hetero cycle

May 12th, 2015
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Heterocyclic ChemistryProfessor J. Stephen ClarkRoom C4-04 Email: stephenc@chem.gla.ac.uk20112012http://www.chem.gla.ac.uk/staff/stephenc/UndergraduateTeaching.html1Recommended Reading Heterocyclic Chemistry J. A. Joule, K. Mills and G. F. Smith Heterocyclic Chemistry (Oxford Primer Series) T. Gilchrist Aromatic Heterocyclic Chemistry D. T. Davies2IntroductionCourse Summary Definition of terms and classification of heterocycles Functional group chemistry: imines, enamines, acetals, enols, and sulfur-containing groupsIntermediates used for the construction of aromatic heterocycles Synthesis of aromatic heterocycles Carbonheteroatom bond formation and choice of oxidation state Examples of commonly used strategies for heterocycle synthesisPyridines General properties, electronic structure Synthesis of pyridines Electrophilic substitution of pyridines Nucleophilic substitution of pyridines Metallation of pyridinesPyridine derivatives Structure and reactivity of oxy-pyridines, alkyl pyridines, pyridinium salts, and pyridine N-oxidesQuinolines and isoquinolines General properties and reactivity compared to pyridine Electrophilic and nucleophilic substitution quinolines and isoquinolines General methods used for the synthesis of quinolines and isoquinolines3Course Summary (cont)Five-membered aromatic heterocycles General properties, structure and reactivity of pyrro

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