Hazardous Materials and the Environment

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fvfu1990

Science

Description

Identify a safe system of work to handle and transport (Aviation Fuel ‘kerosene’).

You will need to:

  • Identify the hazards associated with the chemical agent
  • List and explain the physical properties of the agent
  • Describe the storage and transportation methods for this agent
  • Identify any short and longer term environmental hazards associated with this agent.

Also, carefully consider this points below:

- Concise and clear purpose of the work

- Clarity and focus upon the report aim

- Coherence of research and findings

- Make use of appropriate evidence to support conclusions

- Evidence of understanding of legal and other guidance and its application to the case study

- Well presented with a good structure, Spelling, Grammar and Punctuation



*** Word count: 1500 words.

*** In-Text Citation and references using Harvard style.

*** Note: book has been uploaded named: “Emergency Response Guidebook 2000 and 2016”

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SHIPPING DOCUMENTS (PAPERS)* The shipping document provides vital information when responding to a hazardous materials/dangerous goods** incident. The shipping document contains information needed to identify the materials involved. Use this information to initiate protective actions for your own safety and the safety of the public. The shipping document contains the proper shipping name (see bluebordered pages), the hazard class or division of the material(s), ID number (see yellow-bordered pages), and, where appropriate, the Packing Group. In addition, there must be information available that describes the hazards of the material which can be used in the mitigation of an incident. The information must be entered on or be with the shipping document. This requirement may be satisfied by attaching a guide from the ERG2000 to the shipping document, or by having the entire guidebook available for ready reference. Shipping documents are required for most dangerous goods in transportation. Shipping documents are kept in • the cab of the motor vehicle, • the possession of the train crew member, • a holder on the bridge of a vessel, or • an aircraft pilot’s possession. EMERGENCY CONTACT 1-000-000-0000 EXAMPLE OF EMERGENCY RESPONSE TELEPHONE NUMBER NO. & TYPE OF PACKAGES DESCRIPTION OF ARTICLES 1 TANK TRUCK ISOPROPANOL SHIPPING NAME HAZARD CLASS OR DIVISION NO. 3 UN1219 QUANTITY II ID NUMBER 3,000 LITERS PACKING GROUP EXAMPLE OF PLACARD AND PANEL WITH ID NUMBER The 4-digit ID Number may be shown on the diamond-shaped placard or on an adjacent orange panel displayed on the ends and sides of a cargo tank, vehicle or rail car. 1219 A Numbered Placard or A Placard and an Orange Panel FLAMMABLE 1219 * For the purposes of this book, the terms shipping document/shipping paper are synonymous. ** For the purposes of this book, the terms hazardous materials/dangerous goods are synonymous. RESIST RUSHING IN ! APPROACH INCIDENT FROM UPWIND STAY CLEAR OF ALL SPILLS, VAPORS, FUMES AND SMOKE HOW TO USE THIS GUIDEBOOK DURING AN INCIDENT INVOLVING DANGEROUS GOODS ON E IDENTIFY THE MATERIAL BY FINDING ANY ONE OF THE FOLLOWING: THE 4-DIGIT ID NUMBER ON A PLACARD OR ORANGE PANEL THE 4-DIGIT ID NUMBER (after UN/NA) ON A SHIPPING DOCUMENT OR PACKAGE THE NAME OF THE MATERIAL ON A SHIPPING DOCUMENT, PLACARD OR PACKAGE IF AN ID NUMBER OR THE NAME OF THE MATERIAL CANNOT BE FOUND, SKIP TO THE NOTES BELOW. T WO LOOK UP THE MATERIAL’S 3-DIGIT GUIDE NUMBER IN EITHER: THE ID NUMBER INDEX..(the yellow-bordered pages of the guidebook) THE NAME OF MATERIAL INDEX..(the blue-bordered pages of the guidebook) If the guide number is supplemented with the letter “P”, it indicates that the material may undergo violent polymerization if subjected to heat or contamination. If the index entry is highlighted (in either yellow or blue), it is a TIH (Toxic Inhalation Hazard) material or a Dangerous Water Reactive Material (produces toxic gas upon contact with water). LOOK FOR THE ID NUMBER AND NAME OF THE MATERIAL IN THE TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES (the green-bordered pages). Then, if necessary, BEGIN PROTECTIVE ACTIONS IMMEDIATELY (see Protective Actions on page 314). If protective action is not required, use the information jointly with the 3-digit guide. USE GUIDE 112 FOR ALL EXPLOSIVES EXCEPT FOR EXPLOSIVES 1.4 (EXPLOSIVES C) WHERE GUIDE 114 IS TO BE CONSULTED. THREE TURN TO THE NUMBERED GUIDE (the orange-bordered pages) AND READ CAREFULLY. NOTES IF A NUMBERED GUIDE CANNOT BE OBTAINED BY FOLLOWING THE ABOVE STEPS, AND A PLACARD CAN BE SEEN, LOCATE THE PLACARD IN THE TABLE OF PLACARDS (pages 16-17), THEN GO TO THE 3-DIGIT GUIDE SHOWN NEXT TO THE SAMPLE PLACARD. IF A REFERENCE TO A GUIDE CANNOT BE FOUND AND THIS INCIDENT IS BELIEVED TO INVOLVE DANGEROUS GOODS, TURN TO GUIDE 111 NOW, AND USE IT UNTIL ADDITIONAL INFORMATION BECOMES AVAILABLE. If the shipping document lists an emergency response telephone number, call that number. If the shipping document is not available, or no emergency response telephone number is listed, IMMEDIATELY CALL the appropriate emergency response agency listed on the inside back cover of this guidebook. Provide as much information as possible, such as the name of the carrier (trucking company or railroad) and vehicle number. AS A LAST RESORT, CONSULT THE TABLE OF RAIL CAR AND ROAD TRAILER IDENTIFICATION CHART (pages 18-19). IF THE CONTAINER CAN BE IDENTIFIED, REMEMBER THAT THE INFORMATION ASSOCIATED WITH THESE CONTAINERS IS FOR THE WORST CASE POSSIBLE. Page 1 ERG2000 USER’S GUIDE The 2000 Emergency Response Guidebook (ERG2000) was developed jointly by Transport Canada (TC), the U.S. Department of Transportation (DOT) and the Secretariat of Transport and Communications of Mexico (SCT) for use by fire fighters, police, and other emergency services personnel who may be the first to arrive at the scene of a transportation incident involving dangerous goods. It is primarily a guide to aid first responders in quickly identifying the specific or generic hazards of the material(s) involved in the incident, and protecting themselves and the general public during the initial response phase of the incident. For the purposes of this guidebook, the “initial response phase”is that period following arrival at the scene of an incident during which the presence and/or identification of dangerous goods is confirmed, protective actions and area securement are initiated, and assistance of qualified personnel is requested. It is not intended to provide information on the physical or chemical properties of dangerous goods. This guidebook will assist responders in making initial decisions upon arriving at the scene of a dangerous goods incident. It should not be considered as a substitute for emergency response training, knowledge or sound judgment. ERG2000 does not address all possible circumstances that may be associated with a dangerous goods incident. It is primarily designed for use at a dangerous goods incident occurring on a highway or railroad. Be mindful that there may be limited value in its application at fixed facility locations. ERG2000 incorporates dangerous goods lists from the most recent United Nations Recommendations as well as from other international and national regulations. Explosives are not listed individually by either proper shipping name or ID Number. They do, however, appear under the general heading “Explosives” on the first page of the ID Number index (yellow-bordered pages) and alphabetically in the Name of Material index (blue-bordered pages). Also, the letter “P” following the guide number in the yellow-bordered and bluebordered pages identifies those materials which present a polymerization hazard under certain conditions; for example, Acrolein, inhibited, Guide 131P. First responders at the scene of a dangerous goods incident should seek additional specific information about any material in question as soon as possible. The information received by contacting the appropriate emergency response agency, the emergency response number on the shipping document, or by consulting the information on or accompanying the shipping document, may be more specific and accurate than this guidebook in providing guidance for the materials involved. BECOME FAMILIAR WITH THIS GUIDEBOOK BEFORE USING IT DURING AN EMERGENCY! In the U.S., according to the requirements of the U.S. Department of Labor’s Occupational Safety and Health Administration (OSHA, 29 CFR 1910.120), and regulations issued by the U.S. Environmental Protection Agency (EPA, 40 CFR Part 311), first responders must be trained regarding the use of this guidebook. Page 2 GUIDEBOOK CONTENTS 1-Yellow-bordered pages: Index list of dangerous goods in numerical order of ID number. This section quickly identifies the guide to be consulted from the ID Number of the material involved. This list displays the 4-digit ID number of the material followed by its assigned emergency response guide and the material name. For example: ID No. Guide No. Name of Material 1090 127 Acetone 2-Blue-bordered pages: Index list of dangerous goods in alphabetical order of material name. This section quickly identifies the guide to be consulted from the name of the material involved. This list displays the name of the material followed by its assigned emergency response guide and 4-digit ID number. For example: Name of Material Guide No. ID No. Sulfuric acid 137 1830 3-Orange-bordered pages: This section is the most important section of the guidebook because it is where all safety recommendations are provided. It comprises a total of 62 individual guides, presented in a two-page format. Each guide provides safety recommendations and emergency response information to protect yourself and the public. The left hand page provides safety related information whereas the right hand page provides emergency response guidance and activities for fire situations, spill or leak incidents and first aid. Each guide is designed to cover a group of materials which possess similar chemical and toxicological characteristics. The guide title identifies the general hazards of the dangerous goods covered. For example: Guide 124 - Gases-Toxic and/or Corrosive-Oxidizing. Each guide is divided into three main sections: the first section describes potential hazards that the material may display in terms of fire/explosion and health effects upon exposure. The highest potential is listed first. The emergency responder should consult this section first. This allows the responder to make decisions regarding the protection of the emergency response team as well as the surrounding population. The second section outlines suggested public safety measures based on the situation at hand. It provides general information regarding immediate isolation of the incident site, recommended type of protective clothing and respiratory protection. Suggested evacuation distances are listed for small and large spills and for fire situations (fragmentation hazard). It also directs the reader to consult the tables listing Toxic Inhalation Hazard materials (TIH) and water-reactive materials (green-bordered pages) when the material name is highlighted in the yellow-bordered and blue-bordered pages. The third section covers emergency response actions, including first aid. It outlines special precautions for incidents which involve fire, spill or chemical exposure. Several recommendations are listed under each part which will further assist in the decision making process. The information on first aid is general guidance prior to seeking medical care. Page 3 4-Green-bordered pages: This section contains a table which lists, by ID number, TIH materials, including certain chemical warfare agents, and water-reactive materials which produce toxic gases upon contact with water. The table provides two different types of recommended safe distances which are “Initial isolation distances”and “Protective action distances.” The materials are highlighted for easy identification in both numeric (yellow-bordered pages) and alphabetic (blue-bordered pages) lists of the guidebook. The table provides distances for both small (approximately 200 liters or less) and large spills (more than 200 liters) for all highlighted materials. The list is further subdivided into daytime and nighttime situations. This is necessary due to varying atmospheric conditions which greatly affect the size of the hazardous area. The distances change from daytime to nighttime due to different mixing and dispersion conditions in the air. During the night, the air is generally calmer and this causes the chemical to disperse less and therefore create a toxicity zone which is greater than would usually occur during the day. During the day, the chemical is generally dispersed by a more active atmosphere. The chemical will be present in a larger area; however, the actual area where toxic levels are reached will be smaller (due to increased dispersion). It is the quantity of the chemical that poses problems not its mere presence. The “Initial Isolation Distance”is a distance within which all persons should be considered for evacuation in all directions from the actual spill/leak source. It is a distance (radius) which defines a circle (Initial Isolation Zone) within which persons may be exposed to dangerous concentrations upwind of the source and may be exposed to life threatening concentrations downwind of the source. For example, in the case of Compressed gas, toxic, n.o.s., ID No. 1955, Inhalation Hazard Zone A, the isolation distance for small spills is 430 meters, therefore, representing an evacuation circle of 860 meters in diameter. For the same material, the “Protective Action Distance”is 4.2 kilometers for a daytime incident and 8.4 kilometers for a nighttime incident, these distances represent a downwind distance from the spill/leak source within which Protective Actions could be implemented. Protective Actions are those steps taken to preserve the health and safety of emergency responders and the public. People in this area could be evacuated and/or sheltered in-place. For more information, consult the INTRODUCTION TO THE TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES (pages 311-312). What is a TIH? It is a liquid or a gas which is known to be so toxic to humans as to pose a hazard to health during transportation, or in the absence of adequate data on human toxicity, is presumed to be toxic to humans because when tested on laboratory animals it has an LC50 value of not more than 5000 ppm. It is important to note that even though the term zone is used, the hazard zones do not represent any actual area or distance. The assignment of the zones is strictly a function of their Lethal Concentration 50 (LC50); for example, TIH Zone A is more toxic than Zone D. All distances which are listed in the green-bordered pages are calculated by the use of mathematical models for each TIH material. Page 4 Assignment of hazard zones: HAZARD ZONE A: LC50 of less than or equal to 200 ppm, HAZARD ZONE B: LC50 greater than 200 ppm and less than or equal to 1000 ppm, HAZARD ZONE C: LC50 greater than 1000 ppm and less than or equal to 3000 ppm, HAZARD ZONE D: LC50 greater than 3000 ppm and less than or equal to 5000 ppm. ISOLATION AND EVACUATION DISTANCES Isolation or evacuation distances are shown in the guides (orange-bordered pages) and in the Table of Initial Isolation and Protective Action Distances (green-bordered pages). This may confuse users not thoroughly familiar with ERG2000. It is important to note that some guides refer to non-TIH materials only (40 guides) and some refer to both TIH and non-TIH materials (22 guides). A guide refers to both TIH and non-TIH materials only when the following sentence appears under the title EVACUATION-SPILLS: “See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-highlighted substances, increase, in the downwind direction, as necessary, the isolation distance shown under ‘PUBLIC SAFETY.’” If this sentence does not appear in the guide, then this particular guide refers to non-TIH materials only. If you are dealing with a TIH material (highlighted entries in the index lists), the isolation and evacuation distances are found directly in the green-bordered pages. The guides (orangebordered pages) also remind the user to refer to the green-bordered pages for evacuation specific information involving highlighted materials. If you are dealing with a non-TIH material but the guide refers to both TIH and non-TIH materials, an immediate isolation distance is provided under the heading PUBLIC SAFETY. It applies to the non-TIH materials only. In addition, for evacuation purposes, the guide informs the user under the title EVACUATION-SPILLS to increase, for non-highlighted substances, in the downwind direction, if necessary, the immediate isolation distance listed under “Public Safety.” For example, Guide 124 - Gases-Toxic and/or Corrosive-Oxidizing, instructs the user to: Isolate the spill or leak area immediately for at least 100 to 200 meters (330 to 660 feet) in all directions. In case of a large spill, the isolation area could be expanded from 100 meters to a distance deemed as safe by the On-scene-commander and emergency responders. If you are dealing with a non-TIH material and the guide refers only to non-TIH materials, the immediate isolation and evacuation distances are specified as actual distances in the guide (orange-bordered pages) and are not referenced in the green-bordered pages. Page 5 SAFETY PRECAUTIONS APPROACH CAUTIOUSLY FROM UPWIND. Resist the urge to rush in; others cannot be helped until the situation has been fully assessed. SECURE THE SCENE. Without entering the immediate hazard area, isolate the area and assure the safety of people and the environment, keep people away from the scene and outside the safety perimeter. Allow enough room to move and remove your own equipment. IDENTIFY THE HAZARDS. Placards, container labels, shipping documents, material safety data sheets, Rail Car and Road Trailer Identification Charts, and/or knowledgeable persons on the scene are valuable information sources. Evaluate all available information and consult the recommended guide to reduce immediate risks. Additional information, provided by the shipper or obtained from another authoritative source, may change some of the emphasis or details found in the guide. Remember, the guide provides only the most important and worst case scenario information for the initial response in relation to a family or class of dangerous goods. As more material-specific information becomes available, the response should be tailored to the situation. ASSESS THE SITUATION. Consider the following: Is there a fire, a spill or a leak? What are the weather conditions? What is the terrain like? Who/what is at risk: people, property or the environment? What actions should be taken: Is an evacuation necessary? Is diking necessary? What resources (human and equipment) are required and are readily available? What can be done immediately? OBTAIN HELP. Advise your headquarters to notify responsible agencies and call for assistance from qualified personnel. DECIDE ON SITE ENTRY. Any efforts made to rescue persons, protect property or the environment must be weighed against the possibility that you could become part of the problem. Enter the area only when wearing appropriate protective gear (see PROTECTIVE CLOTHING, page 364). RESPOND. Respond in an appropriate manner. Establish a command post and lines of communication. Rescue casualties where possible and evacuate if necessary. Maintain control of the site. Continually reassess the situation and modify the response accordingly. The first duty is to consider the safety of people in the immediate area, including your own. ABOVE ALL — Do not walk into or touch spilled material. Avoid inhalation of fumes, smoke and vapors, even if no dangerous goods are known to be involved. Do not assume that gases or vapors are harmless because of lack of a smell— odorless gases or vapors may be harmful. Page 6 WHO TO CALL FOR ASSISTANCE Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. Follow the steps outlined in your organization’s standard operating procedures and/or local emergency response plan for obtaining qualified assistance. Generally, the notification sequence and requests for technical information beyond what is available in this guidebook should occur in the following order: 1. ORGANIZATION/AGENCY Notify your organization/agency. This will set in motion a series of events based upon the information provided. Actions may range from dispatching additional trained personnel to the scene to activating the local emergency response plan. Ensure that local fire and police departments have been notified. 2. EMERGENCY RESPONSE TELEPHONE NUMBER Locate and call the telephone number listed on the shipping document. The person answering the phone at the listed emergency response number must be knowledgeable of the materials and mitigation actions to be taken, or must have immediate access to a person who has the required knowledge. 3. NATIONAL ASSISTANCE Contact the appropriate emergency response agency listed on the inside back cover of this guidebook when the emergency response telephone number is not available. Upon receipt of a call describing the nature of the incident, the agency will provide immediate advice on handling the early stages of the incident. The agency will also contact the shipper or manufacturer of the material for more detailed information and request on-scene assistance when necessary. Collect and provide as much of the following information as can safely be obtained to your chain-ofcommand and specialists contacted for technical guidance: Your name, call back telephone number, FAX number Location and nature of problem (spill, fire, etc.) Name and identification number of material(s) involved Shipper/consignee/point of origin Carrier name, rail car or truck number Container type and size Quantity of material transported/released Local conditions (weather, terrain, proximity to schools, hospitals, waterways, etc.) Injuries and exposures Local emergency services that have been notified Page 7 CANADA 1. CANUTEC CANUTEC is the Canadian Transport Emergency Centre operated by the Transport Dangerous Goods Directorate of Transport Canada. CANUTEC provides a national bilingual (French and English) advisory service and is staffed by professional chemists experienced and trained in interpreting technical information and providing emergency response advice. In an emergency, CANUTEC may be called collect at 613-996-6666 (24 hours) *666 cellular (Press Star 666, Canada only) In a non-emergency situation, please call the information line at 613-992-4624 (24 hours). 2. PROVINCIAL AGENCIES Although technical information and emergency response assistance can be obtained from CANUTEC, there are federal and provincial regulations requiring the reporting of dangerous goods incidents to certain authorities. The following list of provincial agencies is supplied for your convenience. Province Emergency Authority and/or Telephone Number Alberta .................................... Local Police and Provincial Authorities 1-800-272-9600* British Columbia ....................... Local Police or 1-800-663-3456 Manitoba ................................. Local Police or fire brigade, as appropriate, or 204-945-4888 New Brunswick ........................ Local Police or 1-800-565-1633** or 902-426-6030 Newfoundland ......................... Local Police or 709-772-2083 Northwest Territories ................ 867-920-8130 Nova Scotia ............................. Local Police or 1-800-565-1633** or 902-426-6030 Nunavut .................................. 867-920-8130 Ontario .................................... Local Police Prince Edward Island ............... Local Police or 1-800-565-1633** or 902-426-6030 Quebec ................................... Local Police Saskatchewan ......................... Local Police or 1-800-667-7525 Yukon Territory ........................ 867-667-7244 * This number is not accessible from outside Alberta. ** This number is not accessible from outside of New Brunswick, Nova Scotia or Prince Edward Island. Page 8 NOTE: 1. The appropriate federal agency must be notified in the case of rail, air or marine incidents. 2. The nearest police department must be notified in the case of lost, stolen or misplaced explosives, radioactive materials or infectious substances. 3. CANUTEC must be notified in the case of: a. b. c. d. lost, stolen or misplaced infectious substances; an incident involving infectious substances; an incident where the shipping documents display CANUTEC’s telephone number 613-996-6666 as the emergency telephone number; or a dangerous goods incident in which a railway vehicle is involved. Page 9 UNITED STATES 1. CHEMTREC®, a 24-hour emergency response communication service, can be reached as follows: CALL CHEMTREC® (24 hours) 1-800-424-9300 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) For calls originating elsewhere: 703-527-3887 (Collect calls are accepted) or 2. CHEM-TEL, INC., a 24-hour emergency response communication service, can be reached as follows: CALL CHEM-TEL, INC. (24 hours) 1-800-255-3924 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) For calls originating elsewhere: 813-248-0585 (Collect calls are accepted) or 3. INFOTRAC, a 24-hour emergency response communication service, can be reached as follows: CALL INFOTRAC (24 hours) 1-800-535-5053 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) For calls originating elsewhere: 352-323-3500 (Collect calls are accepted) or 4. 3E COMPANY, a 24-hour emergency response communication service, can be reached as follows: CALL 3E COMPANY (24 hours) 1-800-451-8346 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) For calls originating elsewhere: 760-602-8703 (Collect calls are accepted) The emergency response information services shown above have requested to be listed as providers of emergency response information and have agreed to provide emergency response information to all callers. They maintain periodically updated lists of state and Federal radiation authorities who provide information and technical assistance on handling incidents involving radioactive materials. Page 10 5. NATIONAL RESPONSE CENTER (NRC) The NRC, which is operated by the U.S. Coast Guard, receives reports required when dangerous goods and hazardous substances are spilled. After receiving notification of an incident, the NRC will immediately notify the appropriate Federal On-Scene Coordinator and concerned Federal agencies. Federal law requires that anyone who releases into the environment a reportable quantity of a hazardous substance (including oil when water is, or may be affected) or a material identified as a marine pollutant, must immediately notify the NRC. When in doubt as to whether the amount released equals the required reporting levels for these materials, the NRC should be notified. CALL NRC (24 hours) 1-800-424-8802 (Toll-free in the U.S., Canada, and the U.S. Virgin Islands) 202-267-2675 in the District of Columbia Calling the emergency response telephone number, CHEMTREC®, CHEM-TEL, INC., INFOTRAC or 3E COMPANY, does not constitute compliance with regulatory requirements to call the NRC. 6. MILITARY SHIPMENTS For assistance at incidents involving materials being shipped by, for, or to the Department of Defense (DOD), call one of the following numbers (24 hours): 703-697-0218 (call collect) (U.S. Army Operations Center) for incidents involving explosives and ammunition. 1-800-851-8061 (toll free in the U.S.) (Defense Logistics Agency) for incidents involving dangerous goods other than explosives and ammunition. The above numbers are for emergencies only. Page 11 MEXICO 1. SETIQ (Emergency Transportation System for the Chemical Industry), a service of the National Association of Chemical Industries (ANIQ), can be reached as follows: Call SETIQ (24 hours) 01-800-00-214-00 in the Mexican Republic For calls originating in Mexico City and the Metropolitan Area 5559-1588 For calls originating elsewhere, call 0-11-52-5-559-1588 2. CECOM, the National Center for Communications of the Civil Protection Agency, can be reached as follows: CALL CECOM (24 hours) 01-800-00-413-00 in the Mexican Republic For calls originating in Mexico City and the Metropolitan Area 5550-1496, 5550-1552, 5550-1485, or 5550-4885 For calls originating elsewhere, call 0-11-52-5-550-1496, or 0-11-52-5-550-1552 0-11-52-5-550-1485, or 0-11-52-5-550-4885 Page 12 HAZARD CLASSIFICATION SYSTEM The hazard class of dangerous goods is indicated either by its class (or division) number or name. For a placard corresponding to the primary hazard class of a material, the hazard class or division number must be displayed in the lower corner of the placard. However, no hazard class or division number may be displayed on a placard representing the subsidiary hazard of a material. For other than Class 7 or the OXYGEN placard, text indicating a hazard (for example, “CORROSIVE”) is not required. Text is shown only in the U.S. The hazard class or division number must appear on the shipping document after each shipping name. Class 1 - Explosives Division 1.1 Division 1.2 Division 1.3 Division 1.4 Division 1.5 Division 1.6 Explosives with a mass explosion hazard Explosives with a projection hazard Explosives with predominantly a fire hazard Explosives with no significant blast hazard Very insensitive explosives; blasting agents Extremely insensitive detonating articles Class 2 - Gases Division 2.1 Division 2.2 Division 2.3 Division 2.4 Flammable gases Non-flammable, non-toxic* compressed gases Gases toxic* by inhalation Corrosive gases (Canada) Class 3 - Flammable liquids (and Combustible liquids [U.S.]) Class 4 - Flammable solids; Spontaneously combustible materials; and Dangerous when wet materials Division 4.1 Division 4.2 Division 4.3 Flammable solids Spontaneously combustible materials Dangerous when wet materials Class 5 - Oxidizers and Organic peroxides Division 5.1 Division 5.2 Oxidizers Organic peroxides Class 6 - Toxic* materials and Infectious substances Division 6.1 Division 6.2 Toxic* materials Infectious substances Class 7 - Radioactive materials Class 8 - Corrosive materials Class 9 - Miscellaneous dangerous goods Division 9.1 Division 9.2 Division 9.3 Miscellaneous dangerous goods (Canada) Environmentally hazardous substances (Canada) Dangerous wastes (Canada) * The words “poison”or “poisonous”are synonymous with the word “toxic”. Page 13 NOTES Page 14 INTRODUCTION TO THE TABLE OF PLACARDS USE THIS TABLE ONLY IF YOU HAVE NOT BEEN ABLE TO IDENTIFY THE MATERIAL(S) IN TRANSPORT BY ID NUMBER OR NAME The next two pages display the placards used on transport vehicles carrying dangerous goods. As you approach a reported or suspected dangerous goods incident involving a placarded vehicle: 1. Approach the incident cautiously from upwind to a point from which you can safely identify and/or read the placard or orange panel information. If wind direction allows, consider approaching the incident from uphill. Use binoculars, if available. 2. Match the vehicle placard(s) with one of the placards displayed on the following pages. 3. Consult the numbered guide associated with the sample placard. Use that information for now. For example, a FLAMMABLE (Class 3) placard leads to Guide 127. A CORROSIVE (Class 8) placard leads to Guide 153. If multiple placards point to more than one guide, initially use the most conservative guide (i.e., the guide requiring the greatest degree of protective actions). 4. Remember that the guides associated with the placards provide the most significant risk and/or hazard information. 5. When specific information, such as ID number or shipping name, becomes available, the more specific guide recommended for that material must be consulted. 6. If Guide 111 is being used because only the DANGER/DANGEROUS placard is displayed or the nature of the spilled, leaking, or burning material is not known, as soon as possible, get more specific information concerning the material(s) involved. 7. Asterisks (*) on orange placards represent explosives "Compatibility Group" letters; refer to the Glossary (page 372). Page 15 TABLE OF PLACARDS AND INITIAL USE THIS TABLE ONLY IF MATERIALS CANNOT BE SPECIFICALLY IDENTIFIED BY 112 111 114 112 112 Page 16 121 118 122 127 125 123 128 RESPONSE GUIDES TO USE ON-SCENE USING THE SHIPPING DOCUMENT, NUMBERED PLACARD, OR ORANGE PANEL NUMBER 136 134 148 143 139 153 151 163 153 158 171 Page 17 RAIL CAR IDENTIFICATION CHART* Hopper car Dry bulk Pressurized tank car Compressed liquefied gases 140 117 Box car Mixed cargo 111 Low pressure tank car Liquids 131 CAUTION: Emergency response personnel must be aware that rail tank cars vary widely in construction, fittings and purpose. Tank cars could transport products that may be solids, liquids or gases. The products may be under pressure. It is essential that products be identified by consulting shipping documents or train consist or contacting dispatch centers before emergency response is initiated. The information stenciled on the sides or ends of tank cars, as illustrated above, may be used to identify the product utilizing: a. the commodity name shown; or b. the other information shown, especially reporting marks and car number which, when supplied to a dispatch center, will facilitate the identification of the product. * The recommended guides should be considered as last resort if product cannot be identified by any other means. Page 18 ROAD TRAILER IDENTIFICATION CHART* MC306 Nonpressure Liquid Tank 131 MC307 Low Pressure Chemical Tank 137 MC-338 Cryogenic Liquid Tank 117 Compressed Gas/ Tube Trailer 117 MC-312 Corrosive Liquid Tank 137 Dry Bulk Cargo Tanker 134 MC-331 High Pressure Tank 117 Mixed Cargo 111 CAUTION: This chart depicts only the most general shapes of road trailers. Emergency response personnel must be aware that there are many variations of road trailers, not illustrated above, that are used for shipping chemical products. The suggested guides are for the most hazardous products that may be transported in these trailer types. * The recommended guides should be considered as last resort if product cannot be identified by any other means. Page 19 HAZARD IDENTIFICATION CODES DISPLAYED ON SOME INTERMODAL CONTAINERS Hazard identification codes, referred to as “hazard identification numbers”under European and some South American regulations, may be found in the top half of an orange panel on some intermodal bulk containers. The 4-digitidentification number is in thebottom half of the orange panel. 33 1203 The hazard identification code in the top half of the orange panel consists of two or three figures. In general, the figures indicate the following hazards: 2 - EMISSION OF GAS DUE TO PRESSURE OR CHEMICAL REACTION 3 - FLAMMABILITY OF LIQUIDS (VAPORS) AND GASES OR SELF-HEATING LIQUID 4 - FLAMMABILITY OF SOLIDS OR SELF-HEATING SOLID 5 - OXIDIZING (FIRE-INTENSIFYING) EFFECT 6 - TOXICITY OR RISK OF INFECTION 7 - RADIOACTIVITY 8 - CORROSIVITY 9 - RISK OF SPONTANEOUS VIOLENT REACTION • Doubling of a figure indicates an intensification of that particular hazard (i.e. 33, 66, 88). • Where the hazard associated with a material can be adequately indicated by a single figure, the figure is followed by a zero (i.e. 30, 40, 50). • A hazard identification code prefixed by the letter “X”indicates that the material will react dangerously with water (i.e. X88). Page 20 HAZARD IDENTIFICATION CODES DISPLAYED ON SOME INTERMODAL CONTAINERS The hazard identification codes listed below have the following meanings: 20 22 223 225 23 236 239 25 26 263 265 266 268 Inert gas Refrigerated gas Refrigerated gas, flammable Refrigerated gas, oxidizing (fire-intensifying) Flammable gas Flammable gas, toxic Flammable gas which can spontaneously lead to violent reaction Oxidizing (fire-intensifying) gas Toxic gas Toxic gas, flammable Toxic gas, oxidizing (fire-intensifying) Highly toxic gas Toxic gas, corrosive 30 323 X323 33 333 X333 336 338 X338 339 36 362 X362 368 38 382 X382 39 Flammable liquid Flammable liquid which reacts with water, emitting flammable gas Flammable liquid which reacts dangerously with water, emitting flammable gas Highly flammable liquid Pyrophoric liquid Pyrophoric liquid which reacts dangerously with water Highly flammable liquid, toxic Highly flammable liquid, corrosive Highly flammable liquid, corrosive, which reacts dangerously with water Highly flammable liquid which can spontaneously lead to violent reaction Flammable liquid, toxic, or self-heating liquid, toxic Flammable liquid, toxic, which reacts with water, emitting flammable gas Flammable liquid, toxic, which reacts dangerously with water, emitting flammable gas Flammable liquid, toxic, corrosive Flammable liquid, corrosive Flammable liquid, corrosive, which reacts with water, emitting flammable gas Flammable liquid, corrosive, which reacts dangerously with water, emitting flammable gas Flammable liquid which can spontaneously lead to violent reaction 40 423 Flammable solid, or self-reactive material, or self-heating material Solid which reacts with water, emitting flammable gas Page 21 HAZARD IDENTIFICATION CODES DISPLAYED ON SOME INTERMODAL CONTAINERS X423 43 44 446 46 462 X462 48 482 X482 Flammable solid which reacts dangerously with water, emitting flammable gas Spontaneously flammable (pyrophoric) solid Flammable solid, in the molten state at an elevated temperature Flammable solid, toxic, in the molten state at an elevated temperature Flammable solid, toxic, or self-heating solid, toxic Toxic solid which reacts with water, emitting flammable gas Solid which reacts with water, emitting toxic gas Flammable or self-heating solid, corrosive Corrosive solid which reacts with water, emitting flammable gas Solid which reacts dangerously with water, emitting corrosive gas 50 539 55 556 558 559 56 568 58 59 Oxidizing (fire-intensifying) substance Flammable organic peroxide Strongly oxidizing (fire-intensifying) substance Strongly oxidizing (fire-intensifying) substance, toxic Strongly oxidizing (fire-intensifying) substance, corrosive Strongly oxidizing (fire-intensifying) substance which can spontaneously lead to violent reaction Oxidizing (fire-intensifying) substance, toxic Oxidizing (fire-intensifying) substance, toxic, corrosive Oxidizing (fire-intensifying) substance, corrosive Oxidizing (fire intensifying) substance which can spontaneously lead to violent reaction 60 606 623 63 638 639 64 642 65 66 663 664 665 668 Toxic material Infectious substance Toxic liquid which reacts with water, emitting flammable gas Toxic liquid, flammable Toxic liquid, flammable, corrosive Toxic liquid, flammable, which can spontaneously lead to violent reaction Toxic solid, flammable or self-heating Toxic solid which reacts with water, emitting flammable gas Toxic material, oxidizing (fire-intensifying) Highly toxic material Highly toxic liquid, flammable Highly toxic solid, flammable or self-heating Highly toxic material, oxidizing (fire-intensifying) Highly toxic material, corrosive Page 22 HAZARD IDENTIFICATION CODES DISPLAYED ON SOME INTERMODAL CONTAINERS 669 68 69 Highly toxic material which can spontaneously lead to violent reaction Toxic material, corrosive Toxic material which can spontaneously lead to violent reaction 70 72 723 73 74 75 76 78 Radioactive material Radioactive gas Radioactive gas, flammable Radioactive liquid, flammable Radioactive solid, flammable Radioactive material, oxidizing (fire-intensifying) Radioactive material, toxic Radioactive material, corrosive 80 X80 823 83 X83 839 X839 84 842 85 856 86 88 X88 883 884 885 886 X886 89 Corrosive material Corrosive material which reacts dangerously with water Corrosive liquid which reacts with water, emitting flammable gas Corrosive liquid, flammable Corrosive liquid, flammable, which reacts dangerously with water Corrosive liquid, flammable, which can spontaneously lead to violent reaction Corrosive liquid, flammable, which can spontaneously lead to violent reaction and which reacts dangerously with water Corrosive solid, flammable or self-heating Corrosive solid which reacts with water, emitting flammable gas Corrosive material, oxidizing (fire-intensifying) Corrosive material, oxidizing and toxic Corrosive material, toxic Highly corrosive material Highly corrosive material which reacts dangerously with water Highly corrosive liquid, flammable Highly corrosive solid, flammable or self-heating Highly corrosive material, oxidizing (fire-intensifying) Highly corrosive material, toxic Highly corrosive material, toxic, which reacts dangerously with water Corrosive material which can spontaneously lead to violent reaction 90 99 Miscellaneous dangerous substance; environmentally hazardous substance Miscellaneous dangerous substance transported at elevated temperature Page 23 Note: Page 24 If an entry is highlighted in either the yellow-bordered or blue-bordered pages AND THERE IS NO FIRE, go directly to the Table of Initial Isolation and Protective Action Distances (green-bordered pages) and look up the ID number and name of material to obtain initial isolation and protective action distances. IF THERE IS A FIRE, or IF A FIRE IS INVOLVED, go directly to the appropriate guide (orangebordered pages) and use the evacuation information shown under PUBLIC SAFETY. ID Guide No. No. Name of Material ID Guide No. No. Name of Material 112 Ammonium nitrate-fuel oil mixtures —— 159 Methylbromoacetone —— 135 p-Nitrosodiethylaniline —— 158 Biological agents —— 171 Plastic molding material —— 112 Blasting agent, n.o.s. —— —— 171 Cargo transport unit under fumigation 171P Polymerizable material, stabilized with dry ice —— 153 Toxins —— 154 Chemical kits (containing corrosive substances) —— 133 Wool waste, wet —— 128 Chemical kits (containing flammable liquids) 1001 116 Acetylene, dissolved —— 133 Chemical kits (containing flammable solids) —— 140 Chemical kits (containing oxidizing substances) —— 153 Chemical kits (containing poisonous liquids) —— 154 Chemical kits (containing poisonous solids) 1005 125 Ammonia, anhydrous —— 153 Chemical kits (containing toxic liquids) 1005 125 Ammonia solution, with more than 50% Ammonia —— 154 Chemical kits (containing toxic solids) 1005 125 Anhydrous ammonia —— 129 1-Chloroheptane —— 129 1-Chlorohexane —— 152 m-Dichlorobenzene —— 136 p-Diethylnitrosoaniline —— 153 2-Ethyl-3-propylacrolein —— 112 Explosive A —— 112 Explosive B —— 114 Explosive C —— 112 Explosives, division 1.1, 1.2, 1.3, 1.5 or 1.6 —— 114 Explosives, division 1.4 —— 133 Fibres, animal or vegetable, burnt, wet or damp —— 133 Fibres, vegetable, dry —— 1001 116 Acetylene 1002 122 Air, compressed 1003 122 Air, refrigerated liquid (cryogenic liquid) 1003 122 Air, refrigerated liquid (cryogenic liquid), nonpressurized 1005 125 Ammonia, anhydrous, liquefied 1005 125 Anhydrous ammonia, liquefied 1006 121 Argon 1006 121 Argon, compressed 1008 125 Boron trifluoride 1008 125 Boron trifluoride, compressed 1009 126 Bromotrifluoromethane 1009 126 Refrigerant gas R-13B1 1010 116P Butadienes, inhibited 1011 115 Butane 1011 115 Butane mixture 1012 115 Butylene 1013 120 Carbon dioxide 1013 120 Carbon dioxide, compressed 1014 122 Carbon dioxide and Oxygen mixture Page 25 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1014 122 Carbon dioxide and Oxygen mixture, compressed 1030 115 1,1-Difluoroethane 1014 122 Oxygen and Carbon dioxide mixture 1030 115 Refrigerant gas R-152a 1014 122 Oxygen and Carbon dioxide mixture, compressed 1033 115 Dimethyl ether 1030 115 Difluoroethane 1032 118 Dimethylamine, anhydrous 1015 126 Carbon dioxide and Nitrous oxide mixture 1035 115 Ethane 1015 126 Nitrous oxide and Carbon dioxide mixture 1036 118 Ethylamine 1016 119 Carbon monoxide 1035 115 Ethane, compressed 1037 115 Ethyl chloride 1016 119 Carbon monoxide, compressed 1038 115 Ethylene, refrigerated liquid (cryogenic liquid) 1017 124 Chlorine 1039 115 Ethyl methyl ether 1018 126 Chlorodifluoromethane 1039 115 Methyl ethyl ether 1018 126 Refrigerant gas R-22 1040 119P Ethylene oxide 1020 126 Chloropentafluoroethane 1040 119P Ethylene oxide with Nitrogen 1020 126 Refrigerant gas R-115 1041 115 Carbon dioxide and Ethylene oxide mixture, with more than 9% but not more than 87% Ethylene oxide 1021 126 1-Chloro-1,2,2,2tetrafluoroethane 1021 126 Chlorotetrafluoroethane 1021 126 Refrigerant gas R-124 1022 126 Chlorotrifluoromethane 1022 126 Refrigerant gas R-13 1023 119 Coal gas 1023 119 Coal gas, compressed 1026 119 Cyanogen 1026 119 Cyanogen, liquefied 1026 119 Cyanogen gas 1027 115 Cyclopropane 1027 115 Cyclopropane, liquefied 1028 126 Dichlorodifluoromethane 1028 126 Refrigerant gas R-12 1041 115 Carbon dioxide and Ethylene oxide mixtures, with more than 6% Ethylene oxide 1041 115 Ethylene oxide and Carbon dioxide mixture, with more than 9% but not more than 87% Ethylene oxide 1041 115 Ethylene oxide and Carbon dioxide mixtures, with more than 6 % Ethylene oxide 1043 125 Fertilizer, ammoniating solution, with free Ammonia 1044 126 Fire extinguishers with compressed gas 1029 126 Dichlorofluoromethane 1044 126 Fire extinguishers with liquefied gas 1029 126 Refrigerant gas R-21 1045 124 Fluorine Page 26 ID Guide No. No. Name of Material 1045 124 Fluorine, compressed 1046 121 Helium 1046 121 Helium, compressed ID Guide No. No. Name of Material 1060 116P Methylacetylene and Propadiene mixture, stabilized 1049 115 Hydrogen 1060 116P Propadiene and Methylacetylene mixture, stabilized 1049 115 Hydrogen, compressed 1061 118 Methylamine, anhydrous 1050 125 Hydrogen chloride, anhydrous 1062 123 Methyl bromide 1051 117 AC 1063 115 Methyl chloride 1051 117 Hydrocyanic acid, aqueous solutions, with more than 20% Hydrogen cyanide 1063 115 Refrigerant gas R-40 1048 125 Hydrogen bromide, anhydrous 1051 117 Hydrocyanic acid, liquefied 1051 117 Hydrogen cyanide, anhydrous, stabilized 1051 117 Hydrogen cyanide, stabilized 1052 125 Hydrogen fluoride, anhydrous 1053 117 Hydrogen sulfide 1053 117 Hydrogen sulfide, liquefied 1053 117 Hydrogen sulphide 1053 117 Hydrogen sulphide, liquefied 1055 115 Isobutylene 1064 117 Methyl mercaptan 1065 121 Neon 1065 121 Neon, compressed 1066 121 Nitrogen 1066 121 Nitrogen, compressed 1067 124 Dinitrogen tetroxide 1067 124 Dinitrogen tetroxide, liquefied 1067 124 Nitrogen dioxide 1067 124 Nitrogen dioxide, liquefied 1067 124 Nitrogen peroxide, liquid 1067 124 Nitrogen tetroxide, liquid 1056 121 Krypton 1069 125 Nitrosyl chloride 1056 121 Krypton, compressed 1070 122 Nitrous oxide 1057 115 Cigarette lighter, with flammable gas 1070 122 Nitrous oxide, compressed 1071 119 Oil gas 1057 115 Flammable gas in lighter for cigars, cigarettes, etc. 1071 119 Oil gas, compressed 1057 115 Lighter refills (cigarettes) (flammable gas) 1072 122 Oxygen, compressed 1057 115 Lighters (cigarettes) (flammable gas) 1058 121 Liquefied gas (nonflammable) 1058 121 Liquefied gases, non-flammable, charged with Nitrogen, Carbon dioxide or Air 1072 122 Oxygen 1073 122 Oxygen, refrigerated liquid (cryogenic liquid) 1075 115 Butane 1075 115 Butane mixture 1075 115 Butylene 1075 115 Isobutane Page 27 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1075 115 Isobutane mixture 1089 129 Acetaldehyde 1075 115 Isobutylene 1090 127 Acetone 1075 115 Liquefied petroleum gas 1091 127 Acetone oils 1075 115 LPG 1092 131P Acrolein, inhibited 1075 115 Petroleum gases, liquefied 1093 131P Acrylonitrile, inhibited 1075 115 Propane 1098 131 Allyl alcohol 1075 115 Propane mixture 1099 131 Allyl bromide 1075 115 Propylene 1100 131 Allyl chloride 1076 125 CG 1104 129 Amyl acetates 1076 125 Diphosgene 1105 129 Amyl alcohols 1076 125 DP 1105 129 Pentanols 1076 125 Phosgene 1106 132 Amylamines 1077 115 Propylene 1107 129 Amyl chloride 1078 126 Dispersant gas, n.o.s. 1108 127 n-Amylene 1078 126 Refrigerant gas, n.o.s. 1108 127 1-Pentene 1079 125 Sulfur dioxide 1109 129 Amyl formates 1079 125 Sulfur dioxide, liquefied 1110 127 n-Amyl methyl ketone 1079 125 Sulphur dioxide 1110 127 Amyl methyl ketone 1079 125 Sulphur dioxide, liquefied 1110 127 Methyl amyl ketone 1080 126 Sulfur hexafluoride 1111 130 Amyl mercaptan 1080 126 Sulphur hexafluoride 1112 140 Amyl nitrate 1081 116P Tetrafluoroethylene, inhibited 1113 129 Amyl nitrite 1082 119P Trifluorochloroethylene 1114 130 Benzene 1082 119P Trifluorochloroethylene, inhibited 1118 130 Brake fluid, hydraulic 1083 118 Trimethylamine, anhydrous 1120 129 Butyl alcohol 1085 116P Vinyl bromide, inhibited 1123 129 Butyl acetates 1086 116P Vinyl chloride 1125 132 n-Butylamine 1086 116P Vinyl chloride, inhibited 1126 129 1-Bromobutane 1086 116P Vinyl chloride, stabilized 1126 129 n-Butyl bromide 1087 116P Vinyl methyl ether 1127 130 Butyl chloride 1087 116P Vinyl methyl ether, inhibited 1127 130 Chlorobutanes 1088 127 Acetal 1128 129 n-Butyl formate Page 28 1120 129 Butanols ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1129 129 Butyraldehyde 1149 127 Dibutyl ethers 1130 128 Camphor oil 1150 130P 1,2-Dichloroethylene 1131 131 Carbon bisulfide 1150 130P Dichloroethylene 1131 131 Carbon bisulphide 1152 130 Dichloropentanes 1131 131 Carbon disulfide 1153 127 Ethylene glycol diethyl ether 1131 131 Carbon disulphide 1154 132 Diethylamine 1133 128 Adhesives (flammable) 1155 127 Diethyl ether 1133 128 Cement (flammable) 1155 127 Ethyl ether 1133 128 Cement, container, linoleum, tile or wallboard, liquid 1156 127 Diethyl ketone 1133 128 Cement, leather 1158 132 Diisopropylamine 1133 128 Cement, liquid, n.o.s. 1159 127 Diisopropyl ether 1133 128 Cement, pyroxylin 1133 128 Cement, roofing, liquid 1160 129 Dimethylamine, aqueous solution 1133 128 Cement, rubber 1160 129 Dimethylamine, solution 1134 130 Chlorobenzene 1161 129 Dimethyl carbonate 1135 131 Ethylene chlorohydrin 1162 155 Dimethyldichlorosilane 1136 128 Coal tar distillates, flammable 1163 131 1,1-Dimethylhydrazine 1137 128 Coal tar distillate 1163 131 Dimethylhydrazine, unsymmetrical 1139 127 Coating solution 1157 127 Diisobutyl ketone 1142 127 Compound, vulcanizing, liquid (flammable) 1164 130 Dimethyl sulfide 1142 127 Compounds, polishing, liquid, etc. (flammable) 1165 127 Dioxane 1142 127 Flammable liquid preparations, n.o.s. 1167 131P Divinyl ether, inhibited 1164 130 Dimethyl sulphide 1166 127 Dioxolane 1143 131P Crotonaldehyde, inhibited 1168 127 Driers, paint or varnish, liquid, n.o.s. 1143 131P Crotonaldehyde, stabilized 1169 127 Extracts, aromatic, liquid 1144 128 Crotonylene 1170 127 Ethanol 1145 128 Cyclohexane 1170 127 Ethanol, solution 1146 128 Cyclopentane 1170 127 Ethyl alcohol 1147 130 Decahydronaphthalene 1170 127 Ethyl alcohol, solution 1148 129 Diacetone alcohol 1171 127 Ethylene glycol monoethyl ether 1149 127 Butyl ethers Page 29 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1172 129 Ethylene glycol monoethyl ether acetate 1199 132P Furaldehydes 1173 129 Ethyl acetate 1199 132P Furfuraldehydes 1175 129 Ethylbenzene 1201 127 Fusel oil 1176 129 Ethyl borate 1202 128 Diesel fuel 1177 129 2-Ethylbutyl acetate 1202 128 Fuel oil 1177 129 Ethylbutyl acetate 1202 128 Fuel oil, no. 1,2,4,5,6 1178 129 2-Ethylbutyraldehyde 1202 128 Gas oil 1179 127 Ethyl butyl ether 1202 128 Heating oil, light 1180 129 Ethyl butyrate 1203 128 Gasohol 1181 155 Ethyl chloroacetate 1203 128 Gasoline 1182 155 Ethyl chloroformate 1203 128 Motor spirit 1183 139 Ethyldichlorosilane 1203 128 Petrol 1184 129 Ethylene dichloride 1204 127 Nitroglycerin, solution in alcohol, with not more than 1% Nitroglycerin 1185 131P Ethyleneimine, inhibited 1188 127 Ethylene glycol monomethyl ether 1189 129 Ethylene glycol monomethyl ether acetate 1199 132P Furfural 1204 127 Spirits of Nitroglycerin, not exceeding 1 % Nitroglycerin 1206 128 Heptanes 1190 129 Ethyl formate 1207 129 Hexaldehyde 1191 129 Ethylhexaldehydes 1208 128 Hexanes 1191 129 Octyl aldehydes 1208 128 Neohexane 1192 129 Ethyl lactate 1210 129 Ink, printer’s, flammable 1193 127 Ethyl methyl ketone 1210 129 Printing ink, flammable 1193 127 Methyl ethyl ketone 1210 129 Printing ink related material 1194 131 Ethyl nitrite, solution 1212 129 Isobutanol 1195 129 Ethyl propionate 1212 129 Isobutyl alcohol 1196 155 Ethyltrichlorosilane 1213 129 Isobutyl acetate 1197 127 Extracts, flavoring, liquid 1214 132 Isobutylamine 1197 127 Extracts, flavouring, liquid 1216 128 Isooctene 1198 132 Formaldehyde, solution, flammable 1218 130P Isoprene, inhibited 1198 132 Formaldehyde, solutions (Formalin) 1219 129 Isopropyl alcohol Page 30 1219 129 Isopropanol ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1220 129 Isopropyl acetate 1244 131 Methylhydrazine 1221 132 Isopropylamine 1245 127 Methyl isobutyl ketone 1222 130 Isopropyl nitrate 1246 127P Methyl isopropenyl ketone, inhibited 1223 128 Kerosene 1224 127 Ketones, liquid, n.o.s. 1226 127 Cigarette lighter, with flammable liquid 1226 127 Lighters for cigars, cigarettes etc. with lighter fluid 1247 129P Methyl methacrylate monomer, inhibited 1247 129P Methyl methacrylate monomer, uninhibited 1248 129 Methyl propionate 1226 127 Lighters for cigars, cigarettes (flammable liquid) 1249 127 Methyl propyl ketone 1228 131 Mercaptan mixture, aliphatic 1251 131P Methyl vinyl ketone 1228 131 Mercaptan mixture, liquid, flammable, poisonous, n.o.s. 1251 131P Methyl vinyl ketone, stabilized 1228 131 Mercaptan mixture, liquid, flammable, toxic, n.o.s. 1255 128 Petroleum naphtha 1228 131 Mercaptan mixtures, liquid, n.o.s. 1257 128 Natural gasoline 1250 155 Methyltrichlorosilane 1255 128 Naphtha, petroleum 1256 128 Naphtha, solvent 1228 131 Mercaptans, liquid, flammable, poisonous, n.o.s. 1259 131 Nickel carbonyl 1228 131 Mercaptans, liquid, flammable, toxic, n.o.s. 1262 128 Isooctane 1229 129 Mesityl oxide 1230 131 Methanol 1261 129 Nitromethane 1262 128 Octanes 1263 128 Paint (flammable) 1230 131 Methyl alcohol 1263 128 Paint related material (flammable) 1231 129 Methyl acetate 1264 129 Paraldehyde 1232 127 Methyl acetone 1265 128 Isopentane 1233 129 Methylamyl acetate 1265 128 n-Pentane 1234 127 Methylal 1265 128 Pentanes 1235 132 Methylamine, aqueous solution 1237 129 Methyl butyrate 1266 127 Perfumery products, with flammable solvents 1238 155 Methyl chloroformate 1267 128 Petroleum crude oil 1239 131 Methyl chloromethyl ether 1268 128 Petroleum distillates, n.o.s. 1242 139 Methyldichlorosilane 1268 128 Petroleum products, n.o.s. 1243 129 Methyl formate 1270 128 Oil, petroleum, n.o.s. Page 31 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1270 128 Petroleum oil 1298 155 Trimethylchlorosilane 1271 128 Petroleum ether 1299 128 Turpentine 1271 128 Petroleum spirit 1300 128 Turpentine substitute 1272 129 Pine oil 1301 129P Vinyl acetate 1274 129 n-Propanol 1301 129P Vinyl acetate, inhibited 1274 129 normal Propyl alcohol 1302 127P Vinyl ethyl ether 1274 129 Propyl alcohol, normal 1302 127P Vinyl ethyl ether, inhibited 1275 129 Propionaldehyde 1303 129P Vinylidene chloride, inhibited 1276 129 n-Propyl acetate 1304 127P Vinyl isobutyl ether 1277 132 Monopropylamine 1304 127P Vinyl isobutyl ether, inhibited 1277 132 Propylamine 1305 155 Vinyltrichlorosilane 1278 129 1-Chloropropane 1305 155 Vinyltrichlorosilane, inhibited 1278 129 Propyl chloride 1306 129 Wood preservatives, liquid 1279 130 1,2-Dichloropropane 1307 130 Xylenes 1279 130 Dichloropropane 1308 170 Zirconium metal, liquid, suspension 1279 130 Propylene dichloride 1280 127P Propylene oxide 1281 129 Propyl formates 1308 170 Zirconium suspended in a flammable liquid 1282 129 Pyridine 1308 170 Zirconium suspended in a liquid (flammable) 1286 127 Rosin oil 1309 170 Aluminum powder, coated 1287 127 Rubber solution 1310 113 Ammonium picrate, wetted with not less than 10% water 1288 128 Shale oil 1289 132 Sodium methylate, alcohol mixture 1312 133 Borneol 1289 132 Sodium methylate, solution in alcohol 1314 133 Calcium resinate, fused 1292 132 Ethyl silicate 1292 132 Tetraethyl silicate 1293 127 Tinctures, medicinal 1294 130 Toluene 1295 139 Trichlorosilane 1296 132 Triethylamine 1297 132 Trimethylamine, aqueous solution Page 32 1313 133 Calcium resinate 1318 133 Cobalt resinate, precipitated 1320 113 Dinitrophenol, wetted with not less than 15% water 1321 113 Dinitrophenolates, wetted with not less than 15% water 1322 113 Dinitroresorcinol, wetted with not less than 15% water 1323 170 Ferrocerium 1324 133 Film ID Guide No. No. Name of Material 1324 133 Films, nitrocellulose base 1325 133 Air bag inflators 1325 133 Air bag modules 1325 133 Antimony sulfide, solid 1325 133 Antimony sulphide, solid 1325 133 Burnt cotton, not picked 1325 133 Cosmetics, n.o.s. 1325 133 Drugs, n.o.s. 1325 133 Flammable solid, n.o.s. 1325 133 Flammable solid, organic, n.o.s. 1325 133 Fusee (rail or highway) 1325 133 Medicines, flammable, solid, n.o.s. 1325 133 N-Methyl-N’-Nitro-NNitrosoguanidine 1325 133 Pyroxylin plastic, rod, sheet, roll, tube or scrap 1325 133 Smokeless powder for small arms 1326 170 Hafnium powder, wetted with not less than 25% water 1327 133 Bhusa, wet, damp or contaminated with oil 1327 133 Hay, wet, damp or contaminated with oil 1327 133 Straw, wet, damp or contaminated with oil 1328 133 Hexamethylenetetramine 1328 133 Hexamine 1330 133 Manganese resinate 1331 133 Matches, “strike anywhere” 1332 133 Metaldehyde 1333 170 Cerium, slabs, ingots or rods 1334 133 Naphthalene, crude 1334 133 Naphthalene, refined ID Guide No. No. Name of Material 1336 113 Nitroguanidine (Picrite), wetted with not less than 20% water 1336 113 Nitroguanidine, wetted with not less than 20% water 1336 113 Picrite, wetted 1337 113 Nitrostarch, wet, with not less than 30% alcohol or solvent 1337 113 Nitrostarch, wetted with not less than 20% water 1337 113 Nitrostarch, wetted with not less than 30% solvent 1338 133 Phosphorus, amorphous 1338 133 Phosphorus, amorphous, red 1338 133 Red phosphorus 1338 133 Red phosphorus, amorphous 1339 139 Phosphorus heptasulfide, free from yellow and white Phosphorus 1339 139 Phosphorus heptasulphide, free from yellow and white Phosphorus 1340 139 Phosphorus pentasulfide, free from yellow and white Phosphorus 1340 139 Phosphorus pentasulphide, free from yellow and white Phosphorus 1341 139 Phosphorus sesquisulfide, free from yellow and white Phosphorus 1341 139 Phosphorus sesquisulphide, free from yellow and white Phosphorus 1343 139 Phosphorus trisulfide, free from yellow and white Phosphorus 1343 139 Phosphorus trisulphide, free from yellow and white Phosphorus Page 33 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1344 113 Picric acid, wet, with not less than 10% water 1357 113 Urea nitrate, wetted with not less than 20% water 1344 113 Trinitrophenol, wetted with not less than 30% water 1358 170 Zirconium metal, powder, wet 1345 133 Rubber scrap, powdered or granulated 1358 170 Zirconium powder, wetted with not less than 25% water 1360 139 Calcium phosphide 1345 133 Rubber shoddy, powdered or granulated 1361 133 Carbon, animal or vegetable origin 1346 170 Silicon powder, amorphous 1361 133 Charcoal 1347 113 Silver picrate, wetted with not less than 30% water 1361 133 Charcoal, briquettes 1348 113 Sodium dinitro-o-cresolate, wetted with not less than 15% water 1348 113 Sodium dinitro-ortho-cresolate, wetted 1349 113 Sodium picramate, wetted with not less than 20% water 1350 133 Sulfur 1350 133 Sulphur 1352 170 Titanium powder, wetted with not less than 25% water 1361 133 Charcoal, shell 1361 133 Charcoal, wood, ground, crushed, granulated or pulverized 1361 133 Charcoal screenings, made from “Pinon” wood 1361 133 Charcoal screenings, other than “Pinon” wood screenings 1362 133 Carbon, activated 1363 135 Copra 1364 133 Cotton waste, oily 1353 133 Fabrics impregnated with weakly nitrated Nitrocellulose, n.o.s. 1365 133 Cotton 1353 133 Fibers impregnated with weakly nitrated Nitrocellulose, n.o.s. 1366 135 Diethylzinc 1353 133 Fibres impregnated with weakly nitrated Nitrocellulose, n.o.s. 1370 135 Dimethylzinc 1353 133 Toe puffs, nitrocellulose base 1354 113 Trinitrobenzene, wetted with not less than 30% water 1355 113 Trinitrobenzoic acid, wetted with not less than 30% water 1356 113 TNT, wetted with not less than 30% water 1356 113 Trinitrotoluene, wetted with not less than 30% water Page 34 1365 133 Cotton, wet 1369 135 p-Nitrosodimethylaniline 1372 133 Fiber, animal or vegetable, n.o.s., burnt, wet or damp 1372 133 Fibers 1373 133 Fabrics, animal, synthetic or vegetable, n.o.s., with oil 1373 133 Fiber, animal, synthetic or vegetable, n.o.s., with oil 1373 133 Fibres, animal, synthetic or vegetable, n.o.s., with oil 1374 133 Fish meal, unstabilized ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1374 133 Fish meal containing less than 6% or more than 12% water 1384 135 Sodium hydrosulfite 1374 133 Fish scrap, unstabilized 1385 135 Sodium sulfide, anhydrous 1374 133 Fish scrap containing less than 6% or more than 12% water 1385 135 Sodium sulfide, with less than 30% water of crystallization 1376 135 Iron oxide, spent 1385 135 Sodium sulphide, anhydrous 1376 135 Iron sponge, spent 1385 135 Sodium sulphide, with less than 30% water of crystallization 1378 170 Metal catalyst, wetted 1379 133 Paper, unsaturated oil treated 1380 135 Pentaborane 1381 136 Phosphorus, white, dry or under water or in solution 1384 135 Sodium hydrosulphite 1386 135 Seed cake, with more than 1.5% oil and not more than 11% moisture 1389 138 Alkali metal amalgam 1381 136 Phosphorus, yellow, dry or under water or in solution 1389 138 Alkali metal amalgam, liquid 1381 136 White phosphorus, dry 1390 139 Alkali metal amides 1381 136 White phosphorus, in solution 1391 138 Alkali metal dispersion 1381 136 White phosphorus, under water 1391 138 Alkaline earth metal dispersion 1381 136 Yellow phosphorus, dry 1392 138 Alkaline earth metal amalgam 1381 136 Yellow phosphorus, in solution 1393 138 Alkaline earth metal alloy, n.o.s. 1381 136 Yellow phosphorus, under water 1394 138 Aluminum carbide 1382 135 Potassium sulfide, anhydrous 1395 139 Aluminum ferrosilicon powder 1382 135 Potassium sulfide, with less than 30% water of crystallization 1396 138 Aluminum powder, uncoated 1382 135 Potassium sulfide, with less than 30% water of hydration 1398 138 Aluminum silicon powder, uncoated 1382 135 Potassium sulphide, anhydrous 1400 138 Barium 1382 135 Potassium sulphide, with less than 30% water of crystallization 1401 138 Calcium 1382 135 Potassium sulphide, with less than 30% water of hydration 1402 138 Calcium carbide 1389 138 Alkali metal amalgam, solid 1397 139 Aluminum phosphide 1401 138 Calcium metal, crystalline 1383 135 Aluminum powder, pyrophoric 1403 138 Calcium cyanamide, with more than 0.1% Calcium carbide 1383 135 Pyrophoric alloy, n.o.s. 1404 138 Calcium hydride 1383 135 Pyrophoric metal, n.o.s. 1405 138 Calcium silicide 1384 135 Sodium dithionite 1406 138 Calcium silicon Page 35 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1407 138 Caesium 1435 138 Zinc residue 1407 138 Cesium 1435 138 Zinc skimmings 1408 139 Ferrosilicon 1436 138 Zinc dust 1409 138 8 Hydrides, metal, n.o.s. 1436 138 Zinc powder 1409 138 Metal hydrides, water-reactive, n.o.s. 1437 138 Zirconium hydride 1410 138 Lithium aluminum hydride 1439 141 Ammonium dichromate 1411 138 Lithium aluminum hydride, ethereal 1442 143 Ammonium perchlorate 1412 139 Lithium amide 1413 138 Lithium borohydride 1414 138 Lithium hydride 1415 138 Lithium 1417 138 Lithium silicon 1418 138 Magnesium alloys powder 1418 138 Magnesium powder 1419 139 Magnesium aluminum phosphide 1420 138 Potassium, metal alloys 1420 138 Potassium, metal liquid alloy 1421 138 Alkali metal alloy, liquid, n.o.s. 1422 138 Potassium sodium alloys 1422 138 Sodium potassium alloys 1423 138 Rubidium 1423 138 Rubidium metal 1426 138 Sodium borohydride 1427 138 Sodium hydride 1428 138 Sodium 1431 138 Sodium methylate 1431 138 Sodium methylate, dry 1432 139 Sodium phosphide 1438 140 Aluminum nitrate 1444 140 Ammonium persulfate 1444 140 Ammonium persulphate 1445 141 Barium chlorate 1445 141 Barium chlorate, wet 1446 141 Barium nitrate 1447 141 Barium perchlorate 1448 141 Barium permanganate 1449 141 Barium peroxide 1450 141 Bromates, inorganic, n.o.s. 1451 140 Caesium nitrate 1451 140 Cesium nitrate 1452 140 Calcium chlorate 1453 140 Calcium chlorite 1454 140 Calcium nitrate 1455 140 Calcium perchlorate 1456 140 Calcium permanganate 1457 140 Calcium peroxide 1458 140 Borate and Chlorate mixtures 1458 140 Chlorate and Borate mixtures 1459 140 Chlorate and Magnesium chloride mixture 1433 139 Stannic phosphides 1459 140 Magnesium chloride and Chlorate mixture 1435 138 Zinc ashes 1461 140 Chlorate, n.o.s., wet 1435 138 Zinc dross 1461 140 Chlorates, inorganic, n.o.s. Page 36 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1462 143 Chlorites, inorganic, n.o.s. 1481 140 Perchlorates, inorganic, n.o.s. 1463 141 Chromic acid, solid 1482 140 Permanganate, n.o.s. 1463 141 Chromic acid mixture, dry 1463 141 Chromium trioxide, anhydrous 1482 140 Permanganates, inorganic, n.o.s. 1465 140 Didymium nitrate 1483 140 Peroxides, inorganic, n.o.s. 1466 140 Ferric nitrate 1484 140 Potassium bromate 1467 143 Guanidine nitrate 1485 140 Potassium chlorate 1469 141 Lead nitrate 1486 140 Potassium nitrate 1470 141 Lead perchlorate 1487 140 Potassium nitrate and Sodium nitrite mixture 1470 141 Lead perchlorate, solid 1470 141 Lead perchlorate, solution 1487 140 Sodium nitrite and Potassium nitrate mixtures 1471 140 Lithium hypochlorite, dry 1487 140 Sodium nitrite mixture 1471 140 Lithium hypochlorite mixture 1488 140 Potassium nitrite 1471 140 Lithium hypochlorite mixtures, dry 1489 140 Potassium perchlorate 1472 143 Lithium peroxide 1473 140 Magnesium bromate 1474 140 Magnesium nitrate 1475 140 Magnesium perchlorate 1476 140 Magnesium peroxide 1477 140 Ammonium sulfate nitrate 1477 140 Ammonium sulphate nitrate 1477 140 Nitrate, n.o.s. 1477 140 Nitrates, inorganic, n.o.s. 1479 140 Compound, tree or weed killing, solid (oxidizer) 1490 140 Potassium permanganate 1491 144 Potassium peroxide 1492 140 Potassium persulfate 1492 140 Potassium persulphate 1493 140 Silver nitrate 1494 141 Sodium bromate 1495 140 Sodium chlorate 1496 143 Sodium chlorite 1498 140 Sodium nitrate 1499 140 Potassium nitrate and Sodium nitrate mixture 1479 140 Cosmetics, n.o.s. 1499 140 Sodium nitrate and Potassium nitrate mixture 1479 140 Drugs, n.o.s. 1500 140 Sodium nitrite 1479 140 Medicines, oxidizing substances, solid, n.o.s. 1502 140 Sodium perchlorate 1479 140 Oxidizing solid, n.o.s. 1479 140 Oxidizing substances, solid, n.o.s. 1481 140 Perchlorate, n.o.s. 1503 140 Sodium permanganate 1504 144 Sodium peroxide 1505 140 Sodium persulfate 1505 140 Sodium persulphate Page 37 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1506 143 Strontium chlorate 1550 151 Antimony lactate 1506 143 Strontium chlorate, solid 1551 151 Antimony potassium tartrate 1506 143 Strontium chlorate, solution 1553 154 Arsenic acid, liquid 1507 140 Strontium nitrate 1554 154 Arsenic acid, solid 1508 140 Strontium perchlorate 1555 151 Arsenic bromide 1509 143 Strontium peroxide 1556 152 Arsenic compound, liquid, n.o.s. 1510 143 Tetranitromethane 1511 140 Urea hydrogen peroxide 1556 152 Arsenic compound, liquid, n.o.s., inorganic 1511 140 Urea peroxide 1556 152 MD 1512 140 Zinc ammonium nitrite 1556 152 Methyldichloroarsine 1513 140 Zinc chlorate 1556 152 PD 1514 140 Zinc nitrate 1556 152 Phenyldichloroarsine 1515 140 Zinc permanganate 1557 152 Arsenic compound, solid, n.o.s. 1516 143 Zinc peroxide 1557 152 Arsenic compound, solid, n.o.s., inorganic 1517 113 Zirconium picramate, wetted with not less than 20% water 1557 152 Arsenic iodide, solid 1541 155 Acetone cyanohydrin, stabilized 1557 152 Arsenic sulfide 1544 151 Alkaloids, solid, n.o.s. (poisonous) 1557 152 Arsenic sulphide 1544 151 Alkaloid salts, solid, n.o.s. (poisonous) 1557 152 Arsenic trisulphide 1545 155 Allyl isothiocyanate, inhibited 1559 151 Arsenic pentoxide 1545 155 Allyl isothiocyanate, stabilized 1560 157 Arsenic chloride 1546 151 Ammonium arsenate 1560 157 Arsenic trichloride 1547 153 Aniline 1561 151 Arsenic trioxide 1548 153 Aniline hydrochloride 1562 152 Arsenical dust 1549 157 Antimony compound, inorganic, n.o.s. 1564 154 Barium compound, n.o.s. 1549 157 Antimony compound, inorganic, solid, n.o.s. 1566 154 Beryllium chloride 1557 152 Arsenic trisulfide 1558 152 Arsenic 1565 157 Barium cyanide 1549 157 Antimony tribromide, solid 1566 154 Beryllium compound, n.o.s. 1549 157 Antimony tribromide, solution 1566 154 Beryllium fluoride 1549 157 Antimony trifluoride, solid 1567 134 Beryllium powder 1549 157 Antimony trifluoride, solution 1569 131 Bromoacetone Page 38 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1570 152 Brucine 1585 151 Copper acetoarsenite 1571 113 Barium azide, wetted with not less than 50% water 1586 151 Copper arsenite 1572 151 Cacodylic acid 1588 157 Cyanides, inorganic, n.o.s. 1573 151 Calcium arsenate 1588 157 Cyanides, inorganic, solid, n.o.s. 1574 151 Calcium arsenate and Calcium arsenite mixture, solid 1589 125 CK 1574 151 Calcium arsenite, solid 1574 151 Calcium arsenite and Calcium arsenate mixture, solid 1587 151 Copper cyanide 1589 125 Cyanogen chloride, inhibited 1590 153 Dichloroanilines 1590 153 Dichloroanilines, liquid 1575 157 Calcium cyanide 1590 153 Dichloroanilines, solid 1577 153 Chlorodinitrobenzenes 1591 152 o-Dichlorobenzene 1577 153 Dinitrochlorobenzene 1592 152 p-Dichlorobenzene 1578 152 Chloronitrobenzenes 1593 160 Dichloromethane 1578 152 Chloronitrobenzenes, liquid 1593 160 Methylene chloride 1578 152 Chloronitrobenzenes, solid 1594 152 Diethyl sulfate 1578 152 Nitrochlorobenzenes, liquid 1594 152 Diethyl sulphate 1578 152 Nitrochlorobenzenes, solid 1595 156 Dimethyl sulfate 1579 153 4-Chloro-o-toluidine hydrochloride 1595 156 Dimethyl sulphate 1580 154 Chloropicrin 1597 152 Dinitrobenzenes 1581 123 Chloropicrin and Methyl bromide mixture 1598 153 Dinitro-o-cresol 1581 123 Methyl bromide and Chloropicrin mixtures 1600 152 Dinitrotoluenes, molten 1581 123 Methyl bromide and more than 2% Chloropicrin mixture, liquid 1596 153 Dinitroanilines 1599 153 Dinitrophenol, solution 1601 151 Disinfectant, solid, poisonous, n.o.s. 1601 151 Disinfectant, solid, toxic, n.o.s. 1582 119 Chloropicrin and Methyl chloride mixture 1601 151 Disinfectants, solid, n.o.s. (poisonous) 1582 119 Methyl chloride and Chloropicrin mixtures 1602 151 Dye, liquid, poisonous, n.o.s. 1583 154 Chloropicrin, absorbed 1602 151 Dye intermediate, liquid, poisonous, n.o.s. 1583 154 Chloropicrin mixture, n.o.s. 1584 151 Cocculus 1602 151 Dye, liquid, toxic, n.o.s. 1602 151 Dye intermediate, liquid, toxic, n.o.s. Page 39 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1603 155 Ethyl bromoacetate 1627 141 Mercurous nitrate 1604 132 Ethylenediamine 1628 151 Mercurous sulfate 1605 154 Ethylene dibromide 1628 151 Mercurous sulphate 1606 151 Ferric arsenate 1629 151 Mercury acetate 1607 151 Ferric arsenite 1630 151 Mercury ammonium chloride 1608 151 Ferrous arsenate 1631 154 Mercury benzoate 1610 159 Halogenated irritating liquid, n.o.s. 1633 151 Mercury bisulfate 1611 151 Hexaethyl tetraphosphate 1633 151 Mercury bisulphate 1611 151 Hexaethyl tetraphosphate, liquid 1634 154 Mercuric bromide 1611 151 Hexaethyl tetraphosphate, solid 1634 154 Mercurous bromide 1612 123 Hexaethyl tetraphosphate and compressed gas mixture 1634 154 Mercury bromides 1613 154 Hydrocyanic acid, aqueous solution, with less than 5% Hydrogen cyanide 1636 154 Mercury cyanide 1613 154 Hydrocyanic acid, aqueous solution, with not more than 20% Hydrogen cyanide 1638 151 Mercury iodide 1613 154 Hydrogen cyanide, aqueous solution, with not more than 20% Hydrogen cyanide 1636 154 Mercuric cyanide 1637 151 Mercury gluconate 1639 151 Mercury nucleate 1640 151 Mercury oleate 1641 151 Mercury oxide 1642 151 Mercuric oxycyanide 1614 131 Hydrogen cyanide, anhydrous, stabilized (absorbed) 1642 151 Mercury oxycyanide, desensitized 1614 131 Hydrogen cyanide, stabilized (absorbed) 1643 151 Mercury potassium iodide 1616 151 Lead acetate 1645 151 Mercuric sulfate 1617 151 Lead arsenates 1645 151 Mercuric sulphate 1618 151 Lead arsenites 1645 151 Mercury sulfate 1620 151 Lead cyanide 1645 151 Mercury sulphate 1621 151 London purple 1646 151 Mercury thiocyanate 1622 151 Magnesium arsenate 1647 151 Ethylene dibromide and Methyl bromide mixture, liquid 1623 151 Mercuric arsenate 1624 154 Mercuric chloride 1625 141 Mercuric nitrate 1626 157 Mercuric potassium cyanide Page 40 1644 151 Mercury salicylate 1647 151 Methyl bromide and Ethylene dibromide mixture, liquid 1648 131 Acetonitrile 1648 131 Methyl cyanide ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1649 131 Motor fuel anti-knock compound 1673 153 Phenylenediamines 1649 131 Motor fuel anti-knock mixture 1674 151 Phenylmercuric acetate 1649 131 Tetraethyl lead, liquid 1677 151 Potassium arsenate 1650 153 beta-Naphthylamine 1678 154 Potassium arsenite 1650 153 Naphthylamine (beta) 1679 157 Potassium cuprocyanide 1651 153 Naphthylthiourea 1680 157 Potassium cyanide 1652 153 Naphthylurea 1683 151 Silver arsenite 1653 151 Nickel cyanide 1684 151 Silver cyanide 1654 151 Nicotine 1685 151 Sodium arsenate 1655 151 Nicotine compound, solid, n.o.s. 1655 151 Nicotine preparation, solid, n.o.s. 1686 154 Sodium arsenite, aqueous solution 1656 151 Nicotine hydrochloride 1687 153 Sodium azide 1656 151 Nicotine hydrochloride, solution 1688 152 Sodium cacodylate 1657 151 Nicotine salicylate 1689 157 Sodium cyanide 1658 151 Nicotine sulfate, solid 1690 154 Sodium fluoride 1658 151 Nicotine sulfate, solution 1690 154 Sodium fluoride, solid 1658 151 Nicotine sulphate, solid 1690 154 Sodium fluoride, solution 1658 151 Nicotine sulphate, solution 1691 151 Strontium arsenite 1659 151 Nicotine tartrate 1692 151 Strychnine 1660 124 Nitric oxide 1692 151 Strychnine salts 1660 124 Nitric oxide, compressed 1693 159 Irritating agent, n.o.s. 1661 153 Nitroanilines 1693 159 ORM-A, n.o.s. 1662 152 Nitrobenzene 1693 159 Tear gas devices 1663 153 Nitrophenols 1693 159 Tear gas substance, liquid, n.o.s. 1664 152 Nitrotoluenes 1693 159 Tear gas substance, solid, n.o.s. 1664 152 Nitrotoluenes, liquid 1694 159 Bromobenzyl cyanides 1664 152 Nitrotoluenes, solid 1694 159 CA 1665 152 Nitroxylenes 1695 131 Chloroacetone, stabilized 1665 152 Nitroxylol 1697 153 Chloroacetophenone 1669 151 Pentachloroethane 1697 153 Chloroacetophenone, liquid 1670 157 Perchloromethyl mercaptan 1697 153 Chloroacetophenone, solid 1671 153 Phenol, solid 1697 153 CN 1672 151 Phenylcarbylamine chloride 1698 154 Adamsite Page 41 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1698 154 Diphenylamine chloroarsine 1707 151 Thallium sulfate, solid 1698 154 DM 1707 151 Thallium sulphate, solid 1699 151 DA 1708 153 Toluidines 1699 151 Diphenylchloroarsine 1708 153 Toluidines, liquid 1699 151 Diphenylchloroarsine, liquid 1708 153 Toluidines, solid 1699 151 Diphenylchloroarsine, solid 1709 151 2,4-Toluenediamine 1700 159 Tear gas candles 1709 151 Toluenediamine 1700 159 Tear gas grenades 1709 151 2,4-Toluylenediamine 1701 152 Xylyl bromide 1710 160 Trichloroethylene 1702 151 1,1,2,2-Tetrachloroethane 1711 153 Xylidines 1702 151 Tetrachloroethane 1712 151 Zinc arsenate 1703 123 Tetraethyl dithiopyrophosphate and gases, in solution 1712 151 Zinc arsenate and Zinc arsenite mixture 1703 123 Tetraethyl dithiopyrophosphate and gases, mixtures 1712 151 Zinc arsenite 1703 123 Tetraethyl dithiopyrophosphate and gases, mixtures, or in solution (LC50 more than 200 ppm but not more than 5000 ppm) 1712 151 Zinc arsenite and Zinc arsenate mixture 1713 151 Zinc cyanide 1714 139 Zinc phosphide 1715 137 Acetic anhydride 1703 123 Tetraethyl dithiopyrophosphate and gases, mixtures, or in solution (LC50 not more than 200 ppm) 1716 156 Acetyl bromide 1704 153 Tetraethyl dithiopyrophosphate 1718 153 Butyl acid phosphate 1704 153 Tetraethyl dithiopyrophosphate, mixture, dry or liquid 1719 154 Alkaline liquid, n.o.s. 1705 123 Tetraethyl pyrophosphate and compressed gas mixtures 1722 155 Allyl chlorocarbonate 1705 123 Tetraethyl pyrophosphate and compressed gas mixtures (LC50 more than 200 ppm but not more than 5000 ppm) 1717 132 Acetyl chloride 1718 153 Acid butyl phosphate 1719 154 Caustic alkali liquid, n.o.s. 1722 155 Allyl chloroformate 1723 132 Allyl iodide 1724 155 Allyltrichlorosilane, stabilized 1725 137 Aluminum bromide, anhydrous 1705 123 Tetraethyl pyrophosphate and compressed gas mixture s (LC50 not more than 200 ppm) 1726 137 Aluminum chloride, anhydrous 1707 151 Thallium compound, n.o.s. 1727 154 Ammonium hydrogendifluoride, solid Page 42 1727 154 Ammonium bifluoride, solid ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1727 154 Ammonium hydrogen fluoride, solid 1750 153 Chloroacetic acid, solution 1728 155 Amyltrichlorosilane 1752 156 Chloroacetyl chloride 1729 156 Anisoyl chloride 1753 156 Chlorophenyltrichlorosilane 1730 157 Antimony pentachloride, liquid 1754 137 Chlorosulfonic acid 1731 157 Antimony pentachloride, solution 1754 137 Chlorosulfonic acid and Sulfur trioxide mixture 1732 157 Antimony pentafluoride 1754 137 Chlorosulphonic acid 1733 157 Antimony trichloride 1754 137 Chlorosulphonic acid and Sulphur trioxide mixture 1733 157 Antimony trichloride, liquid 1733 157 Antimony trichloride, solid 1733 157 Antimony trichloride, solution 1736 137 Benzoyl chloride 1737 156 Benzyl bromide 1738 156 Benzyl chloride 1739 137 Benzyl chloroformate 1740 154 Bifluorides, n.o.s. 1740 154 Hydrogendifluorides, n.o.s. 1741 125 Boron trichloride 1742 157 Boron trifluoride acetic acid complex 1751 153 Chloroacetic acid, solid 1754 137 Sulfur trioxide and Chlorosulfonic acid mixture 1754 137 Sulphur trioxide and Chlorosulphonic acid mixture 1755 154 Chromic acid, solution 1756 154 Chromic fluoride, solid 1757 154 Chromic fluoride, solution 1758 137 Chromium oxychloride 1759 154 Corrosive solid, n.o.s. 1759 154 Cosmetics, solid, n.o.s. 1759 154 Drugs, solid, n.o.s. 1743 157 Boron trifluoride propionic acid complex 1759 154 Ferrous chloride, solid 1744 154 Bromine 1759 154 Stannous chloride, solid 1744 154 Bromine, solution 1760 154 Acid, liquid, n.o.s. 1745 144 Bromine pentafluoride 1760 154 Aluminum phosphate, solution 1746 144 Bromine trifluoride 1760 154 Aluminum sulfate, solution 1747 155 Butyltrichlorosilane 1760 154 Aluminum sulphate, solution 1748 140 Calcium hypochlorite, dry 1760 154 2-(2-Aminoethoxy)ethanol 1748 140 Calcium hypochlorite mixture, dry, with more than 39% available Chlorine (8.8% available Oxygen) 1760 154 Aminopropyldiethanolamine 1749 124 Chlorine trifluoride 1760 154 Compound, rust preventing (corrosive) 1750 153 Chloroacetic acid, liquid 1759 154 Medicines, corrosive, solid, n.o.s. 1760 154 N-Aminopropylmorpholine 1760 154 Chemical kit Page 43 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1760 154 Compound, rust removing (corrosive) 1768 154 Difluorophosphoric acid, anhydrous 1760 154 Compound, tree or weed killing, liquid (corrosive) 1769 156 Diphenyldichlorosilane 1760 154 Compound, vulcanizing, liquid (corrosive) 1771 156 Dodecyltrichlorosilane 1760 154 Compounds, cleaning, liquid (corrosive) 1773 157 Ferric chloride, anhydrous 1760 154 Corrosive liquid, n.o.s. 1760 154 Cosmetics, liquid, n.o.s. 1760 154 2,2-Dichloropropionic acid 1760 154 Drugs, liquid, n.o.s. 1770 153 Diphenylmethyl bromide 1773 157 Ferric chloride 1774 154 Fire extinguisher charges, corrosive liquid 1775 154 Fluoboric acid 1775 154 Fluoroboric acid 1760 154 Ferrous chloride, solution 1776 154 Fluorophosphoric acid, anhydrous 1760 154 Flame retardant compound, liquid (corrosive) 1777 137 Fluorosulfonic acid 1760 154 Hexanoic acid 1760 154 Isopentanoic acid 1760 154 Medicines, corrosive, liquid, n.o.s. 1760 154 Morpholine, aqueous mixture 1760 154 Nitric acid, 40% or less 1760 154 ORM-B, n.o.s. 1760 154 Paint (corrosive) 1760 154 Paint related material (corrosive) 1777 137 Fluorosulphonic acid 1778 154 Fluorosilicic acid 1778 154 Fluosilicic acid 1778 154 Hydrofluorosilicic acid 1778 154 Hydrofluosilicic acid 1779 153 Formic acid 1780 156 Fumaryl chloride 1781 156 Hexadecyltrichlorosilane 1782 154 Hexafluorophosphoric acid 1760 154 Textile treating compound or mixture, liquid (corrosive) 1783 153 Hexamethylenediamine, solution 1760 154 Titanium sulfate, solution 1784 156 Hexyltrichlorosilane 1760 154 Titanium sulphate, solution 1786 157 Hydrofluoric acid and Sulfuric acid mixture 1761 154 Cupriethylenediamine, solution 1762 156 Cyclohexenyltrichlorosilane 1763 156 Cyclohexyltrichlorosilane 1764 153 Dichloroacetic acid 1765 156 Dichloroacetyl chloride 1786 157 Hydrofluoric acid and Sulphuric acid mixture 1786 157 Sulfuric acid and Hydrofluoric acid mixtures 1766 156 Dichlorophenyltrichlorosilane 1786 157 Sulphuric acid and Hydrofluoric acid mixtures 1767 155 Diethyldichlorosilane 1787 154 Hydriodic acid Page 44 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1787 154 Hydriodic acid, solution 1805 154 Phosphoric acid 1788 154 Hydrobromic acid 1806 137 Phosphorus pentachloride 1788 154 Hydrobromic acid, solution 1807 137 Phosphoric anhydride 1789 157 Compound, cleaning liquid (containing Hydrochloric (muriatic) acid) 1807 137 Phosphorus pentoxide 1789 157 Hydrochloric acid 1789 157 Hydrochloric acid, mixture 1789 157 Hydrochloric acid, solution 1789 157 Muriatic acid 1790 157 Compound, cleaning liquid (containing Hydrofluoric acid) 1790 157 Etching acid, liquid, n.o.s. 1790 157 Hydrofluoric acid 1790 157 Hydrofluoric acid, solution 1791 154 Hypochlorite solution 1791 154 Hypochlorite solution, with more than 5% available Chlorine 1808 137 Phosphorus tribromide 1809 137 Phosphorus trichloride 1810 137 Phosphorus oxychloride 1811 154 Potassium bifluoride 1811 154 Potassium hydrogendifluoride 1811 154 Potassium hydrogen fluoride, solution 1812 154 Potassium fluoride 1813 154 Battery 1813 154 Caustic potash, dry, solid 1813 154 Potassium hydroxide, dry, solid 1813 154 Potassium hydroxide, flake 1813 154 Potassium hydroxide, solid 1792 157 Iodine monochloride 1814 154 Caustic potash, liquid 1793 153 Isopropyl acid phosphate 1814 154 Caustic potash, solution 1794 154 Lead sulfate, with more than 3% free acid 1814 154 Potassium hydroxide, solution 1794 154 Lead sulphate, with more than 3% free acid 1816 155 Propyltrichlorosilane 1796 157 Nitrating acid mixture 1798 157 Aqua regia 1798 157 Nitrohydrochloric acid 1799 156 Nonyltrichlorosilane 1800 156 Octadecyltrichlorosilane 1801 156 Octyltrichlorosilane 1802 140 Perchloric acid, with not more than 50% acid 1803 153 Phenolsulfonic acid, liquid 1803 153 Phenolsulphonic acid, liquid 1804 156 Phenyltrichlorosilane 1815 132 Propionyl chloride 1817 137 Pyrosulfuryl chloride 1817 137 Pyrosulphuryl chloride 1818 157 Silicon tetrachloride 1819 154 Sodium aluminate, solution 1821 154 Sodium bisulfate, solid 1821 154 Sodium bisulphate, solid 1821 154 Sodium hydrogen sulfate, solid 1821 154 Sodium hydrogen sulphate, solid 1823 154 Caustic soda, bead 1823 154 Caustic soda, flake 1823 154 Caustic soda, granular Page 45 ID Guide No. No. Name of Material 1823 154 Caustic soda, solid 1823 154 Sodium hydroxide, dry 1823 154 Sodium hydroxide, bead 1823 154 Sodium hydroxide, flake 1823 154 Sodium hydroxide, granular 1823 154 Sodium hydroxide, solid 1824 154 Caustic soda, solution 1824 154 Sodium hydroxide, solution 1825 157 Sodium monoxide 1826 157 Nitrating acid, spent 1826 157 Nitrating acid mixture, spent 1827 137 Stannic chloride, anhydrous ID Guide No. No. Name of Material 1831 137 Oleum, with not less than 30% free Sulfur trioxide 1831 137 Oleum, with not less than 30% free Sulphur trioxide 1831 137 Sulfuric acid, fuming 1831 137 Sulfuric acid, fuming, with less than 30% free Sulfur trioxide 1831 137 Sulfuric acid, fuming, with not less than 30% free Sulfur trioxide 1831 137 Sulphuric acid, fuming 1831 137 Sulphuric acid, fuming, with less than 30% free Sulphur trioxide 1828 137 Sulfur chlorides 1831 137 Sulphuric acid, fuming, with not less than 30% free Sulphur trioxide 1828 137 Sulphur chlorides 1832 137 Sulfuric acid, spent 1829 137 Sulfur trioxide 1832 137 Sulphuric acid, spent 1829 137 Sulfur trioxide, inhibited 1833 154 Sulfurous acid 1829 137 Sulfur trioxide, stabilized 1833 154 Sulphurous acid 1829 137 Sulfur trioxide, uninhibited 1834 137 Sulfuryl chloride 1829 137 Sulphur trioxide 1834 137 Sulphuryl chloride 1829 137 Sulphur trioxide, inhibited 1835 153 Tetramethylammonium hydroxide 1827 137 Tin tetrachloride 1829 137 Sulphur trioxide, stabilized 1829 137 Sulphur trioxide, uninhibited 1830 137 Sulfuric acid 1830 137 Sulfuric acid, with more than 51% acid 1836 137 Thionyl chloride 1837 157 Thiophosphoryl chloride 1838 137 Titanium tetrachloride 1839 153 Trichloroacetic acid 1830 137 Sulphuric acid 1840 154 Zinc chloride, solution 1830 137 Sulphuric acid, with more than 51% acid 1841 171 Acetaldehyde ammonia 1831 137 Oleum 1845 120 Carbon dioxide, solid 1831 137 Oleum, with less than 30% free Sulfur trioxide 1845 120 Dry ice 1831 137 Oleum, with less than 30% free Sulphur trioxide Page 46 1843 141 Ammonium dinitro-o-cresolate 1846 151 Carbon tetrachloride ID Guide No. No. Name of Material 1847 153 Potassium sulfide, hydrated, with not less than 30% water of crystallization 1847 153 Potassium sulfide, hydrated, with not less than 30% water of hydration ID Guide No. No. Name of Material 1867 133 Cigarettes, self-lighting 1868 134 Decaborane 1869 138 Magnesium 1869 138 Magnesium, in pellets, turnings or ribbons 1847 153 Potassium sulphide, hydrated, with not less than 30% water of crystallization 1869 138 Magnesium alloys, with more than 50% Magnesium, in pellets, turnings or ribbons 1847 153 Potassium sulphide, hydrated, with not less than 30% water of hydration 1869 138 Magnesium scrap 1848 132 Propionic acid 1849 153 Sodium sulfide, hydrated, with not less than 30% water 1849 153 Sodium sulphide, hydrated, with not less than 30% water 1851 151 Medicine, liquid, poisonous, n.o.s. 1851 151 Medicine, liquid, toxic, n.o.s. 1854 135 Barium alloys, pyrophoric 1855 135 Calcium, metal and alloys, pyrophoric 1855 135 Calcium, pyrophoric 1855 135 Calcium alloys, pyrophoric 1856 133 Rags, oily 1858 126 Hexafluoropropylene 1858 126 Refrigerant gas R-1216 1859 125 Silicon tetrafluoride 1859 125 Silicon tetrafluoride, compressed 1870 138 Potassium borohydride 1871 170 Titanium hydride 1872 141 Lead dioxide 1872 141 Lead peroxide 1873 143 Perchloric acid, with more than 50% but not more than 72% acid 1884 157 Barium oxide 1885 153 Benzidine 1886 156 Benzylidene chloride 1887 160 Bromochloromethane 1888 151 Chloroform 1889 157 Cyanogen bromide 1891 131 Ethyl bromide 1892 151 ED 1892 151 Ethyldichloroarsine 1894 151 Phenylmercuric hydroxide 1895 151 Phenylmercuric nitrate 1897 160 Perchloroethylene 1860 116P Vinyl fluoride, inhibited 1897 160 Tetrachloroethylene 1862 129 Ethyl crotonate 1898 156 Acetyl iodide 1863 128 Fuel, aviation, turbine engine 1902 153 Di-(2-ethylhexyl)phosphoric acid 1864 128 Gas drips, hydrocarbon 1902 153 Diisooctyl acid phosphate 1865 131 n-Propyl nitrate 1903 153 Disinfectant, liquid, corrosive, n.o.s. 1866 127 Resin solution Page 47 ID Guide No. No. Name of Material 1903 153 Disinfectants, corrosive, liquid, n.o.s. ID Guide No. No. Name of Material 1923 135 Calcium hydrosulphite 1905 154 Selenic acid 1928 135 Methyl magnesium bromide in Ethyl ether 1906 153 Acid, sludge 1929 135 Potassium dithionite 1906 153 Sludge acid 1929 135 Potassium hydrosulfite 1907 154 Soda lime, with more than 4% Sodium hydroxide 1929 135 Potassium hydrosulphite 1908 154 Chlorite solution 1931 171 Zinc hydrosulfite 1908 154 Chlorite solution, with more than 5% available Chlorine 1931 171 Zinc hydrosulphite 1908 154 Sodium chlorite, solution, with more than 5% available Chlorine 1935 157 Cyanide solution, n.o.s. 1931 171 Zinc dithionite 1932 135 Zirconium scrap 1910 157 Calcium oxide 1938 156 Bromoacetic acid 1911 119 Diborane 1938 156 Bromoacetic acid, solid 1911 119 Diborane, compressed 1938 156 Bromoacetic acid, solution 1911 119 Diborane mixtures 1939 137 Phosphorus oxybromide 1912 115 Methyl chloride and Methylene chloride mixture 1939 137 Phosphorus oxybromide, solid 1912 115 Methylene chloride and Methyl chloride mixture 1941 171 Dibromodifluoromethane 1913 120 Neon, refrigerated liquid (cryogenic liquid) 1914 130 Butyl propionates 1940 153 Thioglycolic acid 1942 140 Ammonium nitrate, with not more than 0.2% combustible substances 1915 127 Cyclohexanone 1942 140 Ammonium nitrate, with organic coating 1916 152 2,2'-Dichlorodiethyl ether 1944 133 Matches, safety 1916 152 Dichloroethyl ether 1945 133 Matches, wax “vesta” 1917 129P Ethyl acrylate, inhibited 1950 126 Aerosol dispensers 1918 130 Cumene 1950 126 Aerosols 1918 130 Isopropylbenzene 1951 120 Argon, refrigerated liquid (cryogenic liquid) 1919 129P Methyl acrylate, inhibited 1920 128 Nonanes 1921 131P Propyleneimine, inhibited 1922 132 Pyrrolidine 1923 135 Calcium dithionite 1923 135 Calcium hydrosulfite Page 48 1952 126 Carbon dioxide and Ethylene oxide mixtures, with not more than 6% Ethylene oxide 1952 126 Carbon dioxide and Ethylene oxide mixtures, with not more than 9% Ethylene oxide ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1952 126 Ethylene oxide and Carbon dioxide mixtures, with not more than 6% Ethylene oxide 1953 119 Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone C) 1952 126 Ethylene oxide and Carbon dioxide mixtures, with not more than 9% Ethylene oxide 1953 119 Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone D) 1953 119 Compressed gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone A) 1953 119 Compressed gas, toxic, flammable, n.o.s. 1953 119 Compressed gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone B) 1953 119 Compressed gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone C) 1953 119 Compressed gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone D) 1953 119 Compressed gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone A) 1953 119 Compressed gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone B) 1953 119 Compressed gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone C) 1953 119 Compressed gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone D) 1953 119 Compressed gas, poisonous, flammable, n.o.s. 1953 119 Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone A) 1953 119 Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone B) 1953 119 Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone A) 1953 119 Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone B) 1953 119 Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone C) 1953 119 Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone D) 1953 119 Liquefied gas, flammable, poisonous, n.o.s. 1953 119 Liquefied gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone A) 1953 119 Liquefied gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone B) 1953 119 Liquefied gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone C) 1953 119 Liquefied gas, flammable, poisonous, n.o.s. (Inhalation Hazard Zone D) 1953 119 Liquefied gas, flammable, toxic, n.o.s. 1953 119 Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone A) Page 49 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1953 119 Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone B) 1955 123 Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone D) 1953 119 Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone C) 1955 123 Compressed gas, toxic, n.o.s. 1953 119 Liquefied gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone D) 1955 123 Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone B) 1953 119 Poisonous gas, flammable, n.o.s. 1953 119 Poisonous liquid, flammable, n.o.s. 1954 115 Compressed gas, flammable, n.o.s. 1954 115 Dispersant gas, n.o.s. (flammable) 1954 115 Insecticide gas, flammable, n.o.s. 1954 115 Liquefied gas, flammable, n.o.s. 1954 115 Refrigerant gas, n.o.s. (flammable) 1954 115 Refrigerating machines, containing flammable, liquefied gas 1954 115 Refrigerating machines, containing flammable, nonpoisonous, non-corrosive, liquefied gas 1955 123 Chloropicrin and non-flammable, non-liquefied compressed gas mixture 1955 123 Compressed gas, poisonous, n.o.s. 1955 123 Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone A) 1955 123 Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone B) 1955 123 Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone C) Page 50 1955 123 Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone A) 1955 123 Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone C) 1955 123 Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone D) 1955 123 Liquefied gas, poisonous, n.o.s. 1955 123 Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone A) 1955 123 Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone B) 1955 123 Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone C) 1955 123 Liquefied gas, poisonous, n.o.s. (Inhalation Hazard Zone D) 1955 123 Liquefied gas, toxic, n.o.s. 1955 123 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone A) 1955 123 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone B) 1955 123 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone C) 1955 123 Liquefied gas, toxic, n.o.s. (Inhalation Hazard Zone D) 1955 123 Methyl bromide and nonflammable, nonliquefied compressed gas mixture 1955 123 Organic phosphate compound mixed with compressed gas 1955 123 Organic phosphate mixed with compressed gas ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1955 123 Organic phosphorus compound mixed with compressed gas 1966 115 Hydrogen, refrigerated liquid (cryogenic liquid) 1955 123 Poisonous gas, n.o.s. 1967 123 Insecticide, liquefied gas, containing Poison A or Poison B material 1955 123 Poisonous liquid, n.o.s. 1956 126 Accumulators, pressurized, pneumatic or hydraulic 1956 126 Compressed gas, n.o.s. 1956 126 Hexafluoropropylene oxide 1967 123 Insecticide gas, poisonous, n.o.s. 1967 123 Insecticide gas, toxic, n.o.s. 1956 126 Liquefied gas, n.o.s. 1967 123 Parathion and compressed gas mixture 1956 126 Water pump system 1968 126 Insecticide, liquefied gas 1957 115 Deuterium 1968 126 Insecticide gas, n.o.s. 1957 115 Deuterium, compressed 1969 115 Isobutane 1958 126 1,2-Dichloro-1,1,2,2tetrafluoroethane 1969 115 Isobutane mixture 1958 126 Dichlorotetrafluoroethane 1970 120 Krypton, refrigerated liquid (cryogenic liquid) 1958 126 Refrigerant gas R-114 1971 115 Methane 1959 116P 1,1-Difluoroethylene 1971 115 Methane, compressed 1959 116P Refrigerant gas R-1132a 1971 115 Natural gas, compressed 1960 115 Engine starting fluid 1972 115 Liquefied natural gas (cryogenic liquid) 1961 115 Ethane, refrigerated liquid 1961 115 Ethane-Propane mixture, refrigerated liquid 1961 115 Propane-Ethane mixture, refrigerated liquid 1962 116P Ethylene 1962 116P Ethylene, compressed 1963 120 Helium, refrigerated liquid (cryogenic liquid) 1964 115 Hydrocarbon gas, compressed, n.o.s. 1964 115 Hydrocarbon gas mixture, compressed, n.o.s. 1965 115 Hydrocarbon gas, liquefied, n.o.s. 1965 115 Hydrocarbon gas mixture, liquefied, n.o.s. 1972 115 LNG (cryogenic liquid) 1972 115 Methane, refrigerated liquid (cryogenic liquid) 1972 115 Natural gas, refrigerated liquid (cryogenic liquid) 1973 126 Chlorodifluoromethane and Chloropentafluoroethane mixture 1973 126 Chloropentafluoroethane and Chlorodifluoromethane mixture 1973 126 Refrigerant gas R-502 1974 126 Bromochlorodifluoromethane 1974 126 Chlorodifluorobromomethane 1974 126 Refrigerant gas R-12B1 Page 51 ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1975 124 Dinitrogen tetroxide and Nitric oxide mixture 1982 126 Tetrafluoromethane, compressed 1975 124 Nitric oxide and Dinitrogen tetroxide mixture 1983 126 1-Chloro-2,2,2-trifluoroethane 1975 124 Nitric oxide and Nitrogen dioxide mixture 1983 126 Refrigerant gas R-133a 1975 124 Nitric oxide and Nitrogen tetroxide mixture 1984 126 Trifluoromethane 1983 126 Chlorotrifluoroethane 1984 126 Refrigerant gas R-23 1975 124 Nitrogen dioxide and Nitric oxide mixture 1986 131 Alcohols, flammable, poisonous, n.o.s. 1975 124 Nitrogen tetroxide and Nitric oxide mixture 1986 131 Alcohols, flammable, toxic, n.o.s. 1976 126 Octafluorocyclobutane 1986 131 Alcohols, toxic, n.o.s. 1976 126 Refrigerant gas RC-318 1986 131 Denatured alcohol (toxic) 1977 120 Nitrogen, refrigerated liquid (cryogenic liquid) 1986 131 Propargyl alcohol 1978 115 Propane 1978 115 Propane mixture 1979 121 Rare gases mixture 1979 121 Rare gases mixture, compressed 1986 131 Alcohols, poisonous, n.o.s. 1987 127 Alcohols, n.o.s. 1987 127 Denatured alcohol 1988 131 Aldehydes, flammable, poisonous, n.o.s. 1980 122 Helium-Oxygen mixture 1988 131 Aldehydes, flammable, toxic, n.o.s. 1980 122 Oxygen and Rare gases mixture 1988 131 Aldehydes, poisonous, n.o.s. 1980 122 Oxygen and Rare gases mixture, compressed 1988 131 Aldehydes, toxic, n.o.s. 1980 122 Rare gases and Oxygen mixture 1989 129 Benzaldehyde 1980 122 Rare gases and Oxygen mixture, compressed 1990 129 Benzaldehyde 1981 121 Nitrogen and Rare gases mixture 1981 121 Nitrogen and Rare gases mixture, compressed 1981 121 Rare gases and Nitrogen mixture 1981 121 Rare gases and Nitrogen mixture, compressed 1982 126 Refrigerant gas R-14, compressed 1982 126 Tetrafluoromethane Page 52 1989 129 Aldehydes, n.o.s. 1991 131P Chloroprene, inhibited 1992 131 Flammable liquid, poisonous, n.o.s. 1992 131 Flammable liquid, toxic, n.o.s. 1993 128 Combustible liquid, n.o.s. 1993 128 Compound, tree or weed killing, liquid (flammable) 1993 128 Compounds, cleaning, liquid (flammable) 1993 128 Cosmetics, n.o.s. ID Guide No. No. Name of Material ID Guide No. No. Name of Material 1993 128 Diesel fuel 2010 138 Magnesium hydride 1993 128 Disinfectant, liquid, n.o.s. 2011 139 Magnesium phosphide 1993 128 Drugs, n.o.s. 2012 139 Potassium phosphide 1993 128 Ethyl nitrate 2013 139 Strontium phosphide 1993 128 Flammable liquid, n.o.s. 2014 140 Hydrogen peroxide, aqueous solution, with not less than 20% but not more than 60% Hydrogen peroxide (stabilized as necessary) 1993 128 Fuel oil 1993 128 Heater for refrigerator car, liquid fuel type 1993 128 Medicines, flammable, liquid, n.o.s. 1993 128 Refrigerating machine 2015 143 Hydrogen peroxide, aqueous solution, stabilized, with more than 60% Hydrogen peroxide 1994 131 Iron pentacarbonyl 2015 143...
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