acid base book

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iAcid-base ChemistryofAquatic SystemsAn introduction to the chemistry of acid-base equilibria with emphasis on the carbondioxide system in natural watersKeith A. HunterProfessor in ChemistryDepartment of ChemistryUniversity of OtagoDunedin, New ZealandEmail: khunter@alkali.otago.ac.nzWeb page: http://telperion.otago.ac.nz:800/rweavers/research/KAH-RES.HTMiiiiiPREFACEThe first draft of this book was prepared during a sabbatical leave at the Department ofOceanography, University of Washington, Seattle in 1991. Since then, the subject material hasundergone much revision, particular as new research findings have emerged since that time.Therefore, during the summer vacation of 1997/98, I embarked on a major revision, the result ofwhich is the present version. Most of the structure of the book has been changed, and materialthat had become somewhat dated has been removed.I am particularly grateful to my colleagues who have assisted with various aspects of thisbook, but most of all to the many undergraduate and graduate students whose feedback has beenthe major source of improvements.Keith A. HunterDunedin, March 1998ivTABLE OF CONTENTSChapter 1 Basic Concepts of Acid-Base Chemistry11.1 The Arrhenius Theory of Acids and Bases11.2 The Lowry-Brnsted Theory21.3 The Lewis Theory of Acid-Base Reactions41.4 The Nature of Ions in Solution41.5 The Properties of Water as a Solvent6Chapter 2 Acid-Base Equilibria in Ideal Soluti

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