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Hydrocarbons Analysis Lab Report

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Chemistry
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Experiment No. 7
Analysis of Hydrocarbons
Introduction
Hydrocarbons are the simplest organic compounds that contain only carbon and
hydrogen (1). They can be straight-chain, branched chain, or cyclic molecules (2).
Hydrocarbons can be divided into two groups: aliphatic hydrocarbons and aromatic
hydrocarbons.
Aliphatic hydrocarbons do not contain a benzene ring. They can be saturated,
which means that the compound is joined by single bonds, or unsaturated, which means
than the compound is joined by double or triple bonds (3). All aliphatic saturated
hydrocarbons are combustible (4). Aromatic hydrocarbons are compounds that contain
benzene rings. A benzene ring is a ring of six carbons with alternating double and single
bonds. Aromatic compounds are generally nonpolar because of their symmetrical shape
and they are immiscible with water. Because of their high ratio of carbon to hydrogen,
aromatic compounds are characterized by a sooty yellow flame (5).
The experiment aims to differentiate various types of hydrocarbons, to device a
scheme to distinguish hydrocarbon from each type and to characterize an unknown
hydrocarbon through parallel chemical tests.
Methodology
For the experiment, water bath in a 400mL beaker was prepared first and all of the
necessary reagents were gathered. An unknown sample was obtained and analyzed
through series of chemical tests. Figure 1 shows the schematic diagram of the analysis.
For the Nitration test, 5 drops of sample was mixed with 8 drops of the nitrating
mixture (H
2
SO
4
-HNO
3
) in a dry test tube. The nitrating mixture was prepared by mixing

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NITRATION
REACTION 1
BROMINE
REACTION 3
OXIDATION
REACTION 2
NO
NO
NO
YES
YES
YES
2mL each of H
2
SO
4
and HNO
3
solution
.
No visible change appeared within 2 minutes thus,
the unknown sample was heated in a water bath for 8 minutes. The sample was diluted
with 20 drops of distilled water. Still, no visible change, specifically a yellow oil/precipitate,
appeared. The observation was recorded.
For the Bromine test, 5 drops of sample was mixed with 3 drops of bromine reagent
(5% Br
2
in CH2Cl2) in a dry test tube. The reagent did not decolorize. The observation
was recorded.
The Basic Oxidation test was not necessary anymore since no yellow precipitate
appeared during the nitration test.
Figure 1. Schematic Diagram of the experiment
UNKNOWN
SAMPLE
ALIPHATIC
YELLO
W OIL?
COLORLESS
SOLUTION?
SATURATED
ALIPHATIC
BROWN
PRECIPITATE?
NON ALKYLATED
AROMATICS
UNSATURATED
ALIPHATIC

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Experiment No. 7 Analysis of Hydrocarbons Introduction Hydrocarbons are the simplest organic compounds that contain only carbon and hydrogen (1). They can be straight-chain, branched chain, or cyclic molecules (2). Hydrocarbons can be divided into two groups: aliphatic hydrocarbons and aromatic hydrocarbons. Aliphatic hydrocarbons do not contain a benzene ring. They can be saturated, which means that the compound is joined by single bonds, or unsaturated, which means than the compound is joined by double or triple bonds (3). All aliphatic saturated hydrocarbons are combustible (4). Aromatic hydrocarbons are compounds that contain benzene rings. A benzene ring is a ring of six carbons with alternating double and single bonds. Aromatic compounds are generally nonpolar because of their symmetrical shape and they are immiscible with water. Because of their high ratio of carbon to hydrogen, aromatic compounds are characterized by a sooty yellow flame (5). The experiment aims to differentiate various types of hydrocarbons, to device a scheme to distinguish hydrocarbon from each type and to characterize an unknown hydrocarbon through parallel chemical tests. Methodology For the experiment, water bath in a 400mL beaker was prepared first and all of the necessary reagents were gathered. An unknown sample was obtained and analyzed through series of chemical tests. Figure 1 shows the schematic diagram of the analysis. For the Nitration test, 5 drops of sample was mixed with 8 drops o ...
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