatory notes below. The intersection of columns and rows (cell) contains information concerning the subject treated in that column, for the substance(s) or article(s) of that row: - The first four cells identify the substance(s) or article(s) belonging to that row (additional information in that respect may be given by the special provisions referred to in Column (6); - The following cells give the applicable special provisions, either in the form of complete information or in coded form. The codes cross-refer to detailed information that is to be found in the Part, Chapter, Section and/or Sub-section indicated in the explanatory notes below. An empty cell means either that there is no special provision and that only the general requirements apply, or that the carriage restriction indicated in the explanatory notes is in force. The applicable general requirements are not referred to in the corresponding cells. The explanatory notes below indicate for every column the Part(s), Chapter(s), Section(s) and/or Sub-section(s) where these are to be found. Explanatory notes for each column: Column (1) "UN No." Contains the UN number: Column (2) - of the dangerous substance or article if the substance or article has been assigned its own specific UN number; or - of the generic or n.o.s. entry to which the dangerous substances or articles not mentioned by name shall be assigned in accordance with the criteria ("decision trees") of Part 2. "Name and description" Contains, in upper case characters, the name of the substance or article, if the substance or article has been assigned its own specific UN number, or of the generic or n.o.s. entry to which it has been assigned in accordance with the criteria ("decision trees") of Part 2. This name shall be used as the proper shipping name or, when applicable, as part of the proper shipping name (see 3.1.2 for further details on the proper shipping name). - 285 - Copyright © United Nations, 2010. All rights reserved A descriptive text in lower case characters is added after the proper shipping name to clarify the scope of the entry if the classification and/or carriage conditions of the substance or article may be different under certain conditions. Column (3a) "Class" Contains the number of the class, whose heading covers the dangerous substance or article. This class number is assigned in accordance with the procedures and criteria of Part 2. Column (3b) "Classification code" Contains the classification code of the dangerous substance or article. Column (4) - For dangerous substances or articles of Class 1, the code consists of a division number and compatibility group letter, which are assigned in accordance with the procedures and criteria of 2.2.1.1.4; - For dangerous substances or articles of Class 2, the code consists of a number and hazardous property group, which are explained in 2.2.2.1.2 and 2.2.2.1.3; - For dangerous substances or articles of Classes 3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1, 6.2, 8 and 9, the codes are explained in 2.2.x.1.2 1; - Dangerous substances or articles of Class 7 do not have a classification code. "Packing group" Contains the packing group number(s) (I, II or III) assigned to the dangerous substance. These packing group numbers are assigned on the basis of the procedures and criteria of Part 2. Certain articles and substances are not assigned to packing groups. Column (5) "Labels" Contains the model number of the labels/placards (see 5.2.2.2 and 5.3.1.7) that have to be affixed to packages, containers, tank-containers, portable tanks, MEGCs and vehicles. However, for substances or articles of Class 7, 7X means label model No.7A, 7B or 7C as appropriate according to the category (see 5.1.5.3.4 and 5.2.2.1.11.1) or placard No. 7D (see 5.3.1.1.3 and 5.3.1.7.2). The general provisions on labelling/placarding (e.g. number of labels, their location) are to be found in 5.2.2.1 for packages, and in 5.3.1, for containers, tank-containers, MEGCs, portable tanks and vehicles. NOTE: Special provisions, indicated in Column (6), may change the above labelling provisions. 1 x = the class number of the dangerous substance or article, without dividing point if applicable. - 286 - Copyright © United Nations, 2010. All rights reserved Column (6) "Special provisions" Contains the numeric codes of special provisions that have to be met. These provisions concern a wide array of subjects, mainly connected with the contents of Columns (1) to (5) (e.g. carriage prohibitions, exemptions from requirements, explanations concerning the classification of certain forms of the dangerous goods concerned and additional labelling or marking provisions), and are listed in Chapter 3.3 in numerical order. If Column (6) is empty, no special provisions apply to the contents of Columns (1) to (5) for the dangerous goods concerned. Column (7a) "Limited Quantities" Provides the maximum quantity per inner packaging or article for carrying dangerous goods as limited quantities in accordance with Chapter 3.4. Column (7b) "Excepted Quantities" Contains an alphanumeric code with the following meaning: Column (8) - "E0" signifies that no exemption from the provisions of ADR exists for the dangerous goods packed in excepted quantities; - All the other alphanumerical codes starting with the letter "E" signify that the provisions of ADR are not applicable if the conditions indicated in Chapter 3.5 are fulfilled. "Packing instructions" Contains the alphanumeric codes of the applicable packing instructions: - Alphanumeric codes starting with the letter "P", which refers to packing instructions for packagings and receptacles (except IBCs and large packagings), or "R", which refers to packing instructions for light gauge metal packagings. These are listed in 4.1.4.1 in numerical order, and specify the packagings and receptacles that are authorized. They also indicate which of the general packing provisions of 4.1.1, 4.1.2 and 4.1.3, and which of the special packing provisions of 4.1.5, 4.1.6, 4.1.7, 4.1.8 and 4.1.9 have to be met. If Column (8) does not contain a code starting with the letters "P" or "R", the dangerous goods concerned may not be carried in packagings; - Alphanumeric codes starting with the letters "IBC" refer to packing instructions for IBCs. These are listed in 4.1.4.2 in numerical order, and specify the IBCs that are authorized. They also indicate which of the general packing provisions of 4.1.1, 4.1.2 and 4.1.3, and which of the special packing provisions of 4.1.5, 4.1.6, 4.1.7, 4.1.8 and 4.1.9 have to be met. If Column (8) does not contain a code starting with the letters "IBC", the dangerous goods concerned may not be carried in IBCs; - 287 - Copyright © United Nations, 2010. All rights reserved - Alphanumeric codes starting with the letters "LP" refer to packing instructions for large packagings. These are listed in 4.1.4.3 in numerical order, and specify the large packagings that are authorized. They also indicate which of the general packing provisions of 4.1.1, 4.1.2 and 4.1.3, and which of the special packing provisions of 4.1.5, 4.1.6, 4.1.7, 4.1.8 and 4.1.9 have to be met. If Column (8) does not contain a code starting with the letters "LP", the dangerous goods concerned cannot be carried in large packagings; NOTE: Special packing provisions, indicated in Column (9a), may change the above packing instructions. Column (9a) "Special packing provisions" Contains the alphanumeric codes of the applicable special packing provisions: Column (9b) - Alphanumeric codes starting with the letters "PP" or "RR" refer to special packing provisions for packagings and receptacles (except IBCs and large packagings) that have additionally to be met. These are to be found in 4.1.4.1, at the end of the relevant packing instruction (with the letter "P" or "R") referred to in Column (8). If Column (9a) does not contain a code starting with the letters "PP" or "RR", none of the special packing provisions listed at the end of the relevant packing instruction apply; - Alphanumeric codes starting with the letter "B" or the letters "BB" refer to special packing provisions for IBCs that have additionally to be met. These are to be found in 4.1.4.2, at the end of the relevant packing instruction (with the letters "IBC") referred to in Column (8). If Column (9a) does not contain a code starting with the letter "B" or the letters "BB", none of the special packing provisions listed at the end of the relevant packing instruction apply; - Alphanumeric codes starting with the letter "L" refer to special packing provisions for large packagings that have additionally to be met. These are to be found in 4.1.4.3, at the end of the relevant packing instruction (with the letters "LP") referred to in Column (8). If Column (9a) does not contain a code starting with the letter "L", none of the special packing provisions listed at the end of the relevant packing instruction apply. "Mixed packing provisions" Contains the alphanumeric codes starting with the letters "MP" of the applicable mixed packing provisions. These are listed in 4.1.10 in numerical order. If Column (9b) does not contain a code starting with the letters "MP", only the general requirements apply (see 4.1.1.5 and 4.1.1.6). - 288 - Copyright © United Nations, 2010. All rights reserved Column (10) "Portable tank and bulk container instructions" Contains an alphanumeric code assigned to a portable tank instruction, in accordance with 4.2.5.2.1 to 4.2.5.2.4 and 4.2.5.2.6. This portable tank instruction corresponds to the least stringent provisions that are acceptable for the carriage of the substance in portable tanks. The codes identifying the other portable tank instructions that are also permitted for the carriage of the substance are to be found in 4.2.5.2.5. If no code is given, carriage in portable tanks is not permitted unless a competent authority approval is granted as detailed in 6.7.1.3. The general requirements for the design, construction, equipment, type approval, testing and marking of portable tanks are to be found in Chapter 6.7. The general requirements for the use (e.g. filling) are to be found in 4.2.1 to 4.2.4. The indication of a "(M)" means that the substance may be carried in UN MEGCs. NOTE: Special provisions, indicated in Column (11), may change the above requirements. May also contain alphanumeric codes starting with the letters "BK" referring to types of bulk containers described in Chapter 6.11 which may be used for the carriage of bulk goods in accordance with 7.3.1.1 (a) and 7.3.2. Column (11) "Portable tank and bulk container special provisions" Contains the alphanumeric codes of the portable tank special provisions that have additionally to be met. These codes, starting with the letters "TP" refer to special provisions for the construction or use of these portable tanks. They are to be found in 4.2.5.3. NOTE: If technically relevant, these special provisions are not only applicable to the portable tanks specified in column (10), but also to the portable tanks that may be used according to the table in 4.2.5.2.5. Column (12) "Tank codes for ADR tanks" Contains an alphanumeric code describing a tank type, in accordance with 4.3.3.1.1 (for gases of Class 2) or 4.3.4.1.1 (for substances of Classes 3 to 9). This tank type corresponds to the least stringent tank provisions that are acceptable for the carriage of the relevant substance in ADR tanks. The codes describing the other permitted tank types are to be found in 4.3.3.1.2 (for gases of Class 2) or 4.3.4.1.2 (for substances of Classes 3 to 9). If no code is given, carriage in ADR tanks is not permitted. If in this column a tank code for solids (S) and for liquids (L) is indicated, this means that this substance may be offered for carriage in tanks in the solid or the liquid (molten) state. In general this provision is applicable to substances having melting points from 20 °C to 180 °C. - 289 - Copyright © United Nations, 2010. All rights reserved If for a solid, only a tank code for liquids (L) is indicated in this column, this means that this substance is only offered for carriage in tanks in the liquid (molten) state. The general requirements for the construction, equipment, type approval, testing and marking that are not indicated in the tank code are to be found in 6.8.1, 6.8.2, 6.8.3 and 6.8.5. The general requirements for the use (e.g. maximum degree of filling, minimum test pressure) are to be found in 4.3.1 to 4.3.4. The indication of a "(M)" after the tank code means that the substance can also be carried in battery-vehicles or MEGCs. The indication of a (+) after the tank code means that the alternative use of the tanks is permitted only where this is specified in the certificate of type approval. For fibre-reinforced plastic tanks, see 4.4.1 and Chapter 6.9; for vacuum operated waste tanks, see 4.5.1 and Chapter 6.10. NOTE: Special provisions, indicated in Column (13), may change the above requirements. Column (13) "Special provisions for ADR tanks" Contains the alphanumeric codes of the special provisions for ADR tanks that have additionally to be met: - Alphanumeric codes starting with the letters "TU" refer to special provisions for the use of these tanks. These are to be found in 4.3.5; - Alphanumeric codes starting with the letters "TC" refer to special provisions for the construction of these tanks. These are to be found in 6.8.4 (a); - Alphanumeric codes starting with the letters "TE" refer to special provisions concerning the items of equipment of these tanks. These are to be found in 6.8.4 (b); - Alphanumeric codes starting with the letters "TA" refer to special provisions for the type approval of these tanks. These are to be found in 6.8.4 (c); - Alphanumeric codes starting with the letters "TT" refer to special provisions for the testing of these tanks. These are to be found in 6.8.4 (d); - Alphanumeric codes starting with the letters "TM" refer to special provisions for the marking of these tanks. These are to be found in 6.8.4 (e). NOTE: If technically relevant, these special provisions are not only applicable to the tanks specified in column (12), but also to the tanks that may be used according to the hierarchies in 4.3.3.1.2 and 4.3.4.1.2. - 290 - Copyright © United Nations, 2010. All rights reserved Column (14) "Vehicle for tank carriage" Contains a code designating the vehicle (including the drawing vehicle of trailers or semi-trailers) (see 9.1.1) to be used for the carriage of the substance in tank in accordance with 7.4.2. The requirements concerning the construction and approval of vehicles are to be found in Chapters 9.1, 9.2 and 9.7. Column (15) "Transport category / (Tunnel restriction code)" Contains at the top of the cell a figure indicating the transport category to which the substance or article is assigned for the purposes of exemption related to quantities carried per transport unit (see 1.1.3.6). Contains at the bottom of the cell, between brackets, the tunnel restriction code that refers to the applicable restriction for the passage of vehicles carrying the substance or article through road tunnels. These are to be found in Chapter 8.6. When no tunnel restriction code has been assigned, this is indicated by the mention ‘(─)’. Column (16) "Special provisions for carriage - Packages" Contains the alphanumeric code(s), starting with letter "V", of the applicable special provisions (if any) for carriage in packages. These are listed in 7.2.4. General provisions concerning the carriage in packages are to be found in Chapters 7.1 and 7.2. NOTE: In addition, special provisions indicated in Column (18), concerning loading, unloading and handling, shall be observed. Column (17) "Special provisions for carriage - Bulk" Contains the alphanumeric code(s), starting with letters "VV", of the applicable special provisions for carriage in bulk. These are listed in 7.3.3. If no code is given, carriage in bulk is not permitted. General Provisions concerning the carriage in bulk are to be found in Chapters 7.1 and 7.3. NOTE: In addition, special provisions indicated in Column (18), concerning loading, unloading and handling, shall be observed. Column (18) "Special provisions for carriage - Loading and unloading" Contains the alphanumeric code(s), starting with letters "CV", of the applicable special provisions for loading, unloading and handling. These are listed in 7.5.11. If no code is given, only the general provisions apply (see 7.5.1 to 7.5.10). Column (19) "Special provisions for carriage - Operation" Contains the alphanumeric code(s), starting with letter "S", of the applicable special provisions for operation which are listed in Chapter 8.5. These provisions shall be applied in addition to the requirements of Chapters 8.1 to 8.4 but in the event of conflict with the requirements of Chapters 8.1 to 8.4, the special provisions shall take precedence. - 291 - Copyright © United Nations, 2010. All rights reserved Column (20) "Hazard identification number" Contains a two or three figure number (preceded in certain cases by the letter "X") for substances and articles of classes 2 to 9, and for substances and articles of Class 1, the classification code (see column (3b)). In the cases described in 5.3.2.1, this number shall appear in the upper half of the orange-coloured marking. The meaning of the hazard identification numbers is explained in 5.3.2.3. - 292 - Copyright © United Nations, 2010. All rights reserved TABLE A DANGEROUS GOODS LIST - 293 - Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code 2.2 (1) (2) (3a) 0004 AMMONIUM PICRATE dry 1 or wetted with less than 10% water, by mass 0005 CARTRIDGES FOR 1 WEAPONS with bursting charge 0006 CARTRIDGES FOR 1 WEAPONS with bursting charge 0007 CARTRIDGES FOR 1 WEAPONS with bursting charge 0009 AMMUNITION, 1 INCENDIARY with or without burster, expelling charge or propelling charge 0010 AMMUNITION, 1 INCENDIARY with or without burster, expelling charge or propelling charge 0012 CARTRIDGES FOR 1 WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 0014 CARTRIDGES FOR 1 WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK 0015 AMMUNITION, SMOKE with 1 or without burster, expelling charge or propelling charge 0015 AMMUNITION, SMOKE with 1 or without burster, expelling charge or propelling charge, containing corrosive substances 0016 AMMUNITION, SMOKE with 1 or without burster, expelling charge or propelling charge 0016 AMMUNITION, SMOKE with 1 or without burster, expelling charge or propelling charge, containing corrosive substances 0018 AMMUNITION, TEAR1 PRODUCING with burster, expelling charge or propelling charge 1 0019 AMMUNITION, TEARPRODUCING with burster, expelling charge or propelling charge 0020 AMMUNITION, TOXIC with 1 burster, expelling charge or propelling charge 0021 AMMUNITION, TOXIC with 1 burster, expelling charge or propelling charge 0027 BLACK POWDER 1 (GUNPOWDER), granular or as a meal 0028 BLACK POWDER 1 (GUNPOWDER), COMPRESSED or BLACK POWDER (GUNPOWDER), IN PELLETS 0029 DETONATORS, NON1 ELECTRIC for blasting 0030 DETONATORS, ELECTRIC for blasting 1 Limited and excepted quantities 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3b) 1.1D (4) (5) 1 (6) (7a) 0 (7b) E0 Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 (8) P112(a) P112(b) P112(c) P130 (9a) PP26 PP67 L1 (9b) MP20 1.1F 1 0 E0 MP23 1.1E 1 0 E0 P130 LP101 1.2F 1 0 E0 P130 1.2G 1 0 E0 P130 LP101 PP67 L1 MP23 1.3G 1 0 E0 P130 LP101 PP67 L1 MP23 1.4S 1.4 0 E0 P130 MP23 MP24 1.4S 1.4 0 E0 P130 MP23 MP24 1.2G 1 0 E0 P130 LP101 PP67 L1 MP23 1.2G 1 +8 0 E0 P130 LP101 PP67 L1 MP23 1.3G 1 0 E0 P130 LP101 PP67 L1 MP23 1.3G 1 +8 0 E0 P130 LP101 PP67 L1 MP23 1.2G 1 +6.1 +8 0 E0 P130 LP101 PP67 L1 MP23 1.3G 1 +6.1 +8 0 E0 P130 LP101 PP67 L1 MP23 MP21 MP23 1.2K CARRIAGE PROHIBITED 1.3K CARRIAGE PROHIBITED 1.1D 1 0 E0 P113 PP50 MP20 MP24 1.1D 1 0 E0 P113 PP51 MP20 MP24 1.1B 1 0 E0 P131 PP68 MP23 1.1B 1 0 E0 P131 - 294 - MP23 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 1 (B1000C) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V2 V3 (17) Loading, unloading and handling 7.5.11 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 (19) S1 (20) CV1 CV2 CV3 S1 4 (E) CV1 CV2 CV3 S1 4 (E) CV1 CV2 CV3 S1 CV1 CV2 CV3 CV1 CV2 CV3 S1 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 1 (C5000D) V2 1 (B1000C) V2 1 (C5000D) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV28 CV1 CV2 CV3 CV28 S1 S1 S1 S1 S1 S1 S1 S1 S1 CARRIAGE PROHIBITED CARRIAGE PROHIBITED 1 (B1000C) V2 V3 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 - 295 - CV1 CV2 CV3 CV1 CV2 CV3 S1 CV1 CV2 CV3 CV1 CV2 CV3 S1 S1 S1 Name and description 3.1.2 (1) (2) 0004 AMMONIUM PICRATE dry or wetted with less than 10% water, by mass 0005 CARTRIDGES FOR WEAPONS with bursting charge 0006 CARTRIDGES FOR WEAPONS with bursting charge 0007 CARTRIDGES FOR WEAPONS with bursting charge 0009 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 0010 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 0012 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 0014 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK 0015 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 0015 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge, containing corrosive substances 0016 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 0016 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge, containing corrosive substances 0018 AMMUNITION, TEARPRODUCING with burster, expelling charge or propelling charge 0019 AMMUNITION, TEARPRODUCING with burster, expelling charge or propelling charge 0020 AMMUNITION, TOXIC with burster, expelling charge or propelling charge 0021 AMMUNITION, TOXIC with burster, expelling charge or propelling charge 0027 BLACK POWDER (GUNPOWDER), granular or as a meal 0028 BLACK POWDER (GUNPOWDER), COMPRESSED or BLACK POWDER (GUNPOWDER), IN PELLETS 0029 DETONATORS, NONELECTRIC for blasting 0030 DETONATORS, ELECTRIC for blasting Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 0033 BOMBS with bursting charge (3a) 1 (3b) 1.1F (4) (5) 1 (6) (7a) 0 (7b) E0 (8) P130 (9a) (9b) MP23 0034 BOMBS with bursting charge 1 1.1D 1 0 E0 P130 LP101 PP67 L1 MP21 0035 BOMBS with bursting charge 1 1.2D 1 0 E0 P130 LP101 PP67 L1 MP21 0037 BOMBS, PHOTO-FLASH 1 1.1F 1 0 E0 P130 0038 BOMBS, PHOTO-FLASH 1 1.1D 1 0 E0 P130 LP101 PP67 L1 MP21 0039 BOMBS, PHOTO-FLASH 1 1.2G 1 0 E0 P130 LP101 PP67 L1 MP23 0042 BOOSTERS without detonator 1 1.1D 1 0 E0 P132(a) P132(b) 0043 BURSTERS, explosive 1 1.1D 1 0 E0 P133 0044 PRIMERS, CAP TYPE 1 1.4S 1.4 0 E0 P133 0048 CHARGES, DEMOLITION 1 1.1D 1 0 E0 P130 LP101 0049 CARTRIDGES, FLASH 1 1.1G 1 0 E0 P135 MP23 0050 CARTRIDGES, FLASH 1 1.3G 1 0 E0 P135 MP23 0054 CARTRIDGES, SIGNAL 1 1.3G 1 0 E0 P135 MP23 MP24 0055 CASES, CARTRIDGE, EMPTY, WITH PRIMER 1 1.4S 1.4 0 E0 P136 MP23 0056 CHARGES, DEPTH 1 1.1D 1 0 E0 P130 LP101 PP67 L1 MP21 0059 CHARGES, SHAPED without detonator 1 1.1D 1 0 E0 P137 PP70 MP21 0060 CHARGES, SUPPLEMENTARY, EXPLOSIVE 0065 CORD, DETONATING, flexible 1 1.1D 1 0 E0 P132(a) P132(b) 1 1.1D 1 0 E0 P139 0066 CORD, IGNITER 1 1.4G 1.4 0 E0 P140 MP23 0070 CUTTERS, CABLE, EXPLOSIVE 1 1.4S 1.4 0 E0 P134 LP102 MP23 0072 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE; HEXOGEN; RDX), WETTED with not less than 15% water, by mass 1 1.1D 1 0 E0 P112(a) 0073 DETONATORS FOR AMMUNITION 1 1.1B 1 0 E0 P133 266 - 296 - MP23 MP21 PP69 MP21 MP23 MP24 PP67 L1 MP21 MP21 PP71 PP72 PP45 MP21 MP20 MP23 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 1 (B1000C) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V2 (17) 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 Loading, unloading and handling 7.5.11 4 (E) 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 1 (C5000D) V2 4 (E) 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 4 (E) 1 (B1000C) V2 1 (B1000C) V2 - 297 - Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 (19) S1 (20) CV1 CV2 CV3 Name and description 3.1.2 (1) (2) 0033 BOMBS with bursting charge S1 0034 BOMBS with bursting charge S1 0035 BOMBS with bursting charge S1 0037 BOMBS, PHOTO-FLASH S1 0038 BOMBS, PHOTO-FLASH S1 0039 BOMBS, PHOTO-FLASH S1 0042 BOOSTERS without detonator S1 0043 BURSTERS, explosive S1 0044 PRIMERS, CAP TYPE S1 0048 CHARGES, DEMOLITION S1 0049 CARTRIDGES, FLASH S1 0050 CARTRIDGES, FLASH S1 0054 CARTRIDGES, SIGNAL S1 0055 CASES, CARTRIDGE, EMPTY, WITH PRIMER S1 0056 CHARGES, DEPTH S1 0059 CHARGES, SHAPED without detonator S1 0060 CHARGES, SUPPLEMENTARY, EXPLOSIVE 0065 CORD, DETONATING, flexible S1 S1 0066 CORD, IGNITER S1 0070 CUTTERS, CABLE, EXPLOSIVE S1 0072 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE; HEXOGEN; RDX), WETTED with not less than 15% water, by mass S1 0073 DETONATORS FOR AMMUNITION Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 1 (3b) 1.1A (4) (5) 1 (6) 266 (7a) 0 (7b) E0 (8) P110(b) (9a) PP42 (9b) MP20 0075 DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with not less than 25% nonvolatile, water-insoluble phlegmatizer, by mass 1 1.1D 1 266 0 E0 P115 PP53 PP54 PP57 PP58 MP20 0076 DINITROPHENOL, dry or wetted with less than 15% water, by mass 1 1.1D 1 +6.1 0 E0 P112(a) P112(b) P112(c) PP26 MP20 0077 DINITROPHENOLATES, alkali metals, dry or wetted with less than 15% water, by mass 0078 DINITRORESORCINOL, dry or wetted with less than 15% water, by mass 0079 HEXANITRODIPHENYLAMINE (DIPICRYLAMINE; HEXYL) 1 1.3C 1 +6.1 0 E0 P114(a) P114(b) PP26 MP20 1 1.1D 1 0 E0 PP26 MP20 1 1.1D 1 0 E0 P112(a) P112(b) P112(c) P112(b) P112(c) 0081 EXPLOSIVE, BLASTING, TYPE A 1 1.1D 1 616 617 0 E0 P116 PP63 PP66 MP20 0082 EXPLOSIVE, BLASTING, TYPE B 1 1.1D 1 617 0 E0 P116 MP20 0083 EXPLOSIVE, BLASTING, TYPE C 1 1.1D 1 267 617 0 E0 IBC100 P116 PP61 PP62 PP65 B9 0084 EXPLOSIVE, BLASTING, TYPE D 1 1.1D 1 617 0 E0 P116 MP20 0092 FLARES, SURFACE 1 1.3G 1 0 E0 P135 MP23 0093 FLARES, AERIAL 1 1.3G 1 0 E0 P135 MP23 0094 FLASH POWDER 1 1.1G 1 0 E0 P113 0099 FRACTURING DEVICES, EXPLOSIVE without detonator, for oil wells 0101 FUSE, NON-DETONATING 1 1.1D 1 0 E0 P134 LP102 1 1.3G 1 0 E0 P140 PP74 PP75 MP23 0102 CORD (FUSE), DETONATING, metal clad 1 1.2D 1 0 E0 P139 PP71 MP21 0103 FUSE, IGNITER, tubular, metal clad 1 1.4G 1.4 0 E0 P140 0104 CORD (FUSE), DETONATING, MILD EFFECT, metal clad 0105 FUSE, SAFETY 1 1.4D 1.4 0 E0 P139 PP71 MP21 1 1.4S 1.4 0 E0 P140 PP73 MP23 0106 FUZES, DETONATING 1 1.1B 1 0 E0 P141 MP23 0107 FUZES, DETONATING 1 1.2B 1 0 E0 P141 MP23 (1) (2) 0074 DIAZODINITROPHENOL, WETTED with not less than 40% water, or mixture of alcohol and water, by mass - 298 - MP20 MP20 PP49 MP20 MP21 MP23 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 0 (B) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V2 (17) Loading, unloading and handling 7.5.11 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (18) CV1 CV2 CV3 (19) S1 (20) Name and description 3.1.2 (1) (2) 0074 DIAZODINITROPHENOL, WETTED with not less than 40% water, or mixture of alcohol and water, by mass 1 (B1000C) V2 CV1 CV2 CV3 S1 0075 DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with not less than 25% nonvolatile, water-insoluble phlegmatizer, by mass 1 (B1000C) V2 V3 S1 0076 DINITROPHENOL, dry or wetted with less than 15% water, by mass 1 (C5000D) V2 V3 S1 1 (B1000C) V2 V3 1 (B1000C) V2 V3 CV1 CV2 CV3 CV28 CV1 CV2 CV3 CV28 CV1 CV2 CV3 CV1 CV2 CV3 0077 DINITROPHENOLATES, alkali metals, dry or wetted with less than 15% water, by mass 0078 DINITRORESORCINOL, dry or wetted with less than 15% water, by mass 0079 HEXANITRODIPHENYLAMINE (DIPICRYLAMINE; HEXYL) 1 (B1000C) V2 V3 S1 0081 EXPLOSIVE, BLASTING, TYPE A 1 (B1000C) V2 V3 V12 CV1 CV2 CV3 CV1 CV2 CV3 S1 0082 EXPLOSIVE, BLASTING, TYPE B 1 (B1000C) V2 V3 S1 0083 EXPLOSIVE, BLASTING, TYPE C 1 (B1000C) V2 S1 0084 EXPLOSIVE, BLASTING, TYPE D 1 (C5000D) V2 S1 0092 FLARES, SURFACE 1 (C5000D) V2 S1 0093 FLARES, AERIAL 1 (B1000C) V2 V3 S1 0094 FLASH POWDER 1 (B1000C) V2 S1 1 (C5000D) V2 0099 FRACTURING DEVICES, EXPLOSIVE without detonator, for oil wells 0101 FUSE, NON-DETONATING 1 (B1000C) V2 2 (E) V2 2 (E) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 4 (E) 1 (B1000C) V2 1 (B1000C) V2 - 299 - S1 S1 S1 S1 0102 CORD (FUSE), DETONATING, metal clad S1 0103 FUSE, IGNITER, tubular, metal clad S1 S1 0104 CORD (FUSE), DETONATING, MILD EFFECT, metal clad 0105 FUSE, SAFETY S1 0106 FUZES, DETONATING S1 0107 FUZES, DETONATING Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 1 (3b) 1.4S (4) (5) 1.4 (6) (7a) 0 (7b) E0 (8) P141 (9a) (9b) MP23 0113 GUANYLNITROSAMINOGUANYLIDENE HYDRAZINE, WETTED with not less than 30% water, by mass 0114 GUANYLNITROSAMINOGUANYLTETRAZENE (TETRAZENE), WETTED with not less than 30% water, or mixture of alcohol and water, by mass 0118 HEXOLITE (HEXOTOL), dry or wetted with less than 15% water, by mass 0121 IGNITERS 1 1.1A 1 266 0 E0 P110(b) PP42 MP20 1 1.1A 1 266 0 E0 P110(b) PP42 MP20 1 1.1D 1 0 E0 1 1.1G 1 0 E0 P112(a) P112(b) P112(c) P142 MP23 0124 JET PERFORATING GUNS, CHARGED, oil well, without detonator 0129 LEAD AZIDE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0130 LEAD STYPHNATE (LEAD TRINITRORESORCINATE), WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0131 LIGHTERS, FUSE 1 1.1D 1 0 E0 P101 MP21 1 1.1A 1 266 0 E0 P110(b) PP42 MP20 1 1.1A 1 266 0 E0 P110(b) PP42 MP20 1 1.4S 1.4 0 E0 P142 1 1.3C 1 274 0 E0 P114(a) P114(b) 1 1.1D 1 266 0 E0 P112(a) 1 1.1A 1 266 0 E0 P110(b) 0136 MINES with bursting charge 1 1.1F 1 0 E0 P130 0137 MINES with bursting charge 1 1.1D 1 0 E0 P130 LP101 PP67 L1 MP21 0138 MINES with bursting charge 1 1.2D 1 0 E0 P130 LP101 PP67 L1 MP21 0143 NITROGLYCERIN, DESENSITIZED with not less than 40% non-volatile waterinsoluble phlegmatizer, by mass 0144 NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 10% nitroglycerin 1 1.1D 1 +6.1 266 271 0 E0 P115 PP53 PP54 PP57 PP58 MP20 1 1.1D 1 500 0 E0 P115 PP45 PP55 PP56 PP59 PP60 MP20 0146 NITROSTARCH, dry or wetted with less than 20% water, by mass 1 1.1D 1 0 E0 P112(a) P112(b) P112(c) (1) (2) 0110 GRENADES, PRACTICE, hand or rifle 0132 DEFLAGRATING METAL SALTS OF AROMATIC NITRODERIVATIVES, N.O.S. 0133 MANNITOL HEXANITRATE (NITROMANNITE), WETTED with not less than 40% water, or mixture of alcohol and water, by mass 0135 MERCURY FULMINATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass - 300 - MP20 MP23 PP26 MP2 MP20 PP42 MP20 MP23 MP20 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 4 (E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) (17) Loading, unloading and handling 7.5.11 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (18) CV1 CV2 CV3 CV1 CV2 CV3 (19) S1 (20) 0 (B) V2 0 (B) V2 CV1 CV2 CV3 S1 1 (B1000C) V2 V3 S1 1 (B1000C) V2 1 (B1000C) V2 0 (B) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 0 (B) V2 CV1 CV2 CV3 S1 CV1 CV2 CV3 CV1 CV2 CV3 S1 4 (E) S1 S1 S1 S1 Name and description 3.1.2 (1) (2) 0110 GRENADES, PRACTICE, hand or rifle 0113 GUANYLNITROSAMINOGUANYLIDENE HYDRAZINE, WETTED with not less than 30% water, by mass 0114 GUANYLNITROSAMINOGUANYLTETRAZENE (TETRAZENE), WETTED with not less than 30% water, or mixture of alcohol and water, by mass 0118 HEXOLITE (HEXOTOL), dry or wetted with less than 15% water, by mass 0121 IGNITERS 0124 JET PERFORATING GUNS, CHARGED, oil well, without detonator 0129 LEAD AZIDE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0130 LEAD STYPHNATE (LEAD TRINITRORESORCINATE), WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0131 LIGHTERS, FUSE 1 (C5000D) V2 V3 1 (B1000C) V2 CV1 CV2 CV3 S1 0 (B) V2 CV1 CV2 CV3 S1 1 (B1000C) V2 S1 0136 MINES with bursting charge 1 (B1000C) V2 S1 0137 MINES with bursting charge 1 (B1000C) V2 S1 0138 MINES with bursting charge 1 (B1000C) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV28 S1 1 (B1000C) V2 CV1 CV2 CV3 S1 0143 NITROGLYCERIN, DESENSITIZED with not less than 40% non-volatile waterinsoluble phlegmatizer, by mass 0144 NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 10% nitroglycerin 1 (B1000C) V2 V3 CV1 CV2 CV3 S1 - 301 - S1 0132 DEFLAGRATING METAL SALTS OF AROMATIC NITRODERIVATIVES, N.O.S. 0133 MANNITOL HEXANITRATE (NITROMANNITE), WETTED with not less than 40% water, or mixture of alcohol and water, by mass 0135 MERCURY FULMINATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0146 NITROSTARCH, dry or wetted with less than 20% water, by mass Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 1 (3b) 1.1D (4) (5) 1 (6) (7a) 0 (7b) E0 (8) P112(b) 1 1.1D 1 266 0 E0 P112(a) P112(b) MP20 1 1.1D 1 0 E0 MP20 1 1.1D 1 0 E0 P112(a) P112(b) P112(c) P112(b) P112(c) 1 1.1D 1 0 E0 1 1.1D 1 0 E0 1 1.3C 1 0 E0 0160 POWDER, SMOKELESS 1 1.1C 1 0 E0 P114(b) PP50 PP52 MP20 MP24 0161 POWDER, SMOKELESS 1 1.3C 1 0 E0 P114(b) PP50 PP52 MP20 MP24 0167 PROJECTILES with bursting charge 1 1.1F 1 0 E0 P130 0168 PROJECTILES with bursting charge 1 1.1D 1 0 E0 P130 LP101 PP67 L1 MP21 0169 PROJECTILES with bursting charge 1 1.2D 1 0 E0 P130 LP101 PP67 L1 MP21 0171 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge 0173 RELEASE DEVICES, EXPLOSIVE 1 1.2G 1 0 E0 P130 LP101 PP67 L1 MP23 1 1.4S 1.4 0 E0 P134 LP102 MP23 0174 RIVETS, EXPLOSIVE 1 1.4S 1.4 0 E0 P134 LP102 MP23 0180 ROCKETS with bursting charge 1 1.1F 1 0 E0 P130 MP23 0181 ROCKETS with bursting charge 1 1.1E 1 0 E0 P130 LP101 PP67 L1 MP21 0182 ROCKETS with bursting charge 1 1.2E 1 0 E0 P130 LP101 PP67 L1 MP21 0183 ROCKETS with inert head 1 1.3C 1 0 E0 P130 LP101 PP67 L1 MP22 0186 ROCKET MOTORS 1 1.3C 1 0 E0 P130 LP101 PP67 L1 MP22 MP24 0190 SAMPLES, EXPLOSIVE, other than initiating explosive 1 0 E0 P101 (1) (2) 0147 NITRO UREA 0150 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN), WETTED with not less than 25% water, by mass, or DESENSITIZED with not less than 15% phlegmatizer, by mass 0151 PENTOLITE, dry or wetted with less than 15% water, by mass 0153 TRINITROANILINE (PICRAMIDE) 0154 TRINITROPHENOL (PICRIC ACID), dry or wetted with less than 30% water, by mass 0155 TRINITROCHLOROBENZENE (PICRYL CHLORIDE) 0159 POWDER CAKE (POWDER PASTE), WETTED with not less than 25% water, by mass 266 16 274 - 302 - (9a) (9b) MP20 MP20 P112(a) P112(b) P112(c) P112(b) P112(c) PP26 P111 PP43 MP20 MP20 MP20 MP23 MP2 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 1 (B1000C) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V2 V3 (17) 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (C5000D) V2 1 (B1000C) V2 V3 1 (C5000D) V2 V3 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 Loading, unloading and handling 7.5.11 4 (E) 4 (E) 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 1 (C5000D) V2 0 (E) V2 - 303 - Hazard UN identifi- No. Operation cation No. Name and description 8.5 5.3.2.3 (18) CV1 CV2 CV3 CV1 CV2 CV3 (19) S1 (20) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0160 POWDER, SMOKELESS S1 0161 POWDER, SMOKELESS S1 0167 PROJECTILES with bursting charge S1 0168 PROJECTILES with bursting charge S1 0169 PROJECTILES with bursting charge S1 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0171 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge 0173 RELEASE DEVICES, EXPLOSIVE S1 S1 S1 S1 S1 3.1.2 (1) (2) 0147 NITRO UREA 0150 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN), WETTED with not less than 25% water, by mass, or DESENSITIZED with not less than 15% phlegmatizer, by mass 0151 PENTOLITE, dry or wetted with less than 15% water, by mass 0153 TRINITROANILINE (PICRAMIDE) 0154 TRINITROPHENOL (PICRIC ACID), dry or wetted with less than 30% water, by mass 0155 TRINITROCHLOROBENZENE (PICRYL CHLORIDE) 0159 POWDER CAKE (POWDER PASTE), WETTED with not less than 25% water, by mass S1 0174 RIVETS, EXPLOSIVE S1 0180 ROCKETS with bursting charge S1 0181 ROCKETS with bursting charge S1 0182 ROCKETS with bursting charge S1 0183 ROCKETS with inert head S1 0186 ROCKET MOTORS S1 0190 SAMPLES, EXPLOSIVE, other than initiating explosive Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 1 (3b) 1.4G (4) (5) 1.4 (6) (7a) 0 (7b) E0 (8) P135 0192 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1 1.1G 1 0 E0 P135 MP23 0193 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1 1.4S 1.4 0 E0 P135 MP23 0194 SIGNALS, DISTRESS, ship 1 1.1G 1 0 E0 P135 MP23 MP24 0195 SIGNALS, DISTRESS, ship 1 1.3G 1 0 E0 P135 MP23 MP24 0196 SIGNALS, SMOKE 1 1.1G 1 0 E0 P135 MP23 0197 SIGNALS, SMOKE 1 1.4G 1.4 0 E0 P135 MP23 MP24 0204 SOUNDING DEVICES, EXPLOSIVE 1 1.2F 1 0 E0 P134 LP102 MP23 0207 TETRANITROANILINE 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0208 TRINITROPHENYLMETHYLNITRAMINE (TETRYL) 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0209 TRINITROTOLUENE (TNT), dry or wetted with less than 30% water, by mass 0212 TRACERS FOR AMMUNITION 1 1.1D 1 0 E0 P112(b) P112(c) PP46 MP20 1 1.3G 1 0 E0 P133 PP69 MP23 0213 TRINITROANISOLE 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0214 TRINITROBENZENE, dry or wetted with less than 30% water, by mass 0215 TRINITROBENZOIC ACID, dry or wetted with less than 30% water, by mass 1 1.1D 1 0 E0 MP20 1 1.1D 1 0 E0 P112(a) P112(b) P112(c) P112(a) P112(b) P112(c) 0216 TRINITRO-m-CRESOL 1 1.1D 1 0 E0 P112(b) P112(c) 0217 TRINITRONAPHTHALENE 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0218 TRINITROPHENETOLE 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0219 TRINITRORESORCINOL (STYPHNIC ACID), dry or wetted with less than 20% water, or mixture of alcohol and water, by mass 0220 UREA NITRATE, dry or wetted with less than 20% water, by mass 0221 WARHEADS, TORPEDO with bursting charge 1 1.1D 1 0 E0 P112(a) P112(b) P112(c) 1 1.1D 1 0 E0 1 1.1D 1 0 E0 P112(a) P112(b) P112(c) P130 LP101 1 1.1D 1 0 E0 (1) (2) 0191 SIGNAL DEVICES, HAND 0222 AMMONIUM NITRATE with more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance - 304 - P112(b) P112(c) (9a) (9b) MP23 MP24 MP20 PP26 PP26 MP20 MP20 MP20 PP67 L1 MP21 PP47 MP20 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 2 (E) 1 (B1000C) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V2 (17) Loading, unloading and handling 7.5.11 V2 4 (E) 1 (B1000C) V2 1 (C5000D) V2 1 (B1000C) V2 2 (E) V2 1 (B1000C) V2 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (C5000D) V2 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 1 (B1000C) V2 V3 - 305 - Hazard UN identifi- No. Operation cation No. Name and description 8.5 5.3.2.3 3.1.2 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 (19) S1 (20) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0216 TRINITRO-m-CRESOL S1 0217 TRINITRONAPHTHALENE S1 0218 TRINITROPHENETOLE S1 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0219 TRINITRORESORCINOL (STYPHNIC ACID), dry or wetted with less than 20% water, or mixture of alcohol and water, by mass 0220 UREA NITRATE, dry or wetted with less than 20% water, by mass 0221 WARHEADS, TORPEDO with bursting charge (1) (2) 0191 SIGNAL DEVICES, HAND S1 0192 SIGNALS, RAILWAY TRACK, EXPLOSIVE S1 0193 SIGNALS, RAILWAY TRACK, EXPLOSIVE S1 0194 SIGNALS, DISTRESS, ship S1 0195 SIGNALS, DISTRESS, ship S1 0196 SIGNALS, SMOKE S1 0197 SIGNALS, SMOKE S1 0204 SOUNDING DEVICES, EXPLOSIVE S1 0207 TETRANITROANILINE S1 0208 TRINITROPHENYLMETHYLNITRAMINE (TETRYL) S1 0209 TRINITROTOLUENE (TNT), dry or wetted with less than 30% water, by mass 0212 TRACERS FOR AMMUNITION S1 S1 0213 TRINITROANISOLE S1 0214 TRINITROBENZENE, dry or wetted with less than 30% water, by mass 0215 TRINITROBENZOIC ACID, dry or wetted with less than 30% water, by mass S1 S1 S1 0222 AMMONIUM NITRATE with more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 1 (3b) 1.1A (4) (5) 1 +6.1 (6) (7a) 0 (7b) E0 (8) P110(b) (9a) PP42 (9b) MP20 0225 BOOSTERS WITH DETONATOR 1 1.1B 1 0 E0 P133 PP69 MP23 0226 CYCLOTETRAMETHYLENETETRANITRAMINE (HMX; OCTOGEN), WETTED with not less than 15% water, by mass 0234 SODIUM DINITRO-oCRESOLATE, dry or wetted with less than 15% water, by mass 0235 SODIUM PICRAMATE, dry or wetted with less than 20% water, by mass 0236 ZIRCONIUM PICRAMATE, dry or wetted with less than 20% water, by mass 1 1.1D 1 0 E0 P112(a) PP45 MP20 1 1.3C 1 0 E0 P114(a) P114(b) PP26 MP20 1 1.3C 1 0 E0 P114(a) P114(b) PP26 MP20 1 1.3C 1 0 E0 P114(a) P114(b) PP26 MP20 0237 CHARGES, SHAPED, FLEXIBLE, LINEAR 1 1.4D 1.4 0 E0 P138 MP21 0238 ROCKETS, LINETHROWING 1 1.2G 1 0 E0 P130 MP23 MP24 0240 ROCKETS, LINETHROWING 1 1.3G 1 0 E0 P130 MP23 MP24 0241 EXPLOSIVE, BLASTING, TYPE E 1 1.1D 1 0 E0 P116 0242 CHARGES, PROPELLING, FOR CANNON 1 1.3C 1 0 E0 IBC100 P130 0243 AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 0244 AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 0245 AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 0246 AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 0247 AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge 0248 CONTRIVANCES, WATERACTIVATED with burster, expelling charge or propelling charge 0249 CONTRIVANCES, WATERACTIVATED with burster, expelling charge or propelling charge 0250 ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge 1 1.2H 1 0 E0 P130 LP101 PP67 L1 MP23 1 1.3H 1 0 E0 P130 LP101 PP67 L1 MP23 1 1.2H 1 0 E0 P130 LP101 PP67 L1 MP23 1 1.3H 1 0 E0 P130 LP101 PP67 L1 MP23 1 1.3J 1 0 E0 P101 1 1.2L 1 274 0 E0 P144 PP77 MP1 1 1.3L 1 274 0 E0 P144 PP77 MP1 1 1.3L 1 0 E0 P101 (1) (2) 0224 BARIUM AZIDE, dry or wetted with less than 50% water, by mass 266 617 - 306 - PP61 PP62 PP65 B10 MP20 MP22 MP23 MP1 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 0 (B) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V2 V3 (17) Loading, unloading and handling 7.5.11 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (18) CV1 CV2 CV3 CV28 CV1 CV2 CV3 CV1 CV2 CV3 (19) S1 (20) 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 V3 CV1 CV2 CV3 S1 1 (C5000D) V2 V3 S1 1 (C5000D) V2 V3 CV1 CV2 CV3 CV1 CV2 CV3 2 (E) V2 1 (B1000C) V2 1 (C5000D) V2 1 (B1000C) V2 V12 1 (C5000D) V2 1 (B1000C) V2 1 (C) Name and description 3.1.2 (1) (2) 0224 BARIUM AZIDE, dry or wetted with less than 50% water, by mass S1 0225 BOOSTERS WITH DETONATOR S1 0226 CYCLOTETRAMETHYLENETETRANITRAMINE (HMX; OCTOGEN), WETTED with not less than 15% water, by mass 0234 SODIUM DINITRO-oCRESOLATE, dry or wetted with less than 15% water, by mass 0235 SODIUM PICRAMATE, dry or wetted with less than 20% water, by mass 0236 ZIRCONIUM PICRAMATE, dry or wetted with less than 20% water, by mass S1 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0237 CHARGES, SHAPED, FLEXIBLE, LINEAR S1 0238 ROCKETS, LINETHROWING S1 0240 ROCKETS, LINETHROWING S1 0241 EXPLOSIVE, BLASTING, TYPE E CV1 CV2 CV3 CV1 CV2 CV3 S1 0242 CHARGES, PROPELLING, FOR CANNON S1 V2 CV1 CV2 CV3 S1 1 (B1000C) V2 CV1 CV2 CV3 S1 1 (C) V2 CV1 CV2 CV3 S1 1 (C) V2 CV1 CV2 CV3 S1 0 (B) V2 S1 0 (B) V2 0 (B) V2 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV4 0243 AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 0244 AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 0245 AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 0246 AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 0247 AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge 0248 CONTRIVANCES, WATERACTIVATED with burster, expelling charge or propelling charge 0249 CONTRIVANCES, WATERACTIVATED with burster, expelling charge or propelling charge 0250 ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge - 307 - S1 S1 Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 1 (3b) 1.3G (4) (5) 1 (6) (7a) 0 (7b) E0 (8) P130 LP101 1 1.4B 1.4 0 E0 P131 MP23 0257 FUZES, DETONATING 1 1.4B 1.4 0 E0 P141 MP23 0266 OCTOLITE (OCTOL), dry or wetted with less than 15% water, by mass 0267 DETONATORS, NONELECTRIC for blasting 1 1.1D 1 0 E0 MP20 1 1.4B 1.4 0 E0 P112(a) P112(b) P112(c) P131 PP68 MP23 0268 BOOSTERS WITH DETONATOR 1 1.2B 1 0 E0 P133 PP69 MP23 0271 CHARGES, PROPELLING 1 1.1C 1 0 E0 P143 PP76 MP22 0272 CHARGES, PROPELLING 1 1.3C 1 0 E0 P143 PP76 MP22 0275 CARTRIDGES, POWER DEVICE 1 1.3C 1 0 E0 P134 LP102 MP22 0276 CARTRIDGES, POWER DEVICE 1 1.4C 1.4 0 E0 P134 LP102 MP22 0277 CARTRIDGES, OIL WELL 1 1.3C 1 0 E0 P134 LP102 MP22 0278 CARTRIDGES, OIL WELL 1 1.4C 1.4 0 E0 P134 LP102 MP22 0279 CHARGES, PROPELLING, FOR CANNON 1 1.1C 1 0 E0 P130 MP22 0280 ROCKET MOTORS 1 1.1C 1 0 E0 P130 LP101 PP67 L1 MP22 0281 ROCKET MOTORS 1 1.2C 1 0 E0 P130 LP101 PP67 L1 MP22 0282 NITROGUANIDINE (PICRITE), dry or wetted with less than 20% water, by mass 1 1.1D 1 0 E0 P112(a) P112(b) P112(c) MP20 0283 BOOSTERS without detonator 1 1.2D 1 0 E0 P132(a) P132(b) MP21 0284 GRENADES, hand or rifle, with bursting charge 1 1.1D 1 0 E0 P141 MP21 0285 GRENADES, hand or rifle, with bursting charge 1 1.2D 1 0 E0 P141 MP21 0286 WARHEADS, ROCKET with bursting charge 1 1.1D 1 0 E0 P130 LP101 PP67 L1 MP21 0287 WARHEADS, ROCKET with bursting charge 1 1.2D 1 0 E0 P130 LP101 PP67 L1 MP21 0288 CHARGES, SHAPED, FLEXIBLE, LINEAR 1 1.1D 1 0 E0 P138 0289 CORD, DETONATING, flexible 1 1.4D 1.4 0 E0 P139 (1) (2) 0254 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge 0255 DETONATORS, ELECTRIC for blasting - 308 - (9a) PP67 L1 (9b) MP23 MP21 PP71 PP72 MP21 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 1 (C5000D) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V2 (17) 2 (E) V2 2 (E) V2 1 (B1000C) V2 V3 2 (E) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 1 (C5000D) V2 2 (E) V2 1 (C5000D) V2 2 (E) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 V3 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 Loading, unloading and handling 7.5.11 - 309 - Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (18) CV1 CV2 CV3 (19) S1 (20) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 Name and description 3.1.2 (1) (2) 0254 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge 0255 DETONATORS, ELECTRIC for blasting S1 0257 FUZES, DETONATING S1 0266 OCTOLITE (OCTOL), dry or wetted with less than 15% water, by mass 0267 DETONATORS, NONELECTRIC for blasting S1 S1 0268 BOOSTERS WITH DETONATOR S1 0271 CHARGES, PROPELLING S1 0272 CHARGES, PROPELLING S1 0275 CARTRIDGES, POWER DEVICE S1 0276 CARTRIDGES, POWER DEVICE S1 0277 CARTRIDGES, OIL WELL S1 0278 CARTRIDGES, OIL WELL S1 0279 CHARGES, PROPELLING, FOR CANNON S1 0280 ROCKET MOTORS S1 0281 ROCKET MOTORS S1 0282 NITROGUANIDINE (PICRITE), dry or wetted with less than 20% water, by mass S1 0283 BOOSTERS without detonator S1 0284 GRENADES, hand or rifle, with bursting charge S1 0285 GRENADES, hand or rifle, with bursting charge S1 0286 WARHEADS, ROCKET with bursting charge S1 0287 WARHEADS, ROCKET with bursting charge S1 0288 CHARGES, SHAPED, FLEXIBLE, LINEAR S1 0289 CORD, DETONATING, flexible Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 1 (3b) 1.1D (4) (5) 1 (6) (7a) 0 (7b) E0 (8) P139 0291 BOMBS with bursting charge 1 1.2F 1 0 E0 P130 MP23 0292 GRENADES, hand or rifle, with bursting charge 1 1.1F 1 0 E0 P141 MP23 0293 GRENADES, hand or rifle, with bursting charge 1 1.2F 1 0 E0 P141 MP23 0294 MINES with bursting charge 1 1.2F 1 0 E0 P130 MP23 0295 ROCKETS with bursting charge 1 1.2F 1 0 E0 P130 MP23 0296 SOUNDING DEVICES, EXPLOSIVE 1 1.1F 1 0 E0 P134 LP102 MP23 0297 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge 0299 BOMBS, PHOTO-FLASH 1 1.4G 1.4 0 E0 P130 LP101 PP67 L1 MP23 1 1.3G 1 0 E0 P130 LP101 PP67 L1 MP23 1 1.4G 1.4 0 E0 P130 LP101 PP67 L1 MP23 1 1.4G 1.4 +6.1 +8 0 E0 P130 LP101 PP67 L1 MP23 1 1.4G 1.4 0 E0 P130 LP101 PP67 L1 MP23 1 1.4G 1.4 +8 0 E0 P130 LP101 PP67 L1 MP23 1 1.3G 1 0 E0 P113 PP49 MP20 0306 TRACERS FOR AMMUNITION 1 1.4G 1.4 0 E0 P133 PP69 MP23 0312 CARTRIDGES, SIGNAL 1 1.4G 1.4 0 E0 P135 MP23 MP24 0313 SIGNALS, SMOKE 1 1.2G 1 0 E0 P135 MP23 0314 IGNITERS 1 1.2G 1 0 E0 P142 MP23 0315 IGNITERS 1 1.3G 1 0 E0 P142 MP23 0316 FUZES, IGNITING 1 1.3G 1 0 E0 P141 MP23 0317 FUZES, IGNITING 1 1.4G 1.4 0 E0 P141 MP23 0318 GRENADES, PRACTICE, hand or rifle 1 1.3G 1 0 E0 P141 MP23 0319 PRIMERS, TUBULAR 1 1.3G 1 0 E0 P133 MP23 (1) (2) 0290 CORD (FUSE), DETONATING, metal clad 0300 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 0301 AMMUNITION, TEARPRODUCING with burster, expelling charge or propelling charge 0303 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 0303 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge, containing corrosive substances 0305 FLASH POWDER - 310 - (9a) PP71 (9b) MP21 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 1 (B1000C) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V2 (17) 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 1 (C5000D) V2 2 (E) V2 2 (E) V2 2 (E) V2 2 (E) V2 1 (C5000D) V2 V3 2 (E) V2 2 (E) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 1 (C5000D) V2 2 (E) V2 1 (C5000D) V2 1 (C5000D) V2 Loading, unloading and handling 7.5.11 - 311 - Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 (19) S1 (20) CV1 CV2 CV3 CV1 CV2 CV3 S1 CV1 CV2 CV3 CV28 CV1 CV2 CV3 CV1 CV2 CV3 S1 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 Name and description 3.1.2 (1) (2) 0290 CORD (FUSE), DETONATING, metal clad S1 0291 BOMBS with bursting charge S1 0292 GRENADES, hand or rifle, with bursting charge S1 0293 GRENADES, hand or rifle, with bursting charge S1 0294 MINES with bursting charge S1 0295 ROCKETS with bursting charge S1 0296 SOUNDING DEVICES, EXPLOSIVE S1 0297 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge 0299 BOMBS, PHOTO-FLASH S1 S1 S1 0300 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 0301 AMMUNITION, TEARPRODUCING with burster, expelling charge or propelling charge 0303 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 0303 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge, containing corrosive substances 0305 FLASH POWDER S1 0306 TRACERS FOR AMMUNITION S1 0312 CARTRIDGES, SIGNAL S1 0313 SIGNALS, SMOKE S1 0314 IGNITERS S1 0315 IGNITERS S1 0316 FUZES, IGNITING S1 0317 FUZES, IGNITING S1 0318 GRENADES, PRACTICE, hand or rifle S1 0319 PRIMERS, TUBULAR Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 1 (3b) 1.4G (4) (5) 1.4 (6) (7a) 0 (7b) E0 (8) P133 (9a) (9b) MP23 0321 CARTRIDGES FOR WEAPONS with bursting charge 0322 ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge 1 1.2E 1 0 E0 P130 LP101 PP67 L1 MP21 1 1.2L 1 0 E0 P101 MP1 0323 CARTRIDGES, POWER DEVICE 1 1.4S 1.4 0 E0 P134 LP102 MP23 0324 PROJECTILES with bursting charge 1 1.2F 1 0 E0 P130 MP23 0325 IGNITERS 1 1.4G 1.4 0 E0 P142 MP23 0326 CARTRIDGES FOR WEAPONS, BLANK 1 1.1C 1 0 E0 P130 MP22 0327 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK 0328 CARTRIDGES FOR WEAPONS, INERT PROJECTILE 0329 TORPEDOES with bursting charge 1 1.3C 1 0 E0 P130 MP22 1 1.2C 1 0 E0 P130 LP101 PP67 L1 MP22 1 1.1E 1 0 E0 P130 LP101 PP67 L1 MP21 0330 TORPEDOES with bursting charge 1 1.1F 1 0 E0 P130 0331 EXPLOSIVE, BLASTING, TYPE B (AGENT, BLASTING, TYPE B) 1 1.5D 1.5 617 0 E0 P116 0332 EXPLOSIVE, BLASTING, TYPE E (AGENT, BLASTING, TYPE E) 0333 FIREWORKS 1 1.5D 1.5 617 0 E0 IBC100 P116 1 1.1G 1 645 0 E0 IBC100 P135 0334 FIREWORKS 1 1.2G 1 645 0 E0 P135 MP23 MP24 0335 FIREWORKS 1 1.3G 1 645 0 E0 P135 MP23 MP24 0336 FIREWORKS 1 1.4G 1.4 645 651 0 E0 P135 MP23 MP24 0337 FIREWORKS 1 1.4S 1.4 645 0 E0 P135 MP23 MP24 0338 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK 0339 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 0340 NITROCELLULOSE, dry or wetted with less than 25% water (or alcohol), by mass 1 1.4C 1.4 0 E0 P130 MP22 1 1.4C 1.4 0 E0 P130 MP22 1 1.1D 1 0 E0 P112(a) P112(b) MP20 (1) (2) 0320 PRIMERS, TUBULAR 347 - 312 - Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) MP23 PP61 PP62 PP64 PP65 MP20 T1 TP1 TP17 TP32 PP61 PP62 PP65 MP20 T1 TP1 TP17 TP32 MP23 MP24 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 2 (E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V2 (17) 1 (B1000C) V2 0 (B) V2 Loading, unloading and handling 7.5.11 4 (E) 1 (B1000C) V2 2 (E) V2 1 (B1000C) V2 1 (C5000D) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 EX/III 1 (B1000C) V2 V12 EX/III 1 (B1000C) V2 V12 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (C5000D) V2 V3 2 (E) V2 4 (E) Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 (19) S1 (20) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 S1 3.1.2 (1) (2) 0320 PRIMERS, TUBULAR 0321 CARTRIDGES FOR WEAPONS with bursting charge 0322 ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge S1 S1 0323 CARTRIDGES, POWER DEVICE S1 0324 PROJECTILES with bursting charge S1 0325 IGNITERS S1 0326 CARTRIDGES FOR WEAPONS, BLANK S1 0327 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK 0328 CARTRIDGES FOR WEAPONS, INERT PROJECTILE 0329 TORPEDOES with bursting charge S1 S1 0330 TORPEDOES with bursting charge S1 1.5D 0331 EXPLOSIVE, BLASTING, TYPE B (AGENT, BLASTING, TYPE B) CV1 CV2 CV3 S1 1.5D CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0332 EXPLOSIVE, BLASTING, TYPE E (AGENT, BLASTING, TYPE E) 0333 FIREWORKS S1 0334 FIREWORKS S1 0335 FIREWORKS S1 0336 FIREWORKS S1 0337 FIREWORKS S1 0338 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK 0339 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 0340 NITROCELLULOSE, dry or wetted with less than 25% water (or alcohol), by mass 2 (E) V2 2 (E) V2 CV1 CV2 CV3 S1 1 (B1000C) V2 V3 CV1 CV2 CV3 S1 - 313 - Name and description Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 1 (3b) 1.1D (4) (5) 1 (6) (7a) 0 (7b) E0 (8) P112(b) (9a) (9b) MP20 1 1.3C 1 105 0 E0 P114(a) PP43 MP20 1 1.3C 1 105 0 E0 P111 1 1.4D 1.4 0 E0 P130 LP101 PP67 L1 MP21 0345 PROJECTILES, inert with tracer 1 1.4S 1.4 0 E0 P130 LP101 PP67 L1 MP23 0346 PROJECTILES with burster or expelling charge 1 1.2D 1 0 E0 P130 LP101 PP67 L1 MP21 0347 PROJECTILES with burster or expelling charge 1 1.4D 1.4 0 E0 P130 LP101 PP67 L1 MP21 0348 CARTRIDGES FOR WEAPONS with bursting charge 0349 ARTICLES, EXPLOSIVE, N.O.S. 1 1.4F 1.4 0 E0 P130 MP23 1 1.4S 1.4 178 274 0 E0 P101 MP2 0350 ARTICLES, EXPLOSIVE, N.O.S. 1 1.4B 1.4 178 274 0 E0 P101 MP2 0351 ARTICLES, EXPLOSIVE, N.O.S. 1 1.4C 1.4 178 274 0 E0 P101 MP2 0352 ARTICLES, EXPLOSIVE, N.O.S. 1 1.4D 1.4 178 274 0 E0 P101 MP2 0353 ARTICLES, EXPLOSIVE, N.O.S. 1 1.4G 1.4 178 274 0 E0 P101 MP2 0354 ARTICLES, EXPLOSIVE, N.O.S. 1 1.1L 1 178 274 0 E0 P101 MP1 0355 ARTICLES, EXPLOSIVE, N.O.S. 1 1.2L 1 178 274 0 E0 P101 MP1 0356 ARTICLES, EXPLOSIVE, N.O.S. 1 1.3L 1 178 274 0 E0 P101 MP1 0357 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.1L 1 178 274 0 E0 P101 MP1 0358 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.2L 1 178 274 0 E0 P101 MP1 0359 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.3L 1 178 274 0 E0 P101 MP1 0360 DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting 1 1.1B 1 0 E0 P131 MP23 0361 DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting 1 1.4B 1.4 0 E0 P131 MP23 (1) (2) 0341 NITROCELLULOSE, unmodified or plasticized with less than 18% plasticizing substance, by mass 0342 NITROCELLULOSE, WETTED with not less than 25% alcohol, by mass 0343 NITROCELLULOSE, PLASTICIZED with not less than 18% plasticizing substance, by mass 0344 PROJECTILES with bursting charge - 314 - MP20 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 1 (B1000C) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V2 V3 (17) 1 (C5000D) V2 1 (C5000D) V2 2 (E) V2 Loading, unloading and handling 7.5.11 4 (E) 1 (B1000C) V2 2 (E) V2 2 (E) V2 4 (E) 2 (E) V2 2 (E) V2 2 (E) V2 2 (E) V2 0 (B) V2 0 (B) V2 0 (B) V2 0 (B) V2 0 (B) V2 0 (B) V2 1 (B1000C) V2 2 (E) V2 - 315 - Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (18) CV1 CV2 CV3 (19) S1 (20) CV1 CV2 CV3 CV1 CV2 CV3 S1 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV1 CV2 CV3 S1 S1 Name and description 3.1.2 (1) (2) 0341 NITROCELLULOSE, unmodified or plasticized with less than 18% plasticizing substance, by mass 0342 NITROCELLULOSE, WETTED with not less than 25% alcohol, by mass 0343 NITROCELLULOSE, PLASTICIZED with not less than 18% plasticizing substance, by mass 0344 PROJECTILES with bursting charge S1 0345 PROJECTILES, inert with tracer S1 0346 PROJECTILES with burster or expelling charge S1 0347 PROJECTILES with burster or expelling charge S1 0348 CARTRIDGES FOR WEAPONS with bursting charge 0349 ARTICLES, EXPLOSIVE, N.O.S. S1 S1 0350 ARTICLES, EXPLOSIVE, N.O.S. S1 0351 ARTICLES, EXPLOSIVE, N.O.S. S1 0352 ARTICLES, EXPLOSIVE, N.O.S. S1 0353 ARTICLES, EXPLOSIVE, N.O.S. S1 0354 ARTICLES, EXPLOSIVE, N.O.S. S1 0355 ARTICLES, EXPLOSIVE, N.O.S. S1 0356 ARTICLES, EXPLOSIVE, N.O.S. S1 0357 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0358 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0359 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0360 DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting S1 0361 DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 1 (3b) 1.4G (4) (5) 1.4 (6) (7a) 0 (7b) E0 (8) P130 LP101 (9a) PP67 L1 (9b) MP23 0363 AMMUNITION, PROOF 1 1.4G 1.4 0 E0 P130 LP101 PP67 L1 MP23 0364 DETONATORS FOR AMMUNITION 1 1.2B 1 0 E0 P133 MP23 0365 DETONATORS FOR AMMUNITION 1 1.4B 1.4 0 E0 P133 MP23 0366 DETONATORS FOR AMMUNITION 1 1.4S 1.4 0 E0 P133 MP23 0367 FUZES, DETONATING 1 1.4S 1.4 0 E0 P141 MP23 0368 FUZES, IGNITING 1 1.4S 1.4 0 E0 P141 MP23 0369 WARHEADS, ROCKET with bursting charge 1 1.1F 1 0 E0 P130 MP23 0370 WARHEADS, ROCKET with burster or expelling charge 1 1.4D 1.4 0 E0 P130 LP101 0371 WARHEADS, ROCKET with burster or expelling charge 1 1.4F 1.4 0 E0 P130 MP23 0372 GRENADES, PRACTICE, hand or rifle 1 1.2G 1 0 E0 P141 MP23 0373 SIGNAL DEVICES, HAND 1 1.4S 1.4 0 E0 P135 MP23 MP24 0374 SOUNDING DEVICES, EXPLOSIVE 1 1.1D 1 0 E0 P134 LP102 MP21 0375 SOUNDING DEVICES, EXPLOSIVE 1 1.2D 1 0 E0 P134 LP102 MP21 0376 PRIMERS, TUBULAR 1 1.4S 1.4 0 E0 P133 MP23 0377 PRIMERS, CAP TYPE 1 1.1B 1 0 E0 P133 MP23 0378 PRIMERS, CAP TYPE 1 1.4B 1.4 0 E0 P133 MP23 0379 CASES, CARTRIDGE, EMPTY, WITH PRIMER 1 1.4C 1.4 0 E0 P136 MP22 0380 ARTICLES, PYROPHORIC 1 1.2L 1 0 E0 P101 MP1 0381 CARTRIDGES, POWER DEVICE 1 1.2C 1 0 E0 P134 LP102 MP22 0382 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1 1.2B 1 178 274 0 E0 P101 MP2 0383 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1 1.4B 1.4 178 274 0 E0 P101 MP2 0384 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1 1.4S 1.4 178 274 0 E0 P101 MP2 0385 5-NITROBENZOTRIAZOL 1 1.1D 1 0 E0 P112(b) P112(c) MP20 (1) (2) 0362 AMMUNITION, PRACTICE 347 - 316 - PP67 L1 MP21 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 2 (E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V2 (17) 2 (E) V2 1 (B1000C) V2 2 (E) V2 Loading, unloading and handling 7.5.11 4 (E) 4 (E) 4 (E) 1 (B1000C) V2 2 (E) V2 2 (E) V2 1 (B1000C) V2 4 (E) 1 (B1000C) V2 1 (B1000C) V2 4 (E) 1 (B1000C) V2 2 (E) V2 2 (E) V2 0 (B) V2 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 4 (E) 1 (B1000C) V2 V3 - 317 - (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S1 (20) Name and description 3.1.2 (1) (2) 0362 AMMUNITION, PRACTICE S1 0363 AMMUNITION, PROOF S1 0364 DETONATORS FOR AMMUNITION S1 0365 DETONATORS FOR AMMUNITION S1 0366 DETONATORS FOR AMMUNITION S1 0367 FUZES, DETONATING S1 0368 FUZES, IGNITING S1 0369 WARHEADS, ROCKET with bursting charge S1 0370 WARHEADS, ROCKET with burster or expelling charge S1 0371 WARHEADS, ROCKET with burster or expelling charge S1 0372 GRENADES, PRACTICE, hand or rifle S1 0373 SIGNAL DEVICES, HAND S1 0374 SOUNDING DEVICES, EXPLOSIVE S1 0375 SOUNDING DEVICES, EXPLOSIVE S1 0376 PRIMERS, TUBULAR S1 0377 PRIMERS, CAP TYPE S1 0378 PRIMERS, CAP TYPE S1 0379 CASES, CARTRIDGE, EMPTY, WITH PRIMER S1 0380 ARTICLES, PYROPHORIC S1 0381 CARTRIDGES, POWER DEVICE S1 0382 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. S1 0383 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. S1 0384 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. S1 0385 5-NITROBENZOTRIAZOL Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 1 (3b) 1.1D (4) (5) 1 (6) (7a) 0 (7b) E0 (8) P112(b) P112(c) 0387 TRINITROFLUORENONE 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0388 TRINITROTOLUENE (TNT) AND TRINITROBENZENE MIXTURE or TRINITROTOLUENE (TNT) AND HEXANITROSTILBENE MIXTURE 0389 TRINITROTOLUENE (TNT) MIXTURE CONTAINING TRINITROBENZENE AND HEXANITROSTILBENE 0390 TRITONAL 1 1.1D 1 0 E0 P112(b) P112(c) MP20 1 1.1D 1 0 E0 P112(b) P112(c) MP20 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0391 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE; HEXOGEN; RDX) AND CYCLOTETRAMETHYLENETETRANITRAMINE (HMX; OCTOGEN) MIXTURE, WETTED with not less than 15% water, by mass or DESENSITIZED with not less than 10% phlegmatiser by mass 0392 HEXANITROSTILBENE 1 1.1D 1 0 E0 P112(a) P112(b) MP20 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0393 HEXOTONAL 1 1.1D 1 0 E0 P112(b) MP20 0394 TRINITRORESORCINOL (STYPHNIC ACID), WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0395 ROCKET MOTORS, LIQUID FUELLED 1 1.1D 1 0 E0 P112(a) 1 1.2J 1 0 E0 P101 MP23 0396 ROCKET MOTORS, LIQUID FUELLED 1 1.3J 1 0 E0 P101 MP23 0397 ROCKETS, LIQUID FUELLED with bursting charge 0398 ROCKETS, LIQUID FUELLED with bursting charge 0399 BOMBS WITH FLAMMABLE LIQUID with bursting charge 0400 BOMBS WITH FLAMMABLE LIQUID with bursting charge 0401 DIPICRYL SULPHIDE, dry or wetted with less than 10% water, by mass 0402 AMMONIUM PERCHLORATE 1 1.1J 1 0 E0 P101 MP23 1 1.2J 1 0 E0 P101 MP23 1 1.1J 1 0 E0 P101 MP23 1 1.2J 1 0 E0 P101 MP23 1 1.1D 1 0 E0 MP20 1 1.1D 1 0 E0 P112(a) P112(b) P112(c) P112(b) P112(c) 0403 FLARES, AERIAL 1 1.4G 1.4 0 E0 P135 MP23 0404 FLARES, AERIAL 1 1.4S 1.4 0 E0 P135 MP23 (1) (2) 0386 TRINITROBENZENESULPHONIC ACID 266 152 - 318 - (9a) PP26 PP26 (9b) MP20 MP20 MP20 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 1 (B1000C) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V2 V3 (17) Loading, unloading and handling 7.5.11 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 (19) S1 (20) Name and description 3.1.2 (1) (2) 0386 TRINITROBENZENESULPHONIC ACID 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 CV1 CV2 CV3 S1 1 (B1000C) V2 V3 S1 1 (B1000C) V2 V3 CV1 CV2 CV3 CV1 CV2 CV3 1 (B1000C) V2 V3 S1 1 (B1000C) V2 V3 S1 0393 HEXOTONAL 1 (B1000C) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 0391 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE; HEXOGEN; RDX) AND CYCLOTETRAMETHYLENETETRANITRAMINE (HMX; OCTOGEN) MIXTURE, WETTED with not less than 15% water, by mass or DESENSITIZED with not less than 10% phlegmatiser by mass 0392 HEXANITROSTILBENE S1 1 (B1000C) V2 S1 1 (C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 V3 1 (B1000C) V2 V3 2 (E) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 0394 TRINITRORESORCINOL (STYPHNIC ACID), WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0395 ROCKET MOTORS, LIQUID FUELLED 4 (E) - 319 - S1 0387 TRINITROFLUORENONE S1 0388 TRINITROTOLUENE (TNT) AND TRINITROBENZENE MIXTURE or TRINITROTOLUENE (TNT) AND HEXANITROSTILBENE MIXTURE 0389 TRINITROTOLUENE (TNT) MIXTURE CONTAINING TRINITROBENZENE AND HEXANITROSTILBENE 0390 TRITONAL S1 S1 0396 ROCKET MOTORS, LIQUID FUELLED S1 0397 ROCKETS, LIQUID FUELLED with bursting charge 0398 ROCKETS, LIQUID FUELLED with bursting charge 0399 BOMBS WITH FLAMMABLE LIQUID with bursting charge 0400 BOMBS WITH FLAMMABLE LIQUID with bursting charge 0401 DIPICRYL SULPHIDE, dry or wetted with less than 10% water, by mass 0402 AMMONIUM PERCHLORATE S1 S1 S1 S1 S1 S1 0403 FLARES, AERIAL S1 0404 FLARES, AERIAL Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 0405 CARTRIDGES, SIGNAL (3a) 1 (3b) 1.4S (4) (5) 1.4 (6) (7a) 0 (7b) E0 (8) P135 0406 DINITROSOBENZENE 1 1.3C 1 0 E0 P114(b) MP20 0407 TETRAZOL-1-ACETIC ACID 1 1.4C 1.4 0 E0 P114(b) MP20 0408 FUZES, DETONATING with protective features 1 1.1D 1 0 E0 P141 MP21 0409 FUZES, DETONATING with protective features 1 1.2D 1 0 E0 P141 MP21 0410 FUZES, DETONATING with protective features 1 1.4D 1.4 0 E0 P141 MP21 0411 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN) with not less than 7% wax, by 0412 CARTRIDGES FOR WEAPONS with bursting charge 0413 CARTRIDGES FOR WEAPONS, BLANK 1 1.1D 1 0 E0 P112(b) P112(c) MP20 1 1.4E 1.4 0 E0 P130 LP101 1 1.2C 1 0 E0 P130 MP22 0414 CHARGES, PROPELLING, FOR CANNON 1 1.2C 1 0 E0 P130 MP22 0415 CHARGES, PROPELLING 1 1.2C 1 0 E0 P143 0417 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 0418 FLARES, SURFACE 1 1.3C 1 0 E0 P130 MP22 1 1.1G 1 0 E0 P135 MP23 0419 FLARES, SURFACE 1 1.2G 1 0 E0 P135 MP23 0420 FLARES, AERIAL 1 1.1G 1 0 E0 P135 MP23 0421 FLARES, AERIAL 1 1.2G 1 0 E0 P135 MP23 0424 PROJECTILES, inert with tracer 1 1.3G 1 0 E0 P130 LP101 PP67 L1 MP23 0425 PROJECTILES, inert with tracer 1 1.4G 1.4 0 E0 P130 LP101 PP67 L1 MP23 0426 PROJECTILES with burster or expelling charge 1 1.2F 1 0 E0 P130 MP23 0427 PROJECTILES with burster or expelling charge 1 1.4F 1.4 0 E0 P130 MP23 0428 ARTICLES, PYROTECHNIC for technical purposes 1 1.1G 1 0 E0 P135 MP23 MP24 0429 ARTICLES, PYROTECHNIC for technical purposes 1 1.2G 1 0 E0 P135 MP23 MP24 0430 ARTICLES, PYROTECHNIC for technical purposes 1 1.3G 1 0 E0 P135 MP23 MP24 131 - 320 - (9a) PP67 L1 PP76 (9b) MP23 MP24 MP21 MP22 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 4 (E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) (17) 1 (C5000D) V2 V3 2 (E) V2 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 1 (B1000C) V2 V3 2 (E) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 2 (E) V2 1 (B1000C) V2 2 (E) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 Loading, unloading and handling 7.5.11 - 321 - Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 (19) S1 (20) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 Name and description 3.1.2 (1) (2) 0405 CARTRIDGES, SIGNAL S1 0406 DINITROSOBENZENE S1 0407 TETRAZOL-1-ACETIC ACID S1 0408 FUZES, DETONATING with protective features S1 0409 FUZES, DETONATING with protective features S1 0410 FUZES, DETONATING with protective features S1 0411 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN) with not less than 7% wax, by 0412 CARTRIDGES FOR WEAPONS with bursting charge 0413 CARTRIDGES FOR WEAPONS, BLANK S1 S1 0414 CHARGES, PROPELLING, FOR CANNON S1 0415 CHARGES, PROPELLING S1 S1 0417 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 0418 FLARES, SURFACE S1 0419 FLARES, SURFACE S1 0420 FLARES, AERIAL S1 0421 FLARES, AERIAL S1 0424 PROJECTILES, inert with tracer S1 0425 PROJECTILES, inert with tracer S1 0426 PROJECTILES with burster or expelling charge S1 0427 PROJECTILES with burster or expelling charge S1 0428 ARTICLES, PYROTECHNIC for technical purposes S1 0429 ARTICLES, PYROTECHNIC for technical purposes S1 0430 ARTICLES, PYROTECHNIC for technical purposes Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 0431 ARTICLES, PYROTECHNIC for technical purposes (3a) 1 (3b) 1.4G (4) (5) 1.4 (6) (7a) 0 (7b) E0 (8) P135 0432 ARTICLES, PYROTECHNIC for technical purposes 1 1.4S 1.4 0 E0 P135 MP23 MP24 0433 POWDER CAKE (POWDER PASTE), WETTED with not less than 17% alcohol, by mass 0434 PROJECTILES with burster or expelling charge 1 1.1C 1 0 E0 P111 MP20 1 1.2G 1 0 E0 P130 LP101 PP67 L1 MP23 0435 PROJECTILES with burster or expelling charge 1 1.4G 1.4 0 E0 P130 LP101 PP67 L1 MP23 0436 ROCKETS with expelling charge 1 1.2C 1 0 E0 P130 LP101 PP67 L1 MP22 0437 ROCKETS with expelling charge 1 1.3C 1 0 E0 P130 LP101 PP67 L1 MP22 0438 ROCKETS with expelling charge 1 1.4C 1.4 0 E0 P130 LP101 PP67 L1 MP22 0439 CHARGES, SHAPED, without detonator 1 1.2D 1 0 E0 P137 PP70 MP21 0440 CHARGES, SHAPED, without detonator 1 1.4D 1.4 0 E0 P137 PP70 MP21 0441 CHARGES, SHAPED, without detonator 1 1.4S 1.4 0 E0 P137 PP70 MP23 0442 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 0443 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 0444 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 0445 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 0446 CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER 1 1.1D 1 0 E0 P137 MP21 1 1.2D 1 0 E0 P137 MP21 1 1.4D 1.4 0 E0 P137 MP21 1 1.4S 1.4 0 E0 P137 MP23 1 1.4C 1.4 0 E0 P136 MP22 0447 CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER 1 1.3C 1 0 E0 P136 MP22 0448 5-MERCAPTOTETRAZOL-1ACETIC ACID 1 1.4C 1.4 0 E0 P114(b) MP20 0449 TORPEDOES, LIQUID FUELLED with or without bursting charge 0450 TORPEDOES, LIQUID FUELLED with inert head 1 1.1J 1 0 E0 P101 MP23 1 1.3J 1 0 E0 P101 MP23 0451 TORPEDOES with bursting charge 1 1.1D 1 0 E0 P130 LP101 0452 GRENADES, PRACTICE, hand or rifle 1 1.4G 1.4 0 E0 P141 MP23 0453 ROCKETS, LINETHROWING 1 1.4G 1.4 0 E0 P130 MP23 0454 IGNITERS 1 1.4S 1.4 0 E0 P142 MP23 266 347 347 - 322 - (9a) PP67 L1 (9b) MP23 MP24 MP21 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 2 (E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V2 (17) Loading, unloading and handling 7.5.11 4 (E) 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 1 (B1000C) V2 1 (C5000D) V2 2 (E) V2 1 (B1000C) V2 2 (E) V2 4 (E) 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 4 (E) 2 (E) V2 1 (C5000D) V2 2 (E) V2 1 (B1000C) V2 1 (C) V2 1 (B1000C) V2 2 (E) V2 2 (E) V2 4 (E) - 323 - (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S1 (20) Name and description 3.1.2 (1) (2) 0431 ARTICLES, PYROTECHNIC for technical purposes S1 0432 ARTICLES, PYROTECHNIC for technical purposes S1 0433 POWDER CAKE (POWDER PASTE), WETTED with not less than 17% alcohol, by mass 0434 PROJECTILES with burster or expelling charge S1 S1 0435 PROJECTILES with burster or expelling charge S1 0436 ROCKETS with expelling charge S1 0437 ROCKETS with expelling charge S1 0438 ROCKETS with expelling charge S1 0439 CHARGES, SHAPED, without detonator S1 0440 CHARGES, SHAPED, without detonator S1 0441 CHARGES, SHAPED, without detonator S1 0442 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 0443 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 0444 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 0445 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 0446 CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER S1 S1 S1 S1 S1 0447 CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER S1 0448 5-MERCAPTOTETRAZOL-1ACETIC ACID S1 0449 TORPEDOES, LIQUID FUELLED with or without bursting charge 0450 TORPEDOES, LIQUID FUELLED with inert head S1 S1 0451 TORPEDOES with bursting charge S1 0452 GRENADES, PRACTICE, hand or rifle S1 0453 ROCKETS, LINETHROWING S1 0454 IGNITERS Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 1 (3b) 1.4S (4) (5) 1.4 (6) 347 (7a) 0 (7b) E0 (8) P131 0456 DETONATORS, ELECTRIC for blasting 1 1.4S 1.4 347 0 E0 P131 MP23 0457 CHARGES, BURSTING, PLASTICS BONDED 1 1.1D 1 0 E0 P130 MP21 0458 CHARGES, BURSTING, PLASTICS BONDED 1 1.2D 1 0 E0 P130 MP21 0459 CHARGES, BURSTING, PLASTICS BONDED 1 1.4D 1.4 0 E0 P130 MP21 0460 CHARGES, BURSTING, PLASTICS BONDED 1 1.4S 1.4 347 0 E0 P130 MP23 0461 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1 1.1B 1 178 274 0 E0 P101 MP2 0462 ARTICLES, EXPLOSIVE, N.O.S. 1 1.1C 1 178 274 0 E0 P101 MP2 0463 ARTICLES, EXPLOSIVE, N.O.S. 1 1.1D 1 178 274 0 E0 P101 MP2 0464 ARTICLES, EXPLOSIVE, N.O.S. 1 1.1E 1 178 274 0 E0 P101 MP2 0465 ARTICLES, EXPLOSIVE, N.O.S. 1 1.1F 1 178 274 0 E0 P101 MP2 0466 ARTICLES, EXPLOSIVE, N.O.S. 1 1.2C 1 178 274 0 E0 P101 MP2 0467 ARTICLES, EXPLOSIVE, N.O.S. 1 1.2D 1 178 274 0 E0 P101 MP2 0468 ARTICLES, EXPLOSIVE, N.O.S. 1 1.2E 1 178 274 0 E0 P101 MP2 0469 ARTICLES, EXPLOSIVE, N.O.S. 1 1.2F 1 178 274 0 E0 P101 MP2 0470 ARTICLES, EXPLOSIVE, N.O.S. 1 1.3C 1 178 274 0 E0 P101 MP2 0471 ARTICLES, EXPLOSIVE, N.O.S. 1 1.4E 1.4 178 274 0 E0 P101 MP2 0472 ARTICLES, EXPLOSIVE, N.O.S. 1 1.4F 1.4 178 274 0 E0 P101 MP2 0473 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.1A 1 178 274 0 E0 P101 MP2 0474 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.1C 1 178 274 0 E0 P101 MP2 0475 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.1D 1 178 274 0 E0 P101 MP2 0476 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.1G 1 178 274 0 E0 P101 MP2 0477 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.3C 1 178 274 0 E0 P101 MP2 0478 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.3G 1 178 274 0 E0 P101 MP2 (1) (2) 0455 DETONATORS, NONELECTRIC for blasting - 324 - (9a) PP68 (9b) MP23 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 4 (E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) (17) Loading, unloading and handling 7.5.11 4 (E) 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 4 (E) 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 2 (E) V2 2 (E) V2 0 (B) V2 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (C5000D) V2 V3 1 (C5000D) V2 V3 - 325 - (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S1 (20) Name and description 3.1.2 (1) (2) 0455 DETONATORS, NONELECTRIC for blasting S1 0456 DETONATORS, ELECTRIC for blasting S1 0457 CHARGES, BURSTING, PLASTICS BONDED S1 0458 CHARGES, BURSTING, PLASTICS BONDED S1 0459 CHARGES, BURSTING, PLASTICS BONDED S1 0460 CHARGES, BURSTING, PLASTICS BONDED S1 0461 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. S1 0462 ARTICLES, EXPLOSIVE, N.O.S. S1 0463 ARTICLES, EXPLOSIVE, N.O.S. S1 0464 ARTICLES, EXPLOSIVE, N.O.S. S1 0465 ARTICLES, EXPLOSIVE, N.O.S. S1 0466 ARTICLES, EXPLOSIVE, N.O.S. S1 0467 ARTICLES, EXPLOSIVE, N.O.S. S1 0468 ARTICLES, EXPLOSIVE, N.O.S. S1 0469 ARTICLES, EXPLOSIVE, N.O.S. S1 0470 ARTICLES, EXPLOSIVE, N.O.S. S1 0471 ARTICLES, EXPLOSIVE, N.O.S. S1 0472 ARTICLES, EXPLOSIVE, N.O.S. S1 0473 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0474 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0475 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0476 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0477 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0478 SUBSTANCES, EXPLOSIVE, N.O.S. Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 0479 SUBSTANCES, EXPLOSIVE, N.O.S. (3a) 1 (3b) 1.4C (4) (5) 1.4 (6) 178 274 (7a) 0 (7b) E0 (8) P101 0480 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.4D 1.4 178 274 0 E0 P101 MP2 0481 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.4S 1.4 178 274 0 E0 P101 MP2 0482 SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (SUBSTANCES, EVI), N.O.S. 0483 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE; HEXOGEN; RDX), DESENSITIZED 0484 CYCLOTETRAMETHYLENETETRA-NITRAMINE (HMX; OCTOGEN), DESENSITIZED 0485 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.5D 1.5 178 274 0 E0 P101 MP2 1 1.1D 1 0 E0 P112(b) P112(c) MP20 1 1.1D 1 0 E0 P112(b) P112(c) MP20 1 1.4G 1.4 0 E0 P101 MP2 0486 ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES, EEI) 1 1.6N 1.6 0 E0 P101 MP23 0487 SIGNALS, SMOKE 1 1.3G 1 0 E0 P135 MP23 0488 AMMUNITION, PRACTICE 1 1.3G 1 0 E0 P130 LP101 0489 DINITROGLYCOLURIL (DINGU) 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0490 NITROTRIAZOLONE (NTO) 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0491 CHARGES, PROPELLING 1 1.4C 1.4 0 E0 P143 0492 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1 1.3G 1 0 E0 P135 MP23 0493 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1 1.4G 1.4 0 E0 P135 MP23 0494 JET PERFORATING GUNS, CHARGED, oil well, without detonator 0495 PROPELLANT, LIQUID 1 1.4D 1.4 0 E0 P101 MP21 1 1.3C 1 0 E0 P115 0496 OCTONAL 1 1.1D 1 0 E0 P112(b) P112(c) 0497 PROPELLANT, LIQUID 1 1.1C 1 0 E0 P115 0498 PROPELLANT, SOLID 1 1.1C 1 0 E0 P114(b) MP20 0499 PROPELLANT, SOLID 1 1.3C 1 0 E0 P114(b) MP20 0500 DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting 1 1.4S 1.4 0 E0 P131 MP23 0501 PROPELLANT, SOLID 1 1.4C 1.4 0 E0 P114(b) MP20 178 274 224 224 347 - 326 - (9a) PP67 L1 PP76 PP53 PP54 PP57 PP58 (9b) MP2 MP23 MP22 MP20 MP20 PP53 PP54 PP57 PP58 MP20 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 2 (E) 2 (E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V2 (17) Loading, unloading and handling 7.5.11 V2 4 (E) 1 (B1000C) V2 1 (B1000C) V2 V3 1 (B1000C) V2 V3 2 (E) V2 V3 2 (E) V2 1 (C5000D) V2 1 (C5000D) V2 1 (B1000C) V2 V3 1 (B1000C) V2 V3 2 (E) V2 1 (C5000D) V2 2 (E) V2 2 (E) V2 1 (C5000D) V2 1 (B1000C) V2 V3 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 4 (E) 2 (E) V2 - 327 - Hazard UN identifi- No. Operation cation No. Name and description 8.5 5.3.2.3 3.1.2 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 (19) S1 (20) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 S1 0486 ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES, EEI) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0487 SIGNALS, SMOKE S1 0488 AMMUNITION, PRACTICE S1 0489 DINITROGLYCOLURIL (DINGU) S1 0490 NITROTRIAZOLONE (NTO) S1 0491 CHARGES, PROPELLING S1 0492 SIGNALS, RAILWAY TRACK, EXPLOSIVE S1 0493 SIGNALS, RAILWAY TRACK, EXPLOSIVE S1 S1 0494 JET PERFORATING GUNS, CHARGED, oil well, without detonator 0495 PROPELLANT, LIQUID S1 0496 OCTONAL S1 0497 PROPELLANT, LIQUID S1 0498 PROPELLANT, SOLID S1 0499 PROPELLANT, SOLID S1 0500 DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting S1 0501 PROPELLANT, SOLID (1) (2) 0479 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0480 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0481 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0482 SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (SUBSTANCES, EVI), N.O.S. 0483 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE; HEXOGEN; RDX), DESENSITIZED 0484 CYCLOTETRAMETHYLENETETRA-NITRAMINE (HMX; OCTOGEN), DESENSITIZED 0485 SUBSTANCES, EXPLOSIVE, N.O.S. S1 S1 Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 Portable tanks and bulk containers Instruc- Special tions provisions 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 0502 ROCKETS with inert head (3a) 1 (3b) 1.2C (4) (5) 1 (6) (7a) 0 (7b) E0 (8) P130 LP101 0503 AIR BAG INFLATORS or AIR BAG MODULES or SEAT-BELT 0504 1H-TETRAZOLE 1 1.4G 1.4 235 289 0 E0 P135 1 1.1D 1 0 E0 P112(c) 0505 SIGNALS, DISTRESS, ship 1 1.4G 1.4 0 E0 P135 MP23 MP24 0506 SIGNALS, DISTRESS, ship 1 1.4S 1.4 0 E0 P135 MP23 MP24 0507 SIGNALS, SMOKE 1 1.4S 1.4 0 E0 P135 MP23 MP24 0508 1-HYDROXYBENZOTRIAZOLE, ANHYDROUS, dry or wetted with less than 20% water, by mass 0509 POWDER, SMOKELESS 1 1.3C 1 0 E0 P114(b) PP48 PP50 MP20 1 1.4C 1.4 0 E0 P114(b) MP20 1001 ACETYLENE, DISSOLVED 2 4F 2.1 0 E0 P200 MP9 1002 AIR, COMPRESSED 2 1A 2.2 120 ml E1 P200 MP9 (M) 1003 AIR, REFRIGERATED LIQUID 2 3O 2.2 +5.1 0 E0 P203 MP9 T75 1005 AMMONIA, ANHYDROUS 2 2TC 2.3 +8 0 E0 P200 MP9 (M) T50 1006 ARGON, COMPRESSED 2 1A 2.2 120 ml E1 P200 MP9 (M) 1008 BORON TRIFLUORIDE 2 2TC 2.3 +8 0 E0 P200 MP9 (M) 1009 BROMOTRIFLUOROMETHANE (REFRIGERANT GAS R 13B1) 2 2A 2.2 120 ml E1 P200 MP9 (M) T50 1010 BUTADIENES, STABILIZED or BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED, having a vapour pressure at 70 °C not exceeding 1.1 Mpa (11 bar) and a density at 50 °C not lower than 0.525 kg/l 1011 BUTANE 2 2F 2.1 618 0 E0 P200 MP9 (M) T50 2 2F 2.1 652 0 E0 P200 MP9 (M) T50 1012 BUTYLENES MIXTURE or 1-BUTYLENE or cis-2-BUTYLENE or trans-2-BUTYLENE 1013 CARBON DIOXIDE 2 2F 2.1 0 E0 P200 MP9 (M) T50 2 2A 2.2 120 ml E1 P200 MP9 (M) 1016 CARBON MONOXIDE, COMPRESSED 2 1TF 2.3 +2.1 0 E0 P200 MP9 (M) 1017 CHLORINE 2 2TOC 2.3 +5.1 +8 0 E0 P200 MP9 (M) T50 655 23 584 653 - 328 - (9a) PP67 L1 (9b) MP22 4.2.5.2 7.3.2 (10) 4.2.5.3 (11) MP23 PP48 PP48 MP20 TP5 TP22 TP19 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 1 (B1000C) 2 (E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) (17) Loading, unloading and handling 7.5.11 V2 V2 1 (B1000C) V2 V3 2 (E) V2 4 (E) 4 (E) PxBN(M) CxBN(M) RxBN PxBH(M) TU17 TA4 TT9 TA4 TT9 TU7 TU19 TA4 TT9 TA4 TT8 TT9 1 (C5000D) V2 V3 2 (E) V2 FL 2 (B/D) AT 3 (E) 3 (C/E) AT AT 1 (C/D) V5 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 (19) S1 (20) CV1 CV2 CV3 CV9 CV10 CV36 CV9 CV10 CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 S1 S1 (1) (2) 0502 ROCKETS with inert head S1 S1 0505 SIGNALS, DISTRESS, ship S1 0506 SIGNALS, DISTRESS, ship S1 0507 SIGNALS, SMOKE S1 0508 1-HYDROXYBENZOTRIAZOLE, ANHYDROUS, dry or wetted with less than 20% water, by mass 0509 POWDER, SMOKELESS S2 239 1001 ACETYLENE, DISSOLVED 20 1002 AIR, COMPRESSED S20 225 1003 AIR, REFRIGERATED LIQUID S14 268 1005 AMMONIA, ANHYDROUS 20 1006 ARGON, COMPRESSED 268 1008 BORON TRIFLUORIDE 20 1009 BROMOTRIFLUOROMETHANE (REFRIGERANT GAS R 13B1) 1010 BUTADIENES, STABILIZED or BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED, having a vapour pressure at 70 °C not exceeding 1.1 Mpa (11 bar) and a density at 50 °C not lower than 0.525 kg/l 1011 BUTANE TA4 TT9 AT 3 (E) PxBH(M) TA4 TT9 AT 1 (C/D) PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 FL 2 (B/D) CV9 CV10 CV36 S2 S20 239 PxBN(M) TA4 TT9 FL 2 (B/D) S2 S20 23 PxBN(M) TA4 TT9 FL 2 (B/D) CV9 CV10 CV36 CV9 CV10 CV36 S2 S20 23 PxBN(M) TA4 TT9 AT 3 (C/E) CxBH(M) TA4 TT9 FL 1 (B/D) P22DH(M) TA4 TT9 AT 1 (C/D) - 329 - 3.1.2 0503 AIR BAG INFLATORS or AIR BAG MODULES or SEAT-BELT 0504 1H-TETRAZOLE CxBN(M) CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 Name and description S14 20 1012 BUTYLENES MIXTURE or 1-BUTYLENE or cis-2-BUTYLENE or trans-2-BUTYLENE 1013 CARBON DIOXIDE S2 S14 263 1016 CARBON MONOXIDE, COMPRESSED S14 265 1017 CHLORINE Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 Portable tanks and bulk containers Instruc- Special tions provisions 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1018 CHLORODIFLUOROMETHANE (REFRIGERANT GAS R 22) 1020 CHLOROPENTAFLUOROETHANE (REFRIGERANT GAS R 115) 1021 1-CHLORO-1,2,2,2TETRAFLUOROETHANE (REFRIGERANT GAS R 124) (3a) 2 (3b) 2A (4) (5) 2.2 (6) (7a) 120 ml (7b) E1 (8) P200 2 2A 2.2 120 ml E1 P200 MP9 (M) T50 2 2A 2.2 120 ml E1 P200 MP9 (M) T50 1022 CHLOROTRIFLUOROMETHANE (REFRIGERANT GAS R 13) 1023 COAL GAS, COMPRESSED 2 2A 2.2 120 ml E1 P200 MP9 (M) 2 1TF 2.3 +2.1 0 E0 P200 MP9 (M) 1026 CYANOGEN 2 2TF 2.3 +2.1 0 E0 P200 MP9 (M) 1027 CYCLOPROPANE 2 2F 2.1 0 E0 P200 MP9 (M) T50 1028 DICHLORODIFLUOROMETHANE (REFRIGERANT GAS R 12) 1029 DICHLOROFLUOROMETHANE (REFRIGERANT GAS R 21) 1030 1,1-DIFLUOROETHANE (REFRIGERANT GAS R 152a) 1032 DIMETHYLAMINE, ANHYDROUS 2 2A 2.2 120 ml E1 P200 MP9 (M) T50 2 2A 2.2 120 ml E1 P200 MP9 (M) T50 2 2F 2.1 0 E0 P200 MP9 (M) T50 2 2F 2.1 0 E0 P200 MP9 (M) T50 1033 DIMETHYL ETHER 2 2F 2.1 0 E0 P200 MP9 (M) T50 1035 ETHANE 2 2F 2.1 0 E0 P200 MP9 (M) 1036 ETHYLAMINE 2 2F 2.1 0 E0 P200 MP9 (M) T50 1037 ETHYL CHLORIDE 2 2F 2.1 0 E0 P200 MP9 (M) T50 1038 ETHYLENE, REFRIGERATED LIQUID 2 3F 2.1 0 E0 P203 MP9 T75 1039 ETHYL METHYL ETHER 2 2F 2.1 0 E0 P200 MP9 (M) 1040 ETHYLENE OXIDE 2 2TF 2.3 +2.1 342 0 E0 P200 MP9 (M) 1040 ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1 MPa (10 bar) at 50 °C 1041 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide 1043 FERTILIZER AMMONIATING SOLUTION with free ammonia 1044 FIRE EXTINGUISHERS with compressed or liquefied gas 1045 FLUORINE, COMPRESSED 2 2TF 2.3 +2.1 342 0 E0 P200 MP9 (M) T50 2 2F 2.1 0 E0 P200 MP9 (M) T50 2 4A 2.2 642 2 6A 2.2 225 594 120 ml E0 P003 MP9 2 1TOC 2.3 +5.1 +8 0 E0 P200 MP9 - 330 - (9a) (9b) MP9 4.2.5.2 7.3.2 (10) (M) T50 4.2.5.3 (11) TP5 TP20 Copyright © United Nations, 2010. All rights reserved ADR tank Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 3 (C/E) Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) PxBN(M) (13) TA4 TT9 PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 AT 3 (C/E) CxBH(M) TA4 TT9 FL 1 (B/D) PxBH(M) TA4 TT9 FL 1 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) RxBN TU18 TA4 TT9 TA4 TT9 FL 2 (B/D) FL 2 (B/D) FL 1 (B/D) PxBN(M) PxBH(M) TA4 TT9 FL 1 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) (17) Loading, unloading and handling 7.5.11 (18) CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 V5 CV9 CV10 CV36 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) (20) 20 20 20 20 - 331 - (1) (2) 1018 CHLORODIFLUOROMETHANE (REFRIGERANT GAS R 22) 1020 CHLOROPENTAFLUOROETHANE (REFRIGERANT GAS R 115) 1021 1-CHLORO-1,2,2,2TETRAFLUOROETHANE (REFRIGERANT GAS R 124) S2 S14 263 S2 S14 263 1026 CYANOGEN S2 S20 23 1027 CYCLOPROPANE 20 1028 DICHLORODIFLUOROMETHANE (REFRIGERANT GAS R 12) 1029 DICHLOROFLUOROMETHANE (REFRIGERANT GAS R 21) 1030 1,1-DIFLUOROETHANE (REFRIGERANT GAS R 152a) 1032 DIMETHYLAMINE, ANHYDROUS 20 S2 S20 23 S2 S20 23 S2 S20 23 1033 DIMETHYL ETHER S2 S20 23 1035 ETHANE S2 S20 23 1036 ETHYLAMINE S2 S20 23 1037 ETHYL CHLORIDE S2 S17 223 1038 ETHYLENE, REFRIGERATED LIQUID S2 S20 23 1039 ETHYL METHYL ETHER S2 S14 263 1040 ETHYLENE OXIDE S2 S14 263 S2 S20 239 1040 ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1 MPa (10 bar) at 50 °C 1041 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide 1043 FERTILIZER AMMONIATING SOLUTION with free ammonia 1044 FIRE EXTINGUISHERS with compressed or liquefied gas 1045 FLUORINE, COMPRESSED CV9 CV9 CV10 CV36 3.1.2 1022 CHLOROTRIFLUOROMETHANE (REFRIGERANT GAS R 13) 1023 COAL GAS, COMPRESSED (E) 3 (E) 1 (D) Name and description S14 Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1046 HELIUM, COMPRESSED (3a) 2 (3b) 1A (4) (5) 2.2 (6) (7a) 120 ml (7b) E1 (8) P200 1048 HYDROGEN BROMIDE, ANHYDROUS 2 2TC 2.3 +8 0 E0 1049 HYDROGEN, COMPRESSED 2 1F 2.1 0 1050 HYDROGEN CHLORIDE, ANHYDROUS 2 2TC 2.3 +8 6.1 TF1 I 6.1 +3 8 CT1 I 1053 HYDROGEN SULPHIDE 2 1055 ISOBUTYLENE Portable tanks and bulk containers Instruc- Special tions provisions (9b) MP9 4.2.5.2 7.3.2 (10) (M) P200 MP9 (M) E0 P200 MP9 (M) 0 E0 P200 MP9 (M) 0 E5 P200 MP2 8 +6.1 0 E0 P200 MP2 T10 2TF 2.3 +2.1 0 E0 P200 MP9 (M) 2 2F 2.1 0 E0 P200 MP9 (M) T50 1056 KRYPTON, COMPRESSED 2 1A 2.2 120 ml E1 P200 MP9 (M) 1057 LIGHTERS or LIGHTER REFILLS containing flammable gas 1058 LIQUEFIED GASES, nonflammable, charged with nitrogen, carbon dioxide or air 2 6F 2.1 0 E0 P002 2 2A 2.2 120 ml E1 P200 MP9 (M) 2 2F 2.1 0 E0 P200 MP9 (M) T50 2 2F 2.1 0 E0 P200 MP9 (M) T50 1062 METHYL BROMIDE with not more than 2% chloropicrin 2 2T 2.3 0 E0 P200 MP9 (M) T50 1063 METHYL CHLORIDE (REFRIGERANT GAS R 40) 2 2F 2.1 0 E0 P200 MP9 (M) T50 1064 METHYL MERCAPTAN 2 2TF 2.3 +2.1 0 E0 P200 MP9 (M) T50 1065 NEON, COMPRESSED 2 1A 2.2 120 ml E1 P200 MP9 (M) 1066 NITROGEN, COMPRESSED 2 1A 2.2 120 ml E1 P200 MP9 (M) 1067 DINITROGEN TETROXIDE (NITROGEN DIOXIDE) 2 2TOC 0 E0 P200 MP9 T50 1069 NITROSYL CHLORIDE 2 2TC 2.3 +5.1 +8 2.3 +8 0 E0 P200 MP9 1070 NITROUS OXIDE 2 2O 2.2 +5.1 0 E0 P200 MP9 (M) 1071 OIL GAS, COMPRESSED 2 1TF 2.3 +2.1 0 E0 P200 MP9 (M) 1072 OXYGEN, COMPRESSED 2 1O 2.2 +5.1 0 E0 P200 MP9 (M) 1051 HYDROGEN CYANIDE, STABILIZED containing less than 3% water 1052 HYDROGEN FLUORIDE, ANHYDROUS 1060 METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED such as mixture P1 or mixture P2 1061 METHYLAMINE, ANHYDROUS 603 201 654 581 23 653 584 355 - 332 - (9a) PP84 RR5 4.2.5.3 (11) TP2 MP9 TP21 Copyright © United Nations, 2010. All rights reserved ADR tank Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 3 (E) Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) CxBN(M) (13) TA4 TT9 PxBH(M) TA4 TT9 AT 1 (C/D) CxBN(M) TA4 TT9 FL 2 (B/D) PxBH(M) TA4 TT9 AT 1 (C/D) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) (17) Loading, unloading and handling 7.5.11 0 (D) L21DH(+) TU14 TU34 TC1 TE21 TA4 TT9 TM3 AT 1 (C/D) PxDH(M) TA4 TT9 FL 1 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) CxBN(M) TA4 TT9 AT 3 (E) (18) CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV1 CV13 CV28 CV13 CV28 CV34 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 2 (D) Hazard UN identifi- No. Operation cation No. Name and description 8.5 5.3.2.3 (19) (20) 20 (1) (2) 1046 HELIUM, COMPRESSED S14 268 1048 HYDROGEN BROMIDE, ANHYDROUS S2 S20 23 1049 HYDROGEN, COMPRESSED S14 268 1050 HYDROGEN CHLORIDE, ANHYDROUS S2 S9 S10 S14 3.1.2 1051 HYDROGEN CYANIDE, STABILIZED containing less than 3% water 1052 HYDROGEN FLUORIDE, ANHYDROUS S14 886 S2 S14 263 1053 HYDROGEN SULPHIDE S2 S20 23 1055 ISOBUTYLENE 20 1056 KRYPTON, COMPRESSED S2 1057 LIGHTERS or LIGHTER REFILLS containing flammable gas 1058 LIQUEFIED GASES, nonflammable, charged with nitrogen, carbon dioxide or air PxBN(M) TA4 TT9 AT 3 (C/E) CV9 CV10 CV36 PxBN(M) TA4 TT9 FL 2 (B/D) CV9 CV10 CV36 S2 S20 239 PxBN(M) TA4 TT9 FL 2 (B/D) S2 S20 23 PxBH(M) TA4 TT9 AT 1 (C/D) S14 26 1062 METHYL BROMIDE with not more than 2% chloropicrin PxBN(M) TA4 TT9 FL 2 (B/D) S2 S20 23 1063 METHYL CHLORIDE (REFRIGERANT GAS R 40) PxDH(M) TA4 TT9 FL 1 (B/D) S2 S14 263 1064 METHYL MERCAPTAN CxBN(M) TA4 TT9 AT 3 (E) 20 1065 NEON, COMPRESSED CxBN(M) TA4 TT9 AT 3 (E) 20 1066 NITROGEN, COMPRESSED PxBH(M) TU17 TA4 TT9 AT 1 (C/D) CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 265 1067 DINITROGEN TETROXIDE (NITROGEN DIOXIDE) 1 (D) PxBN(M) TA4 TT9 AT 3 (C/E) CxBH(M) TA4 TT9 FL 1 (B/D) CxBN(M) TA4 TT9 AT 3 (E) - 333 - 20 S14 S14 S2 S14 1060 METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED such as mixture P1 or mixture P2 1061 METHYLAMINE, ANHYDROUS 1069 NITROSYL CHLORIDE 25 1070 NITROUS OXIDE 263 1071 OIL GAS, COMPRESSED 25 1072 OXYGEN, COMPRESSED Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 Portable tanks and bulk containers Instruc- Special tions provisions 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 2 (3b) 3O (4) (5) 2.2 +5.1 (6) (7a) 0 (7b) E0 (8) P203 1075 PETROLEUM GASES, LIQUEFIED 2 2F 2.1 274 583 639 0 E0 P200 MP9 1076 PHOSGENE 2 2TC 2.3 +8 0 E0 P200 MP9 1077 PROPYLENE 2 2F 2.1 0 E0 P200 MP9 (M) T50 1078 REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 1079 SULPHUR DIOXIDE 2 2A 2.2 120 ml E1 P200 MP9 (M) T50 2 2TC 2.3 +8 0 E0 P200 MP9 (M) T50 1080 SULPHUR HEXAFLUORIDE 2 2A 2.2 120 ml E1 P200 MP9 (M) 1081 TETRAFLUOROETHYLENE, STABILIZED 2 2F 2.1 0 E0 P200 MP9 (M) 1082 TRIFLUOROCHLOROETHYLENE, STABILIZED 2 2TF 2.3 +2.1 0 E0 P200 MP9 (M) T50 1083 TRIMETHYLAMINE, ANHYDROUS 2 2F 2.1 0 E0 P200 MP9 (M) T50 1085 VINYL BROMIDE, STABILIZED 2 2F 2.1 0 E0 P200 MP9 (M) T50 1086 VINYL CHLORIDE, STABILIZED 2 2F 2.1 0 E0 P200 MP9 (M) T50 1087 VINYL METHYL ETHER, STABILIZED 2 2F 2.1 0 E0 P200 MP9 (M) T50 1088 ACETAL 3 F1 II 3 1L E2 MP19 T4 TP1 1089 ACETALDEHYDE 3 F1 I 3 0 E3 P001 IBC02 R001 P001 T11 1090 ACETONE 3 F1 II 3 1L E2 TP2 TP7 TP1 1091 ACETONE OILS 3 F1 II 3 1L E2 MP19 T4 TP1 TP8 6.1 TF1 I 6.1 +3 0 E0 P001 IBC02 R001 P001 IBC02 R001 P601 MP7 MP17 MP19 MP8 MP17 T22 TP2 TP7 TP35 3 +6.1 6.1 +3 0 E0 P001 T14 TP2 0 E0 P602 MP7 MP17 MP8 MP17 T20 TP2 TP35 0 E0 P001 MP7 MP17 MP7 MP17 MP19 T14 TP2 T14 TP2 T2 TP1 MP19 T4 TP1 TP29 MP19 T2 TP1 (1) (2) 1073 OXYGEN, REFRIGERATED LIQUID 1092 ACROLEIN, STABILIZED 1093 ACRYLONITRILE, STABILIZED 1098 ALLYL ALCOHOL 3 FT1 I 6.1 TF1 I 1099 ALLYL BROMIDE 3 FT1 I 1100 ALLYL CHLORIDE 3 FT1 I 1104 AMYL ACETATES 3 F1 1105 PENTANOLS 3 1105 PENTANOLS 3 274 582 354 354 0 E0 P001 III 3 +6.1 3 +6.1 3 5L E1 F1 II 3 1L E2 F1 III 3 5L E1 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 - 334 - (9a) (9b) MP9 4.2.5.2 7.3.2 (10) T75 4.2.5.3 (11) TP5 TP22 (M) T50 T4 TP19 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) RxBN (13) TU7 TU19 TA4 TT9 TA4 TT9 PxBN(M) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 3 (C/E) FL 2 (B/D) TU17 TA4 TT9 TA4 TT9 AT 1 (C/D) FL 2 (B/D) PxBN(M) TA4 TT9 AT 3 (C/E) PxDH(M) TA4 TT9 AT 1 (C/D) PxBN(M) TA4 TT9 AT 3 (C/E) FL 2 (B/D) P22DH(M) PxBN(M) S2 S20 23 1075 PETROLEUM GASES, LIQUEFIED S14 268 1076 PHOSGENE S2 S20 23 1077 PROPYLENE 20 268 1078 REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 1079 SULPHUR DIOXIDE 20 1080 SULPHUR HEXAFLUORIDE S14 S2 S20 (1) (2) 1073 OXYGEN, REFRIGERATED LIQUID 1081 TETRAFLUOROETHYLENE, STABILIZED 239 1086 VINYL CHLORIDE, STABILIZED S2 S20 239 1087 VINYL METHYL ETHER, STABILIZED 2 (D/E) S2 S20 33 1088 ACETAL 1 (D/E) 2 (D/E) S2 S20 33 1089 ACETALDEHYDE S2 S20 33 1090 ACETONE S2 S20 33 1091 ACETONE OILS S2 S9 S14 663 1092 ACROLEIN, STABILIZED S2 S22 336 S2 S9 S14 663 1093 ACRYLONITRILE, STABILIZED 1098 ALLYL ALCOHOL S2 S22 336 1099 ALLYL BROMIDE S2 S22 336 1100 ALLYL CHLORIDE S2 30 1104 AMYL ACETATES S2 S20 33 1105 PENTANOLS S2 30 1105 PENTANOLS TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) FL FL LGBF FL LGBF FL 2 (D/E) L15CH TU14 TU15 TE19 TE21 FL 1 (C/D) L10CH TU14 TU15 TE21 TU14 TU15 TE19 TE21 FL 1 (C/E) 1 (C/D) FL (20) 225 S2 S20 PxBN(M) L10CH (19) S20 1085 VINYL BROMIDE, STABILIZED 2 (B/D) FL (18) CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 3.1.2 239 FL TU14 TU15 TE21 TU14 TU15 TE21 (17) 5.3.2.3 S2 S20 TA4 TT9 L10CH (16) V5 8.5 1083 TRIMETHYLAMINE, ANHYDROUS PxBN(M) FL 7.3.3 23 1 (B/D) L10CH 7.2.4 Loading, unloading and handling 7.5.11 S2 S20 FL TU8 Bulk Name and description 239 263 TA4 TT9 L4BN Packages Hazard UN identifi- No. Operation cation No. S2 S14 PxBH(M) LGBF Special provisions for carriage 1 (C/E) 1 (C/E) 3 (D/E) LGBF FL LGBF FL 2 (D/E) LGBF FL 3 (D/E) CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 V12 V12 - 335 - 1082 TRIFLUOROCHLOROETHYLENE, STABILIZED Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 3 (3b) FC (4) II (6) (7a) 1L (7b) E2 1106 AMYLAMINE 3 FC III (5) 3 +8 3 +8 5L E1 1107 AMYL CHLORIDE 3 F1 II 3 1L E2 1108 1-PENTENE (n-AMYLENE) 3 F1 I 3 0 E3 1109 AMYL FORMATES 3 F1 III 3 5L E1 1110 n-AMYL METHYL KETONE 3 F1 III 3 5L E1 1111 AMYL MERCAPTAN 3 F1 II 3 1L E2 1112 AMYL NITRATE 3 F1 III 3 5L E1 1113 AMYL NITRITE 3 F1 II 3 1L E2 1114 BENZENE 3 F1 II 3 1L E2 1120 BUTANOLS 3 F1 II 3 1L E2 1120 BUTANOLS 3 F1 III 3 5L E1 1123 BUTYL ACETATES 3 F1 II 3 1L E2 1123 BUTYL ACETATES 3 F1 III 3 5L E1 1125 n-BUTYLAMINE 3 FC II 1L E2 1126 1-BROMOBUTANE 3 F1 II 3 +8 3 1L E2 1127 CHLOROBUTANES 3 F1 II 3 1L E2 1128 n-BUTYL FORMATE 3 F1 II 3 1L E2 1129 BUTYRALDEHYDE 3 F1 II 3 1L E2 1130 CAMPHOR OIL 3 F1 III 3 5L E1 1131 CARBON DISULPHIDE 3 FT1 I 0 E0 1133 ADHESIVES containing flammable liquid 3 F1 I 3 +6.1 3 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 500 ml E3 P001 1133 ADHESIVES containing flammable liquid (vapour pressure at 50 °C more than 110 kPa) 3 F1 II 3 5L E2 P001 (1) (2) 1106 AMYLAMINE 640C - 336 - (8) P001 IBC02 P001 IBC03 R001 P001 IBC02 R001 P001 (9a) PP31 PP1 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP19 4.2.5.2 7.3.2 (10) T7 MP19 T4 TP1 MP19 T4 TP1 MP7 MP17 MP19 T11 TP2 T2 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 TP29 MP19 T2 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T7 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP7 MP17 MP7 MP17 T14 MP19 T4 TP2 TP7 TP1 TP8 TP27 TP1 TP8 T11 (11) TP1 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L4BH (13) L4BN Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 2 (D/E) FL 3 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) (18) V12 Hazard UN identifi- No. Operation cation No. Name and description 8.5 5.3.2.3 3.1.2 (19) S2 S20 (20) 338 S2 38 1106 AMYLAMINE (1) (2) 1106 AMYLAMINE LGBF FL 2 (D/E) S2 S20 33 1107 AMYL CHLORIDE L4BN FL S2 S20 33 1108 1-PENTENE (n-AMYLENE) LGBF FL 1 (D/E) 3 (D/E) V12 S2 30 1109 AMYL FORMATES LGBF FL 3 (D/E) V12 S2 30 1110 n-AMYL METHYL KETONE LGBF FL 2 (D/E) S2 S20 33 1111 AMYL MERCAPTAN LGBF FL 3 (D/E) S2 30 1112 AMYL NITRATE LGBF FL 2 (D/E) S2 S20 33 1113 AMYL NITRITE LGBF FL 2 (D/E) S2 S20 33 1114 BENZENE LGBF FL 2 (D/E) S2 S20 33 1120 BUTANOLS LGBF FL 3 (D/E) S2 30 1120 BUTANOLS LGBF FL 2 (D/E) S2 S20 33 1123 BUTYL ACETATES LGBF FL 3 (D/E) S2 30 1123 BUTYL ACETATES L4BH FL S2 S20 338 1125 n-BUTYLAMINE LGBF FL 2 (D/E) 2 (D/E) S2 S20 33 1126 1-BROMOBUTANE LGBF FL 2 (D/E) S2 S20 33 1127 CHLOROBUTANES LGBF FL 2 (D/E) S2 S20 33 1128 n-BUTYL FORMATE LGBF FL 2 (D/E) S2 S20 33 1129 BUTYRALDEHYDE LGBF FL 3 (D/E) S2 30 1130 CAMPHOR OIL FL 1 (C/E) 1 (D/E) S2 S22 336 1131 CARBON DISULPHIDE S2 S20 33 1133 ADHESIVES containing flammable liquid S2 S20 33 1133 ADHESIVES containing flammable liquid (vapour pressure at 50 °C more than 110 kPa) L10CH TU14 TU15 TE21 L4BN FL L1.5BN FL V12 V12 V12 V12 CV13 CV28 2 (D/E) - 337 - Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) (3a) 1133 ADHESIVES containing 3 flammable liquid (vapour pressure at 50 °C not more than 110 kPa) 1133 ADHESIVES containing 3 flammable liquid (3b) F1 (4) II (5) 3 (6) 640D (7a) 5L (7b) E2 (8) P001 IBC02 R001 (9a) PP1 F1 III 3 640E 5L E1 3 F1 III 3 640F 5L E1 P001 IBC03 LP01 R001 P001 LP01 R001 3 F1 III 3 640G 5L E1 3 F1 III 3 640H 5L 3 F1 III 3 6.1 TF1 I 6.1 +3 1136 COAL TAR DISTILLATES, FLAMMABLE 3 F1 II 1136 COAL TAR DISTILLATES, FLAMMABLE 3 F1 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (vapour pressure at 50 °C more than 110 kPa) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (vapour pressure at 50 °C not more than 110 kPa) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) 3 1133 ADHESIVES containing flammable liquid (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1133 ADHESIVES containing flammable liquid (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1133 ADHESIVES containing flammable liquid (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1134 CHLOROBENZENE 1135 ETHYLENE CHLOROHYDRIN Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP19 4.2.5.2 7.3.2 (10) T4 PP1 MP19 T2 TP1 PP1 MP19 T2 TP1 P001 LP01 R001 PP1 MP19 T2 TP1 E1 P001 IBC02 LP01 R001 PP1 MP19 T2 TP1 5L E1 MP19 T2 TP1 0 E0 P001 IBC03 LP01 R001 P602 MP8 MP17 T20 TP2 TP37 3 1L E2 MP19 T4 TP1 III 3 5L E1 MP19 T4 TP1 TP29 F1 I 3 500 ml E3 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 MP7 MP17 T11 TP1 TP8 TP27 3 F1 II 3 640C 5L E2 P001 MP19 T4 TP1 TP8 3 F1 II 3 640D 5L E2 P001 IBC02 R001 MP19 T4 TP1 TP8 3 F1 III 3 640E 5L E1 P001 IBC03 LP01 R001 MP19 T2 TP1 354 - 338 - (11) TP1 TP8 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) LGBF (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 2 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) (18) 8.5 5.3.2.3 (19) S2 S20 (20) 33 S2 30 Name and description 3.1.2 (1) (2) 1133 ADHESIVES containing flammable liquid (vapour pressure at 50 °C not more than 110 kPa) 1133 ADHESIVES containing flammable liquid LGBF FL 3 (D/E) L4BN FL 3 (D/E) S2 33 L1.5BN FL 3 (D/E) S2 33 LGBF FL 3 (D/E) S2 33 LGBF FL 3 (D/E) S2 30 FL 1 (C/D) S2 S9 S14 663 1135 ETHYLENE CHLOROHYDRIN LGBF FL 2 (D/E) S2 S20 33 1136 COAL TAR DISTILLATES, FLAMMABLE LGBF FL 3 (D/E) S2 30 1136 COAL TAR DISTILLATES, FLAMMABLE L4BN FL 1 (D/E) S2 S20 33 L1.5BN FL 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (vapour pressure at 50 °C more than 110 kPa) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (vapour pressure at 50 °C not more than 110 kPa) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) L10CH TU14 TU15 TE19 TE21 V12 Hazard UN identifi- No. Operation cation No. V12 CV1 CV13 CV28 V12 V12 - 339 - 1133 ADHESIVES containing flammable liquid (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1133 ADHESIVES containing flammable liquid (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1133 ADHESIVES containing flammable liquid (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1134 CHLOROBENZENE Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) (3a) 1139 COATING SOLUTION 3 (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 3 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 3 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1143 CROTONALDEHYDE or 6.1 CROTONALDEHYDE, STABILIZED 1144 CROTONYLENE 3 (3b) F1 (4) III (5) 3 (6) 640F (7a) 5L (7b) E1 (8) P001 LP01 R001 F1 III 3 640G 5L E1 F1 III 3 640H 5L TF1 I 6.1 +3 324 354 F1 I Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP19 4.2.5.2 7.3.2 (10) T2 P001 LP01 R001 MP19 T2 TP1 E1 P001 IBC02 LP01 R001 MP19 T2 TP1 0 E0 P602 MP8 MP17 T20 TP2 TP35 3 0 E3 P001 T11 TP2 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 MP7 MP17 MP19 T4 TP1 MP19 T7 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T2 TP1 MP19 T7 TP2 MP19 T2 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T7 TP1 1145 CYCLOHEXANE 3 F1 II 3 1L E2 1146 CYCLOPENTANE 3 F1 II 3 1L E2 1147 DECAHYDRONAPHTHALENE 3 F1 III 3 5L E1 1148 DIACETONE ALCOHOL 3 F1 II 3 1L E2 1148 DIACETONE ALCOHOL 3 F1 III 3 5L E1 1149 DIBUTYL ETHERS 3 F1 III 3 5L E1 1150 1,2-DICHLOROETHYLENE 3 F1 II 3 1L E2 1152 DICHLOROPENTANES 3 F1 III 3 5L E1 1153 ETHYLENE GLYCOL DIETHYL ETHER 3 F1 II 3 1L E2 1153 ETHYLENE GLYCOL DIETHYL ETHER 3 F1 III 3 5L E1 1154 DIETHYLAMINE 3 FC II 3 +8 1L E2 - 340 - (9a) (11) TP1 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L4BN (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 3 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) (18) Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S2 (20) 33 Name and description 3.1.2 L1.5BN FL 3 (D/E) S2 33 LGBF FL 3 (D/E) S2 33 FL 1 (C/D) S2 S9 S14 663 L4BN FL S2 S20 339 LGBF FL 1 (D/E) 2 (D/E) (1) (2) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1143 CROTONALDEHYDE or CROTONALDEHYDE, STABILIZED 1144 CROTONYLENE S2 S20 33 1145 CYCLOHEXANE LGBF FL 2 (D/E) S2 S20 33 1146 CYCLOPENTANE LGBF FL 3 (D/E) S2 30 1147 DECAHYDRONAPHTHALENE LGBF FL 2 (D/E) S2 S20 33 1148 DIACETONE ALCOHOL LGBF FL 3 (D/E) V12 S2 30 1148 DIACETONE ALCOHOL LGBF FL 3 (D/E) V12 S2 30 1149 DIBUTYL ETHERS LGBF FL 2 (D/E) S2 S20 33 1150 1,2-DICHLOROETHYLENE LGBF FL 3 (D/E) S2 30 1152 DICHLOROPENTANES LGBF FL 2 (D/E) S2 S20 33 1153 ETHYLENE GLYCOL DIETHYL ETHER LGBF FL 3 (D/E) S2 30 1153 ETHYLENE GLYCOL DIETHYL ETHER L4BH FL 2 (D/E) S2 S20 338 1154 DIETHYLAMINE L10CH TU14 TU15 TE19 TE21 CV1 CV13 CV28 V12 V12 V12 - 341 - Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 3 (3b) F1 (4) I (5) 3 (6) (7a) 0 (7b) E3 (8) P001 3 F1 II 3 1L E2 1157 DIISOBUTYL KETONE 3 F1 III 3 5L E1 1158 DIISOPROPYLAMINE 3 FC II 1L E2 1159 DIISOPROPYL ETHER 3 F1 II 3 +8 3 1L E2 1160 DIMETHYLAMINE AQUEOUS SOLUTION 1161 DIMETHYL CARBONATE 3 FC II 1L E2 3 F1 II 1L E2 3 FC II 0 E2 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 R001 P001 IBC02 P001 IBC02 R001 P010 6.1 TFC I 0 E0 P602 3 F1 II 1L E2 (1) (2) 1155 DIETHYL ETHER (ETHYL ETHER) 1156 DIETHYL KETONE 1162 DIMETHYLDICHLOROSILANE 1163 DIMETHYLHYDRAZINE, UNSYMMETRICAL 1164 DIMETHYL SULPHIDE 3 +8 3 3 +8 6.1 +3 +8 3 354 (9a) Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) T11 4.2.5.3 T4 TP1 MP19 T2 TP1 MP19 T7 TP1 MP19 T4 TP1 MP19 T7 TP1 MP19 T4 TP1 MP19 T10 MP8 MP17 T20 TP2 TP7 TP2 TP35 MP19 T7 TP2 MP19 T4 TP1 MP19 T4 TP1 MP7 MP17 MP7 MP17 MP19 T11 TP2 T4 TP1 TP8 (9b) MP7 MP17 MP19 (11) TP2 1165 DIOXANE 3 F1 II 3 1L E2 1166 DIOXOLANE 3 F1 II 3 1L E2 1167 DIVINYL ETHER, STABILIZED 1169 EXTRACTS, AROMATIC, LIQUID 1169 EXTRACTS, AROMATIC, LIQUID (vapour pressure at 50 °C more than 110 kPa) 1169 EXTRACTS, AROMATIC, LIQUID (vapour pressure at 50 °C not more than 110 kPa) 3 F1 I 3 0 E3 P001 IBC02 P001 IBC02 R001 P001 IBC02 R001 P001 3 F1 I 3 0 E3 P001 3 F1 II 3 601 640C 5L E2 P001 3 F1 II 3 601 640D 5L E2 P001 IBC02 R001 MP19 T4 TP1 TP8 1169 EXTRACTS, AROMATIC, LIQUID 3 F1 III 3 601 640E 5L E1 MP19 T2 TP1 1169 EXTRACTS, AROMATIC, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1169 EXTRACTS, AROMATIC, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1169 EXTRACTS, AROMATIC, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1170 ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) 1170 ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) 3 F1 III 3 601 640F 5L E1 P001 IBC03 LP01 R001 P001 LP01 R001 MP19 T2 TP1 3 F1 III 3 601 640G 5L E1 P001 LP01 R001 MP19 T2 TP1 3 F1 III 3 601 640H 5L E1 P001 IBC02 LP01 R001 MP19 T2 TP1 3 F1 II 3 144 601 1L E2 P001 IBC02 R001 MP19 T4 TP1 3 F1 III 3 144 601 5L E1 P001 IBC03 LP01 R001 MP19 T2 TP1 - 342 - B8 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L4BN (13) LGBF Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 1 (D/E) FL 2 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) (18) Name and description 8.5 5.3.2.3 3.1.2 (19) S2 S20 (20) 33 S2 S20 33 (1) (2) 1155 DIETHYL ETHER (ETHYL ETHER) 1156 DIETHYL KETONE S2 30 1157 DIISOBUTYL KETONE LGBF FL 3 (D/E) L4BH FL S2 S20 338 1158 DIISOPROPYLAMINE LGBF FL 2 (D/E) 2 (D/E) S2 S20 33 1159 DIISOPROPYL ETHER L4BH FL S2 S20 338 LGBF FL 2 (D/E) 2 (D/E) S2 S20 33 1160 DIMETHYLAMINE AQUEOUS SOLUTION 1161 DIMETHYL CARBONATE L4BH FL 2 (D/E) 1 (C/D) S2 S20 X338 S2 S9 S14 663 2 (D/E) 2 (D/E) S2 S20 33 1164 DIMETHYL SULPHIDE S2 S20 33 1165 DIOXANE L10CH TU14 TU15 TE19 TE21 FL V12 Hazard UN identifi- No. Operation cation No. CV1 CV13 CV28 1162 DIMETHYLDICHLOROSILANE 1163 DIMETHYLHYDRAZINE, UNSYMMETRICAL L1.5BN FL LGBF FL LGBF FL 2 (D/E) S2 S20 33 1166 DIOXOLANE L4BN FL S2 S20 339 L4BN FL S2 S20 33 L1.5BN FL 1 (D/E) 1 (D/E) 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 1167 DIVINYL ETHER, STABILIZED 1169 EXTRACTS, AROMATIC, LIQUID 1169 EXTRACTS, AROMATIC, LIQUID (vapour pressure at 50 °C more than 110 kPa) 1169 EXTRACTS, AROMATIC, LIQUID (vapour pressure at 50 °C not more than 110 kPa) LGBF FL 3 (D/E) S2 30 1169 EXTRACTS, AROMATIC, LIQUID L4BN FL 3 (D/E) S2 33 L1.5BN FL 3 (D/E) S2 33 LGBF FL 3 (D/E) S2 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 1169 EXTRACTS, AROMATIC, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1169 EXTRACTS, AROMATIC, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1169 EXTRACTS, AROMATIC, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1170 ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) 1170 ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) V12 V12 - 343 - Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1171 ETHYLENE GLYCOL MONOETHYL ETHER (3a) 3 (3b) F1 (4) III (5) 3 (6) (7a) 5L (7b) E1 1172 ETHYLENE GLYCOL MONOETHYL ETHER ACETATE 3 F1 III 3 5L E1 1173 ETHYL ACETATE 3 F1 II 3 1L E2 1175 ETHYLBENZENE 3 F1 II 3 1L E2 1176 ETHYL BORATE 3 F1 II 3 1L E2 1177 2-ETHYLBUTYL ACETATE 3 F1 III 3 5L E1 1178 2ETHYLBUTYRALDEHYDE 3 F1 II 3 1L E2 1179 ETHYL BUTYL ETHER 3 F1 II 3 1L E2 1180 ETHYL BUTYRATE 3 F1 III 3 5L E1 1181 ETHYL CHLOROACETATE 6.1 TF1 II 100 ml E4 1182 ETHYL CHLOROFORMATE 6.1 TFC I 0 1183 ETHYLDICHLOROSILANE 4.3 WFC I 1184 ETHYLENE DICHLORIDE 3 FT1 II 6.1 TF1 I 6.1 +3 6.1 +3 +8 4.3 +3 +8 3 +6.1 6.1 +3 1188 ETHYLENE GLYCOL MONOMETHYL ETHER 3 F1 III 1189 ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE 3 F1 1190 ETHYL FORMATE 3 1191 OCTYL ALDEHYDES Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP19 4.2.5.2 7.3.2 (10) T2 MP19 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP15 T7 TP2 MP8 MP17 T20 TP2 TP37 MP2 T14 TP2 TP7 (9a) E0 (8) P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 P602 0 E0 P401 RR7 1L E2 MP19 T7 TP1 0 E0 P001 IBC02 P601 MP2 T22 TP2 3 5L E1 MP19 T2 TP1 III 3 5L E1 MP19 T2 TP1 F1 II 3 1L E2 MP19 T4 TP1 3 F1 III 3 5L E1 MP19 T2 TP1 1192 ETHYL LACTATE 3 F1 III 3 5L E1 MP19 T2 TP1 1193 ETHYL METHYL KETONE (METHYL ETHYL KETONE) 3 F1 II 3 1L E2 MP19 T4 TP1 1194 ETHYL NITRITE SOLUTION 3 FT1 I 0 E0 1195 ETHYL PROPIONATE 3 F1 II 3 +6.1 3 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 1L E2 MP7 MP17 MP19 T4 TP1 1196 ETHYLTRICHLOROSILANE 3 FC II 0 E2 MP19 T10 TP2 TP7 1185 ETHYLENEIMINE, STABILIZED 354 354 3 +8 - 344 - P001 IBC02 R001 P010 (11) TP1 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) LGBF (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 3 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) V12 (17) (18) Name and description 8.5 5.3.2.3 3.1.2 (19) S2 (20) 30 (1) (2) 1171 ETHYLENE GLYCOL MONOETHYL ETHER S2 30 1172 ETHYLENE GLYCOL MONOETHYL ETHER ACETATE LGBF FL 3 (D/E) LGBF FL 2 (D/E) S2 S20 33 1173 ETHYL ACETATE LGBF FL 2 (D/E) S2 S20 33 1175 ETHYLBENZENE LGBF FL 2 (D/E) S2 S20 33 1176 ETHYL BORATE LGBF FL 3 (D/E) S2 30 1177 2-ETHYLBUTYL ACETATE LGBF FL 2 (D/E) S2 S20 33 1178 2ETHYLBUTYRALDEHYDE LGBF FL 2 (D/E) S2 S20 33 1179 ETHYL BUTYL ETHER LGBF FL 3 (D/E) S2 30 1180 ETHYL BUTYRATE 2 (D/E) 1 (C/D) S2 S9 S19 63 1181 ETHYL CHLOROACETATE S2 S9 S14 663 1182 ETHYL CHLOROFORMATE S2 S20 X338 1183 ETHYLDICHLOROSILANE S2 S19 336 1184 ETHYLENE DICHLORIDE S2 S9 S14 663 1185 ETHYLENEIMINE, STABILIZED L4BH TU15 TE19 FL L10CH TU14 TU15 TE19 TE21 FL L10DH TU14 TU23 TE21 TM2 TM3 TU15 FL 0 (B/E) FL TU14 TU15 TE19 TE21 FL 2 (D/E) 1 (C/D) L4BH L15CH V12 Hazard UN identifi- No. Operation cation No. V12 V12 CV13 CV28 CV1 CV13 CV28 CV23 V1 CV13 CV28 CV1 CV13 CV28 LGBF FL 3 (D/E) V12 S2 30 1188 ETHYLENE GLYCOL MONOMETHYL ETHER LGBF FL 3 (D/E) V12 S2 30 1189 ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE LGBF FL 2 (D/E) S2 S20 33 1190 ETHYL FORMATE LGBF FL 3 (D/E) V12 S2 30 1191 OCTYL ALDEHYDES LGBF FL 3 (D/E) V12 S2 30 1192 ETHYL LACTATE LGBF FL 2 (D/E) S2 S20 33 1193 ETHYL METHYL KETONE (METHYL ETHYL KETONE) FL 1 (C/E) 2 (D/E) S2 S22 336 1194 ETHYL NITRITE SOLUTION S2 S20 33 1195 ETHYL PROPIONATE S2 S20 X338 L10CH TU14 TU15 TE21 LGBF FL L4BH FL CV13 CV28 2 (D/E) - 345 - 1196 ETHYLTRICHLOROSILANE Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1197 EXTRACTS, FLAVOURING, LIQUID 1197 EXTRACTS, FLAVOURING, LIQUID (vapour pressure at 50 °C more than 110 kPa) 1197 EXTRACTS, FLAVOURING, LIQUID (vapour pressure at 50 °C not more than 110 kPa) 1197 EXTRACTS, FLAVOURING, LIQUID (3a) 3 (3b) F1 (4) I (5) 3 (6) (7a) 0 (7b) E3 (8) P001 3 F1 II 3 601 640C 5L E2 P001 3 F1 II 3 601 640D 5L E2 3 F1 III 3 601 640E 5L E1 1197 EXTRACTS, FLAVOURING, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1197 EXTRACTS, FLAVOURING, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1197 EXTRACTS, FLAVOURING, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1198 FORMALDEHYDE SOLUTION, FLAMMABLE 3 F1 III 3 601 640F 5L E1 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 LP01 R001 3 F1 III 3 601 640G 5L E1 3 F1 III 3 601 640H 5L 3 FC III 3 +8 6.1 TF1 II 1201 FUSEL OIL 3 F1 1201 FUSEL OIL 3 1202 GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flashpoint not more than 60 °C) 1202 DIESEL FUEL complying with standard EN 590:2004 or GAS OIL or HEATING OIL, LIGHT with a flash-point as specified in EN 590:2004 1202 GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flashpoint more than 60 °C and not more than 100 °C) 1203 MOTOR SPIRIT or GASOLINE or PETROL 1199 FURALDEHYDES Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 T4 TP1 TP8 MP19 T4 TP1 TP8 MP19 T2 TP1 MP19 T2 TP1 P001 LP01 R001 MP19 T2 TP1 E1 P001 IBC02 LP01 R001 MP19 T2 TP1 5L E1 MP19 T4 TP1 100 ml E4 MP15 T7 TP2 II 6.1 +3 3 1L E2 MP19 T4 TP1 F1 III 3 5L E1 MP19 T2 TP1 3 F1 III 3 640K 5L E1 MP19 T2 TP1 3 F1 III 3 640L 5L E1 P001 IBC03 R001 P001 IBC02 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 MP19 T2 TP1 3 F1 III 3 640M 5L E1 MP19 T2 TP1 3 F1 II 3 243 534 1L E2 MP19 T4 TP1 601 1L E0 MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 1204 NITROGLYCERIN SOLUTION IN ALCOHOL with not more than 1% nitroglycerin 1206 HEPTANES 3 D II 3 3 F1 II 3 1L E2 1207 HEXALDEHYDE 3 F1 III 3 5L E1 1208 HEXANES 3 F1 II 3 1L E2 - 346 - P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 (9a) (9b) MP7 MP17 MP19 (11) BB2 PP5 MP2 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L4BN (13) L1.5BN Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 1 (D/E) FL 2 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) (18) Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S2 S20 (20) 33 S2 S20 33 S2 S20 33 S2 30 Name and description 3.1.2 (1) (2) 1197 EXTRACTS, FLAVOURING, LIQUID 1197 EXTRACTS, FLAVOURING, LIQUID (vapour pressure at 50 °C more than 110 kPa) 1197 EXTRACTS, FLAVOURING, LIQUID (vapour pressure at 50 °C not more than 110 kPa) 1197 EXTRACTS, FLAVOURING, LIQUID LGBF FL 2 (D/E) LGBF FL 3 (D/E) L4BN FL 3 (D/E) S2 33 L1.5BN FL 3 (D/E) S2 33 LGBF FL 3 (D/E) S2 33 L4BN FL 3 (D/E) S2 38 FL 2 (D/E) 2 (D/E) S2 S9 S19 63 1199 FURALDEHYDES S2 S20 33 1201 FUSEL OIL L4BH TU15 TE19 V12 V12 CV13 CV28 1197 EXTRACTS, FLAVOURING, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1197 EXTRACTS, FLAVOURING, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1197 EXTRACTS, FLAVOURING, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1198 FORMALDEHYDE SOLUTION, FLAMMABLE LGBF FL LGBF FL 3 (D/E) V12 S2 30 1201 FUSEL OIL LGBF FL 3 (D/E) V12 S2 30 1202 GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flashpoint not more than 60 °C) LGBF AT 3 (D/E) V12 S2 30 LGBV AT 3 (D/E) V12 FL 2 (D/E) S2 S20 1202 DIESEL FUEL complying with standard EN 590:2004 or GAS OIL or HEATING OIL, LIGHT with a flash-point as specified in EN 590:2004 1202 GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flashpoint more than 60 °C and not more than 100 °C) 1203 MOTOR SPIRIT or GASOLINE or PETROL 2 (B) S2 S14 S2 S20 33 1204 NITROGLYCERIN SOLUTION IN ALCOHOL with not more than 1% nitroglycerin 1206 HEPTANES S2 30 1207 HEXALDEHYDE S2 S20 33 1208 HEXANES LGBF TU9 LGBF FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) 30 V12 - 347 - 33 Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) (3a) 1210 PRINTING INK, flammable or 3 PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 3 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (vapour pressure at 50 °C more than 110 kPa) 1210 PRINTING INK, flammable or 3 PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (vapour pressure at 50 °C not more than 110 kPa) 1210 PRINTING INK, flammable or 3 PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 3 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1210 PRINTING INK, flammable or 3 PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 3 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1212 ISOBUTANOL (ISOBUTYL 3 ALCOHOL) (3b) F1 (4) I (5) 3 (6) 163 (7a) 500 ml (7b) E3 (8) P001 (9a) (9b) MP7 MP17 F1 II 3 163 640C 5L E2 P001 PP1 F1 II 3 163 640D 5L E2 P001 IBC02 R001 F1 III 3 163 640E 5L E1 F1 III 3 163 640F 5L F1 III 3 163 640G F1 III 3 163 640H F1 III Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) T11 4.2.5.3 MP19 T4 TP1 TP8 PP1 MP19 T4 TP1 TP8 P001 IBC03 LP01 R001 PP1 MP19 T2 TP1 E1 P001 LP01 R001 PP1 MP19 T2 TP1 5L E1 P001 LP01 R001 PP1 MP19 T2 TP1 5L E1 P001 IBC02 LP01 R001 PP1 MP19 T2 TP1 3 5L E1 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 P001 IBC02 R001 P001 MP19 T2 TP1 MP19 T4 TP1 MP19 T7 TP1 MP19 T4 TP1 MP7 MP17 T11 TP2 1213 ISOBUTYL ACETATE 3 F1 II 3 1L E2 1214 ISOBUTYLAMINE 3 FC II 1L E2 1216 ISOOCTENES 3 F1 II 3 +8 3 1L E2 1218 ISOPRENE, STABILIZED 3 F1 I 3 0 E3 - 348 - (11) TP1 TP8 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L4BN (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 1 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) (18) Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S2 S20 (20) 33 Name and description 3.1.2 (1) (2) 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (vapour pressure at 50 °C more than 110 kPa) 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (vapour pressure at 50 °C not more than 110 kPa) 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1212 ISOBUTANOL (ISOBUTYL ALCOHOL) L1.5BN FL 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 L4BN FL 3 (D/E) S2 33 L1.5BN FL 3 (D/E) S2 33 LGBF FL 3 (D/E) S2 33 LGBF FL 3 (D/E) S2 30 LGBF FL 2 (D/E) S2 S20 33 1213 ISOBUTYL ACETATE L4BH FL S2 S20 338 1214 ISOBUTYLAMINE LGBF FL 2 (D/E) 2 (D/E) S2 S20 33 1216 ISOOCTENES L4BN FL 1 (D/E) S2 S20 339 1218 ISOPRENE, STABILIZED V12 V12 - 349 - Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 3 (3b) F1 (4) II (5) 3 (6) 601 (7a) 1L (7b) E2 1220 ISOPROPYL ACETATE 3 F1 II 3 1L E2 1221 ISOPROPYLAMINE 3 FC I 0 E0 1222 ISOPROPYL NITRATE 3 F1 II 3 +8 3 1L E2 (1) (2) 1219 ISOPROPANOL (ISOPROPYL ALCOHOL) 1223 KEROSENE 3 F1 III 3 1224 KETONES, LIQUID, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 1224 KETONES, LIQUID, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1224 KETONES, LIQUID, N.O.S. 3 F1 II 3 3 F1 II 3 F1 1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 1229 MESITYL OXIDE 3 Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP19 4.2.5.2 7.3.2 (10) T4 MP19 T4 TP1 MP7 MP17 MP19 T11 TP2 MP19 T2 TP2 MP19 T7 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 MP19 T7 MP19 T4 TP1 TP8 TP28 TP1 TP8 TP28 TP1 TP29 MP19 T11 TP2 TP27 (8) P001 IBC02 R001 P001 IBC02 R001 P001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 (9a) (11) TP1 B7 5L E1 274 640C 1L E2 3 274 640D 1L E2 III 3 274 5L E1 FT1 II 3 +6.1 274 1L E2 3 FT1 III 3 +6.1 274 5L E1 P001 IBC03 R001 MP19 T7 TP1 TP28 3 F1 III 3 5L E1 MP19 T2 TP1 1230 METHANOL 3 FT1 II 1L E2 MP19 T7 TP2 1231 METHYL ACETATE 3 F1 II 3 +6.1 3 1L E2 MP19 T4 TP1 1233 METHYLAMYL ACETATE 3 F1 III 3 5L E1 MP19 T2 TP1 1234 METHYLAL 3 F1 II 3 1L E2 MP19 T7 TP2 MP19 T7 TP1 MP19 T4 TP1 MP8 MP17 T22 TP2 TP35 MP8 MP17 T22 TP2 TP35 MP2 T14 TP2 TP7 MP7 MP17 MP8 MP17 T11 TP2 T22 TP2 TP35 1235 METHYLAMINE, AQUEOUS SOLUTION 1237 METHYL BUTYRATE 3 FC II 3 F1 II 1238 METHYL CHLOROFORMATE 6.1 TFC I 1239 METHYL CHLOROMETHYL ETHER 6.1 TF1 I 1242 METHYLDICHLOROSILAN E 4.3 WFC I 3 F1 I 6.1 TFC I 1243 METHYL FORMATE 1244 METHYLHYDRAZINE 1L E2 1L E2 354 0 E0 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 P001 IBC02 R001 P602 354 0 E0 P602 0 E0 P401 0 E3 P001 0 E0 P602 279 3 +8 3 6.1 +3 +8 6.1 +3 4.3 +3 +8 3 6.1 +3 +8 354 - 350 - B8 RR7 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) LGBF (13) LGBF L10CH TU14 TE21 Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 2 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) (18) FL 1 (C/E) 2 (E) S2 S20 338 1221 ISOPROPYLAMINE LGBF LGBF S2 S20 V12 1222 ISOPROPYL NITRATE S2 30 1223 KEROSENE 2 (D/E) S2 S20 33 FL 2 (D/E) S2 S20 33 FL 3 (D/E) S2 30 1224 KETONES, LIQUID, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 1224 KETONES, LIQUID, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1224 KETONES, LIQUID, N.O.S. CV13 CV28 S2 S19 336 CV13 CV28 S2 36 S2 30 1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 1229 MESITYL OXIDE S2 S19 336 1230 METHANOL S2 S20 33 1231 METHYL ACETATE S2 30 1233 METHYLAMYL ACETATE S2 S20 33 1234 METHYLAL S2 S20 338 S2 S20 33 1235 METHYLAMINE, AQUEOUS SOLUTION 1237 METHYL BUTYRATE S2 S9 S14 663 1238 METHYL CHLOROFORMATE S2 S9 S14 663 1239 METHYL CHLOROMETHYL ETHER S2 S20 X338 S2 S20 33 1243 METHYL FORMATE S2 S9 S14 663 1244 METHYLHYDRAZINE V12 L4BH TU15 FL 2 (D/E) L4BH TU15 FL 3 (D/E) V12 FL 3 (D/E) V12 FL 2 (D/E) 2 (D/E) LGBF FL LGBF FL 3 (D/E) L1.5BN FL L4BH FL LGBF FL 2 (D/E) 2 (D/E) 2 (D/E) L15CH TU14 TU15 TE19 TE21 FL 1 (C/D) L15CH TU14 TU15 TE19 TE21 FL 1 (C/D) L10DH TU14 TU24 TE21 TM2 TM3 FL 0 (B/E) FL 1 (D/E) 1 (C/D) TU14 TU15 TE19 TE21 (1) (2) 1219 ISOPROPANOL (ISOPROPYL ALCOHOL) 1220 ISOPROPYL ACETATE FL L15CH (20) 33 33 L1.5BN L4BN (19) S2 S20 3.1.2 S2 S20 3 (D/E) TU15 5.3.2.3 2 (D/E) FL L4BH 8.5 Name and description FL LGBF LGBF Hazard UN identifi- No. Operation cation No. FL CV13 CV28 V12 CV1 CV13 CV28 CV1 CV13 CV28 CV23 V1 CV1 CV13 CV28 - 351 - 1242 METHYLDICHLOROSILAN E Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 3 (3b) F1 (4) II (5) 3 (6) (7a) 1L (7b) E2 1246 METHYL ISOPROPENYL KETONE, STABILIZED 3 F1 II 3 1L E2 1247 METHYL METHACRYLATE MONOMER, STABILIZED 3 F1 II 3 1L E2 1248 METHYL PROPIONATE 3 F1 II 3 1L E2 1249 METHYL PROPYL KETONE 3 F1 II 3 1L E2 1250 METHYLTRICHLOROSILANE 1251 METHYL VINYL KETONE, STABILIZED 3 FC II 0 6.1 TFC I 6.1 TF1 I 3 +8 6.1 +3 +8 6.1 +3 1261 NITROMETHANE 3 F1 II 1262 OCTANES 3 F1 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (vapour pressure at 50 °C more than 110 kPa) 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (vapour pressure at 50 °C not more than 110 kPa) 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 3 (1) (2) 1245 METHYL ISOBUTYL KETONE 1259 NICKEL CARBONYL Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 (9a) E2 (8) P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 P010 0 E0 P601 RR7 0 E5 P601 3 1L E2 RR2 II 3 1L E2 F1 I 3 163 650 500 ml E3 P001 R001 P001 IBC02 R001 P001 3 F1 II 3 163 640C 650 5L E2 P001 3 F1 II 3 163 640D 650 5L E2 3 F1 III 3 163 640E 650 5L 3 F1 III 3 163 640F 650 5L 354 - 352 - Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP19 4.2.5.2 7.3.2 (10) T4 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T10 MP8 MP17 T22 TP2 TP7 TP2 TP37 (11) TP1 MP2 MP19 MP19 T4 TP1 MP7 MP17 T11 TP1 TP8 TP27 PP1 MP19 T4 TP1 TP8 TP28 P001 IBC02 R001 PP1 MP19 T4 TP1 TP8 TP28 E1 P001 IBC03 LP01 R001 PP1 MP19 T2 TP1 TP29 E1 P001 LP01 R001 PP1 MP19 T2 TP1 TP29 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) LGBF (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 2 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) (18) Hazard UN identifi- No. Operation cation No. Name and description 8.5 5.3.2.3 3.1.2 (19) S2 S20 (20) 33 (1) (2) 1245 METHYL ISOBUTYL KETONE LGBF FL 2 (D/E) S2 S20 339 1246 METHYL ISOPROPENYL KETONE, STABILIZED LGBF FL 2 (D/E) S2 S20 339 1247 METHYL METHACRYLATE MONOMER, STABILIZED LGBF FL 2 (D/E) S2 S20 33 1248 METHYL PROPIONATE LGBF FL 2 (D/E) S2 S20 33 1249 METHYL PROPYL KETONE L4BH FL 2 (D/E) 1 (C/D) S2 S20 X338 S2 S9 S14 639 1250 METHYLTRICHLOROSILANE 1251 METHYL VINYL KETONE, STABILIZED S2 S9 S14 663 L15CH TU14 TU15 TE19 TE21 FL L15CH TU14 TU15 TU31 TE19 TE21 TM3 FL CV1 CV13 CV28 CV1 CV13 CV28 1 (C/D) 1259 NICKEL CARBONYL 2 (E) 2 (D/E) S2 S20 1261 NITROMETHANE S2 S20 33 1262 OCTANES 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (vapour pressure at 50 °C more than 110 kPa) 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (vapour pressure at 50 °C not more than 110 kPa) 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) LGBF FL L4BN FL 1 (D/E) S2 S20 33 L1.5BN FL 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 L4BN FL 3 (D/E) S2 33 V12 - 353 - Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 3 (3b) F1 (4) III (5) 3 (6) 163 640G 650 (7a) 5L (7b) E1 (8) P001 LP01 R001 (9a) PP1 3 F1 III 3 163 640H 650 5L E1 P001 IBC02 LP01 R001 PP1 3 F1 III 3 5L E1 1265 PENTANES, liquid 3 F1 I 3 0 E3 P001 IBC03 LP01 R001 P001 1265 PENTANES, liquid 3 F1 II 3 1L E2 (1) (2) 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1264 PARALDEHYDE Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP19 4.2.5.2 7.3.2 (10) T2 MP19 T2 TP1 TP29 MP19 T2 TP1 MP7 MP17 MP19 T11 TP2 T4 TP1 MP7 MP17 MP19 T4 TP1 TP8 (11) TP1 TP29 3 F1 I 3 163 0 E3 P001 IBC02 P001 3 F1 II 3 163 640C 5L E2 P001 3 F1 II 3 163 640D 5L E2 P001 IBC02 R001 MP19 T4 TP1 TP8 3 F1 III 3 163 640E 5L E1 MP19 T2 TP1 1266 PERFUMERY PRODUCTS with flammable solvents (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1266 PERFUMERY PRODUCTS with flammable solvents (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1266 PERFUMERY PRODUCTS with flammable solvents (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1267 PETROLEUM CRUDE OIL 3 F1 III 3 163 640F 5L E1 P001 IBC03 LP01 R001 P001 LP01 R001 MP19 T2 TP1 3 F1 III 3 163 640G 5L E1 P001 LP01 R001 MP19 T2 TP1 3 F1 III 3 163 640H 5L E1 P001 IBC02 LP01 R001 MP19 T2 TP1 3 F1 I 3 357 500 ml E3 P001 T11 1267 PETROLEUM CRUDE OIL (vapour pressure at 50 °C more than 110 kPa) 1267 PETROLEUM CRUDE OIL (vapour pressure at 50 °C not more than 110 kPa) 3 F1 II 3 357 640C 1L E2 P001 MP7 MP17 MP19 TP1 TP8 TP1 TP8 3 F1 II 3 357 640D 1L E2 P001 IBC02 R001 MP19 T4 1266 PERFUMERY PRODUCTS with flammable solvents 1266 PERFUMERY PRODUCTS with flammable solvents (vapour pressure at 50 °C more than 110 kPa) 1266 PERFUMERY PRODUCTS with flammable solvents (vapour pressure at 50 °C not more than 110 kPa) 1266 PERFUMERY PRODUCTS with flammable solvents - 354 - B8 T4 TP1 TP8 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L1.5BN (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 3 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) (18) Hazard UN identifi- No. Operation cation No. Name and description 8.5 5.3.2.3 3.1.2 (19) S2 (20) 33 S2 33 S2 30 (1) (2) 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1264 PARALDEHYDE LGBF FL 3 (D/E) LGBF FL 3 (D/E) L4BN FL S2 S20 33 1265 PENTANES, liquid L1.5BN FL S2 S20 33 1265 PENTANES, liquid L4BN FL S2 S20 33 L1.5BN FL 1 (D/E) 2 (D/E) 1 (D/E) 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 1266 PERFUMERY PRODUCTS with flammable solvents 1266 PERFUMERY PRODUCTS with flammable solvents (vapour pressure at 50 °C more than 110 kPa) 1266 PERFUMERY PRODUCTS with flammable solvents (vapour pressure at 50 °C not more than 110 kPa) 1266 PERFUMERY PRODUCTS with flammable solvents L4BN FL 3 (D/E) S2 33 L1.5BN FL 3 (D/E) S2 33 LGBF FL 3 (D/E) S2 33 L4BN FL S2 S20 33 L1.5BN FL 1 (D/E) 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 V12 V12 - 355 - 1266 PERFUMERY PRODUCTS with flammable solvents (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1266 PERFUMERY PRODUCTS with flammable solvents (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1266 PERFUMERY PRODUCTS with flammable solvents (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1267 PETROLEUM CRUDE OIL 1267 PETROLEUM CRUDE OIL (vapour pressure at 50 °C more than 110 kPa) 1267 PETROLEUM CRUDE OIL (vapour pressure at 50 °C not more than 110 kPa) Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 3 (3b) F1 (4) III (5) 3 (6) 357 (7a) 5L (7b) E1 3 F1 I 3 500 ml E3 (8) P001 IBC03 LP01 R001 P001 3 F1 II 3 640C 1L E2 3 F1 II 3 640D 1L 3 F1 III 3 1272 PINE OIL 3 F1 III 1274 n-PROPANOL (PROPYL ALCOHOL, NORMAL) 3 F1 1274 n-PROPANOL (PROPYL ALCOHOL, NORMAL) 3 1275 PROPIONALDEHYDE Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) T2 4.2.5.3 MP7 MP17 T11 TP1 TP8 P001 MP19 T7 TP1 TP8 TP28 E2 P001 IBC02 R001 MP19 T7 TP1 TP8 TP28 5L E1 MP19 T4 TP1 TP29 3 5L E1 MP19 T2 TP1 II 3 1L E2 MP19 T4 TP1 F1 III 3 5L E1 MP19 T2 TP1 3 F1 II 3 1L E2 MP19 T7 TP1 1276 n-PROPYL ACETATE 3 F1 II 3 1L E2 MP19 T4 TP1 1277 PROPYLAMINE 3 FC II 1L E2 MP19 T7 TP1 1278 1-CHLOROPROPANE 3 F1 II 3 +8 3 1L E2 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 P001 IBC02 P001 IBC02 R001 P001 MP19 T7 TP2 MP19 T4 TP1 MP7 MP17 MP19 T11 T4 TP2 TP7 TP1 MP19 T4 TP2 MP7 MP17 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T2 TP1 (1) (2) 1267 PETROLEUM CRUDE OIL 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. 1279 1,2-DICHLOROPROPANE 3 F1 II 3 1L E2 1280 PROPYLENE OXIDE 3 F1 I 3 0 E3 1281 PROPYL FORMATES 3 F1 II 3 1L E2 1282 PYRIDINE 3 F1 II 3 1L E2 1286 ROSIN OIL 3 F1 I 3 0 E3 P001 IBC02 R001 P001 IBC02 R001 P001 1286 ROSIN OIL (vapour pressure at 50 °C more than 110 kPa) 3 F1 II 3 640C 5L E2 P001 1286 ROSIN OIL (vapour pressure at 50 °C not more than 110 kPa) 3 F1 II 3 640D 5L E2 1286 ROSIN OIL 3 F1 III 3 640E 5L E1 1286 ROSIN OIL (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 3 F1 III 3 640F 5L E1 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 LP01 R001 - 356 - (9a) (9b) MP19 (11) TP1 B8 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) LGBF (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 3 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) V12 (17) (18) Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S2 (20) 30 Name and description 3.1.2 (1) (2) 1267 PETROLEUM CRUDE OIL L4BN FL 1 (D/E) S2 S20 33 L1.5BN FL 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) V12 S2 30 LGBF FL 3 (D/E) V12 S2 30 1272 PINE OIL LGBF FL 2 (D/E) S2 S20 33 1274 n-PROPANOL (PROPYL ALCOHOL, NORMAL) LGBF FL 3 (D/E) S2 30 1274 n-PROPANOL (PROPYL ALCOHOL, NORMAL) LGBF FL 2 (D/E) S2 S20 33 1275 PROPIONALDEHYDE LGBF FL 2 (D/E) S2 S20 33 1276 n-PROPYL ACETATE L4BH FL S2 S20 338 1277 PROPYLAMINE L1.5BN FL S2 S20 33 1278 1-CHLOROPROPANE LGBF FL 2 (D/E) 2 (D/E) 2 (D/E) S2 S20 33 1279 1,2-DICHLOROPROPANE L4BN FL S2 S20 33 1280 PROPYLENE OXIDE LGBF FL 1 (D/E) 2 (D/E) S2 S20 33 1281 PROPYL FORMATES LGBF FL 2 (D/E) S2 S20 33 1282 PYRIDINE L4BN FL S2 S20 33 1286 ROSIN OIL L1.5BN FL 1 (D/E) 2 (D/E) S2 S20 33 1286 ROSIN OIL (vapour pressure at 50 °C more than 110 kPa) LGBF FL 2 (D/E) S2 S20 33 1286 ROSIN OIL (vapour pressure at 50 °C not more than 110 kPa) LGBF FL 3 (D/E) S2 30 1286 ROSIN OIL L4BN FL 3 (D/E) S2 33 1286 ROSIN OIL (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) V12 V12 - 357 - 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1286 ROSIN OIL (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) (3a) 3 (3b) F1 (4) III (5) 3 (6) 640G (7a) 5L (7b) E1 (8) P001 LP01 R001 1286 ROSIN OIL (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 3 F1 III 3 640H 5L E1 1287 RUBBER SOLUTION 3 F1 I 3 0 1287 RUBBER SOLUTION (vapour pressure at 50 °C more than 110 kPa) 3 F1 II 3 640C 1287 RUBBER SOLUTION (vapour pressure at 50 °C not more than 110 kPa) 1287 RUBBER SOLUTION 3 F1 II 3 3 F1 III 1287 RUBBER SOLUTION (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 3 F1 1287 RUBBER SOLUTION (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 3 1287 RUBBER SOLUTION (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP19 4.2.5.2 7.3.2 (10) T2 P001 IBC02 LP01 R001 MP19 T2 TP1 E3 P001 5L E2 P001 MP7 MP17 MP19 T4 TP1 TP8 640D 5L E2 MP19 T4 TP1 TP8 3 640E 5L E1 MP19 T2 TP1 III 3 640F 5L E1 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 LP01 R001 MP19 T2 TP1 F1 III 3 640G 5L E1 P001 LP01 R001 MP19 T2 TP1 3 F1 III 3 640H 5L E1 P001 IBC02 LP01 R001 MP19 T2 TP1 1288 SHALE OIL 3 F1 II 3 1L E2 MP19 T4 TP1 TP8 1288 SHALE OIL 3 F1 III 3 5L E1 MP19 T2 TP1 1289 SODIUM METHYLATE SOLUTION in alcohol 1289 SODIUM METHYLATE SOLUTION in alcohol 3 FC II 1L E2 MP19 T7 3 FC III 3 +8 3 +8 5L E1 MP19 T4 TP1 TP8 TP1 1292 TETRAETHYL SILICATE 3 F1 III 3 5L E1 MP19 T2 TP1 1293 TINCTURES, MEDICINAL 3 F1 II 3 601 1L E2 MP19 T4 TP1 TP8 1293 TINCTURES, MEDICINAL 3 F1 III 3 601 5L E1 MP19 T2 TP1 1294 TOLUENE 3 F1 II 3 1L E2 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 MP19 T4 TP1 - 358 - (9a) (11) TP1 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L1.5BN (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 3 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) (18) Hazard UN identifi- No. Operation cation No. Name and description 8.5 5.3.2.3 3.1.2 (19) S2 (20) 33 (1) (2) 1286 ROSIN OIL (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) LGBF FL 3 (D/E) S2 33 1286 ROSIN OIL (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) L4BN FL S2 S20 33 1287 RUBBER SOLUTION L1.5BN FL 1 (D/E) 2 (D/E) S2 S20 33 1287 RUBBER SOLUTION (vapour pressure at 50 °C more than 110 kPa) LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 1287 RUBBER SOLUTION (vapour pressure at 50 °C not more than 110 kPa) 1287 RUBBER SOLUTION L4BN FL 3 (D/E) S2 33 1287 RUBBER SOLUTION (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) L1.5BN FL 3 (D/E) S2 33 1287 RUBBER SOLUTION (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) LGBF FL 3 (D/E) S2 33 1287 RUBBER SOLUTION (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) LGBF FL 2 (D/E) S2 S20 33 1288 SHALE OIL LGBF FL 3 (D/E) S2 30 1288 SHALE OIL L4BH FL S2 S20 338 L4BN FL 2 (D/E) 3 (D/E) S2 38 1289 SODIUM METHYLATE SOLUTION in alcohol 1289 SODIUM METHYLATE SOLUTION in alcohol LGBF FL 3 (D/E) S2 30 1292 TETRAETHYL SILICATE LGBF FL 2 (D/E) S2 S20 33 1293 TINCTURES, MEDICINAL LGBF FL 3 (D/E) S2 30 1293 TINCTURES, MEDICINAL LGBF FL 2 (D/E) S2 S20 33 1294 TOLUENE V12 V12 V12 V12 - 359 - Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 4.3 (3b) WFC (4) I (6) (7a) 0 (7b) E0 (8) P401 1296 TRIETHYLAMINE 3 FC II 1L E2 1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 1298 TRIMETHYLCHLOROSILANE 1299 TURPENTINE 3 FC I (5) 4.3 +3 +8 3 +8 3 +8 0 E0 P001 IBC02 P001 3 FC II 3 +8 1L E2 3 FC III 3 +8 5L 3 FC II 3 F1 III 3 +8 3 1300 TURPENTINE SUBSTITUTE 3 F1 II 1300 TURPENTINE SUBSTITUTE 3 F1 1301 VINYL ACETATE, STABILIZED 3 1302 VINYL ETHYL ETHER, STABILIZED 1303 VINYLIDENE CHLORIDE, STABILIZED 1304 VINYL ISOBUTYL ETHER, STABILIZED Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP2 4.2.5.2 7.3.2 (10) T14 MP19 T7 TP1 MP7 MP17 T11 TP1 P001 IBC02 MP19 T7 TP1 E1 P001 IBC03 R001 MP19 T7 TP1 0 E2 P010 MP19 T10 5L E1 MP19 T2 3 1L E2 MP19 T4 TP1 III 3 5L E1 MP19 T2 TP1 F1 II 3 1L E2 MP19 T4 TP1 3 F1 I 3 0 E3 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 TP2 TP7 TP1 T11 TP2 3 F1 I 3 0 E3 P001 T12 3 F1 II 3 1L E2 TP2 TP7 TP1 1305 VINYLTRICHLOROSILANE 3 FC II 0 E2 MP19 T10 1306 WOOD PRESERVATIVES, LIQUID (vapour pressure at 50 °C more than 110 kPa) 1306 WOOD PRESERVATIVES, LIQUID (vapour pressure at 50 °C not more than 110 kPa) 1306 WOOD PRESERVATIVES, LIQUID 3 F1 II 3 +8 3 P001 IBC02 R001 P010 MP7 MP17 MP7 MP17 MP19 640C 5L E2 P001 MP19 T4 3 F1 II 3 640D 5L E2 MP19 T4 TP1 TP8 3 F1 III 3 640E 5L E1 MP19 T2 TP1 3 F1 III 3 640F 5L E1 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 LP01 R001 MP19 T2 TP1 3 F1 III 3 640G 5L E1 P001 LP01 R001 MP19 T2 TP1 3 F1 III 3 640H 5L E1 P001 IBC02 LP01 R001 MP19 T2 TP1 3 F1 II 3 1L E2 P001 IBC02 R001 MP19 T4 TP1 (1) (2) 1295 TRICHLOROSILANE 1306 WOOD PRESERVATIVES, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1306 WOOD PRESERVATIVES, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1306 WOOD PRESERVATIVES, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1307 XYLENES - 360 - (9a) RR7 T4 (11) TP2 TP7 TP2 TP7 TP1 TP8 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L10DH (13) TU14 TU25 TE21 TM2 TM3 L4BH L10CH Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 0 (B/E) FL TU14 TE21 FL Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V1 (17) Loading, unloading and handling 7.5.11 Hazard UN identifi- No. Operation cation No. Name and description 8.5 5.3.2.3 (19) S2 S20 (20) X338 2 (D/E) 1 (C/E) S2 S20 338 1296 TRIETHYLAMINE S2 S20 338 S2 S20 338 S2 38 S2 S20 X338 S2 30 1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 1298 TRIMETHYLCHLOROSILANE 1299 TURPENTINE S2 S20 33 1300 TURPENTINE SUBSTITUTE S2 30 1300 TURPENTINE SUBSTITUTE (18) CV23 3.1.2 (1) (2) 1295 TRICHLOROSILANE L4BH FL 2 (D/E) L4BN FL 3 (D/E) L4BH FL LGBF FL 2 (D/E) 3 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) S2 S20 339 1301 VINYL ACETATE, STABILIZED L4BN FL S2 S20 339 L4BN FL S2 S20 339 LGBF FL 1 (D/E) 1 (D/E) 2 (D/E) S2 S20 339 1302 VINYL ETHYL ETHER, STABILIZED 1303 VINYLIDENE CHLORIDE, STABILIZED 1304 VINYL ISOBUTYL ETHER, STABILIZED L4BH FL S2 S20 X338 1305 VINYLTRICHLOROSILANE L1.5BN FL 2 (D/E) 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 1306 WOOD PRESERVATIVES, LIQUID (vapour pressure at 50 °C more than 110 kPa) 1306 WOOD PRESERVATIVES, LIQUID (vapour pressure at 50 °C not more than 110 kPa) 1306 WOOD PRESERVATIVES, LIQUID L4BN FL 3 (D/E) S2 33 L1.5BN FL 3 (D/E) S2 33 LGBF FL 3 (D/E) S2 33 LGBF FL 2 (D/E) S2 S20 33 V12 V12 V12 V12 - 361 - 1306 WOOD PRESERVATIVES, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1306 WOOD PRESERVATIVES, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1306 WOOD PRESERVATIVES, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1307 XYLENES Copyright © United Nations, 2010. All rights reserved UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities 3.1.2 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (2) (3a) 3 (3b) F1 (4) III (5) 3 (6) (7a) 5L (7b) E1 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID 3 F1 I 3 0 E3 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID (vapour pressure at 50 °C more than 110 kPa) 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID (vapour pressure at 50 °C not more than 110 kPa) 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID 3 F1 II 3 640C 1L E2 3 F1 II 3 640D 1L 3 F1 III 3 1309 ALUMINIUM POWDER, COATED 1309 ALUMINIUM POWDER, COATED 4.1 F3 II 4.1 F3 1310 AMMONIUM PICRATE, WETTED with not less than 10% water, by mass 1312 BORNEOL 4.1 4.1 (1) 1307 XYLENES Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 (8) P001 IBC03 LP01 R001 P001 (9a) (9b) MP19 PP33 MP7 MP17 P001 R001 PP33 MP19 E2 P001 R001 PP33 MP19 5L E1 P001 R001 4.1 1 kg E2 III 4.1 5 kg E1 D I 4.1 0 E0 P002 IBC08 P002 IBC08 LP02 R001 P406 F1 III 4.1 5 kg E1 T3 TP33 MP11 T1 TP33 PP26 MP2 MP10 T1 TP33 MP11 T1 TP33 MP11 T1 TP33 MP11 T1 TP33 T3 TP33 MP10 T3 TP33 MP10 T1 TP33 MP11 T3 TP33 MP10 T1 TP33 MP11 T1 TP33 F3 III 4.1 5 kg E1 1314 CALCIUM RESINATE, FUSED 4.1 F3 III 4.1 5 kg E1 1318 COBALT RESINATE, PRECIPITATED 4.1 F3 III 4.1 5 kg E1 1320 DINITROPHENOL, WETTED with not less than 15% water, by mass 1321 DINITROPHENOLATES, WETTED with not less than 15% water, by mass 1322 DINITRORESORCINOL, WETTED with not less than 15% water, by mass 1323 FERROCERIUM 4.1 DT I 4.1 +6.1 0 E0 4.1 DT I 4.1 +6.1 0 E0 P406 PP26 MP2 4.1 D I 4.1 0 E0 P406 PP26 MP2 4.1 F3 II 4.1 1 kg E2 P002 IBC08 P002 R001 B4 PP15 F1 III 4.1 1325 FLAMMABLE SOLID, ORGANIC, N.O.S. 1325 FLAMMABLE SOLID, ORGANIC, N.O.S. 4.1 F1 II 4.1 1326 HAFNIUM POWDER, WETTED with not less than 25% water 1327 Hay, Straw or Bhusa 4.1 F1 4.1 F3 4.1 F1 1328 HEXAMETHYLENETETRAMINE 4.1 F1 1330 MANGANESE RESINATE 4.1 F3 III II 4.1 4.1 274 274 586 5 kg E1 1 kg E2 5 kg 1 kg E1 E2 P002 IBC08 P002 IBC08 LP02 R001 P410 IBC06 (11) TP1 MP11 4.1 4.1 4.2.5.3 PP38 B4 PP11 B3 1313 CALCIUM RESINATE 1324 FILMS, NITROCELLULOSE BASE, gelatin coated, except scrap 4.2.5.2 7.3.2 (10) T2 MP19 P002 IBC08 LP02 R001 P002 IBC06 R001 P002 IBC04 R001 P002 IBC06 R001 P406 249 Portable tanks and bulk containers Instruc- Special tions provisions B3 PP26 MP2 MP11 MP11 B4 B3 PP40 NOT SUBJECT TO ADR III III 4.1 5 kg 4.1 5 kg - 362 - E1 E1 P002 IBC08 R001 P002 IBC06 R001 B3 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) LGBF (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 3 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) V12 (17) (18) Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S2 (20) 30 Name and description 3.1.2 (1) 1307 XYLENES (2) L4BN FL 1 (D/E) S2 S20 33 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID L1.5BN FL 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID (vapour pressure at 50 °C more than 110 kPa) 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID (vapour pressure at 50 °C not more than 110 kPa) 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID SGAN AT SGAV AT 2 (E) 3 (E) V11 40 VV1 40 1 (B) S14 1309 ALUMINIUM POWDER, COATED 1309 ALUMINIUM POWDER, COATED SGAV AT 3 (E) VV1 40 1310 AMMONIUM PICRATE, WETTED with not less than 10% water, by mass 1312 BORNEOL SGAV AT 3 (E) VV1 40 1313 CALCIUM RESINATE SGAV AT 3 (E) VV1 40 1314 CALCIUM RESINATE, FUSED SGAV AT 3 (E) VV1 40 1318 COBALT RESINATE, PRECIPITATED 1 (B) CV28 S14 1 (B) CV28 S14 1 (B) SGAN AT SGAN AT SGAV AT SGAN AT S14 2 (E) 3 (E) V11 2 (E) 3 (E) V11 2 (E) V11 40 1320 DINITROPHENOL, WETTED with not less than 15% water, by mass 1321 DINITROPHENOLATES, WETTED with not less than 15% water, by mass 1322 DINITRORESORCINOL, WETTED with not less than 15% water, by mass 1323 FERROCERIUM 1324 FILMS, NITROCELLULOSE BASE, gelatin coated, except scrap 40 VV1 40 1325 FLAMMABLE SOLID, ORGANIC, N.O.S. 1325 FLAMMABLE SOLID, ORGANIC, N.O.S. 40 1326 HAFNIUM POWDER, WETTED with not less than 25% water 1327 Hay, Straw or Bhusa NOT SUBJECT TO ADR SGAV AT 3 (E) VV1 40 1328 HEXAMETHYLENETETRAMINE SGAV AT 3 (E) VV1 40 1330 MANGANESE RESINATE - 363 - Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 (1) (2) 1331 MATCHES, 'STRIKE ANYWHERE' 1332 METALDEHYDE Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 4.1 (3b) F1 (4) III (5) 4.1 (6) 293 (7a) 5 kg (7b) E1 (8) P407 4.1 F1 III 4.1 5 kg E1 (9a) PP27 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 T1 TP33 T1 BK1 BK2 TP33 MP11 T1 TP33 MP11 T3 TP33 (9b) MP12 (11) 1334 NAPHTHALENE, CRUDE or NAPHTHALENE, REFINED 4.1 1336 NITROGUANIDINE (PICRITE), WETTED with not less than 20% water, by mass 1337 NITROSTARCH, WETTED with not less than 20% water, by mass 1338 PHOSPHORUS, AMORPHOUS 4.1 D I 4.1 0 E0 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 LP02 R001 P406 4.1 D I 4.1 0 E0 P406 4.1 F3 III 4.1 5 kg E1 1339 PHOSPHORUS HEPTASULPHIDE, free from yellow and white phosphorus 4.1 F3 II 4.1 602 1 kg E2 P410 IBC08 R001 P410 IBC04 1340 PHOSPHORUS PENTASULPHIDE, free from yellow and white phosphorus 4.3 WF2 II 4.3 +4.1 602 500 g E2 P410 IBC04 MP14 T3 TP33 1341 PHOSPHORUS SESQUISULPHIDE, free from yellow and white phosphorus 4.1 F3 II 4.1 602 1 kg E2 P410 IBC04 MP11 T3 TP33 1343 PHOSPHORUS TRISULPHIDE, free from yellow and white phosphorus 4.1 F3 II 4.1 602 1 kg E2 P410 IBC04 MP11 T3 TP33 1344 TRINITROPHENOL (PICRIC ACID), WETTED with not less than 30% water, by mass 4.1 D I 4.1 0 E0 P406 PP26 1345 RUBBER SCRAP or RUBBER SHODDY, powdered or granulated 1346 SILICON POWDER, AMORPHOUS 4.1 F1 II 4.1 1 kg E2 P002 IBC08 MP11 T3 TP33 B4 MP11 T1 TP33 MP11 T1 BK1 BK2 TP33 MP11 T3 TP33 1333 CERIUM, slabs, ingots or rods 1347 SILVER PICRATE, WETTED with not less than 30% water, by mass 1348 SODIUM DINITRO-oCRESOLATE, WETTED with not less than 15% water, by mass 1349 SODIUM PICRAMATE, WETTED with not less than 20% water, by mass 1350 SULPHUR 1352 TITANIUM POWDER, WETTED with not less than 25% water 1353 FIBRES or FABRICS IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. 1354 TRINITROBENZENE, WETTED with not less than 30% water, by mass 4.1 F3 F1 II III 4.1 4.1 4.1 F3 III 4.1 4.1 D I 4.1 DT 4.1 4.1 1 kg 501 32 5 kg E2 E1 MP11 B4 MP10 B3 MP2 MP2 B3 E1 4.1 0 E0 I 4.1 +6.1 0 E0 P406 PP26 MP2 D I 4.1 0 E0 P406 PP26 MP2 F3 III 4.1 5 kg E1 P002 IBC08 LP02 R001 P410 IBC06 242 F3 II 4.1 586 1 kg E2 4.1 F1 III 4.1 502 5 kg E1 D I 4.1 0 - 364 - E0 P002 IBC08 B3 LP02 R001 P406 PP25 PP26 MP2 5 kg 4.1 4.1 MP10 B3 P410 IBC08 R001 P406 MP2 B3 PP40 MP11 B3 MP2 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) SGAV SGAV Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 4 (E) AT 3 (E) AT 2 (E) 3 (E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) (18) Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) (20) VV1 40 V11 VV2 40 S14 1 (B) S14 AT 3 (E) SGAN AT 2 (E) SGAN AT 0 (D/E) SGAN AT SGAN AT 3.1.2 (1) (2) 1331 MATCHES, 'STRIKE ANYWHERE' 1332 METALDEHYDE 1333 CERIUM, slabs, ingots or rods 1 (B) SGAV Name and description VV1 40 1334 NAPHTHALENE, CRUDE or NAPHTHALENE, REFINED 1336 NITROGUANIDINE (PICRITE), WETTED with not less than 20% water, by mass 1337 NITROSTARCH, WETTED with not less than 20% water, by mass 1338 PHOSPHORUS, AMORPHOUS 40 1339 PHOSPHORUS HEPTASULPHIDE, free from yellow and white phosphorus 423 1340 PHOSPHORUS PENTASULPHIDE, free from yellow and white phosphorus 2 (E) 40 1341 PHOSPHORUS SESQUISULPHIDE, free from yellow and white phosphorus 2 (E) 40 1343 PHOSPHORUS TRISULPHIDE, free from yellow and white phosphorus V1 CV23 1 (B) SGAN AT 4 (E) SGAV AT 3 (E) S14 V11 40 VV1 40 1 (B) S14 1 (B) CV28 1 (B) SGAV AT 3 (E) SGAN AT 2 (E) 1344 TRINITROPHENOL (PICRIC ACID), WETTED with not less than 30% water, by mass S14 S14 VV1 40 V11 40 3 (E) 1 (B) S14 - 365 - 1345 RUBBER SCRAP or RUBBER SHODDY, powdered or granulated 1346 SILICON POWDER, AMORPHOUS 1347 SILVER PICRATE, WETTED with not less than 30% water, by mass 1348 SODIUM DINITRO-oCRESOLATE, WETTED with not less than 15% water, by mass 1349 SODIUM PICRAMATE, WETTED with not less than 20% water, by mass 1350 SULPHUR 1352 TITANIUM POWDER, WETTED with not less than 25% water 1353 FIBRES or FABRICS IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. 1354 TRINITROBENZENE, WETTED with not less than 30% water, by mass Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1355 TRINITROBENZOIC ACID, WETTED with not less than 30% water, by mass 1356 TRINITROTOLUENE (TNT), WETTED with not less than 30% water, by mass 1357 UREA NITRATE, WETTED with not less than 20% water, by mass 1358 ZIRCONIUM POWDER, WETTED with not less than 25% water 1360 CALCIUM PHOSPHIDE (3a) 4.1 (3b) D (4) I (5) 4.1 (6) (7a) 0 (7b) E0 (8) P406 4.1 D I 4.1 0 E0 P406 MP2 4.1 D I 4.1 227 0 E0 P406 MP2 4.1 F3 II 4.1 586 1 kg E2 P410 IBC06 4.3 WT2 I 0 E0 P403 MP2 1361 CARBON, animal or vegetable origin 1361 CARBON, animal or vegetable origin 4.2 S2 II 4.3 +6.1 4.2 0 E2 4.2 S2 III 4.2 0 1362 CARBON, ACTIVATED 4.2 S2 III 4.2 1363 COPRA 4.2 S2 III 4.2 0 1364 COTTON WASTE, OILY 4.2 S2 III 4.2 0 1365 COTTON, WET 4.2 S2 III 4.2 0 1369 p-NITROSODIMETHYLANILINE 1372 Fibres, animal or fibres, vegetable burnt, wet or damp 4.2 S2 II 4.2 0 4.2 S2 P002 PP12 IBC06 E1 P002 PP12 IBC08 B3 LP02 R001 E1 P002 PP11 IBC08 B3 LP02 R001 E1 P003 PP20 IBC08 B3 B6 LP02 R001 E1 P003 PP19 IBC08 B3 B6 LP02 R001 E1 P003 PP19 IBC08 B3 B6 LP02 R001 E2 P410 IBC06 NOT SUBJECT TO ADR 1373 FIBRES or FABRICS, ANIMAL or VEGETABLE or SYNTHETIC, N.O.S. with oil 4.2 S2 III 4.2 0 1374 FISH MEAL (FISH SCRAP), UNSTABILIZED 1376 IRON OXIDE, SPENT or IRON SPONGE, SPENT obtained from coal gas purification 1378 METAL CATALYST, WETTED with a visible excess of liquid 1379 PAPER, UNSATURATED OIL TREATED, incompletely dried (including carbon paper) 1380 PENTABORANE 4.2 4.2 S2 S4 II III 4.2 4.2 4.2 S4 II 4.2 4.2 S2 III 4.2 646 300 592 274 0 0 0 E1 E2 E1 0 E2 0 E1 P410 IBC08 R001 P410 IBC08 P002 IBC08 LP02 R001 P410 IBC01 (9a) PP40 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 T3 TP33 MP14 T3 TP33 MP14 T1 TP33 MP14 T1 TP33 MP14 T3 TP33 MP14 T1 TP33 MP14 T3 TP33 MP14 T1 BK2 TP33 MP14 T3 TP33 (9b) MP2 MP11 (11) MP14 MP14 MP14 B3 B4 B3 PP39 0 E0 P410 IBC08 R001 P601 503 0 E0 P405 MP2 T9 TP3 TP31 4.2 +6.1 503 0 E0 P405 MP2 T9 TP3 TP31 II 4.2 504 0 E2 P410 IBC06 MP14 T3 TP33 I 4.2 274 0 E0 P404 MP13 T21 TP7 TP33 4.2 ST3 I 1381 PHOSPHORUS, WHITE or YELLOW, UNDER WATER or IN SOLUTION 1381 PHOSPHORUS, WHITE or YELLOW, DRY 4.2 ST3 I 4.2 ST4 I 1382 POTASSIUM SULPHIDE, ANHYDROUS or POTASSIUM SULPHIDE with less than 30% water of crystallization 1383 PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. 4.2 S4 4.2 S4 4.2 +6.1 4.2 +6.1 - 366 - MP14 B3 MP2 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) SGAN SGAN Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 1 (B) AT TU11 AT SGAV AT SGAV AT SGAN AT SGAN 7.3.3 (16) (17) (18) Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S14 (20) 1 (B) S14 1 (B) S14 2 (E) V11 1 (E) 2 (D/E) 4 (E) V1 V1 V13 V1 V13 40 CV23 CV28 S20 40 VV4 40 (1) (2) 1355 TRINITROBENZOIC ACID, WETTED with not less than 30% water, by mass 1356 TRINITROTOLUENE (TNT), WETTED with not less than 30% water, by mass 1357 UREA NITRATE, WETTED with not less than 20% water, by mass 1358 ZIRCONIUM POWDER, WETTED with not less than 25% water 1360 CALCIUM PHOSPHIDE 1361 CARBON, animal or vegetable origin 1361 CARBON, animal or vegetable origin VV4 40 1362 CARBON, ACTIVATED 3 (E) V1 VV4 40 1363 COPRA 3 (E) V1 VV4 40 1364 COTTON WASTE, OILY 3 (E) V1 VV4 40 1365 COTTON, WET 40 1369 p-NITROSODIMETHYLANILINE 1372 Fibres, animal or fibres, vegetable burnt, wet or damp 40 1373 FIBRES or FABRICS, ANIMAL or VEGETABLE or SYNTHETIC, N.O.S. with oil 40 1374 FISH MEAL (FISH SCRAP), UNSTABILIZED 1376 IRON OXIDE, SPENT or IRON SPONGE, SPENT obtained from coal gas purification 1378 METAL CATALYST, WETTED with a visible excess of liquid 1379 PAPER, UNSATURATED OIL TREATED, incompletely dried (including carbon paper) 1380 PENTABORANE 2 V1 (D/E) NOT SUBJECT TO ADR V1 V1 VV4 VV4 40 2 (D/E) V1 3 (E) V1 0 (B/E) 0 (B/E) V1 CV28 S20 333 V1 CV28 S20 46 AT 0 (B/E) V1 CV28 S20 46 AT 2 (D/E) V1 AT 0 (B/E) V1 AT 3.1.2 V1 2 (D/E) 3 (E) AT Name and description 4 (E) AT AT L10DH(+) 7.2.4 Loading, unloading and handling 7.5.11 V1 SGAN L10DH(+) Bulk 3 (E) AT TU14 TC1 TE21 TM1 TU14 TU16 TU21 TE3 TE21 TU14 TU16 TU21 TE3 TE21 Packages AT SGAV L21DH Special provisions for carriage 40 VV4 40 40 S20 - 367 - 43 1381 PHOSPHORUS, WHITE or YELLOW, UNDER WATER or IN SOLUTION 1381 PHOSPHORUS, WHITE or YELLOW, DRY 1382 POTASSIUM SULPHIDE, ANHYDROUS or POTASSIUM SULPHIDE with less than 30% water of crystallization 1383 PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) (3a) 1384 SODIUM DITHIONITE 4.2 (SODIUM HYDROSULPHITE) 1385 SODIUM SULPHIDE, 4.2 ANHYDROUS or SODIUM SULPHIDE with less than 30% water of crystallization 1386 SEED CAKE with more than 4.2 1.5% oil and not more than 11% moisture (3b) S4 (4) II (5) 4.2 (6) (7a) 0 (7b) E2 (8) P410 IBC06 S4 II 4.2 504 0 E2 S2 III 4.2 0 E1 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP14 4.2.5.2 7.3.2 (10) T3 P410 IBC06 MP14 T3 TP33 P003 PP20 IBC08 B3 B6 LP02 R001 NOT SUBJECT TO ADR MP14 T3 TP33 (9a) (11) TP33 1387 Wool waste, wet 4.2 S2 1389 ALKALI METAL AMALGAM, LIQUID 1390 ALKALI METAL AMIDES 4.3 W1 I 4.3 182 0 E0 P402 4.3 W2 II 4.3 500 g E2 1391 ALKALI METAL DISPERSION or ALKALINE EARTH METAL DISPERSION 4.3 W1 I 4.3 182 505 182 183 506 0 E0 P410 IBC07 P402 1392 ALKALINE EARTH METAL AMALGAM, LIQUID 4.3 W1 I 4.3 183 506 0 E0 P402 MP2 1393 ALKALINE EARTH METAL ALLOY, N.O.S. 1394 ALUMINIUM CARBIDE 4.3 W2 II 4.3 183 506 500 g E2 MP14 T3 TP33 4.3 W2 II 4.3 500 g E2 MP14 T3 TP33 4.3 WT2 II 500 g E2 PP40 MP14 T3 TP33 4.3 W2 II 4.3 +6.1 4.3 500 g E2 PP40 MP14 T3 TP33 4.3 W2 III 4.3 1 kg E1 P410 IBC07 P410 IBC07 P410 IBC05 P410 IBC07 P410 IBC08 R001 P403 MP14 T1 TP33 MP14 T1 TP33 MP14 T3 TP33 MP14 T3 TP33 MP2 T9 MP14 T3 TP7 TP33 TP33 MP14 T1 TP33 MP14 T3 TP33 MP14 T1 TP33 T1 BK2 TP33 T3 TP33 1395 ALUMINIUM FERROSILICON POWDER 1396 ALUMINIUM POWDER, UNCOATED 1396 ALUMINIUM POWDER, UNCOATED 1397 ALUMINIUM PHOSPHIDE 4.3 WT2 I 4.3 +6.1 4.3 1398 ALUMINIUM SILICON POWDER, UNCOATED 4.3 W2 III 1400 BARIUM 4.3 W2 II 4.3 500 g E2 1401 CALCIUM 4.3 W2 II 4.3 500 g E2 1402 CALCIUM CARBIDE 4.3 W2 I 4.3 0 E0 1402 CALCIUM CARBIDE 4.3 W2 II 4.3 500 g E2 1403 CALCIUM CYANAMIDE with more than 0.1% calcium carbide 1404 CALCIUM HYDRIDE 4.3 W2 III 4.3 1 kg E1 4.3 W2 I 4.3 0 E0 1405 CALCIUM SILICIDE 4.3 W2 II 4.3 500 g E2 1405 CALCIUM SILICIDE 4.3 W2 III 4.3 1 kg E1 1407 CAESIUM 4.3 W2 I 4.3 1408 FERROSILICON with 30% or more but less than 90% silicon 4.3 WT2 III 4.3 +6.1 1409 METAL HYDRIDES, WATER- 4.3 REACTIVE, N.O.S. W2 I 1409 METAL HYDRIDES, WATER- 4.3 REACTIVE, N.O.S. W2 1410 LITHIUM ALUMINIUM HYDRIDE W2 4.3 507 0 E0 37 1 kg E1 38 P410 IBC08 R001 P410 IBC07 P410 IBC07 P403 IBC04 P410 IBC07 P410 IBC08 R001 P403 P410 IBC07 P410 IBC08 R001 P403 IBC04 RR8 MP2 MP14 RR8 MP2 B4 MP2 B4 B4 MP2 B4 0 E0 39 1 kg E1 4.3 274 508 0 E0 II 4.3 274 508 500 g E2 P410 IBC04 MP14 I 4.3 0 E0 P403 MP2 - 368 - P003 IBC08 R001 P403 MP2 PP20 B4 B6 MP14 MP2 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) SGAN (13) SGAN Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 2 (D/E) AT Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) V1 (17) (18) 2 (D/E) V1 3 (E) V1 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) (20) 40 40 VV4 40 NOT SUBJECT TO ADR L10BN(+) TU1 TE5 TT3 TM2 SGAN AT AT 1 (B/E) 0 (D/E) 1 (B/E) CV23 S20 X323 V1 CV23 V1 CV23 S20 X323 1391 ALKALI METAL DISPERSION or ALKALINE EARTH METAL DISPERSION S20 X323 1392 ALKALINE EARTH METAL AMALGAM, LIQUID 1393 ALKALINE EARTH METAL ALLOY, N.O.S. 1394 ALUMINIUM CARBIDE 423 AT L10BN(+) TU1 TE5 TT3 TM2 AT 1 (B/E) V1 CV23 SGAN AT V1 CV23 423 SGAN AT CV23 423 SGAN AT AT CV23 CV28 CV23 462 SGAN SGAN AT 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 3 (E) VV5 CV23 423 VV5 CV23 CV28 CV23 SGAN AT SGAN AT AT SGAN AT SGAN AT SGAN AT SGAN AT L10CH(+) SGAN SGAN TU2 TU14 TE5 TE21 TT3 TM2 V1 VV5 V1 V1 V1 1 (E) 3 (E) V1 2 (D/E) 2 (D/E) 1 (B/E) 2 (D/E) 0 (E) V1 1 (E) 2 (D/E) 3 (E) V1 423 S20 1389 ALKALI METAL AMALGAM, LIQUID 1390 ALKALI METAL AMIDES 1395 ALUMINIUM FERROSILICON POWDER 1396 ALUMINIUM POWDER, UNCOATED 1396 ALUMINIUM POWDER, UNCOATED 1397 ALUMINIUM PHOSPHIDE 423 1398 ALUMINIUM SILICON POWDER, UNCOATED CV23 423 1400 BARIUM V1 CV23 423 1401 CALCIUM V1 CV23 X423 1402 CALCIUM CARBIDE CV23 423 1402 CALCIUM CARBIDE V1 CV23 423 V1 CV23 1403 CALCIUM CYANAMIDE with more than 0.1% calcium carbide 1404 CALCIUM HYDRIDE V1 VV5 S20 S20 V1 VV7 CV23 423 1405 CALCIUM SILICIDE V1 VV5 VV7 CV23 423 1405 CALCIUM SILICIDE AT 1 (B/E) V1 AT 3 (E) V1 1 (E) V1 CV23 2 (D/E) V1 CV23 1 (E) V1 CV23 AT (1) (2) 1384 SODIUM DITHIONITE (SODIUM HYDROSULPHITE) 1385 SODIUM SULPHIDE, ANHYDROUS or SODIUM SULPHIDE with less than 30% water of crystallization 1386 SEED CAKE with more than 1.5% oil and not more than 11% moisture V1 TU1 TE5 TT3 TM2 AT 3.1.2 1387 Wool waste, wet L10BN(+) SGAN Name and description CV23 VV1 - 369 - S20 X423 462 CV23 CV28 S20 1408 FERROSILICON with 30% or more but less than 90% silicon 1409 METAL HYDRIDES, WATERREACTIVE, N.O.S. 423 S20 1407 CAESIUM 1409 METAL HYDRIDES, WATERREACTIVE, N.O.S. 1410 LITHIUM ALUMINIUM HYDRIDE Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1411 LITHIUM ALUMINIUM HYDRIDE, ETHEREAL 1413 LITHIUM BOROHYDRIDE (3a) 4.3 (3b) WF1 (4) I (6) (7a) 0 (7b) E0 (8) P402 4.3 W2 I (5) 4.3 +3 4.3 0 E0 P403 MP2 1414 LITHIUM HYDRIDE 4.3 W2 I 4.3 0 E0 P403 MP2 1415 LITHIUM 4.3 W2 I 4.3 0 E0 MP2 1417 LITHIUM SILICON 4.3 W2 II 4.3 500 g E2 1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER 1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER 1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER 1419 MAGNESIUM ALUMINIUM PHOSPHIDE 1420 POTASSIUM METAL ALLOYS, LIQUID 1421 ALKALI METAL ALLOY, LIQUID, N.O.S. 1422 POTASSIUM SODIUM ALLOYS, LIQUID 1423 RUBIDIUM 4.3 WS I 4.3 +4.2 0 E0 P403 IBC04 P410 IBC07 P403 4.3 WS II 4.3 +4.2 0 E2 P410 IBC05 4.3 WS III 4.3 +4.2 0 E1 0 E0 P410 IBC08 R001 P403 0 E0 P402 0 E0 P402 (9a) RR8 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 T3 TP33 MP14 T3 TP33 MP14 T1 TP33 T9 TP3 TP7 TP31 (9b) MP2 MP14 (11) MP2 B4 4.3 WT2 I 4.3 W1 I 4.3 +6.1 4.3 4.3 W1 I 4.3 4.3 W1 I 4.3 0 E0 P402 MP2 4.3 W2 I 4.3 0 E0 P403 IBC04 MP2 1426 SODIUM BOROHYDRIDE 4.3 W2 I 4.3 0 E0 P403 MP2 1427 SODIUM HYDRIDE 4.3 W2 I 4.3 0 E0 P403 MP2 1428 SODIUM 4.3 W2 I 4.3 0 E0 MP2 T9 1431 SODIUM METHYLATE 4.2 SC4 II 0 E2 MP14 T3 TP7 TP33 TP33 1432 SODIUM PHOSPHIDE 4.3 WT2 I 0 E0 1433 STANNIC PHOSPHIDES 4.3 WT2 I 0 E0 P403 MP2 1435 ZINC ASHES 4.3 W2 III 4.2 +8 4.3 +6.1 4.3 +6.1 4.3 P403 IBC04 P410 IBC05 P403 1 kg E1 P002 IBC08 R001 P403 T1 TP33 MP14 T3 TP33 MP14 T1 TP33 MP11 T3 TP33 MP10 T1 BK1 BK2 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 1436 ZINC POWDER or ZINC DUST 1436 ZINC POWDER or ZINC DUST 1436 ZINC POWDER or ZINC DUST 4.3 WS I 4.3 WS II 4.3 WS III 182 4.3 +4.2 4.3 +4.2 4.3 +4.2 0 E0 0 E2 0 E1 1437 ZIRCONIUM HYDRIDE 4.1 F3 II 4.1 1 kg E2 1438 ALUMINIUM NITRATE 5.1 O2 III 5.1 5 kg E1 1439 AMMONIUM DICHROMATE 1442 AMMONIUM PERCHLORATE 1444 AMMONIUM PERSULPHATE 1445 BARIUM CHLORATE, SOLID 1446 BARIUM NITRATE 1447 BARIUM PERCHLORATE, SOLID 5.1 O2 II 5.1 5.1 O2 II 5.1 5.1 O2 III 5.1 5.1 OT2 II 5.1 OT2 II 5.1 OT2 II 1 kg 152 5.1 +6.1 5.1 +6.1 5.1 +6.1 1 kg E2 5 kg E1 1 kg E2 1 kg E2 1 kg - 370 - E2 E2 P410 IBC07 P410 IBC08 R001 P410 IBC04 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC06 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC08 P002 IBC06 MP2 MP2 RR8 MP2 MP2 MP14 B4 MP2 PP40 B4 PP40 B3 B4 B3 B4 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code 4.3 (12) L10BN(+) SGAN Vehicle for Transport category tank Special (Tunnel carriage provisions restriction code) 4.3.5, 6.8.4 9.1.1.2 1.1.3.6 (8.6) (13) (14) (15) 1 (E) 1 (E) 1 (E) TU1 TE5 TT3 AT 1 TM2 (B/E) AT 2 (D/E) 1 (E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V1 (17) 5.3.2.3 (18) CV23 (19) S2 S20 (20) V1 CV23 S20 (1) (2) 1411 LITHIUM ALUMINIUM HYDRIDE, ETHEREAL 1413 LITHIUM BOROHYDRIDE V1 CV23 S20 1414 LITHIUM HYDRIDE V1 CV23 S20 V1 CV23 V1 CV23 CV23 423 CV23 423 AT 2 (D/E) V1 SGAN AT 3 (E) V1 1 (E) 1 (B/E) 1 (B/E) 1 (B/E) 1 (B/E) V1 L10BN(+) L10BN(+) L10CH(+) L10BN(+) TU1 TE5 TT3 TM2 TU1 TE5 TT3 TM2 TU1 TE5 TT3 TM2 TU2 TU14 TE5 TE21 TT3 TM2 TU1 TE5 TT3 TM2 SGAN AT AT AT AT AT AT SGAN AT SGAN AT SGAN AT SGAN AT SGAV TU3 AT SGAN TU3 AT AT SGAV TU3 AT SGAN TU3 AT SGAN TU3 AT SGAN TU3 AT 1 (E) 1 (E) 1 (B/E) 2 (D/E) 1 (E) 1 (E) 3 (E) 1 (E) 2 (D/E) 3 (E) Name and description 8.5 SGAN L10BN(+) Loading, unloading and handling 7.5.11 Hazard UN identifi- No. Operation cation No. VV5 X423 423 S20 S20 3.1.2 1415 LITHIUM 1417 LITHIUM SILICON 1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER 1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER 1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER 1419 MAGNESIUM ALUMINIUM PHOSPHIDE 1420 POTASSIUM METAL ALLOYS, LIQUID 1421 ALKALI METAL ALLOY, LIQUID, N.O.S. 1422 POTASSIUM SODIUM ALLOYS, LIQUID 1423 RUBIDIUM V1 CV23 CV28 CV23 S20 X323 V1 CV23 S20 X323 V1 CV23 S20 X323 V1 CV23 S20 X423 V1 CV23 S20 1426 SODIUM BOROHYDRIDE V1 CV23 S20 1427 SODIUM HYDRIDE V1 CV23 S20 V1 X423 48 V1 1428 SODIUM 1431 SODIUM METHYLATE CV23 CV28 CV23 CV28 CV23 S20 1432 SODIUM PHOSPHIDE S20 1433 STANNIC PHOSPHIDES V1 CV23 S20 V1 CV23 423 CV23 423 V1 V1 V1 2 (E) 3 (E) VV5 VV5 VV8 2 (E) 2 (E) 3 (E) V11 2 (E) 2 (E) 2 (E) V11 V11 423 1437 ZIRCONIUM HYDRIDE CV24 50 1438 ALUMINIUM NITRATE CV24 50 1439 AMMONIUM DICHROMATE 50 1442 AMMONIUM PERCHLORATE 1444 AMMONIUM PERSULPHATE CV24 VV8 CV24 50 CV24 CV28 CV24 CV28 CV24 CV28 56 V11 - 371 - 1436 ZINC POWDER or ZINC DUST 1436 ZINC POWDER or ZINC DUST 1436 ZINC POWDER or ZINC DUST 40 VV8 V11 1435 ZINC ASHES S23 56 S23 56 1445 BARIUM CHLORATE, SOLID 1446 BARIUM NITRATE 1447 BARIUM PERCHLORATE, SOLID Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1448 BARIUM PERMANGANATE (3a) 5.1 (3b) OT2 (4) II (6) (7a) 1 kg (7b) E2 1449 BARIUM PEROXIDE 5.1 OT2 II 1 kg E2 1450 BROMATES, INORGANIC, N.O.S. 1451 CAESIUM NITRATE 5.1 O2 II (5) 5.1 +6.1 5.1 +6.1 5.1 1 kg E2 1452 CALCIUM CHLORATE 1453 CALCIUM CHLORITE 1454 CALCIUM NITRATE 5.1 5.1 5.1 5.1 O2 O2 O2 O2 III II II III 274 350 5.1 5 kg 5.1 1 kg 5.1 5.1 1 kg 208 5 kg E1 E2 E2 E1 1455 CALCIUM PERCHLORATE 5.1 O2 II 5.1 1 kg E2 1456 CALCIUM PERMANGANATE 1457 CALCIUM PEROXIDE 5.1 O2 II 5.1 1 kg E2 5.1 O2 II 5.1 1 kg E2 5.1 O2 II 5.1 1 kg E2 1458 CHLORATE AND BORATE MIXTURE 1458 CHLORATE AND BORATE MIXTURE 1459 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID 1459 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID 1461 CHLORATES, INORGANIC, N.O.S. 1462 CHLORITES, INORGANIC, N.O.S. 5.1 5.1 5.1 O2 O2 O2 III II III 5.1 5.1 O2 II 5.1 5.1 O2 II 5.1 1463 CHROMIUM TRIOXIDE, ANHYDROUS 5.1 OTC II 1465 DIDYMIUM NITRATE 5.1 5.1 +6.1 +8 5.1 1466 FERRIC NITRATE 1467 GUANIDINE NITRATE 1469 LEAD NITRATE 1470 LEAD PERCHLORATE, SOLID 1471 LITHIUM HYPOCHLORITE, DRY or LITHIUM HYPOCHLORITE MIXTURE 1471 LITHIUM HYPOCHLORITE, DRY or LITHIUM HYPOCHLORITE MIXTURE 5.1 5.1 5.1 O2 O2 OT2 III III III II 5.1 OT2 II 5.1 O2 II 5.1 O2 III 1 kg 5.1 5.1 O2 5 kg 5 kg 274 351 274 352 509 510 1 kg E2 1 kg E2 5 kg 5.1 +6.1 5.1 +6.1 5.1 1 kg 5.1 E1 E2 5 kg 5.1 E2 1 kg 5 kg 5.1 E1 E1 E1 E1 E2 1 kg E2 1 kg E2 5 kg E1 1472 LITHIUM PEROXIDE 5.1 O2 II 5.1 1 kg E2 1473 MAGNESIUM BROMATE 5.1 O2 II 5.1 1 kg E2 - 372 - Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 (8) P002 IBC06 P002 IBC06 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC06 P002 IBC06 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC06 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC06 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC08 (9a) Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP2 4.2.5.2 7.3.2 (10) T3 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 BK1 BK2 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T1 TP33 MP2 T3 TP33 MP2 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 TP33 MP10 T1 TP33 MP10 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 (11) TP33 B4 B3 B4 B4 B3 B4 B3 B4 B3 B4 B3 B3 B3 B4 MP10 B4 B3 B4 Copyright © United Nations, 2010. All rights reserved ADR tank Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 2 (E) AT 2 (E) AT 2 (E) AT 3 (E) Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) SGAN (13) TU3 SGAN TU3 SGAV TU3 SGAV TU3 SGAV TU3 AT SGAN TU3 AT SGAV TU3 AT SGAV TU3 AT SGAN TU3 AT SGAN TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT 2 (E) SGAV TU3 AT 3 (E) SGAV TU3 AT SGAN TU3 AT 2 (E) 2 (E) SGAN TU3 AT 2 (E) SGAV TU3 AT 3 (E) SGAV TU3 AT SGAV TU3 SGAN Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V11 (17) Loading, unloading and handling 7.5.11 2 (E) 2 (E) 3 (E) V11 2 (E) 2 (E) 2 (E) 2 (E) 3 (E) V11 8.5 5.3.2.3 (19) (20) 56 Name and description 3.1.2 VV8 (18) CV24 CV28 CV24 CV28 CV24 VV8 CV24 50 1450 BROMATES, INORGANIC, N.O.S. 1451 CAESIUM NITRATE VV8 CV24 50 1452 CALCIUM CHLORATE CV24 50 1453 CALCIUM CHLORITE VV8 CV24 50 1454 CALCIUM NITRATE VV8 CV24 50 1455 CALCIUM PERCHLORATE 1456 CALCIUM PERMANGANATE 1457 CALCIUM PEROXIDE V11 V11 Hazard UN identifi- No. Operation cation No. V11 S23 (1) (2) 1448 BARIUM PERMANGANATE 56 1449 BARIUM PEROXIDE 50 V11 CV24 50 V11 CV24 50 VV8 CV24 50 VV8 CV24 50 VV8 CV24 50 VV8 CV24 50 VV8 CV24 50 V11 CV24 50 V11 CV24 CV28 568 1463 CHROMIUM TRIOXIDE, ANHYDROUS VV8 CV24 50 1465 DIDYMIUM NITRATE 3 (E) VV8 CV24 50 1466 FERRIC NITRATE AT 3 (E) VV8 CV24 50 1467 GUANIDINE NITRATE TU3 AT 1469 LEAD NITRATE TU3 AT 56 SGAN TU3 AT CV24 CV28 CV24 CV28 CV24 56 SGAN 2 (E) 2 (E) 2 (E) SGAV TU3 AT 3 (E) 1470 LEAD PERCHLORATE, SOLID 1471 LITHIUM HYPOCHLORITE, DRY or LITHIUM HYPOCHLORITE MIXTURE 1471 LITHIUM HYPOCHLORITE, DRY or LITHIUM HYPOCHLORITE MIXTURE SGAN TU3 AT SGAV TU3 AT 2 (E) 2 (E) V11 V11 V11 V11 V11 V11 V11 V11 VV8 - 373 - S23 50 1458 CHLORATE AND BORATE MIXTURE 1458 CHLORATE AND BORATE MIXTURE 1459 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID 1459 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID 1461 CHLORATES, INORGANIC, N.O.S. 1462 CHLORITES, INORGANIC, N.O.S. CV24 50 CV24 50 1472 LITHIUM PEROXIDE CV24 50 1473 MAGNESIUM BROMATE Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 (1) (2) 1474 MAGNESIUM NITRATE 1475 MAGNESIUM PERCHLORATE 1476 MAGNESIUM PEROXIDE 1477 NITRATES, INORGANIC, N.O.S. 1477 NITRATES, INORGANIC, N.O.S. Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 5.1 (3b) O2 (4) III (5) 5.1 (6) 332 (7a) 5 kg (7b) E1 5.1 O2 II 5.1 1 kg E2 5.1 O2 II 5.1 1 kg E2 5.1 O2 II 5.1 1 kg E2 5.1 O2 III 5.1 511 511 5 kg E1 1479 OXIDIZING SOLID, N.O.S. 5.1 O2 I 5.1 274 0 E0 1479 OXIDIZING SOLID, N.O.S. 5.1 O2 II 5.1 274 1 kg E2 1479 OXIDIZING SOLID, N.O.S. 1481 PERCHLORATES, INORGANIC, N.O.S. 1481 PERCHLORATES, INORGANIC, N.O.S. 1482 PERMANGANATES, INORGANIC, N.O.S. 1482 PERMANGANATES, INORGANIC, N.O.S. 1483 PEROXIDES, INORGANIC, N.O.S. 1483 PEROXIDES, INORGANIC, N.O.S. 1484 POTASSIUM BROMATE 1485 POTASSIUM CHLORATE 1486 POTASSIUM NITRATE 1487 POTASSIUM NITRATE AND SODIUM NITRITE MIXTURE 1488 POTASSIUM NITRITE 1489 POTASSIUM PERCHLORATE 1490 POTASSIUM PERMANGANATE 1491 POTASSIUM PEROXIDE 5.1 O2 III 5.1 274 5 kg E1 5.1 O2 II 5.1 1 kg E2 5.1 O2 III 5.1 5 kg E1 5.1 O2 II 5.1 5.1 O2 III 5.1 274 353 274 353 1 kg E2 5 kg E1 5.1 O2 II 5.1 1 kg E2 5.1 O2 III 5.1 5 kg E1 5.1 5.1 5.1 5.1 5.1 O2 O2 O2 O2 O2 II II III II II 5.1 1 kg 5.1 1 kg 5.1 5.1 5 kg 607 5.1 1 kg 1 kg E2 E2 E1 E2 E2 5.1 O2 II 5.1 1 kg E2 5.1 O2 II 5.1 1 kg E2 5.1 O2 I 5.1 0 E0 1492 POTASSIUM PERSULPHATE 5.1 O2 III 5.1 5 kg E1 1493 SILVER NITRATE 5.1 1494 SODIUM BROMATE 1495 SODIUM CHLORATE 1496 SODIUM CHLORITE 5.1 5.1 5.1 O2 O2 O2 O2 II II II II 5.1 1 kg 5.1 1 kg 5.1 1 kg 5.1 1 kg - 374 - E2 E2 E2 E2 Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 (8) P002 IBC08 LP02 R001 P002 IBC06 P002 IBC06 P002 IBC08 P002 IBC08 LP02 R001 P503 IBC05 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P002 IBC06 P002 IBC08 P503 IBC06 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 (9a) Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP10 4.2.5.2 7.3.2 (10) T1 BK1 BK2 MP2 T3 TP33 MP2 T3 TP33 MP10 T3 TP33 MP10 T1 TP33 MP2 T3 TP33 MP2 T1 TP33 MP2 T3 TP33 MP2 T1 TP33 MP2 T3 TP33 MP2 T1 TP33 MP2 T3 TP33 MP2 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 BK1 BK2 TP33 MP10 T3 TP33 MP10 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 TP33 MP10 T3 TP33 MP2 T3 TP33 MP2 T3 BK1 BK2 T3 TP33 B3 (11) TP33 B4 B3 MP2 B4 B3 B3 B3 B3 B4 B4 B3 B4 B4 B4 MP2 B3 B4 B4 B4 MP2 B4 TP33 Copyright © United Nations, 2010. All rights reserved ADR tank Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 3 (E) Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) SGAV (13) TU3 SGAV TU3 AT SGAN TU3 AT SGAN TU3 AT SGAV TU3 AT 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) VV8 2 (E) 2 (E) 2 (E) 3 (E) V11 VV8 1 (E) 2 (E) 3 (E) V10 CV24 V11 CV24 50 1479 OXIDIZING SOLID, N.O.S. CV24 50 1479 OXIDIZING SOLID, N.O.S. 2 (E) 3 (E) V11 1481 PERCHLORATES, INORGANIC, N.O.S. 1481 PERCHLORATES, INORGANIC, N.O.S. 2 (E) 3 (E) V11 2 (E) 3 (E) V11 2 (E) 2 (E) 3 (E) V11 V11 AT SGAN TU3 AT SGAV TU3 AT SGAV TU3 AT SGAN TU3 AT SGAN TU3 AT SGAN TU3 AT SGAN TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT 2 (E) SGAV TU3 AT SGAV TU3 AT SGAN TU3 AT AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAN TU3 AT Name and description Bulk TU3 TU3 Hazard UN identifi- No. Operation cation No. Packages SGAN SGAV Special provisions for carriage 8.5 5.3.2.3 (18) CV24 (19) (20) 50 CV24 S23 50 V11 CV24 50 V11 CV24 50 CV24 50 VV8 S20 3.1.2 (1) (2) 1474 MAGNESIUM NITRATE 1475 MAGNESIUM PERCHLORATE 1476 MAGNESIUM PEROXIDE 1477 NITRATES, INORGANIC, N.O.S. 1477 NITRATES, INORGANIC, N.O.S. 1479 OXIDIZING SOLID, N.O.S. VV8 CV24 S23 50 VV8 CV24 S23 50 CV24 50 CV24 50 CV24 50 CV24 50 VV8 CV24 50 1484 POTASSIUM BROMATE VV8 CV24 50 1485 POTASSIUM CHLORATE VV8 CV24 50 1486 POTASSIUM NITRATE V11 VV8 CV24 50 2 (E) 2 (E) 2 (E) 1 (E) 3 (E) V11 VV8 CV24 50 1487 POTASSIUM NITRATE AND SODIUM NITRITE MIXTURE 1488 POTASSIUM NITRITE V11 VV8 CV24 2 (E) 2 (E) 2 (E) 2 (E) V11 V11 CV24 V10 CV24 S23 50 50 S20 1482 PERMANGANATES, INORGANIC, N.O.S. 1482 PERMANGANATES, INORGANIC, N.O.S. 1483 PEROXIDES, INORGANIC, N.O.S. 1483 PEROXIDES, INORGANIC, N.O.S. 1489 POTASSIUM PERCHLORATE 1490 POTASSIUM PERMANGANATE 1491 POTASSIUM PEROXIDE VV8 CV24 50 1492 POTASSIUM PERSULPHATE V11 VV8 CV24 50 1493 SILVER NITRATE V11 VV8 CV24 50 1494 SODIUM BROMATE V11 VV8 CV24 50 1495 SODIUM CHLORATE CV24 50 1496 SODIUM CHLORITE - 375 - Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 (1) (2) 1498 SODIUM NITRATE Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 5.1 (3b) O2 (4) III (5) 5.1 (6) (7a) 5 kg (7b) E1 1499 SODIUM NITRATE AND POTASSIUM NITRATE MIXTURE 5.1 1500 SODIUM NITRITE 5.1 O2 OT2 III III 5.1 5 kg 5.1 +6.1 5 kg E1 E1 1502 SODIUM PERCHLORATE 5.1 O2 II 5.1 1 kg E2 1503 SODIUM PERMANGANATE 5.1 O2 II 5.1 1 kg E2 1504 SODIUM PEROXIDE 5.1 O2 I 5.1 0 E0 1505 SODIUM PERSULPHATE 5.1 O2 III 5.1 5 kg E1 1506 STRONTIUM CHLORATE 1507 STRONTIUM NITRATE 5.1 5.1 O2 O2 II III 5.1 1 kg 5.1 5 kg E2 E1 1508 STRONTIUM PERCHLORATE 1509 STRONTIUM PEROXIDE 5.1 O2 II 5.1 1 kg E2 5.1 O2 II 5.1 1 kg E2 1510 TETRANITROMETHANE 6.1 TO1 I 6.1 +5.1 0 E0 1511 UREA HYDROGEN PEROXIDE 5.1 OC2 III 5.1 +8 5 kg E1 1512 ZINC AMMONIUM NITRITE 5.1 5.1 1 kg 354 609 Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 (8) P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 R001 P002 IBC06 P002 IBC06 P503 IBC05 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC06 P602 (9a) Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) T1 BK1 BK2 4.2.5.3 MP10 T1 BK1 BK2 TP33 MP10 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 TP33 MP2 T3 TP33 MP10 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T1 TP33 MP10 T3 TP33 MP2 T3 TP33 MP10 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 (9b) MP10 B3 B3 (11) TP33 B3 MP2 B3 B4 B3 MP8 MP17 1515 ZINC PERMANGANATE 5.1 O2 II 5.1 1 kg E2 1516 ZINC PEROXIDE 5.1 O2 II 5.1 1 kg E2 1517 ZIRCONIUM PICRAMATE, WETTED with not less than 20% water, by mass 4.1 D I 4.1 0 E0 P002 IBC08 R001 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC06 P002 IBC06 P406 1541 ACETONE CYANOHYDRIN, STABILIZED 6.1 T1 I 6.1 354 0 E0 P602 MP8 MP17 T20 TP2 TP37 1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. 1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. 1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. 6.1 T2 I 6.1 43 274 0 E5 P002 IBC07 MP18 T6 TP33 6.1 T2 II 6.1 43 274 500 g E4 P002 IBC08 MP10 T3 TP33 43 274 5 kg MP10 T1 TP33 1545 ALLYL ISOTHIOCYANATE, STABILIZED 6.1 TF1 II 6.1 +3 100 ml E4 MP15 T7 TP2 1546 AMMONIUM ARSENATE 6.1 T5 II 6.1 500 g E4 MP10 T3 TP33 MP15 T7 TP2 1513 ZINC CHLORATE 1514 ZINC NITRATE 1547 ANILINE 5.1 5.1 6.1 6.1 O2 O2 O2 T2 T1 II II II III II 5.1 1 kg 5.1 6.1 6.1 1 kg 279 - 376 - 100 ml E2 E2 E2 E1 E4 P002 IBC08 LP02 R001 P001 IBC02 P002 IBC08 P001 IBC02 B3 B4 B4 B4 PP26 MP2 B4 B3 B4 Copyright © United Nations, 2010. All rights reserved ADR tank Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 3 (E) Special provisions for carriage Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) SGAV (13) TU3 SGAV TU3 AT 3 (E) SGAN TU3 AT 3 (E) SGAV TU3 AT V11 SGAN TU3 AT 2 (E) 2 (E) 1 (E) 3 (E) 2 (E) 3 (E) V11 2 (E) 2 (E) 1 (B/D) V11 SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAN TU3 AT L10CH TU14 TU15 TE19 TE21 AT SGAN TU3 AT 3 (E) SGAN TU3 AT SGAV TU3 AT SGAN TU3 AT SGAN TU3 AT SGAN TU3 AT 2 (E) 2 (E) 2 (E) 2 (E) 2 (E) 1 (B) Hazard UN identifi- No. Operation cation No. Name and description Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) VV8 (18) CV24 VV8 CV24 50 1499 SODIUM NITRATE AND POTASSIUM NITRATE MIXTURE CV24 CV28 56 1500 SODIUM NITRITE 50 1502 SODIUM PERCHLORATE 50 1503 SODIUM PERMANGANATE VV8 CV24 8.5 5.3.2.3 (19) (20) 50 S23 V11 CV24 CV24 V10 S20 3.1.2 (1) (2) 1498 SODIUM NITRATE 1504 SODIUM PEROXIDE VV8 CV24 50 1505 SODIUM PERSULPHATE VV8 CV24 50 1506 STRONTIUM CHLORATE VV8 CV24 50 1507 STRONTIUM NITRATE VV8 CV24 50 50 1508 STRONTIUM PERCHLORATE 1509 STRONTIUM PEROXIDE 665 1510 TETRANITROMETHANE 58 1511 UREA HYDROGEN PEROXIDE CV24 50 1512 ZINC AMMONIUM NITRITE CV24 50 1513 ZINC CHLORATE V11 CV24 50 1514 ZINC NITRATE V11 CV24 50 1515 ZINC PERMANGANATE V11 CV24 50 1516 ZINC PEROXIDE V11 CV24 CV1 CV13 CV28 CV24 V11 V11 S23 VV8 S9 S14 S14 L10CH TU14 TU15 TE19 TE21 AT 1 (C/D) S10AH TU15 TE19 AT 1 (C/E) V10 SGAH L4BH TU15 TE19 AT 2 (D/E) V11 SGAH L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 FL 2 (D/E) SGAH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (D/E) VV9 V11 - 377 - 1517 ZIRCONIUM PICRAMATE, WETTED with not less than 20% water, by mass CV1 CV13 CV28 S9 S14 669 1541 ACETONE CYANOHYDRIN, STABILIZED CV1 CV13 CV28 CV13 CV28 S9 S14 66 S9 S19 60 CV13 CV28 S9 60 1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. 1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. 1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. CV13 CV28 S2 S9 S19 639 1545 ALLYL ISOTHIOCYANATE, STABILIZED CV13 CV28 CV13 CV28 S9 S19 60 1546 AMMONIUM ARSENATE S9 S19 60 1547 ANILINE Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1548 ANILINE HYDROCHLORIDE (3a) 6.1 (3b) T2 (4) III (5) 6.1 (6) (7a) 5 kg (7b) E1 1549 ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S. 6.1 1550 ANTIMONY LACTATE 6.1 T5 T5 III 45 274 512 6.1 5 kg 5 kg 6.1 T4 I 6.1 0 E5 1554 ARSENIC ACID, SOLID 6.1 T5 II 6.1 500 g E4 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1557 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1557 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1557 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1558 ARSENIC 1559 ARSENIC PENTOXIDE II 5 kg E1 1553 ARSENIC ACID, LIQUID T5 6.1 E1 6.1 6.1 III 6.1 1551 ANTIMONY POTASSIUM TARTRATE 1555 ARSENIC BROMIDE T5 III 6.1 500 g E1 E4 Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 (8) P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P001 P002 IBC08 P002 IBC08 P001 (9a) Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP10 4.2.5.2 7.3.2 (10) T1 MP10 T1 TP33 MP10 T1 TP33 MP10 T1 TP33 MP8 MP17 T20 TP2 TP7 MP10 T3 TP33 MP10 T3 TP33 MP8 MP17 T14 TP2 TP27 (11) TP33 B3 B3 B3 B3 B4 B4 6.1 T4 I 6.1 43 274 0 E5 6.1 T4 II 6.1 43 274 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 6.1 T4 III 6.1 43 274 5L E1 P001 IBC03 LP01 R001 MP19 T7 TP2 TP28 6.1 T5 I 6.1 43 274 0 E5 P002 IBC07 MP18 T6 TP33 6.1 T5 II 6.1 43 274 500 g E4 P002 IBC08 MP10 T3 TP33 43 274 5 kg MP10 T1 TP33 MP10 T3 TP33 MP10 T3 TP33 MP8 MP17 T14 TP2 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T1 TP33 6.1 6.1 6.1 T5 T5 T5 III II II 6.1 6.1 500 g 6.1 500 g E1 E4 E4 1560 ARSENIC TRICHLORIDE 6.1 T4 I 6.1 0 E5 1561 ARSENIC TRIOXIDE 6.1 T5 II 6.1 500 g E4 1562 ARSENICAL DUST Packaging 6.1 1564 BARIUM COMPOUND, N.O.S. 6.1 1564 BARIUM COMPOUND, N.O.S. 6.1 T5 T5 T5 II II III 6.1 6.1 6.1 500 g 177 274 513 587 177 274 513 587 - 378 - 500 g 5 kg E4 E4 E1 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P602 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 LP02 R001 B4 B3 B4 B4 B4 B4 B4 B3 Copyright © United Nations, 2010. All rights reserved ADR tank Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 2 (E) Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) SGAH (13) TU15 TE19 SGAH L4BH TU15 TE19 AT SGAH L4BH TU15 TE19 SGAH L4BH Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) (17) VV9 2 (E) AT TU15 TE19 L10CH SGAH L4BH SGAH L4BH L10CH Loading, unloading and handling 7.5.11 Hazard UN identifi- No. Operation cation No. Name and description 8.5 5.3.2.3 (18) CV13 CV28 (19) S9 (20) 60 VV9 CV13 CV28 S9 60 1549 ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S. 2 (E) VV9 CV13 CV28 S9 60 1550 ANTIMONY LACTATE AT 2 (E) VV9 CV13 CV28 S9 60 1551 ANTIMONY POTASSIUM TARTRATE TU14 TU15 TE19 TE21 AT 1 (C/E) S9 S14 66 1553 ARSENIC ACID, LIQUID TU15 TE19 AT S9 S19 60 1554 ARSENIC ACID, SOLID TU15 TE19 AT S9 S19 60 1555 ARSENIC BROMIDE TU14 TU15 TE19 TE21 AT 2 (D/E) 2 (D/E) 1 (C/E) CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 S9 S14 66 L4BH TU15 TE19 AT 2 (D/E) CV13 CV28 S9 S19 60 L4BH TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 S10AH L10CH TU15 TE19 AT 1 (C/E) V10 CV1 CV13 CV28 S9 S14 66 SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV13 CV28 S9 S19 60 SGAH L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 SGAH TU15 TE19 AT V11 60 TU15 TE19 AT S9 S19 60 1559 ARSENIC PENTOXIDE L10CH TU14 TU15 TE19 TE21 AT S9 S14 66 1560 ARSENIC TRICHLORIDE SGAH TU15 TE19 AT V11 S9 S19 60 1561 ARSENIC TRIOXIDE SGAH TU15 TE19 AT S9 S19 60 1562 ARSENICAL DUST SGAH L4BH TU15 TE19 AT 2 (D/E) 2 (D/E) 2 (D/E) CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 SGAH 2 (D/E) 2 (D/E) 1 (C/E) 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1557 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1557 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1557 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1558 ARSENIC S9 S19 60 1564 BARIUM COMPOUND, N.O.S. SGAH L4BH TU15 TE19 AT CV13 CV28 S9 60 1564 BARIUM COMPOUND, N.O.S. 2 (E) V11 V11 VV9 V11 V11 V11 VV9 - 379 - 3.1.2 (1) (2) 1548 ANILINE HYDROCHLORIDE Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1565 BARIUM CYANIDE (3a) 6.1 (3b) T5 (4) I (5) 6.1 (6) (7a) 0 (7b) E5 (8) P002 IBC07 1566 BERYLLIUM COMPOUND, N.O.S. 1566 BERYLLIUM COMPOUND, N.O.S. 6.1 T5 II 6.1 274 514 274 514 500 g E4 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 P602 1567 BERYLLIUM POWDER 6.1 6.1 T5 TF3 III II 6.1 6.1 +4.1 6.1 +3 6.1 1569 BROMOACETONE 6.1 TF1 II 1570 BRUCINE 6.1 T2 I 1571 BARIUM AZIDE, WETTED with not less than 50% water, by mass 1572 CACODYLIC ACID 4.1 DT I 4.1 +6.1 6.1 T5 II 6.1 1573 CALCIUM ARSENATE 1574 CALCIUM ARSENATE AND CALCIUM ARSENITE MIXTURE, SOLID 1575 CALCIUM CYANIDE 1577 CHLORODINITROBENZENES, LIQUID 1578 CHLORONITROBENZENES, SOLID 1579 4-CHLORO-o-TOLUIDINE HYDROCHLORIDE, SOLID 1580 CHLOROPICRIN 1581 CHLOROPICRIN AND METHYL BROMIDE MIXTURE with more than 2% chloropicrin 1582 CHLOROPICRIN AND METHYL CHLORIDE MIXTURE 1583 CHLOROPICRIN MIXTURE, N.O.S. 1583 CHLOROPICRIN MIXTURE, N.O.S. 1583 CHLOROPICRIN MIXTURE, N.O.S. 1585 COPPER ACETOARSENITE 1586 COPPER ARSENITE 1587 COPPER CYANIDE 6.1 6.1 T5 T5 II II I 6.1 6.1 T1 II 6.1 6.1 T2 II 6.1 T2 III TP33 MP15 T20 TP2 T6 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 43 0 E5 P002 IBC07 MP18 568 0 E0 P406 MP2 500 g E4 P002 IBC08 P002 IBC08 P002 IBC08 500 g 500 g E4 E4 B4 B4 B4 0 E5 P002 IBC07 MP18 T6 TP33 279 100 ml E4 MP15 T7 TP2 279 500 g E4 MP10 T3 TP33 MP10 T1 TP33 MP8 MP17 T22 TP2 TP37 MP9 (M) T50 2.3 0 E0 P200 MP9 (M) T50 0 E5 P602 MP8 MP17 100 ml E4 MP15 5L E1 500 g E4 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC07 I 6.1 6.1 T1 II 6.1 6.1 T1 III 6.1 6.1 T5 II 6.1 6.1 5 kg 354 274 315 515 274 515 274 515 6.1 500 g 6.1 500 g E1 E4 E4 1588 CYANIDES, INORGANIC, SOLID, N.O.S. 6.1 T5 I 6.1 47 274 0 E5 1588 CYANIDES, INORGANIC, SOLID, N.O.S. 1588 CYANIDES, INORGANIC, SOLID, N.O.S. 6.1 T5 II 6.1 47 274 47 274 500 g E4 III T3 P200 T1 T5 MP10 B4 E0 6.1 6.1 TP33 0 2T II T1 2.3 2 T5 MP10 B3 E0 2T 6.1 TP33 0 2 II T3 E4 6.1 T1 T5 E4 MP10 6.1 (11) TP33 B4 P001 IBC02 P002 IBC08 P002 IBC08 LP02 R001 P601 6.1 6.1 I E1 4.2.5.3 (9b) MP18 4.2.5.2 7.3.2 (10) T6 0 6.1 T5 6.1 500 g 6.1 6.1 5 kg (9a) Portable tanks and bulk containers Instruc- Special tions provisions - 380 - 5 kg E1 P002 IBC08 P002 IBC08 LP02 R001 B4 B3 MP19 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 B4 B4 B4 B4 B3 Copyright © United Nations, 2010. All rights reserved ADR tank Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 1 (C/E) Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) S10AH (13) TU15 TE19 SGAH L4BH SGAH L4BH TU15 TE19 AT TU15 TE19 AT SGAH TU15 TE19 AT L4BH TU15 TE19 FL S10AH L10CH TU14 TU15 TE19 TE21 AT Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V10 (17) 2 (D/E) 2 (E) V11 2 (D/E) 2 (D/E) 1 (C/E) V11 Loading, unloading and handling 7.5.11 VV9 V10 1 (B) SGAH TU15 TE19 AT 2 (D/E) 2 (D/E) 2 (D/E) V11 SGAH TU15 TE19 AT SGAH TU15 TE19 AT S10AH TU15 TE19 AT 1 (C/E) V10 L4BH TU15 TE19 AT SGAH TU15 TE19 AT SGAH L4BH TU15 TE19 AT 2 (D/E) 2 (D/E) 2 (E) L15CH TU14 TU15 TE19 TE21 AT 1 (C/D) PxBH(M) TA4 TT9 AT 1 (C/D) PxBH(M) TA4 TT9 AT 1 (C/D) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (E) SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT S10AH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT V11 V11 V11 VV9 V12 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/E) V11 2 (D/E) 2 (E) V11 V11 V11 V10 VV9 - 381 - Hazard UN identifi- No. Operation cation No. Name and description 8.5 5.3.2.3 (18) CV1 CV13 CV28 CV13 CV28 CV13 CV28 (19) S9 S14 (20) 66 S9 S19 60 S9 60 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV28 S9 S19 64 1567 BERYLLIUM POWDER S2 S9 S19 63 1569 BROMOACETONE S9 S14 66 1570 BRUCINE (1) (2) 1565 BARIUM CYANIDE 1566 BERYLLIUM COMPOUND, N.O.S. 1566 BERYLLIUM COMPOUND, N.O.S. CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 60 1571 BARIUM AZIDE, WETTED with not less than 50% water, by mass 1572 CACODYLIC ACID S9 S19 60 1573 CALCIUM ARSENATE S9 S19 60 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 S9 S14 66 1574 CALCIUM ARSENATE AND CALCIUM ARSENITE MIXTURE, SOLID 1575 CALCIUM CYANIDE S9 S19 60 S9 S19 60 S9 60 CV1 CV13 CV28 CV9 CV10 CV36 S9 S14 66 1580 CHLOROPICRIN S14 26 CV9 CV10 CV36 CV1 CV13 CV28 CV13 CV28 CV13 CV28 S14 26 S9 S14 66 1581 CHLOROPICRIN AND METHYL BROMIDE MIXTURE with more than 2% chloropicrin 1582 CHLOROPICRIN AND METHYL CHLORIDE MIXTURE 1583 CHLOROPICRIN MIXTURE, N.O.S. S9 S19 60 S9 60 S9 S19 60 1585 COPPER ACETOARSENITE S9 S19 60 1586 COPPER ARSENITE S9 S19 60 1587 COPPER CYANIDE S9 S14 66 1588 CYANIDES, INORGANIC, SOLID, N.O.S. S9 S19 60 S9 60 1588 CYANIDES, INORGANIC, SOLID, N.O.S. 1588 CYANIDES, INORGANIC, SOLID, N.O.S. CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 S14 3.1.2 1577 CHLORODINITROBENZENES, LIQUID 1578 CHLORONITROBENZENES, SOLID 1579 4-CHLORO-o-TOLUIDINE HYDROCHLORIDE, SOLID 1583 CHLOROPICRIN MIXTURE, N.O.S. 1583 CHLOROPICRIN MIXTURE, N.O.S. Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1589 CYANOGEN CHLORIDE, STABILIZED (3a) 2 (3b) 2TC (4) (5) 2.3 +8 (6) (7a) 0 (7b) E0 (8) P200 1590 DICHLOROANILINES, LIQUID 1591 o-DICHLOROBENZENE 6.1 T1 II 6.1 279 100 ml E4 6.1 T1 III 6.1 279 5L E1 1593 DICHLOROMETHANE 6.1 T1 III 6.1 516 5L E1 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P602 1594 DIETHYL SULPHATE 6.1 T1 II 6.1 1595 DIMETHYL SULPHATE 6.1 TC1 I 6.1 +8 1596 DINITROANILINES 6.1 T2 II 6.1 1597 DINITROBENZENES, LIQUID 1597 DINITROBENZENES, LIQUID 1598 DINITRO-o-CRESOL 1599 DINITROPHENOL SOLUTION 1599 DINITROPHENOL SOLUTION 354 100 ml E4 0 E0 500 g E4 6.1 T1 II 6.1 100 ml E4 6.1 T1 III 6.1 5L E1 6.1 T2 II 6.1 500 g E4 43 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 6.1 T1 II 6.1 100 ml E4 6.1 T1 III 6.1 5L E1 1600 DINITROTOLUENES, MOLTEN 1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 6.1 T1 II 6.1 0 E0 6.1 T2 I 6.1 274 0 E5 P002 IBC07 1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 6.1 T2 II 6.1 274 500 g E4 P002 IBC08 P002 IBC08 LP02 R001 P001 6.1 T2 III 6.1 274 5 kg E1 (9a) 4.2.5.2 7.3.2 (10) 4.2.5.3 MP15 T7 TP2 MP19 T4 TP1 MP19 T7 TP2 MP15 T7 TP2 MP8 MP17 T20 TP2 TP35 MP10 T3 TP33 MP15 T7 TP2 MP19 T7 TP2 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP1 T7 TP3 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP15 T7 TP2 MP15 T7 TP2 MP8 MP17 T20 TP2 TP37 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP15 T7 TP2 (9b) MP9 B4 B4 B4 B3 T1 I 6.1 274 0 E5 6.1 T1 II 6.1 274 100 ml E4 P001 IBC02 MP15 6.1 T1 III 6.1 274 5L E1 MP19 6.1 TF1 II 100 ml E4 8 CF1 II 1L E2 1605 ETHYLENE DIBROMIDE 6.1 T1 I 6.1 +3 8 +3 6.1 0 E0 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 P602 1606 FERRIC ARSENATE 6.1 T5 II 6.1 500 g E4 1603 ETHYL BROMOACETATE 1604 ETHYLENEDIAMINE 1607 FERRIC ARSENITE 1608 FERROUS ARSENATE 1611 HEXAETHYL TETRAPHOSPHATE 6.1 6.1 6.1 T5 T5 T1 II II II 354 6.1 500 g 6.1 500 g 6.1 100 ml - 382 - E4 E4 E4 P002 IBC08 P002 IBC08 P002 IBC08 P001 IBC02 (11) B8 6.1 1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. Portable tanks and bulk containers Instruc- Special tions provisions MP8 MP17 B4 B4 B4 Copyright © United Nations, 2010. All rights reserved ADR tank Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 1 (D) Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) L4BH TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT 2 (D/E) 1 (C/D) SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT L4BH TU15 TE19 AT SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT S10AH L10CH TU15 TE19 AT SGAH L4BH SGAH L4BH TU15 TE19 AT TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 FL 2 (D/E) 2 (D/E) 1 (C/D) L4BN FL L10CH TU14 TU15 TE19 TE21 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (E) 2 (D/E) 2 (D/E) 2 (E) 2 (D/E) 2 (D/E) 2 (E) 0 (D/E) 1 (C/E) 2 (D/E) 2 (E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) (17) Loading, unloading and handling 7.5.11 V12 V12 V11 V12 V11 V12 V10 V11 VV9 5.3.2.3 (19) S14 (20) S9 S19 60 S9 60 1590 DICHLOROANILINES, LIQUID 1591 o-DICHLOROBENZENE CV13 CV28 S9 60 1593 DICHLOROMETHANE CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 60 1594 DIETHYL SULPHATE S9 S14 668 1595 DIMETHYL SULPHATE S9 S19 60 1596 DINITROANILINES S9 S19 60 S9 60 1597 DINITROBENZENES, LIQUID 1597 DINITROBENZENES, LIQUID CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 60 1598 DINITRO-o-CRESOL S9 S19 60 S9 60 1599 DINITROPHENOL SOLUTION 1599 DINITROPHENOL SOLUTION CV13 S9 S19 60 CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 S14 66 S9 S19 60 S9 60 S9 S14 66 S9 S19 60 CV13 CV28 S9 60 CV13 CV28 S2 S9 S19 63 1603 ETHYL BROMOACETATE S2 83 1604 ETHYLENEDIAMINE S9 S14 66 1605 ETHYLENE DIBROMIDE S9 S19 60 1606 FERRIC ARSENATE S9 S19 60 1607 FERRIC ARSENITE S9 S19 60 1608 FERROUS ARSENATE S9 S19 60 1611 HEXAETHYL TETRAPHOSPHATE (18) CV9 CV10 CV36 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 V11 V11 V11 - 383 - Name and description 8.5 CV1 CV13 CV28 CV13 CV28 V12 Hazard UN identifi- No. Operation cation No. 3.1.2 (1) (2) 1589 CYANOGEN CHLORIDE, STABILIZED 1600 DINITROTOLUENES, MOLTEN 1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 (1) (2) 1612 HEXAETHYL TETRAPHOSPHATE AND COMPRESSED GAS MIXTURE 1613 HYDROCYANIC ACID, AQUEOUS SOLUTION (HYDROGEN CYANIDE, AQUEOUS SOLUTION) with not more than 20% hydrogen cyanide 1614 HYDROGEN CYANIDE, STABILIZED, containing less than 3% water and absorbed in a porous inert material 1616 LEAD ACETATE 1617 LEAD ARSENATES 1618 LEAD ARSENITES 1620 LEAD CYANIDE 1621 LONDON PURPLE 1622 MAGNESIUM ARSENATE 1623 MERCURIC ARSENATE 1624 MERCURIC CHLORIDE 1625 MERCURIC NITRATE Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 2 (3b) 1T (4) (5) 2.3 (6) (7a) 0 (7b) E0 (8) P200 6.1 TF1 I 6.1 +3 48 0 E5 P601 6.1 TF1 I 6.1 +3 603 0 E5 P099 P601 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 T5 T5 T5 T5 T5 T5 T5 T5 T5 III II II II II II II II II 6.1 5 kg 6.1 500 g 6.1 500 g 6.1 6.1 500 g 43 6.1 500 g 500 g 6.1 500 g 6.1 500 g 6.1 500 g E1 E4 E4 E4 E4 E4 E4 E4 E4 6.1 T5 I 6.1 0 E5 1627 MERCUROUS NITRATE 6.1 T5 II 6.1 500 g E4 1630 MERCURY AMMONIUM CHLORIDE 1631 MERCURY BENZOATE 1634 MERCURY BROMIDES 1636 MERCURY CYANIDE 1637 MERCURY GLUCONATE 1638 MERCURY IODIDE 1639 MERCURY NUCLEATE 1640 MERCURY OLEATE 1641 MERCURY OXIDE 1642 MERCURY OXYCYANIDE, DESENSITIZED 1643 MERCURY POTASSIUM IODIDE 1644 MERCURY SALICYLATE 1645 MERCURY SULPHATE 1646 MERCURY THIOCYANATE 1647 METHYL BROMIDE AND ETHYLENE DIBROMIDE MIXTURE, LIQUID Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 1626 MERCURIC POTASSIUM CYANIDE 1629 MERCURY ACETATE Packaging 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 T5 T5 T5 T5 T5 T5 T5 T5 T5 T5 T5 T5 T5 T5 T5 T1 II II II II II II II II II II II II II II II I 6.1 500 g 6.1 500 g 6.1 500 g 6.1 500 g 6.1 500 g 6.1 500 g 6.1 500 g 6.1 500 g 6.1 500 g 6.1 500 g 6.1 500 g 6.1 500 g 6.1 500 g 6.1 500 g 6.1 6.1 500 g 354 - 384 - 0 E4 E4 E4 E4 E4 E4 E4 E4 E4 E4 E4 E4 E4 E4 E4 E0 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC07 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P602 (9a) Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) (M) 4.2.5.3 T14 TP2 MP10 T1 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP8 MP17 T20 TP2 (9b) MP9 MP8 MP17 (11) MP2 RR10 B3 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) CxBH(M) (13) TA4 TT9 L15DH(+) TU14 TU15 TE19 TE21 Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 1 (C/D) FL Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) (17) Loading, unloading and handling 7.5.11 Hazard UN identifi- No. Operation cation No. Name and description 8.5 5.3.2.3 (18) CV9 CV10 CV36 (19) S14 (20) 26 0 (C/D) CV1 CV13 CV28 S2 S9 S14 663 0 (D) CV1 CV13 CV28 S2 S9 S10 S14 CV13 CV28 S9 60 (1) (2) 1612 HEXAETHYL TETRAPHOSPHATE AND COMPRESSED GAS MIXTURE 1613 HYDROCYANIC ACID, AQUEOUS SOLUTION (HYDROGEN CYANIDE, AQUEOUS SOLUTION) with not more than 20% hydrogen cyanide 1614 HYDROGEN CYANIDE, STABILIZED, containing less than 3% water and absorbed in a porous inert material 1616 LEAD ACETATE CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 S9 S19 60 1617 LEAD ARSENATES S9 S19 60 1618 LEAD ARSENITES S9 S19 60 1620 LEAD CYANIDE S9 S19 60 1621 LONDON PURPLE S9 S19 60 1622 MAGNESIUM ARSENATE S9 S19 60 1623 MERCURIC ARSENATE S9 S19 60 1624 MERCURIC CHLORIDE S9 S19 60 1625 MERCURIC NITRATE S9 S14 66 1626 MERCURIC POTASSIUM CYANIDE S9 S19 60 1627 MERCUROUS NITRATE S9 S19 60 1629 MERCURY ACETATE S9 S19 60 S9 S19 60 1630 MERCURY AMMONIUM CHLORIDE 1631 MERCURY BENZOATE S9 S19 60 1634 MERCURY BROMIDES S9 S19 60 1636 MERCURY CYANIDE S9 S19 60 1637 MERCURY GLUCONATE S9 S19 60 1638 MERCURY IODIDE S9 S19 60 1639 MERCURY NUCLEATE S9 S19 60 1640 MERCURY OLEATE S9 S19 60 1641 MERCURY OXIDE S9 S19 60 S9 S19 60 S9 S19 60 1642 MERCURY OXYCYANIDE, DESENSITIZED 1643 MERCURY POTASSIUM IODIDE 1644 MERCURY SALICYLATE S9 S19 60 1645 MERCURY SULPHATE S9 S19 60 1646 MERCURY THIOCYANATE S9 S14 66 1647 METHYL BROMIDE AND ETHYLENE DIBROMIDE MIXTURE, LIQUID SGAH L4BH TU15 TE19 AT 2 (E) SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT S10AH TU15 TE19 AT 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/E) SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/D) VV9 V11 V11 V11 V11 V11 V11 V11 V11 V10 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 - 385 - 3.1.2 Copyright © United Nations, 2010. All rights reserved UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities 3.1.2 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1648 ACETONITRILE (3a) 3 (3b) F1 (4) II (5) 3 (6) (7a) 1L (7b) E2 1649 MOTOR FUEL ANTIKNOCK MIXTURE 6.1 T3 I 6.1 0 E5 1650 beta-NAPHTHYLAMINE, SOLID 1651 NAPHTHYLTHIOUREA 6.1 T2 II 6.1 500 g E4 1652 NAPHTHYLUREA 1653 NICKEL CYANIDE 6.1 6.1 6.1 T2 T2 T5 II II II 6.1 6.1 6.1 T1 II 6.1 1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 1656 NICOTINE HYDROCHLORIDE, LIQUID or SOLUTION 1656 NICOTINE HYDROCHLORIDE, LIQUID or SOLUTION 6.1 T2 I 6.1 6.1 T2 II 6.1 1657 NICOTINE SALICYLATE 1658 NICOTINE SULPHATE, SOLUTION 1658 NICOTINE SULPHATE, SOLUTION 1659 NICOTINE TARTRATE 1660 NITRIC OXIDE, COMPRESSED 1661 NITROANILINES (o-, m-, p-) T2 III 6.1 500 g 500 g 6.1 1654 NICOTINE 6.1 43 500 g E4 E4 E4 100 ml E4 43 274 0 E5 43 274 500 g E4 43 274 5 kg E1 6.1 T1 II 6.1 43 100 ml E4 6.1 T1 III 6.1 43 5L E1 6.1 T2 II 6.1 500 g E4 6.1 T1 II 6.1 100 ml E4 6.1 T1 III 6.1 5L E1 6.1 T2 II 6.1 500 g E4 2 1TOC 6.1 T2 II 2.3 +5.1 +8 6.1 279 0 E0 500 g E4 1662 NITROBENZENE 6.1 T1 II 6.1 279 100 ml E4 1663 NITROPHENOLS (o-, m-, p-) 6.1 T2 III 6.1 279 5 kg E1 1664 NITROTOLUENES, LIQUID 6.1 T1 II 6.1 100 ml E4 1665 NITROXYLENES, LIQUID 6.1 T1 II 6.1 100 ml E4 1669 PENTACHLOROETHANE 6.1 T1 II 6.1 100 ml E4 1670 PERCHLOROMETHYL MERCAPTAN 6.1 T1 I 6.1 354 0 E0 1671 PHENOL, SOLID 6.1 T2 II 6.1 279 500 g E4 1672 PHENYLCARBYLAMINE CHLORIDE 6.1 T1 I 6.1 0 - 386 - E5 Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 (8) P001 IBC02 R001 P602 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P001 IBC02 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P200 P002 IBC08 P001 IBC02 P002 IBC08 LP02 R001 P001 IBC02 P001 IBC02 P001 IBC02 P602 P002 IBC08 P602 (9a) Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) T7 4.2.5.3 MP8 MP17 T14 TP2 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP10 T3 TP33 MP15 T7 TP2 MP19 T7 TP2 MP10 T3 TP33 MP10 T3 TP33 MP15 T7 TP2 MP10 T1 TP33 MP15 T7 TP2 MP15 T7 TP2 MP15 T7 TP2 MP8 MP17 T20 TP2 TP37 MP10 T3 TP33 MP8 MP17 T14 TP2 (9b) MP19 (11) TP2 B4 B4 B4 B4 MP15 B4 B3 MP15 MP19 B4 B4 MP9 B4 B3 B4 Copyright © United Nations, 2010. All rights reserved ADR tank Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 2 (D/E) Special provisions for carriage Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) LGBF (13) L10CH TU14 TU15 TE19 TE21 TT6 TU15 TE19 AT 1 (C/E) AT V11 TU15 TE19 AT SGAH TU15 TE19 AT SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT S10AH L10CH TU15 TE19 AT 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/E) SGAH L4BH TU15 TE19 AT 2 (D/E) V11 SGAH L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT L4BH TU15 TE19 AT SGAH L4BH TU15 TE19 AT SGAH L4BH SGAH SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT SGAH L4BH TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT SGAH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) Hazard UN identifi- No. Operation cation No. Name and description 8.5 5.3.2.3 (18) (19) S2 S20 (20) 33 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 S9 S14 66 1649 MOTOR FUEL ANTIKNOCK MIXTURE S9 S19 60 S9 S19 60 1650 beta-NAPHTHYLAMINE, SOLID 1651 NAPHTHYLTHIOUREA S9 S19 60 1652 NAPHTHYLUREA S9 S19 60 1653 NICKEL CYANIDE S9 S19 60 1654 NICOTINE S9 S14 66 CV13 CV28 S9 S19 60 CV13 CV28 S9 60 CV13 CV28 S9 S19 60 V12 CV13 CV28 S9 60 1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 1656 NICOTINE HYDROCHLORIDE, LIQUID or SOLUTION 1656 NICOTINE HYDROCHLORIDE, LIQUID or SOLUTION 2 (D/E) 2 (D/E) 2 (E) V11 CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 60 1657 NICOTINE SALICYLATE S9 S19 60 S9 60 1658 NICOTINE SULPHATE, SOLUTION 1658 NICOTINE SULPHATE, SOLUTION 2 (D/E) 1 (D) V11 S9 S19 60 2 (D/E) 2 (D/E) 2 (E) V11 CV13 CV28 CV9 CV10 CV36 CV13 CV28 CV13 CV28 CV13 CV28 V11 V11 V11 V10 VV9 V12 VV9 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/D) 2 (D/E) 1 (C/E) CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 V11 - 387 - S14 3.1.2 (1) (2) 1648 ACETONITRILE 1659 NICOTINE TARTRATE 1660 NITRIC OXIDE, COMPRESSED S9 S19 60 1661 NITROANILINES (o-, m-, p-) S9 S19 60 1662 NITROBENZENE S9 60 1663 NITROPHENOLS (o-, m-, p-) S9 S19 60 1664 NITROTOLUENES, LIQUID S9 S19 60 1665 NITROXYLENES, LIQUID S9 S19 60 1669 PENTACHLOROETHANE S9 S14 66 1670 PERCHLOROMETHYL MERCAPTAN S9 S19 60 1671 PHENOL, SOLID S9 S14 66 1672 PHENYLCARBYLAMINE CHLORIDE Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1673 PHENYLENEDIAMINES (o-, m-, p-) (3a) 6.1 (3b) T2 (4) III (5) 6.1 (6) 279 (7a) 5 kg (7b) E1 1674 PHENYLMERCURIC ACETATE 1677 POTASSIUM ARSENATE 6.1 1678 POTASSIUM ARSENITE 1679 POTASSIUM CUPROCYANIDE 1680 POTASSIUM CYANIDE, SOLID 1683 SILVER ARSENITE 1684 SILVER CYANIDE 1685 SODIUM ARSENATE 1686 SODIUM ARSENITE, AQUEOUS SOLUTION 1686 SODIUM ARSENITE, AQUEOUS SOLUTION 1687 SODIUM AZIDE 1688 SODIUM CACODYLATE 6.1 6.1 6.1 T3 T5 T5 T5 II II II II 6.1 43 6.1 500 g 500 g 6.1 500 g 6.1 500 g E4 E4 E4 E4 6.1 T5 I 6.1 0 E5 6.1 T5 II 6.1 500 g E4 6.1 6.1 T5 T5 II II 6.1 500 g 6.1 500 g E4 E4 6.1 T4 II 6.1 43 100 ml E4 6.1 T4 III 6.1 43 5L E1 6.1 T5 II 6.1 500 g E4 6.1 T5 II 6.1 500 g E4 1689 SODIUM CYANIDE, SOLID 6.1 T5 I 6.1 0 E5 1690 SODIUM FLUORIDE, SOLID 6.1 T5 III 6.1 5 kg E1 1691 STRONTIUM ARSENITE 6.1 T5 II 6.1 1692 STRYCHNINE or STRYCHNINE SALTS 6.1 T2 I 6.1 1693 TEAR GAS SUBSTANCE, LIQUID, N.O.S. 6.1 T1 I 6.1 1693 TEAR GAS SUBSTANCE, LIQUID, N.O.S. 1694 BROMOBENZYL CYANIDES, LIQUID 6.1 T1 II 6.1 T1 1695 CHLOROACETONE, STABILIZED 6.1 1697 CHLOROACETOPHENONE, SOLID 1698 DIPHENYLAMINE CHLOROARSINE 6.1 500 g E4 Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 (8) P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC07 P002 IBC08 P002 IBC08 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P002 IBC08 P002 IBC07 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC07 4.2.5.3 (9b) MP10 4.2.5.2 7.3.2 (10) T1 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP2 MP10 T3 TP33 MP18 T6 TP33 MP10 T1 TP33 MP10 T3 TP33 MP18 T6 TP33 MP8 MP17 T14 TP2 MP8 MP17 T20 TP2 TP35 MP10 T3 TP33 MP18 T6 TP33 MP15 T7 TP2 MP15 T7 TP2 MP15 T7 TP2 MP10 T3 TP33 B4 B4 B4 B4 B4 B4 B4 MP10 B4 B4 B3 B4 E5 274 0 E5 P001 MP8 MP17 6.1 274 0 E4 MP15 I 6.1 138 0 E5 P001 IBC02 P001 TFC I 354 0 E0 P602 T2 II 6.1 +3 +8 6.1 0 E4 6.1 T3 I 6.1 0 E5 1699 DIPHENYLCHLOROARSINE, LIQUID 6.1 T3 I 6.1 0 E5 P001 1700 TEAR GAS CANDLES 6.1 TF3 II 0 E0 P600 1701 XYLYL BROMIDE, LIQUID 6.1 T1 II 6.1 +4.1 6.1 0 E4 1702 1,1,2,2TETRACHLOROETHANE 1704 TETRAETHYL DITHIOPYROPHOSPHATE 6.1 T1 II 6.1 100 ml E4 6.1 T1 II 6.1 43 100 ml E4 P001 IBC02 P001 IBC02 P001 IBC02 6.1 T5 II 6.1 43 274 500 g E4 - 388 - P002 IBC08 (11) TP33 B3 0 P002 IBC08 P002 1707 THALLIUM COMPOUND, N.O.S. (9a) Portable tanks and bulk containers Instruc- Special tions provisions B4 MP8 MP17 B4 Copyright © United Nations, 2010. All rights reserved ADR tank Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 2 (E) Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) SGAH L4BH (13) TU15 TE19 SGAH L4BH SGAH TU15 TE19 AT TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT S10AH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT SGAH TU15 TE19 AT 2 (E) SGAH TU15 TE19 AT S10AH TU15 TE19 AT 2 (D/E) 1 (C/E) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT 2 (D/E) 1 (C/E) L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) SGAH L4BH S10AH TU15 TE19 AT TU15 TE19 AT 2 (D/E) 1 (C/E) TU14 TU15 TE19 TE21 AT AT L4BH TU15 TE19 AT SGAH L4BH TU15 TE19 AT (17) VV9 V11 AT TU15 TE19 (16) 2 (D/E) 2 (D/E) 1 (C/E) TU15 TE19 L4BH 7.3.3 V11 S10AH AT 7.2.4 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (E) AT TU15 TE19 Bulk V11 TU15 TE19 L4BH Packages 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/E) SGAH L10CH Special provisions for carriage Loading, unloading and handling 7.5.11 V11 V11 V11 V10 V11 V11 V12 V11 V10 VV9 V11 V10 V11 1 (C/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) V11 Name and description 8.5 5.3.2.3 (18) CV13 CV28 (19) S9 (20) 60 (1) (2) 1673 PHENYLENEDIAMINES (o-, m-, p-) CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 60 S9 S19 60 1674 PHENYLMERCURIC ACETATE 1677 POTASSIUM ARSENATE S9 S19 60 1678 POTASSIUM ARSENITE S9 S19 60 S9 S14 66 1679 POTASSIUM CUPROCYANIDE 1680 POTASSIUM CYANIDE, SOLID S9 S19 60 1683 SILVER ARSENITE S9 S19 60 1684 SILVER CYANIDE S9 S19 60 1685 SODIUM ARSENATE S9 S19 60 S9 60 1686 SODIUM ARSENITE, AQUEOUS SOLUTION 1686 SODIUM ARSENITE, AQUEOUS SOLUTION CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 S9 S19 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 - 389 - Hazard UN identifi- No. Operation cation No. 3.1.2 1687 SODIUM AZIDE S9 S19 60 1688 SODIUM CACODYLATE S9 S14 66 1689 SODIUM CYANIDE, SOLID S9 60 1690 SODIUM FLUORIDE, SOLID S9 S19 60 1691 STRONTIUM ARSENITE S9 S14 66 1692 STRYCHNINE or STRYCHNINE SALTS S9 S14 66 1693 TEAR GAS SUBSTANCE, LIQUID, N.O.S. S9 S19 60 S9 S14 66 1693 TEAR GAS SUBSTANCE, LIQUID, N.O.S. 1694 BROMOBENZYL CYANIDES, LIQUID S2 S9 S14 663 1695 CHLOROACETONE, STABILIZED S9 S19 60 S9 S14 66 1697 CHLOROACETOPHENONE, SOLID 1698 DIPHENYLAMINE CHLOROARSINE S9 S14 66 S9 S19 1699 DIPHENYLCHLOROARSINE, LIQUID 1700 TEAR GAS CANDLES S9 S19 60 1701 XYLYL BROMIDE, LIQUID S9 S19 60 S9 S19 60 1702 1,1,2,2TETRACHLOROETHANE 1704 TETRAETHYL DITHIOPYROPHOSPHATE S9 S19 60 1707 THALLIUM COMPOUND, N.O.S. Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1708 TOLUIDINES, LIQUID (3a) 6.1 (3b) T1 (4) II (5) 6.1 (6) 279 (7a) 100 ml (7b) E4 1709 2,4-TOLUYLENEDIAMINE, SOLID 6.1 T2 III 6.1 5 kg E1 1710 TRICHLOROETHYLENE 6.1 T1 III 6.1 5L E1 1711 XYLIDINES, LIQUID 6.1 T1 II 6.1 100 ml E4 1712 ZINC ARSENATE, ZINC ARSENITE or ZINC ARSENATE AND ZINC ARSENITE MIXTURE 1713 ZINC CYANIDE 6.1 T5 II 6.1 500 g E4 6.1 T5 I 6.1 0 E5 1714 ZINC PHOSPHIDE 4.3 WT2 I 0 1715 ACETIC ANHYDRIDE 8 CF1 II 1716 ACETYL BROMIDE 8 C3 II 4.3 +6.1 8 +3 8 1717 ACETYL CHLORIDE 3 FC II 1718 BUTYL ACID PHOSPHATE 8 C3 III 3 +8 8 1719 CAUSTIC ALKALI LIQUID, N.O.S. 1719 CAUSTIC ALKALI LIQUID, N.O.S. 8 C5 II 8 8 C5 III 8 1722 ALLYL CHLOROFORMATE 6.1 TFC I 1723 ALLYL IODIDE 3 FC II 1724 ALLYLTRICHLOROSILANE, STABILIZED 1725 ALUMINIUM BROMIDE, ANHYDROUS 1726 ALUMINIUM CHLORIDE, ANHYDROUS 1727 AMMONIUM HYDROGENDIFLUORIDE, SOLID 1728 AMYLTRICHLOROSILANE 8 CF1 II 8 C2 II 6.1 +3 +8 3 +8 8 +3 8 8 C3 II 8 0 E2 P010 1729 ANISOYL CHLORIDE 8 C4 II 8 1 kg E2 P002 IBC08 P001 IBC02 8 8 C2 C2 II II 8 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP15 4.2.5.2 7.3.2 (10) T7 MP10 T1 TP33 MP19 T4 TP1 MP15 T7 TP2 MP10 T3 TP33 P002 IBC07 MP18 T6 TP33 E0 P403 MP2 1L E2 MP15 T7 TP2 1L E2 MP15 T8 TP2 1L E2 MP19 T8 TP2 5L E1 MP19 T4 TP1 274 1L E2 MP15 T11 274 5L E1 MP19 T7 TP2 TP27 TP1 TP28 0 E5 P001 IBC02 P001 IBC02 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 R001 P001 MP8 MP17 T14 TP2 1L E2 MP19 T7 TP2 0 E2 P001 IBC02 P010 MP15 T10 1 kg E2 MP10 T3 TP2 TP7 TP33 MP10 T3 TP33 MP10 T3 TP33 MP15 T10 MP10 T3 TP2 TP7 TP33 MP15 T7 TP2 588 588 8 1 kg 1 kg E2 E2 (8) P001 IBC02 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P001 IBC02 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 (9a) (11) TP2 B3 B4 B4 B4 B4 B4 1730 ANTIMONY PENTACHLORIDE, LIQUID 8 C1 II 8 1L E2 1731 ANTIMONY PENTACHLORIDE SOLUTION 1731 ANTIMONY PENTACHLORIDE SOLUTION 8 C1 II 8 1L E2 P001 IBC02 MP15 T7 TP2 8 C1 III 8 5L E1 MP19 T4 TP1 8 CT1 II 1L E2 MP15 T7 TP2 8 C2 II 8 +6.1 8 1 kg E2 P001 IBC03 LP01 R001 P001 IBC02 P002 IBC08 P001 IBC02 P001 IBC02 MP10 T3 TP33 MP15 T8 TP2 MP15 T8 TP2 1732 ANTIMONY PENTAFLUORIDE 1733 ANTIMONY TRICHLORIDE 1736 BENZOYL CHLORIDE 1737 BENZYL BROMIDE 8 C3 II 8 1L E2 6.1 TC1 II 6.1 +8 0 E4 - 390 - B4 Copyright © United Nations, 2010. All rights reserved ADR tank Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 2 (D/E) AT 2 (E) Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L4BH (13) TU15 TE19 SGAH L4BH TU15 TE19 L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT SGAH TU15 TE19 AT 2 (D/E) 2 (D/E) S10AH TU15 TE19 AT L4BN FL L4BN AT L4BH FL L4BN AT L4BN AT L4BN AT L10CH 7.3.3 (16) (17) 2 (E) 3 (E) L4BN FL SGAN AT SGAN AT SGAN AT 2 (D/E) 2 (D/E) 2 (E) 2 (E) 2 (E) L4BN AT SGAN L4BN L4BN AT AT L4BN AT 2 (E) L4BN AT 3 (E) L4BN AT SGAN L4BN L4BN AT 2 (E) 2 (E) 2 (E) 2 (D/E) 2 (E) 2 (E) 2 (E) Loading, unloading and handling 7.5.11 VV9 V12 V11 V1 FL AT 7.2.4 1 (E) 2 (D/E) 2 (E) 2 (D/E) 3 (E) L4BH TU15 TE19 Bulk V10 1 (C/D) AT Packages 1 (C/E) FL L4BH TU14 TU15 TE19 TE21 Special provisions for carriage Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (18) CV13 CV28 CV13 CV28 (19) S9 S19 (20) 60 S9 60 1709 2,4-TOLUYLENEDIAMINE, SOLID CV13 CV28 S9 60 1710 TRICHLOROETHYLENE CV13 CV28 CV13 CV28 S9 S19 60 1711 XYLIDINES, LIQUID S9 S19 60 CV1 CV13 CV28 CV23 CV28 S9 S14 66 1712 ZINC ARSENATE, ZINC ARSENITE or ZINC ARSENATE AND ZINC ARSENITE MIXTURE 1713 ZINC CYANIDE S14 S2 S2 S20 V12 V12 CV1 CV13 CV28 (1) (2) 1708 TOLUIDINES, LIQUID 83 1715 ACETIC ANHYDRIDE 80 1716 ACETYL BROMIDE X338 1717 ACETYL CHLORIDE 80 1718 BUTYL ACID PHOSPHATE 80 1719 CAUSTIC ALKALI LIQUID, N.O.S. 1719 CAUSTIC ALKALI LIQUID, N.O.S. S2 S9 S14 668 1722 ALLYL CHLOROFORMATE S2 S20 338 1723 ALLYL IODIDE S2 X839 V11 80 V11 80 V11 80 X80 V11 80 X80 80 V12 80 CV13 CV28 86 V11 CV13 CV28 3.1.2 1714 ZINC PHOSPHIDE 80 - 391 - Name and description S9 S19 1724 ALLYLTRICHLOROSILANE, STABILIZED 1725 ALUMINIUM BROMIDE, ANHYDROUS 1726 ALUMINIUM CHLORIDE, ANHYDROUS 1727 AMMONIUM HYDROGENDIFLUORIDE, SOLID 1728 AMYLTRICHLOROSILANE 1729 ANISOYL CHLORIDE 1730 ANTIMONY PENTACHLORIDE, LIQUID 1731 ANTIMONY PENTACHLORIDE SOLUTION 1731 ANTIMONY PENTACHLORIDE SOLUTION 80 1732 ANTIMONY PENTAFLUORIDE 1733 ANTIMONY TRICHLORIDE 80 1736 BENZOYL CHLORIDE 68 1737 BENZYL BROMIDE Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 6.1 (3b) TC1 (4) II (6) (7a) 0 (7b) E4 1739 BENZYL CHLOROFORMATE 1740 HYDROGENDIFLUORIDES, SOLID, N.O.S. 1740 HYDROGENDIFLUORIDES, SOLID, N.O.S. 8 C9 I (5) 6.1 +8 8 0 E0 8 C2 II 8 517 1 kg E2 1741 BORON TRICHLORIDE 2 2TC 1742 BORON TRIFLUORIDE ACETIC ACID COMPLEX, LIQUID 1743 BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, LIQUID 1744 BROMINE or BROMINE SOLUTION 8 C3 8 (1) (2) 1738 BENZYL CHLORIDE 8 C2 III 8 517 5 kg E1 Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 (8) P001 IBC02 P001 P002 IBC08 P002 IBC08 LP02 R001 P200 (9a) Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) T8 4.2.5.3 MP8 MP17 MP10 T10 TP2 T3 TP33 MP10 T1 TP33 MP9 (M) (9b) MP15 (11) TP2 B4 B3 2.3 +8 0 E0 II 8 1L E2 P001 IBC02 MP15 T8 TP2 C3 II 8 1L E2 P001 IBC02 MP15 T8 TP2 8 CT1 I 8 +6.1 0 E0 P804 MP2 T22 TP2 TP10 1745 BROMINE PENTAFLUORIDE 5.1 OTC I 0 E0 P200 MP2 T22 TP2 1746 BROMINE TRIFLUORIDE 5.1 OTC I 0 E0 P200 MP2 T22 TP2 1747 BUTYLTRICHLOROSILANE 8 CF1 II 0 E2 P010 MP15 T10 TP2 TP7 1748 CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) 1748 CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) 1749 CHLORINE TRIFLUORIDE 5.1 O2 II 5.1 +6.1 +8 5.1 +6.1 +8 8 +3 5.1 1 kg E2 P002 IBC08 1750 CHLOROACETIC ACID SOLUTION 1751 CHLOROACETIC ACID, SOLID 1752 CHLOROACETYL CHLORIDE 5.1 O2 III 2 2TOC 6.1 TC1 II 6.1 TC2 II 6.1 TC1 I 8 C3 II 5.1 2.3 +5.1 +8 6.1 +8 6.1 +8 6.1 +8 314 316 5 kg E1 P002 IBC08 R001 MP10 B4 B13 MP10 B4 B13 0 E0 P200 MP9 (M) 100 ml E4 MP15 T7 TP2 500 g E4 MP10 T3 TP33 MP8 MP17 T20 TP2 TP35 0 E0 P001 IBC02 P002 IBC08 P602 8 0 E2 P010 MP15 T10 0 E0 P001 MP8 MP17 T20 TP2 TP7 TP2 P001 IBC02 P001 IBC02 LP01 R001 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 MP15 T8 TP2 MP19 T4 TP1 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP1 354 1753 CHLOROPHENYLTRICHLOROSILANE 1754 CHLOROSULPHONIC ACID (with or without sulphur trioxide) 1755 CHROMIC ACID SOLUTION 8 C1 I 8 8 C1 II 8 518 1L E2 1755 CHROMIC ACID SOLUTION 8 C1 III 8 518 5L E1 1756 CHROMIC FLUORIDE, SOLID 1757 CHROMIC FLUORIDE SOLUTION 1757 CHROMIC FLUORIDE SOLUTION 8 C2 II 8 1 kg E2 8 C1 II 8 1L E2 8 C1 III 8 5L E1 - 392 - B4 B4 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L4BH (13) TU15 TE19 L10BH SGAN SGAV Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 2 (D/E) AT 1 (E) AT 2 (E) AT 3 (E) AT 1 (C/D) L4BN AT L4BN Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) (17) Loading, unloading and handling 7.5.11 (18) CV13 CV28 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S9 S19 (20) 68 S20 88 V11 80 VV9 80 CV9 CV10 CV36 S14 Name and description 3.1.2 (1) (2) 1738 BENZYL CHLORIDE 1739 BENZYL CHLOROFORMATE 1740 HYDROGENDIFLUORIDES, SOLID, N.O.S. 1740 HYDROGENDIFLUORIDES, SOLID, N.O.S. 268 1741 BORON TRICHLORIDE 2 (E) 80 AT 2 (E) 80 1742 BORON TRIFLUORIDE ACETIC ACID COMPLEX, LIQUID 1743 BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, LIQUID 1744 BROMINE or BROMINE SOLUTION L21DH(+) TU14 TU33 TC5 TE21 TT2 TM3 TM5 AT 1 (C/D) CV13 CV28 S14 886 L10DH TU3 AT 1 (B/E) CV24 CV28 S14 568 1745 BROMINE PENTAFLUORIDE L10DH TU3 AT 1 (B/E) CV24 CV28 S14 568 1746 BROMINE TRIFLUORIDE FL 2 (D/E) 2 (E) S2 X83 1747 BUTYLTRICHLOROSILANE CV24 CV35 50 50 1748 CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) 1748 CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) 1749 CHLORINE TRIFLUORIDE L4BN SGAN TU3 AT SGAV TU3 AT 3 (E) CV24 CV35 PxBH(M) TA4 TT9 AT 1 (C/D) L4BH TU15 TE19 AT SGAH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT 2 (D/E) 2 (D/E) 1 (C/D) CV9 CV10 CV36 CV13 CV28 CV13 CV28 CV1 CV13 CV28 L4BN AT L10BH AT L4BN AT L4BN AT SGAN AT L4BN AT L4BN AT V11 V11 2 (E) 1 (E) 265 S9 S19 68 S9 S19 68 S9 S14 668 X80 S20 2 (E) 3 (E) 2 (E) 2 (E) 3 (E) S14 V11 80 1753 CHLOROPHENYLTRICHLOROSILANE 1754 CHLOROSULPHONIC ACID (with or without sulphur trioxide) 1755 CHROMIC ACID SOLUTION 80 1755 CHROMIC ACID SOLUTION 80 1756 CHROMIC FLUORIDE, SOLID 1757 CHROMIC FLUORIDE SOLUTION 1757 CHROMIC FLUORIDE SOLUTION X88 80 V12 80 - 393 - 1750 CHLOROACETIC ACID SOLUTION 1751 CHLOROACETIC ACID, SOLID 1752 CHLOROACETYL CHLORIDE Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special cation provigroup code sions Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1758 CHROMIUM OXYCHLORIDE 1759 CORROSIVE SOLID, N.O.S. (3a) 8 (3b) C1 (4) I (5) 8 (6) (7a) 0 (7b) E0 (8) P001 8 C10 I 8 274 0 E0 1759 CORROSIVE SOLID, N.O.S. 8 C10 II 8 274 1 kg E2 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P001 1759 CORROSIVE SOLID, N.O.S. 8 C10 III 8 274 5 kg E1 1760 CORROSIVE LIQUID, N.O.S. 8 C9 I 8 274 0 E0 1760 CORROSIVE LIQUID, N.O.S. 8 C9 II 8 274 1L E2 1760 CORROSIVE LIQUID, N.O.S. 8 C9 III 8 274 5L E1 1761 CUPRIETHYLENEDIAMINE SOLUTION 1761 CUPRIETHYLENEDIAMINE SOLUTION 8 CT1 II 1L E2 8 CT1 III 8 +6.1 8 +6.1 5L E1 1762 CYCLOHEXENYLTRICHLOROSILANE 1763 CYCLOHEXYLTRICHLOROSILANE 1764 DICHLOROACETIC ACID 8 C3 II 8 0 8 C3 II 8 8 C3 II 8 C3 8 1765 DICHLOROACETYL CHLORIDE 1766 DICHLOROPHENYLTRICHLOROSILANE 1767 DIETHYLDICHLOROSILANE 1768 DIFLUOROPHOSPHORIC ACID, ANHYDROUS 1769 DIPHENYLDICHLOROSILANE 1770 DIPHENYLMETHYL BROMIDE 1771 DODECYLTRICHLOROSILANE 1773 FERRIC CHLORIDE, ANHYDROUS 1774 FIRE EXTINGUISHER CHARGES, corrosive liquid 1775 FLUOROBORIC ACID (9a) Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) T10 4.2.5.3 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP8 MP17 MP15 T14 MP19 T7 TP2 TP27 TP2 TP27 TP1 TP28 MP15 T7 TP2 (9b) MP8 MP17 MP18 (11) TP2 B4 B3 MP19 T7 TP1 TP28 E2 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 R001 P010 MP15 T10 0 E2 P010 MP15 T10 8 1L E2 MP15 T8 II 8 1L E2 MP15 T7 TP2 C3 II 8 0 E2 P001 IBC02 P001 IBC02 P010 TP2 TP7 TP2 TP7 TP2 MP15 T10 8 CF1 II 0 E2 P010 MP15 T10 8 C1 II 8 +3 8 1L E2 MP15 T8 8 C3 II 8 0 E2 P001 IBC02 P010 TP2 TP7 TP2 TP7 TP2 MP15 T10 8 C10 II 8 1 kg E2 MP10 T3 MP15 T10 MP10 T1 TP2 TP7 TP33 MP15 T7 TP2 MP15 T8 TP2 MP8 MP17 MP15 T10 TP2 T8 TP2 MP15 T7 TP2 MP15 T7 TP2 MP15 T10 MP15 T8 TP2 TP7 TP2 MP15 T7 TP2 MP19 T4 TP1 MP15 T10 TP2 TP7 8 C3 II 8 8 C2 III 8 590 0 E2 5 kg E1 8 C11 II 8 1L E0 8 C1 II 8 1L E2 1776 FLUOROPHOSPHORIC ACID, ANHYDROUS 1777 FLUOROSULPHONIC ACID 8 C1 II 8 1L E2 8 C1 I 8 0 E0 1778 FLUOROSILICIC ACID 8 C1 II 8 1L E2 1779 FORMIC ACID with more than 85% acid by mass 1780 FUMARYL CHLORIDE 8 CF1 II 1L E2 8 C3 II 8 +3 8 1L E2 1781 HEXADECYLTRICHLOROSILANE 1782 HEXAFLUOROPHOSPHORIC ACID 1783 HEXAMETHYLENEDIAMINE SOLUTION 1783 HEXAMETHYLENEDIAMINE SOLUTION 8 C3 II 8 0 E2 8 C1 II 8 1L E2 8 C7 II 8 1L E2 8 C7 III 8 5L E1 1784 HEXYLTRICHLOROSILANE 8 C3 II 8 0 E2 - 394 - P002 IBC08 P010 P002 IBC08 LP02 R001 P001 P001 IBC02 P001 IBC02 P001 P001 IBC02 P001 IBC02 P001 IBC02 P010 P001 IBC02 P001 IBC02 P001 IBC03 LP01 R001 P010 T11 TP2 TP7 TP33 B4 B3 PP4 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L10BH (13) S10AN L10BH SGAN L4BN SGAV L4BN Vehicle for Transport tank category carriage (Tunnel restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 1 (E) AT 1 (E) AT 2 (E) AT 3 (E) L10BH AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN FL L4BN AT L4BN AT SGAN L4BN L4BN AT AT SGAV AT L4BN AT L4BN AT L10BH AT L4BN AT L4BN FL L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT 1 (E) 2 (E) 3 (E) 2 (E) 3 (E) 2 (E) 2 (E) 2 (E) 2 (E) 2 (E) 2 (D/E) 2 (E) 2 (E) 2 (E) 2 (E) 3 (E) 2 (E) 2 (E) 2 (E) 1 (E) 2 (E) 2 (D/E) 2 (E) 2 (E) 2 (E) 2 (E) 3 (E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) (18) V10 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S20 (20) X88 S20 88 (1) (2) 1758 CHROMIUM OXYCHLORIDE 1759 CORROSIVE SOLID, N.O.S. 80 1759 CORROSIVE SOLID, N.O.S. 80 1759 CORROSIVE SOLID, N.O.S. 88 1760 CORROSIVE LIQUID, N.O.S. 80 1760 CORROSIVE LIQUID, N.O.S. 80 1760 CORROSIVE LIQUID, N.O.S. 86 1761 CUPRIETHYLENEDIAMINE SOLUTION 1761 CUPRIETHYLENEDIAMINE SOLUTION V11 VV9 S20 V12 CV13 CV28 CV13 CV28 V12 86 X80 X80 80 X80 X80 S2 X83 80 X80 V11 80 X80 VV9 80 80 80 S20 S2 1765 DICHLOROACETYL CHLORIDE 1766 DICHLOROPHENYLTRICHLOROSILANE 1767 DIETHYLDICHLOROSILANE 1768 DIFLUOROPHOSPHORIC ACID, ANHYDROUS 1769 DIPHENYLDICHLOROSILANE 1770 DIPHENYLMETHYL BROMIDE 1771 DODECYLTRICHLOROSILANE 1773 FERRIC CHLORIDE, ANHYDROUS 1774 FIRE EXTINGUISHER CHARGES, corrosive liquid 1775 FLUOROBORIC ACID 80 1778 FLUOROSILICIC ACID 83 1779 FORMIC ACID with more than 85% acid by mass 1780 FUMARYL CHLORIDE 80 80 80 X80 - 395 - 1762 CYCLOHEXENYLTRICHLOROSILANE 1763 CYCLOHEXYLTRICHLOROSILANE 1764 DICHLOROACETIC ACID 88 X80 2 (E) 3.1.2 1776 FLUOROPHOSPHORIC ACID, ANHYDROUS 1777 FLUOROSULPHONIC ACID 80 V12 Name and description 1781 HEXADECYLTRICHLOROSILANE 1782 HEXAFLUOROPHOSPHORIC ACID 1783 HEXAMETHYLENEDIAMINE SOLUTION 1783 HEXAMETHYLENEDIAMINE SOLUTION 1784 HEXYLTRICHLOROSILANE Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 8 (3b) CT1 (4) I (5) 8 +6.1 (6) (7a) 0 (7b) E0 (8) P001 8 C1 II 8 1L E2 1787 HYDRIODIC ACID 8 C1 III 8 5L E1 1788 HYDROBROMIC ACID 8 C1 II 8 519 1L E2 1788 HYDROBROMIC ACID 8 C1 III 8 519 5L E1 1789 HYDROCHLORIC ACID 8 C1 II 8 520 1L E2 1789 HYDROCHLORIC ACID 8 C1 III 8 520 5L E1 1790 HYDROFLUORIC ACID with more than 85% hydrogen fluoride 8 CT1 I 8 +6.1 640I 0 E0 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P802 1790 HYDROFLUORIC ACID with more than 60% but not more than 85% hydrogen fluoride 1790 HYDROFLUORIC ACID with not more than 60% hydrogen fluoride 1791 HYPOCHLORITE SOLUTION 1791 HYPOCHLORITE SOLUTION 8 CT1 I 8 +6.1 640J 0 E0 P001 8 CT1 II 8 +6.1 1L E2 P001 IBC02 8 C9 II 8 521 1L E2 8 C9 III 8 521 5L E1 1792 IODINE MONOCHLORIDE 8 C1 II 8 1L E2 1793 ISOPROPYL ACID PHOSPHATE 8 C3 III 8 5L E1 1794 LEAD SULPHATE with more than 3% free acid 1796 NITRATING ACID MIXTURE with more than 50% nitric acid 1796 NITRATING ACID MIXTURE with not more than 50% nitric acid 1798 NITROHYDROCHLORIC ACID 1799 NONYLTRICHLOROSILANE 8 C2 II 8 1 kg E2 P001 IBC02 P001 IBC02 LP01 R001 P001 IBC02 P001 IBC02 LP01 R001 P002 IBC08 P001 (1) (2) 1786 HYDROFLUORIC ACID AND SULPHURIC ACID MIXTURE 1787 HYDRIODIC ACID 591 (9a) PP81 PP10 B5 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) T10 4.2.5.3 MP15 T7 TP2 MP19 T4 TP1 MP15 T7 TP2 MP19 T4 TP1 MP15 T8 TP2 MP19 T4 TP1 MP2 T10 TP2 MP8 MP17 T10 TP2 MP15 T8 TP2 MP15 T7 MP19 T4 TP2 TP24 TP2 TP24 MP15 T7 TP2 MP19 T4 TP1 MP10 T3 TP33 MP8 MP17 T10 TP2 MP15 T8 TP2 (9b) MP8 MP17 B5 (11) TP2 B4 8 CO1 I 8 +5.1 0 E0 8 C1 II 8 1L E2 8 COT 8 C3 II 8 0 E2 P010 MP15 T10 8 C3 II 8 0 E2 P010 MP15 T10 8 C3 II 8 0 E2 P010 MP15 T10 1802 PERCHLORIC ACID with not more than 50% acid, by mass 8 CO1 II 8 +5.1 1L E2 P001 IBC02 MP3 T7 TP2 TP7 TP2 TP7 TP2 TP7 TP2 1803 PHENOLSULPHONIC ACID, LIQUID 1804 PHENYLTRICHLOROSILANE 1805 PHOSPHORIC ACID, SOLUTION 8 C3 II 8 1L E2 MP15 T7 TP2 8 C3 II 8 0 E2 P001 IBC02 P010 MP15 T10 8 C1 III 8 5L E1 MP19 T4 TP2 TP7 TP1 8 C2 II 8 1 kg E2 MP10 T3 TP33 1800 OCTADECYLTRICHLOROSILANE 1801 OCTYLTRICHLOROSILANE 1806 PHOSPHORUS PENTACHLORIDE P001 IBC02 CARRIAGE PROHIBITED 522 - 396 - P001 IBC03 LP01 R001 P002 IBC08 B4 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L10DH (13) TU14 TE21 Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 1 (C/D) L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT 2 (E) 3 (E) 2 (E) 3 (E) 2 (E) 3 (E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) (17) Loading, unloading and handling 7.5.11 (18) CV13 CV28 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S14 (20) 886 V12 V12 V12 Name and description 3.1.2 80 (1) (2) 1786 HYDROFLUORIC ACID AND SULPHURIC ACID MIXTURE 1787 HYDRIODIC ACID 80 1787 HYDRIODIC ACID 80 1788 HYDROBROMIC ACID 80 1788 HYDROBROMIC ACID 80 1789 HYDROCHLORIC ACID 80 1789 HYDROCHLORIC ACID L21DH(+) TU14 TU34 TC1 TE21 TA4 TT9 TM3 AT 1 (C/D) CV13 CV28 S14 886 1790 HYDROFLUORIC ACID with more than 85% hydrogen fluoride L10DH TU14 TE21 AT 1 (C/D) CV13 CV28 S14 886 L4DH TU14 TE21 AT 2 (E) CV13 CV28 L4BV(+) TE11 AT 80 L4BV(+) TE11 AT 2 (E) 3 (E) 1790 HYDROFLUORIC ACID with more than 60% but not more than 85% hydrogen fluoride 1790 HYDROFLUORIC ACID with not more than 60% hydrogen fluoride 1791 HYPOCHLORITE SOLUTION 1791 HYPOCHLORITE SOLUTION 2 (E) 3 (E) 80 1792 IODINE MONOCHLORIDE 80 1793 ISOPROPYL ACID PHOSPHATE 80 1794 LEAD SULPHATE with more than 3% free acid 1796 NITRATING ACID MIXTURE with more than 50% nitric acid 1796 NITRATING ACID MIXTURE with not more than 50% nitric acid 1798 NITROHYDROCHLORIC ACID 1799 NONYLTRICHLOROSILANE L4BN AT L4BN AT SGAN AT L10BH L4BN TC6 TT1 AT AT 2 (E) 1 (E) 86 80 V11 VV9 CV24 2 (E) S14 885 80 CARRIAGE PROHIBITED L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT SGAN AT 2 (E) 2 (E) 2 (E) 2 (E) 2 (E) 2 (E) 3 (E) 2 (E) X80 X80 X80 CV24 85 1802 PERCHLORIC ACID with not more than 50% acid, by mass 80 1803 PHENOLSULPHONIC ACID, LIQUID 1804 PHENYLTRICHLOROSILANE 1805 PHOSPHORIC ACID, SOLUTION X80 V12 80 V11 80 - 397 - 1800 OCTADECYLTRICHLOROSILANE 1801 OCTYLTRICHLOROSILANE 1806 PHOSPHORUS PENTACHLORIDE Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 (1) (2) 1807 PHOSPHORUS PENTOXIDE 1808 PHOSPHORUS TRIBROMIDE 1809 PHOSPHORUS TRICHLORIDE 1810 PHOSPHORUS OXYCHLORIDE 1811 POTASSIUM HYDROGENDIFLUORIDE, SOLID 1812 POTASSIUM FLUORIDE, SOLID Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 8 (3b) C2 (4) II (5) 8 (6) (7a) 1 kg (7b) E2 8 C1 II 8 1L E2 6.1 TC3 I 6.1 +8 354 0 E0 (8) P002 IBC08 P001 IBC02 P602 6.1 TC3 I 6.1 +8 354 0 E0 P602 8 CT2 II 8 +6.1 1 kg E2 P002 IBC08 6.1 5 kg 6.1 8 T5 C6 III II 8 1 kg E1 E2 8 C5 II 8 1L E2 8 C5 III 8 5L E1 1815 PROPIONYL CHLORIDE 3 FC II 1L E2 1816 PROPYLTRICHLOROSILANE 1817 PYROSULPHURYL CHLORIDE 1818 SILICON TETRACHLORIDE 8 CF1 II 0 E2 8 C1 II 3 +8 8 +3 8 1L E2 8 C1 II 8 0 E2 1819 SODIUM ALUMINATE SOLUTION 1819 SODIUM ALUMINATE SOLUTION 8 C5 II 8 1L E2 8 C5 III 8 5L E1 1823 SODIUM HYDROXIDE, SOLID 1824 SODIUM HYDROXIDE SOLUTION 1824 SODIUM HYDROXIDE SOLUTION 8 C6 II 8 1 kg E2 1826 NITRATING ACID MIXTURE, SPENT, with more than 50% nitric acid 1826 NITRATING ACID MIXTURE, SPENT, with not more than 50% nitric acid 1827 STANNIC CHLORIDE, ANHYDROUS 1828 SULPHUR CHLORIDES Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 1813 POTASSIUM HYDROXIDE, SOLID 1814 POTASSIUM HYDROXIDE SOLUTION 1814 POTASSIUM HYDROXIDE SOLUTION 1825 SODIUM MONOXIDE Packaging 8 C5 II 8 1L E2 8 C5 III 8 5L E1 8 C6 II 8 1 kg E2 P002 IBC08 LP02 R001 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P010 (9a) 4.2.5.3 (9b) MP10 4.2.5.2 7.3.2 (10) T3 MP15 T7 TP2 MP8 MP17 T20 TP2 TP35 MP8 MP17 T20 TP2 TP37 MP10 T3 TP33 MP10 T1 TP33 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP1 MP19 T7 TP1 MP15 T10 MP15 T8 TP2 TP7 TP2 MP15 T10 MP15 T7 TP2 TP7 TP2 MP19 T4 TP1 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP1 MP10 T3 TP33 MP8 MP17 T10 TP2 (11) TP33 B4 B4 B3 B4 P001 IBC02 P010 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P001 Portable tanks and bulk containers Instruc- Special tions provisions B4 B4 8 CO1 I 8 +5.1 113 0 E0 8 C1 II 8 113 1L E2 P001 IBC02 MP15 T8 TP2 8 C1 II 8 1L E2 MP15 T7 TP2 8 C1 I 8 0 E0 P001 IBC02 P602 T20 TP2 1829 SULPHUR TRIOXIDE, STABILIZED 8 C1 I 8 0 E0 P001 MP8 MP17 MP8 MP17 T20 TP4 TP25 TP26 1830 SULPHURIC ACID with more than 51% acid 1831 SULPHURIC ACID, FUMING 8 C1 II 8 1L E2 MP15 T8 TP2 8 CT1 I 0 E0 TP2 8 C1 II 1L E2 MP8 MP17 MP15 T20 1832 SULPHURIC ACID, SPENT 8 +6.1 8 P001 IBC02 P602 T8 TP2 1833 SULPHUROUS ACID 8 C1 II 8 1L E2 MP15 T7 TP2 623 113 - 398 - P001 IBC02 P001 IBC02 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) SGAN (13) L4BN L10CH TU14 TU15 TE19 TE21 L10CH TU14 TU15 TE19 TE21 Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 2 (E) AT 2 (E) AT 1 (C/D) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) V11 (17) (18) CV1 CV13 CV28 CV1 CV13 CV28 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) (20) 80 (1) (2) 1807 PHOSPHORUS PENTOXIDE X80 1808 PHOSPHORUS TRIBROMIDE 1809 PHOSPHORUS TRICHLORIDE S9 S14 668 S9 S14 X668 AT 1 (C/D) AT 2 (E) AT 2 (E) SGAN AT L4BN AT L4BN AT 2 (E) 2 (E) 3 (E) L4BH FL L4BN FL L4BN AT L4BN AT L4BN AT L4BN AT SGAN AT L4BN AT L4BN AT SGAN AT L10BH AT L4BN AT 2 (E) 80 L4BN AT X80 L10BH AT 2 (E) 1 (E) 1 (E) SGAN SGAH L10BH TU15 TE19 TU32 TE13 TT5 TM3 AT L4BN AT L10BH AT L4BN AT L4BN AT 2 (D/E) 2 (D/E) 2 (E) 2 (E) 2 (E) 3 (E) 2 (E) 2 (E) 3 (E) 2 (E) 1 (E) V11 CV13 CV28 VV9 CV13 CV28 Name and description 86 S9 V11 60 80 80 V12 80 3.1.2 1810 PHOSPHORUS OXYCHLORIDE 1811 POTASSIUM HYDROGENDIFLUORIDE, SOLID 1812 POTASSIUM FLUORIDE, SOLID 1813 POTASSIUM HYDROXIDE, SOLID 1814 POTASSIUM HYDROXIDE SOLUTION 1814 POTASSIUM HYDROXIDE SOLUTION S2 S20 338 1815 PROPIONYL CHLORIDE S2 X83 1816 PROPYLTRICHLOROSILANE 1817 PYROSULPHURYL CHLORIDE 1818 SILICON TETRACHLORIDE X80 X80 80 V12 80 V11 80 80 1819 SODIUM ALUMINATE SOLUTION 1819 SODIUM ALUMINATE SOLUTION 1823 SODIUM HYDROXIDE, SOLID 1824 SODIUM HYDROXIDE SOLUTION 1824 SODIUM HYDROXIDE SOLUTION V12 80 V11 80 1825 SODIUM MONOXIDE 885 1826 NITRATING ACID MIXTURE, SPENT, with more than 50% nitric acid 1826 NITRATING ACID MIXTURE, SPENT, with not more than 50% nitric acid 1827 STANNIC CHLORIDE, ANHYDROUS 1828 SULPHUR CHLORIDES CV24 2 (E) 1 (C/D) 2 (E) 2 (E) S14 S20 X88 S20 X88 80 CV13 CV28 - 399 - S14 X886 1829 SULPHUR TRIOXIDE, STABILIZED 1830 SULPHURIC ACID with more than 51% acid 1831 SULPHURIC ACID, FUMING 80 1832 SULPHURIC ACID, SPENT 80 1833 SULPHUROUS ACID Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 6.1 (3b) TC3 (4) I (5) 6.1 +8 (6) 354 (7a) 0 (7b) E0 (8) P602 1835 TETRAMETHYLAMMONIUM HYDROXIDE SOLUTION 1835 TETRAMETHYLAMMONIUM HYDROXIDE SOLUTION 8 C7 II 8 1L E2 P001 IBC02 8 C7 III 8 5L E1 1836 THIONYL CHLORIDE 8 C1 I 8 0 E0 P001 IBC03 LP01 R001 P802 1837 THIOPHOSPHORYL CHLORIDE 1838 TITANIUM TETRACHLORIDE 8 C1 II 8 1L E2 6.1 TC3 I 6.1 +8 0 E0 1839 TRICHLOROACETIC ACID 8 C4 II 8 1 kg E2 1840 ZINC CHLORIDE SOLUTION 8 C1 III 8 5L 1841 ACETALDEHYDE AMMONIA 9 M11 III 9 5 kg 1843 AMMONIUM DINITRO-oCRESOLATE, SOLID 1845 Carbon dioxide, solid (Dry ice) 6.1 T2 II 6.1 500 g 9 M11 1846 CARBON TETRACHLORIDE 6.1 T1 II 6.1 100 ml E4 1847 POTASSIUM SULPHIDE, HYDRATED with not less than 30% water of crystallization 8 C6 II 8 1 kg E2 1848 PROPIONIC ACID with not less than 10% and less than 90% acid by mass 8 C3 III 8 1849 SODIUM SULPHIDE, HYDRATED with not less than 30% water 1851 MEDICINE, LIQUID, TOXIC, N.O.S. 1851 MEDICINE, LIQUID, TOXIC, N.O.S. 8 C6 II 8 (1) (2) 1834 SULPHURYL CHLORIDE 6.1 T1 II 6.1 6.1 T1 III 6.1 4.2 S4 I 4.2 S4 I 4.2 4.2 2 S2 S2 2A 2 1860 VINYL FLUORIDE, STABILIZED 1854 BARIUM ALLOYS, PYROPHORIC 1855 CALCIUM, PYROPHORIC or CALCIUM ALLOYS, PYROPHORIC 1856 Rags, oily 1857 Textile waste, wet 1858 HEXAFLUOROPROPYLENE (REFRIGERANT GAS R 1216) 1859 SILICON TETRAFLUORIDE 354 523 523 221 601 221 601 (9a) P001 IBC02 P602 P002 IBC08 B4 E1 P001 IBC03 LP01 R001 E1 P002 IBC08 B3 B6 LP02 R001 E4 P002 IBC08 B4 NOT SUBJECT TO ADR 5L E1 1 kg E2 P001 IBC02 P002 IBC08 P001 IBC03 LP01 R001 P002 IBC08 4.2.5.2 7.3.2 (10) T20 4.2.5.3 MP15 T7 TP2 MP19 T7 TP2 MP8 MP17 MP15 T10 TP2 T7 TP2 MP8 MP17 T20 TP2 TP37 MP10 T3 TP33 MP19 T4 TP1 MP10 T1 TP33 MP10 T3 TP33 MP15 T7 TP2 MP10 T3 TP33 MP19 T4 TP1 MP10 T3 TP33 T21 TP7 TP33 (9b) MP8 MP17 B4 E4 P001 MP15 5L E1 MP19 4.2 0 E0 P001 LP01 R001 P404 MP13 4.2 0 E0 P404 MP13 NOT SUBJECT TO ADR NOT SUBJECT TO ADR E1 P200 120 ml 2TC 2.3 +8 0 E0 2 2F 2.1 0 1862 ETHYL CROTONATE 3 F1 II 3 1863 FUEL, AVIATION, TURBINE ENGINE 3 F1 I 3 - 400 - (11) TP2 B4 100 ml 2.2 Portable tanks and bulk containers Instruc- Special tions provisions MP9 (M) T50 P200 MP9 (M) E0 P200 MP9 (M) 1L E2 MP19 T4 TP2 500 ml E3 P001 IBC02 R001 P001 MP7 MP17 T11 TP1 TP8 TP28 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L10CH (13) TU14 TU15 TE19 TE21 Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 1 (C/D) L4BN AT 2 (E) L4BN AT 3 (E) L10BH AT L4BN AT 1 (E) 2 (E) 1 (C/D) L10CH TU14 TU15 TE19 TE21 AT SGAN L4BN L4BN AT AT SGAV AT 2 (E) 3 (E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) (17) Loading, unloading and handling 7.5.11 (18) CV1 CV13 CV28 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S9 S14 (20) X668 80 V12 80 S20 CV1 CV13 CV28 S9 S14 Name and description 3.1.2 (1) (2) 1834 SULPHURYL CHLORIDE 1835 TETRAMETHYLAMMONIUM HYDROXIDE SOLUTION 1835 TETRAMETHYLAMMONIUM HYDROXIDE SOLUTION X88 1836 THIONYL CHLORIDE X80 1837 THIOPHOSPHORYL CHLORIDE 1838 TITANIUM TETRACHLORIDE X668 V11 80 1839 TRICHLOROACETIC ACID V12 80 1840 ZINC CHLORIDE SOLUTION 90 1841 ACETALDEHYDE AMMONIA 3 (E) VV3 SGAH TU15 TE19 AT 2 V11 (D/E) NOT SUBJECT TO ADR CV13 CV28 S9 S19 60 1843 AMMONIUM DINITRO-oCRESOLATE, SOLID 1845 Carbon dioxide, solid (Dry ice) L4BH TU15 TE19 AT 2 (D/E) 2 (E) CV13 CV28 S9 S19 60 1846 CARBON TETRACHLORIDE V11 80 1847 POTASSIUM SULPHIDE, HYDRATED with not less than 30% water of crystallization SGAN L4BN AT L4BN AT 3 (E) V12 80 1848 PROPIONIC ACID with not less than 10% and less than 90% acid by mass SGAN L4BN AT 2 (E) V11 80 2 (D/E) 2 (E) 1849 SODIUM SULPHIDE, HYDRATED with not less than 30% water 1851 MEDICINE, LIQUID, TOXIC, N.O.S. 1851 MEDICINE, LIQUID, TOXIC, N.O.S. L4BH TU15 TE19 AT L4BH TU15 TE19 AT AT 0 (B/E) 0 (E) CV13 CV28 CV13 CV28 V1 TA4 TT9 AT PxBH(M) TA4 TT9 AT 1 (C/D) PxBN(M) TA4 TT9 FL 2 (B/D) LGBF FL L4BN FL 60 S9 60 S20 43 V1 S20 NOT SUBJECT TO ADR NOT SUBJECT TO ADR 3 (C/E) PxBN(M) S9 S19 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 20 1854 BARIUM ALLOYS, PYROPHORIC 1855 CALCIUM, PYROPHORIC or CALCIUM ALLOYS, PYROPHORIC 1856 Rags, oily 1857 Textile waste, wet 1858 HEXAFLUOROPROPYLENE (REFRIGERANT GAS R 1216) 1859 SILICON TETRAFLUORIDE S14 268 S2 S20 239 1860 VINYL FLUORIDE, STABILIZED 2 (D/E) S2 S20 33 1862 ETHYL CROTONATE 1 (D/E) S2 S20 33 1863 FUEL, AVIATION, TURBINE ENGINE - 401 - Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) (3a) 1863 FUEL, AVIATION, TURBINE 3 ENGINE (vapour pressure at 50 °C more than 110 kPa) 1863 FUEL, AVIATION, TURBINE 3 ENGINE (vapour pressure at 50 °C not more than 110 kPa) 1863 FUEL, AVIATION, TURBINE 3 ENGINE (3b) F1 (4) II (5) 3 (6) 640C (7a) 1L (7b) E2 (8) P001 F1 II 3 640D 1L E2 F1 III 3 5L E1 F1 II 3 1L E2 (9a) Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP19 4.2.5.2 7.3.2 (10) T4 MP19 T4 TP1 TP8 MP19 T2 TP1 MP7 MP17 T11 TP1 TP8 TP28 TP1 TP8 (11) TP1 TP8 500 ml E3 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 640C 5L E2 P001 PP1 MP19 T4 3 640D 5L E2 PP1 MP19 T4 TP1 TP8 III 3 640E 5L E1 PP1 MP19 T2 TP1 F1 III 3 640F 5L E1 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 LP01 R001 PP1 MP19 T2 TP1 3 F1 III 3 640G 5L E1 P001 LP01 R001 PP1 MP19 T2 TP1 3 F1 III 3 640H 5L E1 P001 IBC02 LP01 R001 PP1 MP19 T2 TP1 4.1 FT2 II 1 kg E2 T3 TP33 4.1 F3 III 5 kg E1 P002 IBC06 P002 IBC08 LP02 R001 MP10 1869 MAGNESIUM or MAGNESIUM ALLOYS with more than 50% magnesium in pellets, turnings or ribbons 4.1 +6.1 4.1 MP11 T1 TP33 1870 POTASSIUM BOROHYDRIDE 1871 TITANIUM HYDRIDE 4.3 W2 I 4.3 0 E0 P403 4.1 F3 II 4.1 1 kg E2 MP11 T3 TP33 1872 LEAD DIOXIDE 5.1 OT2 III 5.1 +6.1 5 kg E1 P410 IBC04 P002 IBC08 LP02 R001 P502 MP2 T1 TP33 MP3 T10 TP1 MP10 T1 TP33 MP10 T3 TP33 MP15 T7 TP2 1865 n-PROPYL NITRATE 3 1866 RESIN SOLUTION, flammable 3 F1 I 3 1866 RESIN SOLUTION, flammable (vapour pressure at 50 °C more than 110 kPa) 1866 RESIN SOLUTION, flammable (vapour pressure at 50 °C not more than 110 kPa) 1866 RESIN SOLUTION, flammable 3 F1 II 3 3 F1 II 3 F1 3 1866 RESIN SOLUTION, flammable (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1866 RESIN SOLUTION, flammable (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1866 RESIN SOLUTION, flammable (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1868 DECABORANE 1873 PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass 1884 BARIUM OXIDE 1885 BENZIDINE 1886 BENZYLIDENE CHLORIDE 5.1 OC1 I 5.1 +8 6.1 T5 III 6.1 6.1 6.1 T2 T1 II II 59 60 6.1 0 E0 5 kg E1 500 g 6.1 100 ml - 402 - E4 E4 P002 IBC08 LP02 R001 P002 IBC08 P001 IBC02 MP19 B7 B3 MP2 PP40 B3 PP28 B3 B4 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L1.5BN (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 2 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) (18) V12 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S2 S20 (20) 33 S2 S20 33 S2 30 2 (E) S2 S20 Name and description 3.1.2 (1) (2) 1863 FUEL, AVIATION, TURBINE ENGINE (vapour pressure at 50 °C more than 110 kPa) 1863 FUEL, AVIATION, TURBINE ENGINE (vapour pressure at 50 °C not more than 110 kPa) 1863 FUEL, AVIATION, TURBINE ENGINE 1865 n-PROPYL NITRATE L4BN FL 1 (D/E) S2 S20 33 1866 RESIN SOLUTION, flammable L1.5BN FL 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 1866 RESIN SOLUTION, flammable (vapour pressure at 50 °C more than 110 kPa) 1866 RESIN SOLUTION, flammable (vapour pressure at 50 °C not more than 110 kPa) 1866 RESIN SOLUTION, flammable L4BN FL 3 (D/E) S2 33 L1.5BN FL 3 (D/E) S2 33 LGBF FL 3 (D/E) S2 33 SGAN AT V11 SGAV AT 2 (E) 3 (E) 1 (E) 2 (E) 3 (E) V1 SGAN AT SGAN TU3 AT L4DN(+) TU3 TU28 AT 1 (B/E) SGAH L4BH TU15 TE19 AT 2 (E) SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT 2 (D/E) 2 (D/E) V12 CV28 46 VV1 40 CV23 S20 CV24 CV28 VV9 V11 - 403 - 1866 RESIN SOLUTION, flammable (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (boiling point not more than 35 °C) 1866 RESIN SOLUTION, flammable (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa, boiling point of more than 35 °C) 1866 RESIN SOLUTION, flammable (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1868 DECABORANE 1869 MAGNESIUM or MAGNESIUM ALLOYS with more than 50% magnesium in pellets, turnings or ribbons 40 1870 POTASSIUM BOROHYDRIDE 1871 TITANIUM HYDRIDE 56 1872 LEAD DIOXIDE CV24 S20 558 CV13 CV28 S9 60 1873 PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass 1884 BARIUM OXIDE CV13 CV28 CV13 CV28 S9 S19 60 1885 BENZIDINE S9 S19 60 1886 BENZYLIDENE CHLORIDE Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) (3a) 1887 BROMOCHLOROMETHANE 6.1 (3b) T1 (4) III (5) 6.1 (6) (7a) 5L (7b) E1 1888 CHLOROFORM 6.1 T1 III 6.1 5L E1 1889 CYANOGEN BROMIDE 6.1 TC2 I 6.1 +8 0 E5 1891 ETHYL BROMIDE 6.1 T1 II 6.1 100 ml E4 1892 ETHYLDICHLOROARSINE 6.1 T3 I 6.1 1894 PHENYLMERCURIC HYDROXIDE 1895 PHENYLMERCURIC NITRATE 1897 TETRACHLOROETHYLENE 6.1 T3 II 6.1 6.1 T3 II 354 6.1 0 E0 500 g E4 500 g E4 6.1 T1 III 6.1 5L E1 1898 ACETYL IODIDE 8 C3 II 8 1L E2 1902 DIISOOCTYL ACID PHOSPHATE 8 C3 III 8 5L E1 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 8 C9 I 8 274 0 E0 8 C9 II 8 274 1L E2 8 C9 III 8 274 5L 1905 SELENIC ACID 8 C2 I 8 0 1906 SLUDGE ACID 8 C1 II 8 1L 1907 SODA LIME with more than 4% sodium hydroxide 8 C6 III 8 62 5 kg 1908 CHLORITE SOLUTION 8 C9 II 8 521 1L 1908 CHLORITE SOLUTION 8 C9 III 8 521 5L 1910 Calcium oxide 8 C6 1911 DIBORANE 2 2TF 2.3 +2.1 1912 METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE 1913 NEON, REFRIGERATED LIQUID 2 2F 2.1 2 3A 2.2 1914 BUTYL PROPIONATES 3 F1 III 1915 CYCLOHEXANONE 3 F1 6.1 TF1 1916 2,2'-DICHLORODIETHYL ETHER Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 (8) P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P002 P001 IBC02 P602 P002 IBC08 P002 IBC08 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 (9a) Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP19 4.2.5.2 7.3.2 (10) T4 MP19 T7 TP2 MP18 T6 TP33 MP15 T7 TP2 MP8 MP17 T20 TP2 TP37 MP10 T3 TP33 MP10 T3 TP33 MP19 T4 TP1 MP15 T7 TP2 MP19 T4 TP1 MP18 T6 TP33 MP15 T8 MP10 T1 TP2 TP28 TP33 MP15 T7 MP19 T4 (11) TP1 B8 B4 B4 P001 IBC02 E1 P001 IBC03 LP01 R001 E0 P002 IBC07 E2 P001 IBC02 E1 P002 IBC08 B3 LP02 R001 E2 P001 IBC02 E1 P001 IBC03 LP01 R001 NOT SUBJECT TO ADR MP8 MP17 MP15 MP19 TP2 TP24 TP2 TP24 0 E0 P200 MP9 228 0 E0 P200 MP9 (M) T50 593 120 ml E1 P203 MP9 T75 TP5 3 5L E1 MP19 T2 TP1 III 3 5L E1 MP19 T2 TP1 II 6.1 +3 100 ml E4 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 MP15 T7 TP2 - 404 - Copyright © United Nations, 2010. All rights reserved ADR tank Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 2 (E) Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) L4BH (13) TU15 TE19 L4BH TU15 TE19 AT 2 (E) S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT 2 (D/E) 1 (C/D) SGAH TU15 TE19 AT SGAH TU15 TE19 AT L4BH TU15 TE19 AT L4BN AT L4BN AT L10BH AT L4BN AT L4BN AT S10AN AT L4BN AT SGAV AT L4BV(+) TE11 AT L4BV(+) TE11 AT 2 (D/E) 2 (D/E) 2 (E) 2 (E) 3 (E) 1 (E) 2 (E) 3 (E) 1 (E) 2 (E) 3 (E) 2 (E) 3 (E) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) V12 (17) Loading, unloading and handling 7.5.11 V12 V11 V11 V12 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (18) CV13 CV28 (19) S9 (20) 60 CV13 CV28 S9 60 1888 CHLOROFORM CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 S9 S14 668 1889 CYANOGEN BROMIDE S9 S19 60 1891 ETHYL BROMIDE S9 S14 66 1892 ETHYLDICHLOROARSINE S9 S19 60 S9 S19 60 S9 60 1894 PHENYLMERCURIC HYDROXIDE 1895 PHENYLMERCURIC NITRATE 1897 TETRACHLOROETHYLENE 80 1898 ACETYL IODIDE 80 1902 DIISOOCTYL ACID PHOSPHATE 88 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. V12 S20 80 V12 80 V10 S20 VV9 V12 FL 2 (B/D) RxBN TU19 TA4 TT9 AT 3 (C/E) V5 LGBF FL 3 (D/E) LGBF FL 3 (D/E) FL 2 (D/E) L4BH TU15 TE19 (1) (2) 1887 BROMOCHLOROMETHANE 1905 SELENIC ACID 80 1906 SLUDGE ACID 80 1907 SODA LIME with more than 4% sodium hydroxide 80 1908 CHLORITE SOLUTION 80 1908 CHLORITE SOLUTION 1910 Calcium oxide 1 (D) TA4 TT9 3.1.2 88 NOT SUBJECT TO ADR PxBN(M) Name and description CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV11 CV36 S2 S14 1911 DIBORANE S2 S20 23 S20 22 V12 S2 30 1914 BUTYL PROPIONATES V12 S2 30 1915 CYCLOHEXANONE S2 S9 S19 63 1916 2,2'-DICHLORODIETHYL ETHER CV13 CV28 - 405 - 1912 METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE 1913 NEON, REFRIGERATED LIQUID Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 3 (3b) F1 (4) II (5) 3 (6) (7a) 1L (7b) E2 1918 ISOPROPYLBENZENE 3 F1 III 3 5L E1 1919 METHYL ACRYLATE, STABILIZED 3 F1 II 3 1L E2 1920 NONANES 3 F1 III 3 5L E1 1921 PROPYLENEIMINE, STABILIZED 1922 PYRROLIDINE 3 FT1 I 0 E0 3 FC II 1L E2 4.2 S4 II 3 +6.1 3 +8 4.2 0 E2 4.3 WF1 I 4.3 +3 0 E0 P402 4.2 S4 II 4.2 0 E2 P410 IBC06 9 M11 III 9 5 kg E1 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P001 (1) (2) 1917 ETHYL ACRYLATE, STABILIZED 1923 CALCIUM DITHIONITE (CALCIUM HYDROSULPHITE) 1928 METHYL MAGNESIUM BROMIDE IN ETHYL ETHER 1929 POTASSIUM DITHIONITE (POTASSIUM HYDROSULPHITE) 1931 ZINC DITHIONITE (ZINC HYDROSULPHITE) 1932 ZIRCONIUM SCRAP 4.2 S4 III 4.2 524 592 0 E1 1935 CYANIDE SOLUTION, N.O.S. 6.1 T4 I 6.1 274 525 0 E5 1935 CYANIDE SOLUTION, N.O.S. 1935 CYANIDE SOLUTION, N.O.S. 6.1 T4 II 6.1 100 ml E4 6.1 T4 III 6.1 274 525 274 525 5L E1 1938 BROMOACETIC ACID SOLUTION 1938 BROMOACETIC ACID SOLUTION 8 C3 II 8 1L E2 8 C3 III 8 5L E1 1939 PHOSPHORUS OXYBROMIDE 1940 THIOGLYCOLIC ACID 8 C2 II 8 1 kg E2 (8) P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 (9a) P001 IBC02 P410 IBC06 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 LP01 R001 P002 IBC08 P001 IBC02 P001 LP01 R001 P002 IBC08 LP02 R001 RR8 4.2.5.3 (9b) MP19 4.2.5.2 7.3.2 (10) T4 MP19 T2 TP1 MP19 T4 TP1 MP19 T2 TP1 MP2 T14 TP2 MP19 T7 TP1 MP14 T3 TP33 MP14 T3 TP33 MP10 T1 TP33 MP14 T1 TP33 MP8 MP17 T14 TP2 TP27 MP15 T11 MP19 T7 TP2 TP27 TP2 TP28 MP15 T7 TP2 MP19 T7 TP2 MP10 T3 TP33 MP15 T7 TP2 MP15 T11 TP2 MP10 T1 BK1 BK2 TP33 B3 B3 B4 C3 II 8 1L E2 9 M11 III 9 5L E1 1942 AMMONIUM NITRATE with not more than 0.2% total combustible material, including any organic substance calculated as carbon, to the exclusion of any other added substance 1944 MATCHES, SAFETY (book, card or strike on box) 5.1 O2 III 5.1 306 611 5 kg E1 4.1 F1 III 4.1 293 5 kg E1 P407 R001 MP11 1945 MATCHES, WAX 'VESTA' 4.1 F1 III 4.1 293 5 kg E1 P407 R001 MP11 - 406 - (11) TP1 MP2 8 1941 DIBROMODIFLUOROMETHANE Portable tanks and bulk containers Instruc- Special tions provisions B3 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) LGBF (13) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) FL 1 (C/E) 2 (D/E) 2 (D/E) L15CH TU14 TU15 TE21 L4BH FL SGAN AT L10DH TU4 TU14 TU22 TE21 TM2 Special provisions for carriage Packages Bulk 7.2.4 7.3.3 Loading, unloading and handling 7.5.11 (16) (17) (18) V12 V12 CV13 CV28 0 (B/E) V1 SGAN AT 2 (D/E) V1 SGAV AT 3 (E) SGAN AT 3 (E) TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (E) L4BN AT L4BN AT SGAN AT L4BN AT L4BN AT SGAV TU3 AT 5.3.2.3 (19) S2 S20 (20) 339 S2 30 1918 ISOPROPYLBENZENE S2 S20 339 1919 METHYL ACRYLATE, STABILIZED S2 30 1920 NONANES S2 S22 336 S2 S20 338 1921 PROPYLENEIMINE, STABILIZED 1922 PYRROLIDINE V1 40 CV23 S2 S20 3 (E) X323 40 3.1.2 (1) (2) 1917 ETHYL ACRYLATE, STABILIZED 1923 CALCIUM DITHIONITE (CALCIUM HYDROSULPHITE) 1928 METHYL MAGNESIUM BROMIDE IN ETHYL ETHER 1929 POTASSIUM DITHIONITE (POTASSIUM HYDROSULPHITE) VV3 90 1931 ZINC DITHIONITE (ZINC HYDROSULPHITE) VV4 40 1932 ZIRCONIUM SCRAP S9 S14 66 1935 CYANIDE SOLUTION, N.O.S. S9 S19 60 S9 60 1935 CYANIDE SOLUTION, N.O.S. 1935 CYANIDE SOLUTION, N.O.S. CV1 CV13 CV28 CV13 CV28 CV13 CV28 V12 2 (E) 3 (E) 2 (E) 2 (E) 3 (E) Name and description 8.5 V1 FL L10CH Hazard UN identifi- No. Operation cation No. 80 80 V11 80 80 VV8 4 (E) 4 (E) CV24 S23 1938 BROMOACETIC ACID SOLUTION 1938 BROMOACETIC ACID SOLUTION 1939 PHOSPHORUS OXYBROMIDE 1940 THIOGLYCOLIC ACID 90 1941 DIBROMODIFLUOROMETHANE 50 1942 AMMONIUM NITRATE with not more than 0.2% total combustible material, including any organic substance calculated as carbon, to the exclusion of any other added substance 1944 MATCHES, SAFETY (book, card or strike on box) 1945 MATCHES, WAX 'VESTA' - 407 - Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 2 (3b) 5A (4) (5) 2.2 (7a) 1L (7b) E0 (8) P003 1950 AEROSOLS, corrosive 2 5C 2.2 +8 1L E0 LP02 P003 1950 AEROSOLS, corrosive, oxidizing 2 5CO 2.2 +5.1 +8 1L E0 LP02 P003 1950 AEROSOLS, flammable 2 5F 2.1 1L E0 LP02 P003 1950 AEROSOLS, flammable, corrosive 2 5FC 2.1 +8 1L E0 LP02 P003 1950 AEROSOLS, oxidizing 2 5O 2.2 +5.1 1L E0 LP02 P003 1950 AEROSOLS, toxic 2 5T 2.2 +6.1 120 ml E0 LP02 P003 1950 AEROSOLS, toxic, corrosive 2 5TC 2.2 +6.1 +8 120 ml E0 LP02 P003 1950 AEROSOLS, toxic, flammable 2 5TF 2.1 +6.1 120 ml E0 LP02 P003 1950 AEROSOLS, toxic, flammable, corrosive 2 5TFC 2.1 +6.1 +8 120 ml E0 LP02 P003 1950 AEROSOLS, toxic, oxidizing 2 5TO 2.2 +5.1 +6.1 120 ml E0 LP02 P003 1950 AEROSOLS, toxic, oxidizing, corrosive 2 5TOC 120 ml E0 LP02 P003 1951 ARGON, REFRIGERATED LIQUID 2 3A 2.2 +5.1 +6.1 +8 2.2 (6) 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 593 120 ml E1 LP02 P203 1952 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with not more than 9% ethylene oxide 1953 COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. 2 2A 2.2 120 ml E1 2 1TF 2.3 +2.1 274 0 1954 COMPRESSED GAS, FLAMMABLE, N.O.S. 2 1F 2.1 274 1955 COMPRESSED GAS, TOXIC, N.O.S. 2 1T 2.3 1956 COMPRESSED GAS, N.O.S. 2 1A 2.2 1957 DEUTERIUM, COMPRESSED 2 1F 1958 1,2-DICHLORO-1,1,2,2TETRAFLUOROETHANE (REFRIGERANT GAS R 114) 2 2A (1) (2) 1950 AEROSOLS, asphyxiant Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.2 7.3.2 (10) 4.2.5.3 MP9 T75 TP5 P200 MP9 (M) E0 P200 MP9 (M) 0 E0 P200 MP9 (M) 274 0 E0 P200 MP9 (M) 274 120 ml E1 P200 MP9 (M) 2.1 0 E0 P200 MP9 (M) 2.2 120 ml E1 P200 MP9 (M) T50 - 408 - (9a) PP17 PP87 RR6 L2 PP17 PP87 RR6 L2 PP17 PP87 RR6 L2 PP17 PP87 RR6 L2 PP17 PP87 RR6 L2 PP17 PP87 RR6 L2 PP17 PP87 RR6 L2 PP17 PP87 RR6 L2 PP17 PP87 RR6 L2 PP17 PP87 RR6 L2 PP17 PP87 RR6 L2 PP17 PP87 RR6 L2 (9b) MP9 (11) MP9 MP9 MP9 MP9 MP9 MP9 MP9 MP9 MP9 MP9 MP9 Copyright © United Nations, 2010. All rights reserved ADR tank Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) (13) RxBN PxBN(M) CxBH(M) CxBN(M) CxBH(M) CxBN(M) Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) 3 (E) Packages Bulk 7.2.4 7.3.3 (16) V14 (17) Loading, unloading and handling 7.5.11 (18) CV9 CV12 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) (20) Name and description 3.1.2 (1) (2) 1950 AEROSOLS, asphyxiant 1 (E) V14 CV9 CV12 1950 AEROSOLS, corrosive 1 (E) V14 CV9 CV12 1950 AEROSOLS, corrosive, oxidizing 2 (D) V14 CV9 CV12 S2 1950 AEROSOLS, flammable 1 (D) V14 CV9 CV12 S2 1950 AEROSOLS, flammable, corrosive 3 (E) V14 CV9 CV12 1950 AEROSOLS, oxidizing 1 (D) V14 CV9 CV12 CV28 1950 AEROSOLS, toxic 1 (D) V14 CV9 CV12 CV28 1950 AEROSOLS, toxic, corrosive 1 (D) V14 CV9 CV12 CV28 S2 1950 AEROSOLS, toxic, flammable 1 (D) V14 CV9 CV12 CV28 S2 1950 AEROSOLS, toxic, flammable, corrosive 1 (D) V14 CV9 CV12 CV28 1950 AEROSOLS, toxic, oxidizing 1 (D) V14 CV9 CV12 CV28 1950 AEROSOLS, toxic, oxidizing, corrosive V5 CV9 CV11 CV36 CV9 CV10 CV36 S20 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 S2 S14 263 S2 S20 23 1954 COMPRESSED GAS, FLAMMABLE, N.O.S. S14 26 1955 COMPRESSED GAS, TOXIC, N.O.S. 20 1956 COMPRESSED GAS, N.O.S. 23 1957 DEUTERIUM, COMPRESSED 20 1958 1,2-DICHLORO-1,1,2,2TETRAFLUOROETHANE (REFRIGERANT GAS R 114) TU19 TA4 TT9 TA4 TT9 AT 3 (C/E) AT 3 (C/E) TU6 TA4 TT9 TA4 TT9 FL 1 (B/D) FL 2 (B/D) AT 1 (C/D) AT 3 (E) TU6 TA4 TT9 TA4 TT9 Special provisions for carriage CxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 AT 3 (C/E) - 409 - S2 S20 22 1951 ARGON, REFRIGERATED LIQUID 20 1952 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with not more than 9% ethylene oxide 1953 COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 2 (3b) 2F (4) (5) 2.1 (6) (7a) 0 (7b) E0 (8) P200 2 3F 2.1 0 E0 1962 ETHYLENE 2 2F 2.1 0 1963 HELIUM, REFRIGERATED LIQUID 2 3A 2.2 593 1964 HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. 1965 HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S. such as mixtures A, A01, A02, A0, A1, B1, B2, B or C 1966 HYDROGEN, REFRIGERATED LIQUID 2 1F 2.1 2 2F 2.1 2 3F 2.1 1967 INSECTICIDE GAS, TOXIC, N.O.S. 2 2T 2.3 1968 INSECTICIDE GAS, N.O.S. 2 2A 2.2 1969 ISOBUTANE 2 2F 2.1 1970 KRYPTON, REFRIGERATED LIQUID 2 3A 2.2 1971 METHANE, COMPRESSED or NATURAL GAS, COMPRESSED with high methane content 1972 METHANE, REFRIGERATED LIQUID or NATURAL GAS, REFRIGERATED LIQUID 1973 CHLORODIFLUOROMETHANE AND CHLOROPENTAFLUOROETHANE MIXTURE with fixed boiling point, with approximately 49% chlorodifluoromethane (REFRIGERANT GAS R 502) 1974 CHLORODIFLUOROBROM O-METHANE (REFRIGERANT GAS R 1975 NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURE (NITRIC OXIDE AND NITROGEN DIOXIDE MIXTURE) 1976 OCTAFLUOROCYCLOBUTANE (REFRIGERANT GAS RC 318) 1977 NITROGEN, REFRIGERATED LIQUID 2 1F 2 Portable tanks and bulk containers Instruc- Special tions provisions 4.2.5.3 (9b) MP9 4.2.5.2 7.3.2 (10) (M) P203 MP9 T75 TP5 E0 P200 MP9 (M) 120 ml E1 P203 MP9 T75 274 0 E0 P200 MP9 (M) 274 583 652 0 E0 P200 MP9 (M) T50 0 E0 P203 MP9 T75 274 0 E0 P200 MP9 (M) 274 120 ml E1 P200 MP9 (M) 0 E0 P200 MP9 (M) T50 120 ml E1 P203 MP9 T75 2.1 0 E0 P200 MP9 (M) 3F 2.1 0 E0 P203 MP9 T75 2 2A 2.2 120 ml E1 P200 MP9 (M) T50 2 2A 2.2 120 ml E1 P200 MP9 (M) T50 2 2TOC 2.3 +5.1 +8 0 E0 P200 MP9 2 2A 2.2 120 ml E1 P200 MP9 (M) T50 2 3A 2.2 120 ml E1 P203 MP9 T75 1978 PROPANE 2 2F 2.1 0 E0 P200 MP9 (M) T50 1982 TETRAFLUOROMETHANE (REFRIGERANT GAS R 14) 2 2A 2.2 120 ml E1 P200 MP9 (M) (1) (2) 1959 1,1-DIFLUOROETHYLENE (REFRIGERANT GAS R 1132a) 1961 ETHANE, REFRIGERATED LIQUID 593 345 346 593 652 - 410 - (9a) (11) TP5 TP34 TP5 TP23 TP34 TP5 TP5 TP5 Copyright © United Nations, 2010. All rights reserved ADR tank Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) FL 2 (B/D) Tank code Special provisions 4.3 4.3.5, 6.8.4 (12) PxBN(M) (13) TA4 TT9 RxBN TU18 TA4 TT9 TA4 TT9 FL 2 (B/D) FL 2 (B/D) TU19 TA4 TT9 TA4 TT9 AT 3 (C/E) FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) RxBN TU18 TA4 TT9 TU6 TA4 TT9 TA4 TT9 FL 2 (B/D) AT 1 (C/D) AT 3 (C/E) PxBN(M) RxBN CxBN(M) PxBH(M) PxBN(M) Special provisions for carriage Packages Bulk 7.2.4 7.3.3 (16) (17) Loading, unloading and handling 7.5.11 V5 V5 V5 (18) CV9 CV10 CV36 CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV11 CV36 CV9 CV10 CV36 Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) S2 S20 (20) 239 S2 S17 223 S2 S20 23 1962 ETHYLENE S20 22 1963 HELIUM, REFRIGERATED LIQUID S2 S20 23 S2 S20 23 S2 S17 223 1964 HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. 1965 HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S. such as mixtures A, A01, A02, A0, A1, B1, B2, B or C 1966 HYDROGEN, REFRIGERATED LIQUID S14 26 1967 INSECTICIDE GAS, TOXIC, N.O.S. 20 1968 INSECTICIDE GAS, N.O.S. S2 S20 23 1969 ISOBUTANE S20 22 1970 KRYPTON, REFRIGERATED LIQUID S2 S20 23 S2 S17 223 1971 METHANE, COMPRESSED or NATURAL GAS, COMPRESSED with high methane content 1972 METHANE, REFRIGERATED LIQUID or NATURAL GAS, REFRIGERATED LIQUID 1973 CHLORODIFLUOROMETHANE AND CHLOROPENTAFLUOROETHANE MIXTURE with fixed boiling point, with approximately 49% chlorodifluoromethane (REFRIGERANT GAS R 502) 1974 CHLORODIFLUOROBROM O-METHANE (REFRIGERANT GAS R 1975 NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURE (NITRIC OXIDE AND NITROGEN DIOXIDE MIXTURE) 1976 OCTAFLUOROCYCLOBUTANE (REFRIGERANT GAS RC 318) 1977 NITROGEN, REFRIGERATED LIQUID PxBN(M) TA4 TT9 FL 2 (B/D) RxBN TU19 TA4 TT9 TA4 TT9 AT 3 (C/E) FL 2 (B/D) RxBN TU18 TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 AT 3 (C/E) CV9 CV10 CV36 20 PxBN(M) TA4 TT9 AT 3 (C/E) CV9 CV10 CV36 CV9 CV10 CV36 20 CxBN(M) V5 V5 CV9 CV11 CV36 1 (D) PxBN(M) TA4 TT9 AT 3 (C/E) RxBN TU19 TA4 TT9 TA4 TT9 AT 3 (C/E) FL 2 (B/D) TA4 TT9 AT 3 (C/E) PxBN(M) PxBN(M) CV9 CV10 CV36 CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV10 CV36 V5 - 411 - Name and description S14 20 3.1.2 (1) (2) 1959 1,1-DIFLUOROETHYLENE (REFRIGERANT GAS R 1132a) 1961 ETHANE, REFRIGERATED LIQUID S20 22 S2 S20 23 1978 PROPANE 20 1982 TETRAFLUOROMETHANE (REFRIGERANT GAS R 14) Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special provication group sions code Limited and excepted quantities Packaging Packing Special Mixed instruc- packing packing tions provisions provisions 4.1.4 4.1.4 4.1.10 Portable tanks and bulk containers Instruc- Special tions provisions 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (1) (2) 1983 1-CHLORO-2,2,2TRIFLUOROETHANE (REFRIGERANT GAS R 1984 TRIFLUOROMETHANE (REFRIGERANT GAS R 23) (3a) 2 (3b) 2A (4) (5) 2.2 (6) (7a) 120 ml (7b) E1 (8) P200 2 2A 120 ml E1 P200 MP9 (M) 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3 FT1 I 3 +6.1 274 0 E0 P001 MP7 MP17 T14 TP2 TP27 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3 FT1 II 3 +6.1 274 1L E2 P001 IBC02 MP19 T11 TP2 TP27 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3 FT1 III 3 +6.1 274 5L E1 MP19 T7 TP1 TP28 1987 ALCOHOLS, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 3 F1 II 3 274 601 640C 1L E2 P001 IBC03 R001 P001 MP19 T7 TP1 TP8 TP28 1987 ALCOHOLS, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1987 ALCOHOLS, N.O.S. 3 F1 II 3 1L E2 T7 F1 III 3 5L E1 MP19 T4 TP1 TP8 TP28 TP1 TP29 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 1989 ALDEHYDES, N.O.S. 3 FT1 I 3 +6.1 274 0 E0 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 MP19 3 274 601 640D 274 601 MP7 MP17 T14 TP2 TP27 3 FT1 II 3 +6.1 274 1L E2 P001 IBC02 MP19 T11 TP2 TP27 3 FT1 III 3 +6.1 274 5L E1 MP19 T7 TP1 TP28 3 F1 I 3 274 0 E3 P001 IBC03 R001 P001 T11 1989 ALDEHYDES, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 3 F1 II 3 274 640C 1L E2 P001 MP7 MP17 MP19 TP1 TP27 TP1 TP8 TP28 1989 ALDEHYDES, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1989 ALDEHYDES, N.O.S. 3 F1 II 3 274 640D 1L E2 MP19 T7 3 F1 III 3 274 5L E1 MP19 T4 1990 BENZALDEHYDE 9 M11 III 9 5L E1 MP15 T2 TP1 1991 CHLOROPRENE, STABILIZED 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 3 FT1 I 0 E0 FT1 I 274 0 E0 P001 3 FT1 II 274 1L E2 TP2 TP6 TP2 TP27 TP2 3 FT1 III 274 5L E1 MP19 T7 TP1 TP28 3 F1 I 3 274 0 E3 P001 IBC02 P001 IBC03 R001 P001 MP7 MP17 MP7 MP17 MP19 T14 3 3 +6.1 3 +6.1 3 +6.1 3 +6.1 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 T11 3 F1 II 3 1L E2 P001 3 F1 II 3 274 601 640C 274 601 640D MP7 MP17 MP19 1L E2 P001 IBC02 R001 MP19 T7 TP1 TP27 TP1 TP8 TP28 TP1 TP8 TP28 1993 FLAMMABLE LIQUID, N.O.S. 1993 FLAMMABLE LIQUID, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 1993 FLAMMABLE LIQUID, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 2.2 - 412 - (9a) (9b) MP9 4.2.5.2 7.3.2 (10) (M) T50 T7 T14 T7 T7 4.2.5.3 (11) TP1 TP8 TP28 TP1 TP29 Copyright © United Nations, 2010. All rights reserved ADR tank Vehicle for Transport category tank (Tunnel carriage restriction code) 9.1.1.2 1.1.3.6 (8.6) (14) (15) AT 3 (C/E) Special provisions for carriage Tank code Special provisions Packages Bulk 7.2.4 7.3.3 (16) (17) Loading, unloading and handling 7.5.11 4.3 4.3.5, 6.8.4 (12) PxBN(M) (13) TA4 TT9 PxBN(M) TA4 TT9 AT 3 (C/E) L10CH TU14 TU15 TE21 FL 1 (C/E) (18) CV9 CV10 CV36 CV9 CV10 CV36 CV13 CV28 L4BH TU15 FL 2 (D/E) L4BH TU15 FL 3 (D/E) L1.5BN FL LGBF LGBF Hazard UN identifi- No. Operation cation No. 8.5 5.3.2.3 (19) (20) 20 20 Name and description 3.1.2 (1) (2) 1983 1-CHLORO-2,2,2TRIFLUOROETHANE (REFRIGERANT GAS R 1984 TRIFLUOROMETHANE (REFRIGERANT GAS R 23) S2 S22 336 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. CV13 CV28 S2 S22 336 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. CV13 CV28 S2 36 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 2 (D/E) S2 S20 33 1987 ALCOHOLS, N.O.S. (vapour pressure at 50 °C more than 110 kPa) FL 2 (D/E) S2 S20 33 FL 3 (D/E) S2 30 1987 ALCOHOLS, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1987 ALCOHOLS, N.O.S. V12 V12 L10CH TU14 TU15 TE21 FL 1 (C/E) CV13 CV28 S2 S22 336 L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S22 336 L4BH TU15 FL 3 (D/E) CV13 CV28 S2 36 L4BN FL S2 S20 33 L1.5BN FL 1 (D/E) 2 (D/E) S2 S20 33 1989 ALDEHYDES, N.O.S. (vapour pressure at 50 °C more than 110 kPa) LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) V12 S2 30 1989 ALDEHYDES, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1989 ALDEHYDES, N.O.S. LGBV AT 3 (E) V12 90 1990 BENZALDEHYDE FL 1 (C/E) 1 (C/E) 2 (D/E) 3 (D/E) S2 S22 336 S2 S22 336 S2 S22 336 S2 36 1991 CHLOROPRENE, STABILIZED 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 1 (D/E) 2 (D/E) S2 S20 33 S2 S20 33 2 (D/E) S2 S20 33 L10CH L4BH TU14 TU15 TE21 TU14 TU15 TE21 TU15 FL L4BH TU15 FL L10CH FL L4BN FL L1.5BN FL LGBF FL V12 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 V12 - 413 - 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 1989 ALDEHYDES, N.O.S. 1993 FLAMMABLE LIQUID, N.O.S. 1993 FLAMMABLE LIQUID, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 1993 FLAMMABLE LIQUID, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) Copyright © United Nations, 2010. All rights reserved UN No. Name and description 3.1.2 Class Classifi- Packing Labels Special cation provigroup code sions Limited and excepted quantities 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (3a) 3 (3b) F1 (4) III (5) 3 (6) 274 601 640E (7a) 5L (7b) E1 3 F1 III 3 274 601 640F 5L E1 3 F1 III 3 274 601 640G 5L E1 3 F1 III 3 274 601 640H 5L 6.1 TF1 I 6.1 +3 354 1999 TARS, LIQUID, including road oils, and cutback bitumens (vapour pressure at 50 °C more than 110 kPa) 3 F1 II 3 1999 TARS, LIQUID, including road oils, and cutback bitumens (vapour pressure at 50 °C not more than 110 kPa) 1999 TARS, LIQUID, including road oils, and cutback bitumens 3 F1 II