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CHEM 231-01 Organic Chemistry I Quiz-4 (Chapter 4)
Name__________________________________ May 28, 2018
1. Give the wedge-dash structures and R/S notations for all stereoisomers of
2-bromo-3-chloro butane. (4 points)
2. In 1992 the Food and Drug Administration approved the use of taxol for
treatment-resistant ovarian cancers, and in 1994 the FDA also approved taxol
for recurrent breast cancer chemotherapy. The structure of taxol is shown
below. Use asterisk * to identify and give R/S configuration for any two
chirality centers in the molecule (3 points)
2. Give the structure for the following molecule as required in the box. (3
points)
Molecules
Sawhorse
Newman
Projection
Fisher Projection
H Br
H
H3C 2 3 Br
CH2CH3
3. Give the relationship (constitutional isomers, or enantiomers, or diastereomers or
identical molecules) between the following pair of compounds. (4 points)
H
CH3
C Br
CH3CH2
H3C
H
C CH2CH3 and
Br
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