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Kinetic Theory and The Ideal Gas : The Van Der Waals Equation of state

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Physics
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

The Van Der Waals Equaon of state:

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,        %   
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Kinetic Theory and The Ideal Gas The Van Der Waals Equation of state: Kinetic theory provides the complete description about the behavior of an ideal gas. But some assumptions of kinetic theory of an ideal gas are not valid when applied to real gases. For example while deriving the ideal gas equation PV = nRT, on the basis of kinetic molecular theory, it was assumed that, (1)The size of molecules of the gas is negligibly small. (2)The intermolecular forces are not present. But it was observed that at high pressure, the size of the molecules becomes significant and cannot be neglected as compared to the volume of the container. Also at high pressure, the molecules of the gas come close enough that the intermolecular forces between them become appreciable. An equation of state that relates the pressure, volume and absolute temperature of the gas, taking into account the finite size of the ...
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