Safety Data Sheet SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Bright-Cut Metalworking Fluid AH, AM, NM Product Use: Metal Working Fluid Product Number(s): 233944, 233945, 233946 Company Identification AAA Products Company a division of AAA U.S.A. Inc. 6001 Harvest Rd. Anycity, CA 90000 United States of America Transportation Emergency Response CHEMTREC: (800) 555-9300 or (703) 555-3887 Health Emergency AAA Emergency Information Center: Located in the USA. International collect calls accepted. (800)555 -0623 or (510) 555-0623 Product Information email : msds@aaa.com Product Information: 1 (800) 555-3835, LUBET@aaa.com SECTION 2 HAZARDS IDENTIFICATION CLASSIFICATION: Not classified as hazardous according to 29 CFR 1910.1200 (2012). HAZARDS NOT OTHERWISE CLASSIFIED: Not Applicable SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS COMPONENTS CAS NUMBER AMOUNT Highly refined mineral oil (C15 - C50) Mixture 70 - 99 %weight _____________________________________________________________________ Revision Number: 12 Revision Date: APRIL 20, 2015 1 of 8 Bright-Cut Metalworking Fluid AH, AM, NM SDS : 7721 SECTION 4 FIRST AID MEASURES Description of first aid measures Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and flush eyes with water. Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes if contaminated. To remove the material from skin, use soap and water. Discard contaminated clothing and shoes or thoroughly clean before reuse. Ingestion: No specific first aid measures are required. Do not induce vomiting. As a precaution, get medical advice. Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the air, move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs. Most important symptoms and effects, both acute and delayed IMMEDIATE HEALTH EFFECTS Eye: Not expected to cause prolonged or significant eye irritation. Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Contact with the skin is not expected to cause an allergic skin response. Not expected to be harmful to internal organs if absorbed through the skin. Ingestion: Not expected to be harmful if swallowed. Inhalation: Not expected to be harmful if inhaled. Contains a petroleum-based mineral oil. May cause respiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at airborne levels above the recommended mineral oil mist exposure limit. Symptoms of respiratory irritation may include coughing and difficulty breathing. DELAYED OR OTHER HEALTH EFFECTS: Not classified Indication of any immediate medical attention and special treatment needed Not Applicable SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. PROTECTION OF FIRE FIGHTERS: Fire Fighting Instructions: This material will burn although it is not easily ignited. See Section 7 for proper handling and storage. For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self-contained breathing apparatus. Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this material undergoes combustion. Combustion may form oxides of: Sulfur. SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures: Eliminate all sources of ignition in vicinity of spilled material. Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing _____________________________________________________________________ Revision Number: 12 Revision Date: APRIL 20, 2015 2 of 8 Bright-Cut Metalworking Fluid AH, AM, NM SDS : 7721 precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-combustible absorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800) 555-8802 as appropriate or required. SECTION 7 HANDLING AND STORAGE General Handling Information: Avoid contaminating soil or releasing this material into sewage and drainage systems and bodies of water. Precautionary Measures: Do not breathe oil mist at concentrations above the recommended mineral oil mist exposure limit. Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION GENERAL CONSIDERATIONS: Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances. ENGINEERING CONTROLS: Use in a well-ventilated area. PERSONAL PROTECTIVE EQUIPMENT Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear safety glasses with side shields as a good safety practice. Skin Protection: No special protective clothing is normally required. Where splashing is possible, select protective clothing depending on operations conducted, physical requirements and other substances in the workplace. Suggested materials for protective gloves include: 4H (PE/EVAL), Nitrile Rubber, Silver Shield, Viton. Respiratory Protection: No respiratory protection is normally required. If user operations generate an oil mist, determine if airborne concentrations are below the occupational exposure limit for mineral oil mist. If not, wear an approved respirator that provides adequate protection from the measured concentrations of this material. For air-purifying respirators use a particulate cartridge. _____________________________________________________________________ Revision Number: 12 Revision Date: APRIL 20, 2015 3 of 8 Bright-Cut Metalworking Fluid AH, AM, NM SDS : 7721 Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide adequate protection. Occupational Exposure Limits: Component Agency TWA STEL Ceiling Notation Highly refined mineral oil (C15 C50) Highly refined mineral oil (C15 C50) OSHA Z-1 5 mg/m3 -- -- -- ACGIH 5 mg/m3 10 mg/m3 -- -- Consult local authorities for appropriate values. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Attention: the data below are typical values and do not constitute a specification. Color: Colorless to yellow Physical State: Liquid Odor: Petroleum odor Odor Threshold: No data available pH: Not Applicable Vapor Pressure: 1 Minimum Initial Boiling Point: 315°C (599°F) Minimum Solubility: Soluble in hydrocarbons; insoluble in water Freezing Point: Not Applicable Melting Point: No data available Specific Gravity: 0.86 - 0.88 @ 15.6°C (60.1°F) / 15.6°C (60.1°F) Density: 0.87 kg/l @ 15°C (59°F) (Typical) Viscosity: 35.2 mm2/s @ 40°C (104°F) Minimum Evaporation Rate: No data available Decomposition temperature: No data available Octanol/Water Partition Coefficient: No data available FLAMMABLE PROPERTIES: Flammability (solid, gas): No Data Available Flashpoint: (ASTM D92) 180 °C (356 °F) Minimum Autoignition: No data available Flammability (Explosive) Limits (% by volume in air): Lower: Not Applicable Upper: Not Applicable SECTION 10 STABILITY AND REACTIVITY Reactivity: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Incompatibility With Other Materials: Not applicable Hazardous Decomposition Products: Hydrogen Sulfide (Elevated temperatures) _____________________________________________________________________ Revision Number: 12 Revision Date: APRIL 20, 2015 4 of 8 Bright-Cut Metalworking Fluid AH, AM, NM SDS : 7721 Hazardous Polymerization: Hazardous polymerization will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Information on toxicological effects Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for product components. Skin Corrosion/Irritation: The skin irritation hazard is based on evaluation of data for product components. Skin Sensitization: The skin sensitization hazard is based on evaluation of data for product components. Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for product components. Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for product components. Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for product components. Acute Toxicity Estimate: Not Determined Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material. Carcinogenicity: The hazard evaluation is based on data for components or a similar material. Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material. Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for components or a similar material. Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for components or a similar material. ADDITIONAL TOXICOLOGY INFORMATION: This product contains petroleum base oils which may be refined by various processes including severe solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the International Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). These oils have not been classified by the American Conference of Governmental Industrial Hygienists (ACGIH) as: confirmed human carcinogen (A1), suspected human carcinogen (A2), or confirmed animal carcinogen with unknown relevance to humans (A3). SECTION 12 ECOLOGICAL INFORMATION ECOTOXICITY This material is not expected to be harmful to aquatic organisms. The product has not been tested. The statement has been derived from the properties of the individual _____________________________________________________________________ Revision Number: 12 Revision Date: APRIL 20, 2015 5 of 8 Bright-Cut Metalworking Fluid AH, AM, NM SDS : 7721 components. MOBILITY No data available. PERSISTENCE AND DEGRADABILITY This material is not expected to be readily biodegradable. The biodegradability of this material is based on an evaluation of data for the components or a similar material. The product has not been tested. The statement has been derived from the properties of the individual components. POTENTIAL TO BIOACCUMULATE Bioconcentration Factor: No data available. Octanol/Water Partition Coefficient: No data available SECTION 13 DISPOSAL CONSIDERATIONS Use material for its intended purpose or recycle if possible. Oil collection services are available for used oil recycling or disposal. Place contaminated materials in containers and dispose of in a manner consistent with applicable regulations. Contact your sales representative or local environmental or health authorities for approved disposal or recycling methods. SECTION 14 TRANSPORT INFORMATION The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific shipping requirements. DOT Shipping Description: NOT REGULATED AS A HAZARDOUS MATERIAL UNDER 49 CFR IMO/IMDG Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT UNDER THE IMDG CODE ICAO/IATA Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT UNDER ICAO Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code: Not applicable SECTION 15 REGULATORY INFORMATION EPCRA 311/312 CATEGORIES: 1. 2. 3. 4. 5. Immediate (Acute) Health Effects: Delayed (Chronic) Health Effects: Fire Hazard: Sudden Release of Pressure Hazard: Reactivity Hazard: NO NO NO NO NO _____________________________________________________________________ Revision Number: 12 Revision Date: APRIL 20, 2015 6 of 8 Bright-Cut Metalworking Fluid AH, AM, NM SDS : 7721 REGULATORY LISTS SEARCHED: 01-1=IARC Group 1 03=EPCRA 313 01-2A=IARC Group 2A 04=CA Proposition 65 01-2B=IARC Group 2B 05=MA RTK 02=NTP Carcinogen 06=NJ RTK 07=PA RTK No components of this material were found on the regulatory lists above. CHEMICAL INVENTORIES: All components comply with the following chemical inventory requirements: DSL (Canada), EINECS (European Union), IECSC (China), KECI (Korea), PICCS (Philippines), TSCA (United States). One or more components does not comply with the following chemical inventory requirements: AICS (Australia), ENCS (Japan). NEW JERSEY RTK CLASSIFICATION: Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to be identified as follows: PETROLEUM OIL (Cutting oil) SECTION 16 OTHER INFORMATION NFPA RATINGS: Health: 0 Flammability: 1 Reactivity: 0 HMIS RATINGS: Health: 1 Flammability: 1 Reactivity: 0 (0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings). LABEL RECOMMENDATION: Label Category : METALWORKING FLUID 1 - MWF1 REVISION STATEMENT: This revision updates the following sections of this Safety Data Sheet: 1,2,3,4,6,7,8,9,10,12,14,16 Revision Date: APRIL 20, 2015 ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT: TLV - STEL - Threshold Limit Value TWA - Time Weighted Average Short-term Exposure Limit PEL - Permissible Exposure Limit GHS - Globally Harmonized System CAS - Chemical Abstract Service Number ACGIH - American Conference of Governmental IMO/IMDG International Maritime Dangerous Goods Industrial Hygienists Code API - American Petroleum Institute SDS HMIS - Hazardous Materials Information System NFPA DOT - Department of Transportation (USA) NTP - Safety Data Sheet - - National Fire Protection Association (USA) National Toxicology Program (USA) _____________________________________________________________________ Revision Number: 12 Revision Date: APRIL 20, 2015 7 of 8 Bright-Cut Metalworking Fluid AH, AM, NM SDS : 7721 IARC Cancer International Agency for Research on NCEL - New Chemical Exposure Limit OSHA - Occupational Safety and Health Administration EPA - Environmental Protection Agency SCBA - Self-Contained Breathing Apparatus Prepared according to the 29 CFR 1910.1200 (2012) by Chevron Energy Technology Company, 6001 Bollinger Canyon Road San Ramon, CA 94583. The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. _____________________________________________________________________ Revision Number: 12 Revision Date: APRIL 20, 2015 8 of 8 Bright-Cut Metalworking Fluid AH, AM, NM SDS : 7721 Laboratory Results for Unit VIII Research Paper Employee 1 2 3 4 5 6 Position Machining Machining Welding Cleaning Welding Cleaning Paint Booth Paint Booth/Cleaning Nozzles Analyte Mineral oil mist Mineral oil mist Hexavalent chromium Hexavalent chromium Xylene MEK 1,3 butadiene Sample Time 480 minutes 480 minutes 360 minutes 120 minutes 300 minutes 180 minutes 480 minutes 15 minutes Sample Result 1.1 mg/m3 0.9 mg/m3 8.5 µg/m3 0.5 µg/m3 10.0 µg/m3 0.2 µg/m3 24 ppm 60 ppm 6.0 ppm Noise Dosimetry Data Employee 1 2 3 4 5 Position Setting up parts for press Operating 2,000-ton press Clean-up Setting up parts for press Operating 200-ton press Clean-up Machining Paint Booth Shipping/Receiving/Forklift Driver Sample Time 60 minutes 400 minutes 20 minutes 30 minutes 430 minutes 20 minutes 480 minutes 480 minutes 480 minutes Sample Result 82.0 dBA 100 dBA 80.0 dBA 80.0 dBA 89.0 dBA 80.0 dBA 85.5 dBA 80.5 dBA 82.0 dBA
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