organometallic chemistry of the transition metals

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Propose a structure for [Mn(µ-PH2)(L)4]3, show all your work and discuss why you think your structure is correct.

metal fragment, MLn, might you suggest for creating LnM=MLn, analogous to HC=CH?

bond energy for vanadocene is higher than that of ferrocene.

structure (η5 -C5H5)(PPh3)Ir(η2 -NCC6H4Cl)

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CHEM 507 Advanced Inorganic Brian Bellott Spring 2018 Homework 4 This homework set is due at the start of class Friday. Please turn in the homework on pages separate from this one. Turn in the problems in the order they were assigned. Remove any “spiral fringe” from the homework prior to turning in the homework set, failure to do so will result in the loss of 5 points. 1. Propose a structure for [Mn(µ-PH2)(L)4]3, show all your work and discuss why you think your structure is correct. 2. What metal fragment, MLn, might you suggest for creating LnM=MLn, analogous to HC=CH? Why? 3. The average bond energy for vanadocene is higher than that of ferrocene. Why? 4. Discuss the following structure (η5-C5H5)(PPh3)Ir(η2-NCC6H4Cl). What is somewhat unique about the structure?
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hello buddy if you will have any question concerning the assignment, please let me know
Attached.

Running Head: Organometallic Chemistry

1

Student Name:
Institution Affiliation:
Date:

ADVANCED INORGANIC

2

1. Propose a structure for [Mn(μ-PH2)(L)4]3, show all your work and discuss why you
think your structure is correct
The structure for [Mn(μ-PH2)(L)4]

L

L

L

L

Mn
H

H

P

H

L

Mn

P

H

Mn

L
L

L
L

L

P

L

L
H

H

Consider the 18 ...


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